SlideShare a Scribd company logo
1 of 39
Download to read offline
EAST FORK WATERSHED WATER QUALITY
            MONITORING AND MODELING COOPERATIVE
            (EFWCOOP): JANUARY 19 2012 MEETING.




1.


     January 20,
        2011
ATTENDEES
   Melody Draggo, Brown County
   Chuck Lane, USEPA
   Erich Emery, USACE
   Jade Young, USACE
   Matt Heberling, USEPA
   Lilit Yegahzarian, UC
   Balaji Ramakrishnan, Shaw
   Roy Martin, USEPA
   Tom Yeager, Clermont County
   Heather Golden, USEPA
   Eric Waits, USEPA
   John McManus, Clermont County
   Chris Nietch, USEPA
   Eric Heiser, Clermont County
   Don Brown, USEPA
Recalling Some of Our Primary
Objectives
1.   Integration of natural and built systems
2.   Coupled modeling and monitoring programs for decision
     support
3.   BMP/GI performance to effectiveness linkages
4.   Informational (data) architectures and required cooperation for
     sustainable total water management
5.   Consider scaling and extrapolation within and across systems
6.   Defining and modeling drinking water treatability translations
7.   Evaluation of Water Quality Trading models
8.   TMDL Development Support
Discussion Topics
     Update on Monitoring Program
     Planning for 2012 w/ OEPA’s TMDL development effort
     Update on DBP formation tests
     Update on UEFW and GRT Modeling Projects
     Update on Harsha WQ Modeling and Developing
      2012 Remote Sensing Pilot Project
     Update on watershed projects
       CC-CIG
       Tipping Points

     Other Issues/Items to discuss.
Large Midwestern watershed
draining to a National Scenic
River and then the Ohio River



                                Agriculture
Weekly field site grab
  sampling continues
Added an additional Site at
  GRT outlet thanks to
  Hannah
Picked-up weekly Monitoring
  at GRSSY0.3 as CC is in
  winter mode
Added three Brown County
  Sites
EFWCoop Monitoring Sites and Point Sources
A flavor for the Nutrient DataBase




           450                                                           2500
           400

           350                                                           2000




                                                  Nitrate-Nitrie (ppb)
           300
                                                                         1500
           250
TP (ppb)




           200
                                                                         1000
           150

           100
                                                                         500
            50

            0                                                              0


                 EFG   EFB   DAM    EFK     EFC                                 EFG   EFB   DAM   EFK   EFC
2011 & Proposed 2012 Monitoring

   Demonstration Project
    CIG Monitoring
     Cover Crop & Ag.
      Pond Effectiveness
     Biweekly, year-round
      grabs at 3 sites
     ~5 Wet weather
      events
   TMDL/HUC 12
    biweekly monitoring &
    D.O. profiles at 9 sites
   Biological Monitoring       Discharge, T, DO, sp.cond., pH,
    of small tributaries, <     DOC, TOC, N-NH3, NO2-NO3,
    5 mi2                      TKN, P-TP, Ortho-P, E.coli, TSS,
                                  atrazine, simazine, alachlor
Characterization of Monitoring Sites

Site       General Land Use
POPLR2.1   Park land, Low dens. residential, Agriculture
STEFLMR    Low dens. residential, Agriculture
BARNS1.9   Agriculture, Low dens. residential,
EFRM9.1    WWTP, Residential
EFRM15.6   Low density residential, East Fork Lake
EFRM34.8   WWTP, Agriculture, Low dens. residential
EFRM70.1   WWTP, Agriculture, Low dens. residential
EFRM75.3   Agriculture, Low dens. residential
DODSN1.4   Agriculture, EWH
1.7
        1.6
              Avg. Nutrient Conc.                     NO2NO3
                                                                        10000
                                                                                     Avg. Nutrient Loads
        1.5          May- Aug.                                                             May - Aug.        NO2NO3 (ppm)
        1.4                                           TKN
        1.3                                           PTOT                   1000                            TKN (ppm)
        1.2
        1.1                                  WWH NO3-criteria                                                PTOT
        1.0




                                                                    kg/day
        0.9
mg/L




                                                                              100
        0.8
        0.7
        0.6                                      EWH NO0-criteria
        0.5
        0.4                                                                    10
        0.3
        0.2                                            EWH TP-
        0.1                                             criteria
        0.0                                                                     1




       1400   Avg. Bacteria                                                    45   Avg. Suspended Solids
                 May- Aug.                                                     40          May- Aug.
       1200                            E. coli                                                          SS
                                                                               35
       1000
                                                                               30
       800
mg/L




