2. 2
JET is a subsidiary of JNG based in Ridgefield Park, NJ
JNG has 80% market shares in ammonia-based desulfurization (EADS) with 400+ installed units
Applications
• Flue gas desulfurization in power industry
• SRU tail gas and FCC flue gas treatment in Oil & Gas industry
Ammonia-based desulfurization and carbon capture (ADSC) technology
Technology Overview
3. Technology developed by JNG
Ammonia is used as the absorbent to capture SOx and CO2 in the flue gas
SOx is converted to ammonium sulfate (AS) and CO2 to ammonium bicarbonate (ABC)
AS and ABC are saleable fertilizers
Ammonia-based Desulfurization & Carbon Capture (ADSC) Technology
4. 4
Carbon Capture: Challenges
Process Amine-based Ammonia-based
Advantages Proven technology for CO2 capture Up to twice the CO2 absorption capacity
49 – 64% less regeneration heat
80+% reduction in solvent makeup cost
Negligible oxidative or thermal degradation
Disadvantages Amine: High cost and sensitive to O2, SO2
Regeneration: High energy consumption
Ammonia slip due to high volatility of ammonia
Requiring post-scrubbing - cost and wastewater issues
5. ADSC Technology: Process
Desulfurization system (EADS) CO2 capture system AS & ABC system
Waste heat recovery
Desulfurization
absorber
Decarburization
absorber
Ammonia
scrubber
Make-up water
Crystallizer
Thickener
Centrifuge
Packaging machine
AS product
Centrifuge
Dryer
ABC product
Feed gas
Hydrocyclone
Air
Ammonia
6. 6
ADSC Technology: Features
Residual ammonia in the flue gas after decarbonization is scrubbed with desulfurization
solution, which resolves the ammonia slip issue and simplifies the process
SO2 and CO2 in the waste stream are converted to (NH4)2SO4 and NH4HCO3 fertilizers
Carbon capture process is simplified and CAPEX/OPEX is reduced by at least 50% compared
to the amine-based process
By-product NH4HCO3 can be sold or decomposed to CO2 (as a product or to be sequestrated)
and ammonia (for reuse)
Synergistic multi-pollutant control makes coal cleaner and more economical than natural gas
7. Item
Limestone FGD with NaOH scrubbing +
Amine-based CO2 capture
ADSC
Absorbent CaCO3 & NaOH + Ethanolamine Ammonia (anhydrous or aqueous)
Byproduct Gypsum (solid waste) + waste alkaline solution AS and ABC (fertilizers)
Byproduct utilization CO2 must be compressed and piped for storage Direct use as fertilizer
Wastewater ~0.035 t/MWh No
Solid/liquid waste Yes No
CO2 emission
1 ton CO2 per ton of SO2 removed (including carbon
footprint due to higher energy consumption)
No
CAPEX * 100% 50~60%
OPEX 100% 40~50%
* CAPEX for limestone/ammonia FGD is not included.
ADSC Technology: ADSC vs traditional process
8. 8
ADSC: Pilot unit testing
Capacity: 100 tpa CO2
CO2 capture from a side-stream of flue gas of an existing
NH3-based FGD unit at a coal-fired power plant
Testing started in Jan 2022 and completed in May 2022
Pilot testing unit
9. 9
ADSC Pilot Unit: Performance
CO2 capture ≥ 70%
SO2 ≤ 10 mg/Nm3, Ammonia slip ≤ 3 mg/Nm3, PM ≤ 5 mg/Nm3
Ammonium bicarbonate and ammonium sulfate byproducts meet the
fertilizer standards
ADSC technology received the Appraisal Certificate of Science and
Technology Achievement by China Electricity Council (CEC) in Aug
2022
10. 10
200,000 TPA Carbon Capture Demo Project
Project location: Inner Mongolia
CO2 source: Coal-fired boilers (capacity: 3X280 tph steam)
NH3 source: NH3 synthesized from H2 recovered from coke oven gas
Design parameters:
CO2 capture efficiency ≥ 60%
Ammonia slip ≤ 8 mg/Nm3
