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Dr. Hassan Z. Harraz
hharraz2006@yahoo.com
Autum 2023
“Iron Ore is more Integral to the Global
Economy than any Other Commodity,
Except Perhaps Oil”.
Christopher LaFemina, mining analyst at Barclays Capital
(In 2011 the Financial Times quoted)
DIRECT REDUCED IRON ORE:
Production
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
DOI: 10.13140/RG.2.2.27808.15366
Contents
1. INTRODUCTION
1.1. Definition of Direct Reduced Iron
1.2. Direct Reduction Processes
1.2.1. Coal-based processes
1.2.2. Gas-based processes
2. RAW MATERIALS
2.1. Iron Ore
2.2. Coal
2.3. Natural Gas
2.4. Dolomite/Limestone
2.5. Sizes of Raw Materials
2.6. Composite Pellets
2.7. Quality Requirements For Raw
Materials
3. REACTIONS OF DIRECT REDUCTION
PROCESSES
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DIRECT REDUCED IRON ORE: Production
2
4. DIRECT REDUCTION PROCESSES
4.1. Coal-Based Processes
4.1.1. Rotary kiln process
4.1.2. Rotary hearth process
4.1.2.1. FASTMET process.
4.1.2.2. ITmk3 process.
4.2. Gas-Based Processes
4.2.1. Midrex process
4.2.2. HyL process
4.2.2.1. HyL III process.
4.2.2.2. HyL IV M process.
4.4.3. Purofer process
4.4.4. Finmet process
4.4.5. HIB process
5. CHARACTERISTICS AND USES OF DRI
5.1. Characteristics of DRI
5.2. Quality of DRI
5.3. Reoxidation, Storage, and Transportation of DRI
5.3.2.1. The hazards of DRI.
5.3.2.2. Classification of DRI according to the IMSBC
Code.
5.4. Usages of DRI
Abstract
1. INTRODUCTION
1. INTRODUCTION ……. (Cont.)
1.1. Definition of Direct Reduced Iron
1.2. Direct Reduction Processes
❑ Based on the types of reductant used, the DR processes can be broadly classified into
two groups:
1) Using solid reductant, that is, coal-based DR process.
2) Using gaseous reductant, that is, gas-based DR process
❑ DR processes are summarized in Table 1.
Table 1: Direct reduction processes.
Direct Reduction Reactor/Furnace Types
1.2.1. Coal-based processes
1.2.1. Coal-based processes
1.2.2. Gas-based processes
Overview of Gas-based Direct Reduction
Process Types
2. RAW MATERIALS
2.1. Iron Ore
2.1. Iron Ore (Cont.)
2.2. Coal
2.3. Natural Gas
2.4. Limestone or Dolomite Materials
2.5. Sizes of Raw Materials
2.6. Composite Pellets
2.7. Quality Requirements For Raw Materials
3. REACTIONS OF DIRECT REDUCTION PROCESSES
3.3. Reduction Reaction for Gaseous Reductant:
Direct Reduction Processes For Iron
4. DIRECT REDUCTION PROCESSES
4.1.1. Rotary kiln process
SL/RN process
Fig.3: SL/RN direct reduction process flowsheet
iii) SL / RN process
4.1.1. Rotary kiln process
4.1.1. Rotary kiln process
4.1.1. Rotary kiln process
4.1.2. Rotary hearth process
4.1.2.1. FASTMET process
4.1.2.1. FASTMET process
Fig. 4: Flow sheet of the FASTMET process.
4.1.2.2. ITmk3 process
4.1.2.2. ITmk3 process
Fig. 5: Flow sheet of the ITmk3 process.
4.2. Gas-Based Processes
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
38
Midrex® process
Midrex® direct reduction process flowsheet
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
40
4.2.1. Midrex process
4.2.2. HyL process
Fig. 7: Flow sheet of the HyL I/II process
4.2.2. HyL process
4.2.2.1. HyL III process
Fig.8: Flow sheet of the HyL III process
4.2.2.2. HyL IV M process.
Fig.9: Flow sheet of the HyL-IV M process
4.4.3. Purofer process
4.4.4. Finmet process
Finmet / Finored Megatrain process
4.4.5. HIB process
5. CHARACTERISTICS AND USES OF DRI
5.1. Characteristics of DRI
5.1. Characteristics of DRI
Fig. 10 Different forms of DRI: (A) Lump, (B)
Pellets, and (C) Hot-Briquetted Iron (HBI).