                                                                       mg/L
                                                                               25
       600                                                                     20

       400                                                                     15
                                                                               10
       200                   30 day avg. criteria = 126 (#/100mL)
                                                                                5
         0                                                                      0
11
                                3-day deployment,
                          10   Not all data collected
                                during same time
                           9
                                       period
Dissolved Oxygen (mg/L)




                           8


                           7


                           6
                               EWH Dissolved Oxygen
                               criteria = 5.0 mg/L
                           5
                                                      DODSN1.4
                           4                          EFRM75.3
                                                      EFRM70.1
                           3                          EFRM60.1
                                                      EFRM44.1
                           2                          EFRM15.6
                                                      EFRM9.1
3-day deployment,
                          12
                                              Not all data collected
                                               during same time
                          10
                                                      period
Dissolved Oxygen (mg/L)




                           8



                           6

                                      WWH criteria
                                      Min D.O. = 4.0 mg/L
                           4

                                                            BARNS1.9
                           2                                CLOVE5.1
                                                            POPLR2.1
                                                            ST13.4
                           0                                BRUSH0.3
                                                            ST5.7
                               Time                         STEFLMR
in-situ monitoring continues at the Lake DWTP intake
                                            River and/or Reservoir                    Treatment Plant Processes
         chlorophyll a                        Ecology Processes                        coagulation, settling, filtration,
                                                                                  chlorination, activated carbon, membrane
phycocyanin (cyanobact. pigment)       biogeochemistry, hydrology, ecology
                                                                                                 filtration
              DO
               pH
              ORP
            turbidity
          Conductivity
     UV absorbance (DOM)                                                                 In Plant Data

                                    Reservoir         Modeling               Source        Modeling
                                      Data -                                  Water                       Finished
                                                       fate and                           Treatment         Water
                                     various                                  Data -
                                                      transport                           Processes         Data
                                     depths                                  1_depth
   Grab sampling
               chlorophyll a
  phycocyanin (cyano bact. pigment)
algal taxonomy (species level counting)                                                    Grab sampling
                 nutrients                                                           DBPs -THMs, HAAs
                    pH                                                              UV absorbance (DOM)
              turbidity/sechi                                                    fluorescence EEMs (DOM)
   DOC/TOC, UV absorbance (DOM)                                                     Chlorine demand, etc.
       fluorescence EEMs (DOM)
    DBP (THMs) formation potential
Controlled DBP Formation Tests

                                                                                                                       90
                                                                                                                                              ppb CFE
                             2.5

                                                 UFC example                                                           80

                              2                                  y = 0.0077x 2 + 0.592x - 2.5576
                                                                                                                       70
                                                                          R² = 0.9961

                                                                                                                       60
   chlorine residual (ppm)




                             1.5                                                                                                                                  Cl3
                                                                                                                       50                                         BrCl2

                                                                                                                                                                  Br2Cl
                                                                                                                       40
                              1                                                                                                                                   Br3

                                                                                                                       30                                         THM4(ppb)


                             0.5                                                               Series2                 20
                                                                                               Poly. (Series2)

                                                                                                                       10

                              0
                                   4.5          5        5.5           6             6.5           7             7.5   0
                                                                                                                                                                                        Kinetics Example
                                                               chlorine dose (ppm)                                          4.5   5   5.5        6          6.5               7   7.5
                                                                                                                                            Chlorine dose

                                         rxn Temp           Final    final TOT-
rxn pH                                   (20)      FAC dose FAC      Cl         THMs
always 8                                 always 20 6 diff   measured measured measured
Mike's constant temp THM reactions
More DOC = more Cl2 demand24                                                                                 Poor relationship with Cl2 demand 24
                     5.0
                     4.5
                                                                                                              120.0        and THMs
                     4.0                                                                                            100.0
24 hour Cl2 demand




                     3.5
                     3.0                                                                                             80.0
                     2.5




                                                                                                             THMs
                                                                                                                     60.0
                     2.0
                     1.5                              y = 2.5519x - 4.2233                                           40.0
                     1.0                                   R² = 0.8025                                                                        y = 7.5476x + 45.724
                     0.5                                                                                             20.0                          R² = 0.1109
                     0.0
                                                                                                                      0.0
                           2    2.2           2.4   2.6    2.8        3        3.2     3.4       3.6
                                                                                                                         2.00   2.50   3.00        3.50    4.00      4.50   5.00
                                                           DOC
                                                                                                                                               Cl2demand24