SO2 ≤ 35 mg/Nm3 (dry basis, 6% O2)
PM ≤ 5 mg/Nm3 (dry basis, 6% O2)
NOx ≤ 50 mg/Nm3 (dry basis, 6% O2)
ABC product meets spec of GB 3559-2001 (Ammonium Bicarbonate for Agriculture Use)
Phase CO2 capacity, tpa ABC capacity, tpa Power capacity, MW Completion date
I 200,000 360,000 50 End of 2022
II 200,000 360,000 50 2023
III 400,000 720,000 100 2024
IV 400,000 720,000 100 2025
11. 11
200,000 TPA Carbon Capture Demo Project: Overall Process
H2 recovery
Ammonia
synthesis
Carbon capture
(Phase I)
Air Separation
Unit
Desulfurization
Plant factory
7,867 m2
Flue gas
NH3
NH3
AS
Flue gas
ABC
Flue gas (3x414,799 Nm3.hr)
Coke
oven gas
N2
Air
H2
Fruits &
Vegetables
77,682 tpa
29,191 tpa 113,598 tpa
359,504 tpa
(200,230 tpa CO2)
170,000 Nm3/hr
AS – Ammonium sulfate (NH4)2SO4
ABC – Ammonium bicarbonate NH4HCO3
Boilers
(3x100 MW)
Coal
12. 12
ADSC Demo Project: Ammonia-based Desulfurization
3 Coal-fired boilers: 280 tph steam per boiler
Flue gas flow: 414,799 Nm3/hr per boiler Temperature: 132 ˚C
Composition: SO2 5,500 mg/Nm3; O2 6.34%; H2O: 8.59%; CO2 13.4%
No. Item Specification Unit Annual usage Unit cost, RMB Annual cost, kRMB
1 Ammonia 99.6% t 29,191 3,000 87,573
2 Process water t 261,036 2 522
3 Electricity 380V, 10kV kWh 26,165,520 0.552 14,443
4 Steam 1.0 Mpa t 26,127 120 3,135
5 Instrument air 0.7 Mpa Nm3 480,000 0.15 72
6 Recirculating cooling water 0.3 Mpa t 160,000 0.15 24
7 Packaging bag 50 kg 2,271,952 2 4,544
8 Labor cost man-yr 9 80,000 720
9 Maintenance cost 1,600
10 Direct OPEX 112,633
11 Revenue from (NH4)2SO4 sales t 113,598 1,300 147,677
12 Net OPEX -35,044
13 Annual SO2 removed t 54,454
14 SO2 capture cost RMB/kg -0.644
Capital cost: 66,000 kRMB
13. No. Item Specification Unit Annual usage Unit price, RMB Annual cost, 1000 RMB
Carbon capture unit
1.1 Anhydrous ammonia 99.6% t 77,682 3000 233,045
1.2 Desalinated water 0.3MPa t 264,000 7.8 2,059
1.3 Electricity 380V, 10kV kWh 33,872,960 0.552 18,698
1.4 Instrument air 0.7MPa Nm3 720,000 0.15 108
1.5 Recirculation cooling water 0.4MPa T 7,990,465 0.15 1,199
1.6 Packaging bag 50kg 7,190,077 1 7,190
1.7 Labor cost man-year 9 80000 720
1.8 Maintenance cost 4,000
1.9 Direct operating cost 267,019
1.10 Revenue from ammonium bicarbonate t 359,504 800.0 287,603
1.11 Carbon credit 50 10,011
1.12 Annual CO2 capture t 200,230
Refrigeration with heat recovered from flue gas
2.1 Electricity 380V kWh 288,000 0.552 159
2.2 Recirculation cooling water 0.4MPa t 6,759,934 0.15 1,014
Refrigeration by hot water
2.3 Electricity 380V kWh 373,333 0.552 206
2.4 Recirculation cooling water 0.4MPa t 8,586,667 0.15 1,288
Refrigeration by steam
2.5 Electricity 380V kWh 373,333 0.552 206
2.6 Steam 0.6MPa t 41,701 120 5,004
2.7 Recirculation cooling water 0.4MPa t 6,808,018 0.15 1,021
2.8 Direct operating cost 8,898
3.1 Net annual revenue 21,697
3.2 Net revenue per ton CO2 captured RMB/kg 0.108
ADSC Demo Project: Ammonia-based Carbon Capture (Capex: 210,000 kRMB)
16. THANK YOU
CONTACT INFO
65 Challenger Rd, Ridgefield Park, NJ, 07660, USA
www.jet-inc.com
Peter Lu: 201-889-7670 peter.lu@jet-inc.com
TQ Xu: 201-406-6663 tianqi.xu@jet-inc.com
Editor's Notes
Good Afternoon --- to all our SA participants - and
Good Morning to everyone joining us from - the US
I am Niren Mangali - from Triloq Process Engineering, part of the SMEI-TRILOQ Joint Venture
Thank You - for affording us your time and the opportunity to share with you -
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