Table 6: Typical chemical composition of Direct Reduction
Iron.
Table 7: Physical properties of Direct Reduction Iron.
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
54
5.2. Quality of DRI
Table 8: Heat effects during reoxidation of DRI.
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
56
5.3. Reoxidation, Storage, and Transportation of DRI
5.3. Reoxidation, Storage, and Transportation of DRI
5.3. Reoxidation, Storage, and Transportation of DRI
Table 9: High-density type, DRI (A).
Table 10: Low-density type, DRI (B).
5.3.2.2. Classification of DRI according to the IMSBC Code
5.4. Usages of DRI
5.4. Advantages Usages of DRI
6. ENVIRONMENTAL SUSTAINABILITY
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DIRECT REDUCED IRON ORE: Production
65
REFERENCES
• Sujay Kumar Dutta , RameshwarSah . Direct Reduced Iron: Production. In Encyclopedia of Iron, Steel, and Their Alloys. Taylor and Francis : New York,
Published online: 30 Mar 2016; 1082-1108. http://dx.doi.org/10.1081/E-EISA-120050996
1. Dutta, S.K.; Roy Chowdhury, P.J. IE(I) J.—MM 1986, 66(2), 91.
2. Prasad, K.K. Steel, Metall. 2004, 6(8), 29.
3. Mehta, P. Special Report, 1987, Personal communication.
4. Chatterjee, A. In Proceedings of International Conference on Alternative Routes of Iron and Steelmaking, Perth, Australia, 1999; 3.
5. 2013 World Direct Reduction Statistics, Direct from Midrex, 2nd Quarter 2014, 2.
6. Dutta, S.K.; Roy Chowdhury, P.J.; Gadgeel, V.L. IE(I) J.— MM (Spl) 1988, 68(2), 52.
7. Vijayavergia, R.K.; Chauhan, G.I.S. Awakening of the Indian Steel Industry: 2005–2020; Chatterjee, A., Ed.; IIM: Jamshedpur, India, 2006; 27.
8. Chatterjee, A.; Sathe, A.V.; Singh, R.; Chakravarty, P.K.In Proceedings of Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM:
Rourkela, India, 1982; 133.
9. Schlebusch, D.; Choudgury, L.R.; Dayal, R. Proceedings of Symposium on Direct Reduction Processes in Iron and Steelmaking. 36th ATM of IIM: Rourkela,
India, 1982; 166.
10. Ghosh, A.; Chatterjee, A. Ironmaking Steelmaking: Theory and Practice; Prentice-Hall of India Pvt Ltd: New Delhi, India, 2008, Chap. 13, 225.
11. Dutta, B.B. IE(I) J.-CH 1993, 73, 69.
12. Pandit, A.; Sarangi, B.M.; Kesava Babu, A.; Sheshadri, M.K. Steel World, 2003.
13. Dutta, S.K.; Ghosh, A. Trans. Indian Inst. Met. 1995, 48(1), 1.
14. Dutta, S.K.; Sah, R.; Chokshi, Y. Iron Ore–Coal/Coke Composite Pellets; LAMBERT Academic Publishing, Saarbru¨cken: Germany, 2013.
15. Dutta, S.K.; Sah, R. Proceedings of Asia Steel International Conference, Jamshedpur, India, 2003. Vol. I, 1.d.4.1.
16. Prasad, K.K.; Ray, H.S. Advances in Rotary Kiln Sponge Iron Plant; New Age International Publishers: New Delhi, India, 2009, Chap. 3.
17. Kubaschewski, O.; Alcock, C.B. Metallurgical Thermochemistry, 5th Ed.; Pergamon Press: Oxford, U.K., 1979.
18. Dutta, S.K.; Sah, R. Alternate Methods of IronmakingS. Chand & Co Ltd: New Delhi, India, 2012.
19. Stephenson, R.L.; Smailer, R.M., Direct Reduced Iron: Technology and Economics of Production and Use; The Iron & Steel Society of AIME: USA, 1980.