                                      120.0
                               Some trend with DOC and THMs
                                      100.0

                                       80.0
                               THMs




                                       60.0

                                       40.0                               y = 45.871x - 67.129
                                                                               R² = 0.5856
                                       20.0

                                        0.0
                                               2             2.5                 3                     3.5   4
                                                                                DOC
UEFW SWAT MODELING
UPDATE AND WQT CASE
STUDY – LARGE SCALE
MODELING
Upper EFW SWAT Model
   Final Descretization Achieved (shown here)
   NexRad rain file compiled for watershed.
   Still Working on a Land Use Layer using hierarchical
    ordering rules and ArcGIS zonal statistics function.
   Almost have septic coverages for areas withoiut GIS
    coverage. Next will need to parameterize
   Starting to address how to parameterize agBMPs,
    including Wetlands
PRECIPITATION EVENT CENTROIDS
DERIVED
                                    90
                                         EFK
  precipitation (event total, mm)




                                    80
                                         CWL
                                    70
                                    60
                                    50
                                    40
                                    30
                                    20
                                    10
                                    0
Land Use in SWAT Model
•   Developed a set of
    rules for establishing
    land use based on the
    NHD, NLCD, and NASS-
    CDL.
•   Trying to capture
    temporal changes (crop
    rotations) in one spatial
    layer. Have identified
    approximately 50
    rotation patterns.
•   Having some problems
    identifying parcels with
    septic systems when a
    septic layer is not
    available.
Septics in Land Use Layer
   The septic rule: if the centroid of a parcel is not classified
    as water, wetland, or urban, put a septic at the centroid
    of the parcel.
   Using the Clermont County septic layer, we looked at how
    the rules performed.
   Note in the following figure that green parcels are those
    that are labeled on the county layer as having a septic,
    red dots are rule based septic locations. The rules are
    clearly overestimating septics. There are several reasons
    why the rules are overestimating, but these reasons are
    not easily addressed by changing the rules (for example,
    one house sits on two parcels).
   Also note that the right side of the map is Brown County.
Septic Comparison
Septic Comparison
The Septic System Model in SWAT
CIG effort Update
-SOME COVER CROPS PLANTED
-PREP FOR BASIN DESIGN
-SMALL-SCALE MODELING CONTINUES
-GRT SITE ESTABLISHED
-BROWN COUNTY 319 CC MONITORING
-COVER CROP WORKSHOP SET FOR 3/2/2012
GRT Modeling




-Fully Parameterized
-Moving into Calibration Phase

    id   season    n    mtp      mtrp   mtn    mtno23   mtnh4   mturea   mdoc    mtoc
   CWL     Fall    14   451      364    1334    130       47      84     14650   13570
   CWL    Spring   14   422      146    3647    788      348     186     12285   12985
   CWL   Summer    10   306      184    2063    824       86      45     16400   17150
   CWL    Winter   2    228      128    2780    213       34      96     15420   14280
Brown County Cover Crop Sheds
 added to AgBMP experimental
    effort – Melody Dragoo
Remote Sensing Pilot Study
PURPOSE.
Demonstrate the use of remote sensing to estimate water
quality parameters in inland reservoirs and lakes to
enhance Corps water quality management practices as
described in ERDC/EL TR-11-13 (Reif, 2011).
Draft SOW Prepared-Objectives
   1) examine remote sensing imagery assets and analytical capabilities for
    interpreting water quality parameters in inland lakes and reservoirs
   2) demonstrate and use the best available image types and interpretation
    techniques for a study area (i.e. Corps reservoir) in the Great Lakes and
    Ohio River Division
      Examine and select a lake, reservoir or series of lakes/reservoirs in the
        LRD AO (e.g. Harsha Lake) representing a variety of environmental
        conditions, including water bodies with potential nutrient loading that
        may be vulnerable to Harmful Algal Blooms (HABs) and will provide an
        appropriate study site for development and demonstration of water
        quality interpretation using remote sensing
          Should we consider adding a 2nd site – are there any lakes/reservoirs nearby to
           Harsha that may have different/worse water quality conditions?
          Is Harsha big enough to be covered by MERIS?
CE-QUAL-W2 Modeling
   Update Submitted by Jeff last time, no new info.
   Inflow discrepancy issue unresolved
DO Temperature Recovery Hypothesis.
                          Date       Year      Days since Avg. temp. Avg. DO
                           11/4/2002      2002          0       14.1         0
                          11/12/2002                    8       13.1       3.2
                          11/19/2002                   15       11.9       3.9
                          11/26/2002                   22       10.6       3.9
                           12/4/2002                   30        8.6       5.7