20. Thatoi, K.C.; Sen Singh, V.; Sohal, G.D.S. Proceedings of Conference on Direct Reduction and Direct Smelting. 2001. Jamshedpur, India, 2011, 11.
21. Kosuke, S. Proceedings of International Seminar on Alternative Routes for Ironmaking in India, Kolkata, India, 2009, 39.
22. Klawonn, R.M.; Hoffman, G.E. Direct from Midrex, 2nd Qtr. 2005; 4.
23. Chatterjee, A. Proceedings of International Seminar on Alternative Routes for Ironmaking in India, Kolkata, India, 2009, 5.
24. MSTS Iron making; The AISE Steel Foundation: Pittsburgh, PA, 1999; Chap. 11, Vol. I, 741.
25. Ganguly, A.; Gupta, K.N.; Aswath, H.S. Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM, Rourkela, India, November 1982,
90.
26. Gerigk, E.; Knop, K.; Pena, J.M. Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM, Rourkela, India, November 1982, 192.
27. Dutta, S.K.; Lele, A.B. Miner. Met. Rev. 1997, 23(1), 79.
28. Taylor, C.R. Ed. Electric Furnace Steelmaking, Iron & Steel Society: AIME, Chap. 10, 115.
29. Dutta, S.K.; Lele, A.B Tool & Alloy Steels, 1993, 27(11), 349.
30. Paswan, M.; Mukherjee, C. IIM Metal News February 2009; 6.
31. http://www.skuld.com/topics/cargo/dangerous-cargo/dri/ Loss-Prevention-Advice-on-the-Carriage-of-Direct-ReducedIron-and-its-Derivatives.pdf.
32. http://www.intercargo.org/pdf_members/intercargo on dri. pdf.
33. http://www.cargohandbook.com/index.php title Direct_ Reduced_Iron.
34. Dutta, S.K. Perform. Rev. Iron Steel, JPC 2007–2008; 31.
35. Dutta, S.K. JPC Bull. Iron Steel 2006, VI(5), 17.
@Hassan Harraz 2023
DIRECT REDUCED IRON ORE: Production
66

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Direct Reduced Iron-Production.pdf

  • 1. Dr. Hassan Z. Harraz hharraz2006@yahoo.com Autum 2023 “Iron Ore is more Integral to the Global Economy than any Other Commodity, Except Perhaps Oil”. Christopher LaFemina, mining analyst at Barclays Capital (In 2011 the Financial Times quoted) DIRECT REDUCED IRON ORE: Production @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production DOI: 10.13140/RG.2.2.27808.15366
  • 2. Contents 1. INTRODUCTION 1.1. Definition of Direct Reduced Iron 1.2. Direct Reduction Processes 1.2.1. Coal-based processes 1.2.2. Gas-based processes 2. RAW MATERIALS 2.1. Iron Ore 2.2. Coal 2.3. Natural Gas 2.4. Dolomite/Limestone 2.5. Sizes of Raw Materials 2.6. Composite Pellets 2.7. Quality Requirements For Raw Materials 3. REACTIONS OF DIRECT REDUCTION PROCESSES @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 2 4. DIRECT REDUCTION PROCESSES 4.1. Coal-Based Processes 4.1.1. Rotary kiln process 4.1.2. Rotary hearth process 4.1.2.1. FASTMET process. 4.1.2.2. ITmk3 process. 4.2. Gas-Based Processes 4.2.1. Midrex process 4.2.2. HyL process 4.2.2.1. HyL III process. 4.2.2.2. HyL IV M process. 4.4.3. Purofer process 4.4.4. Finmet process 4.4.5. HIB process 5. CHARACTERISTICS AND USES OF DRI 5.1. Characteristics of DRI 5.2. Quality of DRI 5.3. Reoxidation, Storage, and Transportation of DRI 5.3.2.1. The hazards of DRI. 5.3.2.2. Classification of DRI according to the IMSBC Code. 5.4. Usages of DRI
  • 6. 1.1. Definition of Direct Reduced Iron
  • 7. 1.2. Direct Reduction Processes ❑ Based on the types of reductant used, the DR processes can be broadly classified into two groups: 1) Using solid reductant, that is, coal-based DR process. 2) Using gaseous reductant, that is, gas-based DR process ❑ DR processes are summarized in Table 1. Table 1: Direct reduction processes.
  • 12. Overview of Gas-based Direct Reduction Process Types
  • 15. 2.1. Iron Ore (Cont.)
  • 18. 2.4. Limestone or Dolomite Materials
  • 19. 2.5. Sizes of Raw Materials
  • 21. 2.7. Quality Requirements For Raw Materials
  • 22. 3. REACTIONS OF DIRECT REDUCTION PROCESSES
  • 23. 3.3. Reduction Reaction for Gaseous Reductant:
  • 25. 4. DIRECT REDUCTION PROCESSES
  • 27. SL/RN process Fig.3: SL/RN direct reduction process flowsheet
  • 28. iii) SL / RN process
  • 34. 4.1.2.1. FASTMET process Fig. 4: Flow sheet of the FASTMET process.
  • 36. 4.1.2.2. ITmk3 process Fig. 5: Flow sheet of the ITmk3 process.
  • 38. @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 38
  • 39.
  • 40. Midrex® process Midrex® direct reduction process flowsheet @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 40
  • 42. 4.2.2. HyL process Fig. 7: Flow sheet of the HyL I/II process
  • 44. 4.2.2.1. HyL III process
  • 45. Fig.8: Flow sheet of the HyL III process
  • 46. 4.2.2.2. HyL IV M process.
  • 47. Fig.9: Flow sheet of the HyL-IV M process
  • 50. Finmet / Finored Megatrain process
  • 52. 5. CHARACTERISTICS AND USES OF DRI 5.1. Characteristics of DRI
  • 54. Fig. 10 Different forms of DRI: (A) Lump, (B) Pellets, and (C) Hot-Briquetted Iron (HBI). Table 6: Typical chemical composition of Direct Reduction Iron. Table 7: Physical properties of Direct Reduction Iron. @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 54
  • 56. Table 8: Heat effects during reoxidation of DRI. @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 56
  • 57. 5.3. Reoxidation, Storage, and Transportation of DRI
  • 58. 5.3. Reoxidation, Storage, and Transportation of DRI
  • 59. 5.3. Reoxidation, Storage, and Transportation of DRI
  • 60. Table 9: High-density type, DRI (A). Table 10: Low-density type, DRI (B).
  • 61. 5.3.2.2. Classification of DRI according to the IMSBC Code
  • 62.
  • 65. 6. ENVIRONMENTAL SUSTAINABILITY @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 65
  • 66. REFERENCES • Sujay Kumar Dutta , RameshwarSah . Direct Reduced Iron: Production. In Encyclopedia of Iron, Steel, and Their Alloys. Taylor and Francis : New York, Published online: 30 Mar 2016; 1082-1108. http://dx.doi.org/10.1081/E-EISA-120050996 1. Dutta, S.K.; Roy Chowdhury, P.J. IE(I) J.—MM 1986, 66(2), 91. 2. Prasad, K.K. Steel, Metall. 2004, 6(8), 29. 3. Mehta, P. Special Report, 1987, Personal communication. 4. Chatterjee, A. In Proceedings of International Conference on Alternative Routes of Iron and Steelmaking, Perth, Australia, 1999; 3. 5. 2013 World Direct Reduction Statistics, Direct from Midrex, 2nd Quarter 2014, 2. 6. Dutta, S.K.; Roy Chowdhury, P.J.; Gadgeel, V.L. IE(I) J.— MM (Spl) 1988, 68(2), 52. 7. Vijayavergia, R.K.; Chauhan, G.I.S. Awakening of the Indian Steel Industry: 2005–2020; Chatterjee, A., Ed.; IIM: Jamshedpur, India, 2006; 27. 