                                         16


    No new developments
                                                                                 y = -0.1825x + 14.397

                                        14
                                         12
                                         10




                            DO or Temp
                                                                                      Avg. temp.
                                         8
                                                                                      Avg. DO
                                         6                                            Linear (Avg. temp.)
                                         4                                            Linear (Avg. DO)
                                         2
                                         0                                        y = 0.165x + 0.8655
                                              0   10        20         30   40
                                                    Days since turnover




Low DO Duration Hypothesis
   No new developments
Low DO Duration Hypothesis
           No new developments




data testDO4; set testDO1;
title "MixedModel";
if yr<2001 then delete;
if julD < 125 then delete; if julD > 250 then delete;
If depth1 < 20 then delete;
proc mixed data=testDO4; class yr depth1 julD;
model mlnDO= yr julD yr*juld/outp=Mone; random
depth1(yr); repeated julD/sub= depth1(yr); lsmeans
yr*julD; run;
proc print; run;
January Sampling
of GHG and
nutrients at the lake
FALL AND WINTER SAMPLING RESULTS- GHG
                       CH4 Emission Variations Across
FLUXES                            the Lake                     250
                                                               10




                                          μmol CH4 min-1 m-2
                                                                1

                                                               0.1                                                Below
                                                                                                                  detection
                                                           0.01
                                                                     0              5                 10     15
                                                                                  km from mouth of stream

                                                                             N2O Emission Variations Across
                                                               150                     the Lake




                                            μg N2O-N m-2 h-1
                                                               100                                                 October
                                                                                                                   December
                                                                50

                                                                 0
                                                                         0          5                10     15
                                                                                  km from mouth of stream
Sampling shows that just after fall                                          CO2 Emission Variations Across
turnover, GHG fluxes were very high                       600
                                                                                       the Lake
and detected at all points on the lake.
                                          μg CO2-N m-2 h-1
                                                          500
                                                                                                                   October
                                                          400
In the winter, GHG fluxes were still
                                                                                                                   December
                                                          300
                                                          200
detected but at overall lower levels.                     100
                                                            0
                                                                     0              5                 10     15
                                                                                  km from mouth of stream
TIPPING POINT RESEARCH –
CHUCK, HEATHER, ERIC, ROY’S WORK


     Trying to establish good sites for using
     metagenomic approaches to fish population
     health indicators,

     Looking for sites to represent significant
     gradients for ecological tipping point
     analyses/research.
MONITORING PROGRAM ISSUES


ANY NEW ONES?
Next Meeting Date:
January 19th, 2012 (Provided that Hannah can get us a place and
 be in attendance,)
We’ll focus on 2012 monitoring program adjustments. I’ll try to
have 2011 loading estimates compiled, please send me update
materials for inclusion in the meeting slidedeck by COB Tuesday
before the meeting.




                    *The ideas and opinions expressed herein are those of
                    the primary author and do not reflect official EPA position
                    or policy.
  January 19,
     2011

More Related Content

Viewers also liked

Julie's birthday powerpoint
Julie's birthday powerpointJulie's birthday powerpoint
Julie's birthday powerpoint
juliejohnson0115
 
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules and...
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules  and...Hazardous Wastes (Management, Handling and Transboundary Movement) Rules  and...
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules and...
Ranveer Singh Mahwar
 
Skyfall poster analysis
Skyfall poster analysisSkyfall poster analysis
Skyfall poster analysis
chloebuckland
 

Viewers also liked (11)

Ef coop meetingpres_11102011
Ef coop meetingpres_11102011Ef coop meetingpres_11102011
Ef coop meetingpres_11102011
 
Julie's birthday powerpoint
Julie's birthday powerpointJulie's birthday powerpoint
Julie's birthday powerpoint
 
Evaluation
EvaluationEvaluation
Evaluation
 
Identification of industrial wastes suitable for application of the accelerat...
Identification of industrial wastes suitable for application of the accelerat...Identification of industrial wastes suitable for application of the accelerat...
Identification of industrial wastes suitable for application of the accelerat...
 