8. Chatterjee, A.; Sathe, A.V.; Singh, R.; Chakravarty, P.K.In Proceedings of Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM: Rourkela, India, 1982; 133. 9. Schlebusch, D.; Choudgury, L.R.; Dayal, R. Proceedings of Symposium on Direct Reduction Processes in Iron and Steelmaking. 36th ATM of IIM: Rourkela, India, 1982; 166. 10. Ghosh, A.; Chatterjee, A. Ironmaking Steelmaking: Theory and Practice; Prentice-Hall of India Pvt Ltd: New Delhi, India, 2008, Chap. 13, 225. 11. Dutta, B.B. IE(I) J.-CH 1993, 73, 69. 12. Pandit, A.; Sarangi, B.M.; Kesava Babu, A.; Sheshadri, M.K. Steel World, 2003. 13. Dutta, S.K.; Ghosh, A. Trans. Indian Inst. Met. 1995, 48(1), 1. 14. Dutta, S.K.; Sah, R.; Chokshi, Y. Iron Ore–Coal/Coke Composite Pellets; LAMBERT Academic Publishing, Saarbru¨cken: Germany, 2013. 15. Dutta, S.K.; Sah, R. Proceedings of Asia Steel International Conference, Jamshedpur, India, 2003. Vol. I, 1.d.4.1. 16. Prasad, K.K.; Ray, H.S. Advances in Rotary Kiln Sponge Iron Plant; New Age International Publishers: New Delhi, India, 2009, Chap. 3. 17. Kubaschewski, O.; Alcock, C.B. Metallurgical Thermochemistry, 5th Ed.; Pergamon Press: Oxford, U.K., 1979. 18. Dutta, S.K.; Sah, R. Alternate Methods of IronmakingS. Chand & Co Ltd: New Delhi, India, 2012. 19. Stephenson, R.L.; Smailer, R.M., Direct Reduced Iron: Technology and Economics of Production and Use; The Iron & Steel Society of AIME: USA, 1980. 20. Thatoi, K.C.; Sen Singh, V.; Sohal, G.D.S. Proceedings of Conference on Direct Reduction and Direct Smelting. 2001. Jamshedpur, India, 2011, 11. 21. Kosuke, S. Proceedings of International Seminar on Alternative Routes for Ironmaking in India, Kolkata, India, 2009, 39. 22. Klawonn, R.M.; Hoffman, G.E. Direct from Midrex, 2nd Qtr. 2005; 4. 23. Chatterjee, A. Proceedings of International Seminar on Alternative Routes for Ironmaking in India, Kolkata, India, 2009, 5. 24. MSTS Iron making; The AISE Steel Foundation: Pittsburgh, PA, 1999; Chap. 11, Vol. I, 741. 25. Ganguly, A.; Gupta, K.N.; Aswath, H.S. Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM, Rourkela, India, November 1982, 90. 26. Gerigk, E.; Knop, K.; Pena, J.M. Symposium on Direct Reduction Processes in Iron and Steelmaking, 36th ATM of IIM, Rourkela, India, November 1982, 192. 27. Dutta, S.K.; Lele, A.B. Miner. Met. Rev. 1997, 23(1), 79. 28. Taylor, C.R. Ed. Electric Furnace Steelmaking, Iron & Steel Society: AIME, Chap. 10, 115. 29. Dutta, S.K.; Lele, A.B Tool & Alloy Steels, 1993, 27(11), 349. 30. Paswan, M.; Mukherjee, C. IIM Metal News February 2009; 6. 31. http://www.skuld.com/topics/cargo/dangerous-cargo/dri/ Loss-Prevention-Advice-on-the-Carriage-of-Direct-ReducedIron-and-its-Derivatives.pdf. 32. http://www.intercargo.org/pdf_members/intercargo on dri. pdf. 33. http://www.cargohandbook.com/index.php title Direct_ Reduced_Iron. 34. Dutta, S.K. Perform. Rev. Iron Steel, JPC 2007–2008; 31. 35. Dutta, S.K. JPC Bull. Iron Steel 2006, VI(5), 17. @Hassan Harraz 2023 DIRECT REDUCED IRON ORE: Production 66