Personal protection in galvanizing industry
Personal protection in galvanizing industryPersonal protection in galvanizing industry
Personal protection in galvanizing industry
 
Integra Realty Resources-Mpls/St. Paul Viewpoint 2012 Outlook
Integra Realty Resources-Mpls/St. Paul Viewpoint 2012 OutlookIntegra Realty Resources-Mpls/St. Paul Viewpoint 2012 Outlook
Integra Realty Resources-Mpls/St. Paul Viewpoint 2012 Outlook
 
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules and...
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules  and...Hazardous Wastes (Management, Handling and Transboundary Movement) Rules  and...
Hazardous Wastes (Management, Handling and Transboundary Movement) Rules and...
 
Eval Q2
Eval Q2Eval Q2
Eval Q2
 
Skyfall poster analysis
Skyfall poster analysisSkyfall poster analysis
Skyfall poster analysis
 
Informe de diagnostico situacional.
Informe de diagnostico situacional.Informe de diagnostico situacional.
Informe de diagnostico situacional.
 
Best Management Practices & Environmental Regulations For Galvanizing Indust...
Best Management Practices& Environmental Regulations For Galvanizing Indust...Best Management Practices& Environmental Regulations For Galvanizing Indust...
Best Management Practices & Environmental Regulations For Galvanizing Indust...
 

Similar to Ef coop meetingpres_01192012

Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
Mawuli Dzakpasu
 
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of PharmacyIOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
iosrphr_editor
 
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of PharmacyIOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
iosrphr_editor
 
Hodnik - Environmental Progress and Challenges
Hodnik - Environmental Progress and ChallengesHodnik - Environmental Progress and Challenges
Hodnik - Environmental Progress and Challenges
Environmental Initiative
 
Timmins schiffman wun 2011
Timmins schiffman wun 2011Timmins schiffman wun 2011
Timmins schiffman wun 2011
emmats
 
Proyecto A Gran Escala Hydromentia Presentation
Proyecto A Gran Escala Hydromentia PresentationProyecto A Gran Escala Hydromentia Presentation
Proyecto A Gran Escala Hydromentia Presentation
H2RAmbiental
 
Water resources and biofuels water quality april 2012
Water resources and biofuels water quality   april 2012Water resources and biofuels water quality   april 2012
Water resources and biofuels water quality april 2012
Sharon Lezberg
 
Sigma xi nanzhang_20130312_3
Sigma xi nanzhang_20130312_3Sigma xi nanzhang_20130312_3
Sigma xi nanzhang_20130312_3
nkzhangnan
 
Five Years of Land Surface Phenology in an Arctic Landscape
Five Years of Land Surface Phenology in an Arctic LandscapeFive Years of Land Surface Phenology in an Arctic Landscape
Five Years of Land Surface Phenology in an Arctic Landscape
Santonu Goswami
 

Similar to Ef coop meetingpres_01192012 (20)

Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
Nutrient Leaching and Groundwater Quality Assessment near Integrated Construc...
 
Application of NMR and MS based Metabolomics in Natural Product Science
Application of NMR and MS based Metabolomics in Natural Product ScienceApplication of NMR and MS based Metabolomics in Natural Product Science
Application of NMR and MS based Metabolomics in Natural Product Science
 
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of PharmacyIOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
 
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of PharmacyIOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
IOSRPHR(www.iosrphr.org) IOSR Journal of Pharmacy
 
NRDC PA Marcellus Fracking Wastewater Report
NRDC PA Marcellus Fracking Wastewater ReportNRDC PA Marcellus Fracking Wastewater Report
NRDC PA Marcellus Fracking Wastewater Report
 
Hodnik - Environmental Progress and Challenges
Hodnik - Environmental Progress and ChallengesHodnik - Environmental Progress and Challenges
Hodnik - Environmental Progress and Challenges
 
Timmins schiffman wun 2011
Timmins schiffman wun 2011Timmins schiffman wun 2011
Timmins schiffman wun 2011
 
Energy as Motor of Seawater Reverse Osmosis Desalination Development
Energy as Motor of Seawater Reverse Osmosis Desalination DevelopmentEnergy as Motor of Seawater Reverse Osmosis Desalination Development
Energy as Motor of Seawater Reverse Osmosis Desalination Development
 
Lake Erie Phosphorus Task Force Results
Lake Erie Phosphorus Task Force ResultsLake Erie Phosphorus Task Force Results
Lake Erie Phosphorus Task Force Results
 
Electrochemical stripping studies of amlodipine using mwcnt modified glassy c...
Electrochemical stripping studies of amlodipine using mwcnt modified glassy c...Electrochemical stripping studies of amlodipine using mwcnt modified glassy c...
Electrochemical stripping studies of amlodipine using mwcnt modified glassy c...
 
11.electrochemical stripping studies of amlodipine using mwcnt modified glass...
11.electrochemical stripping studies of amlodipine using mwcnt modified glass...11.electrochemical stripping studies of amlodipine using mwcnt modified glass...
11.electrochemical stripping studies of amlodipine using mwcnt modified glass...
 
Proyecto A Gran Escala Hydromentia Presentation
Proyecto A Gran Escala Hydromentia PresentationProyecto A Gran Escala Hydromentia Presentation
Proyecto A Gran Escala Hydromentia Presentation
 
Water resources and biofuels water quality april 2012
Water resources and biofuels water quality   april 2012Water resources and biofuels water quality   april 2012
Water resources and biofuels water quality april 2012
 
2009 Convegno Malattie Rare Benigni [23 01]
2009 Convegno Malattie Rare Benigni [23 01]2009 Convegno Malattie Rare Benigni [23 01]
2009 Convegno Malattie Rare Benigni [23 01]
 
Meeting Nutrient Limits with Activated Sludge and Control Strategies | Wastew...
Meeting Nutrient Limits with Activated Sludge and Control Strategies | Wastew...Meeting Nutrient Limits with Activated Sludge and Control Strategies | Wastew...
Meeting Nutrient Limits with Activated Sludge and Control Strategies | Wastew...
 
Lee, Charles - Organic Materials Chemistry - Spring Review 2012
Lee, Charles - Organic Materials Chemistry - Spring Review 2012Lee, Charles - Organic Materials Chemistry - Spring Review 2012
Lee, Charles - Organic Materials Chemistry - Spring Review 2012
 
Sigma xi nanzhang_20130312_3
Sigma xi nanzhang_20130312_3Sigma xi nanzhang_20130312_3
Sigma xi nanzhang_20130312_3
 
Thesis defense
Thesis defenseThesis defense
Thesis defense
 
Application of ICP-MS and LC-ICP-MS in Drug Development
Application of ICP-MS and LC-ICP-MS in Drug DevelopmentApplication of ICP-MS and LC-ICP-MS in Drug Development
Application of ICP-MS and LC-ICP-MS in Drug Development
 
Five Years of Land Surface Phenology in an Arctic Landscape
Five Years of Land Surface Phenology in an Arctic LandscapeFive Years of Land Surface Phenology in an Arctic Landscape
Five Years of Land Surface Phenology in an Arctic Landscape
 

Recently uploaded

Beyond the EU: DORA and NIS 2 Directive's Global Impact
Beyond the EU: DORA and NIS 2 Directive's Global ImpactBeyond the EU: DORA and NIS 2 Directive's Global Impact
Beyond the EU: DORA and NIS 2 Directive's Global Impact
PECB
 
Gardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch LetterGardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch Letter
MateoGardella
 
Gardella_Mateo_IntellectualProperty.pdf.
Gardella_Mateo_IntellectualProperty.pdf.Gardella_Mateo_IntellectualProperty.pdf.
Gardella_Mateo_IntellectualProperty.pdf.
MateoGardella
 
Making and Justifying Mathematical Decisions.pdf
Making and Justifying Mathematical Decisions.pdfMaking and Justifying Mathematical Decisions.pdf
Making and Justifying Mathematical Decisions.pdf
Chris Hunter
 
1029 - Danh muc Sach Giao Khoa 10 . pdf
1029 -  Danh muc Sach Giao Khoa 10 . pdf1029 -  Danh muc Sach Giao Khoa 10 . pdf
1029 - Danh muc Sach Giao Khoa 10 . pdf
QucHHunhnh
 

Recently uploaded (20)

Unit-IV; Professional Sales Representative (PSR).pptx
Unit-IV; Professional Sales Representative (PSR).pptxUnit-IV; Professional Sales Representative (PSR).pptx
Unit-IV; Professional Sales Representative (PSR).pptx
 
fourth grading exam for kindergarten in writing
fourth grading exam for kindergarten in writingfourth grading exam for kindergarten in writing
fourth grading exam for kindergarten in writing
 
This PowerPoint helps students to consider the concept of infinity.
This PowerPoint helps students to consider the concept of infinity.This PowerPoint helps students to consider the concept of infinity.
This PowerPoint helps students to consider the concept of infinity.
 
Beyond the EU: DORA and NIS 2 Directive's Global Impact
Beyond the EU: DORA and NIS 2 Directive's Global ImpactBeyond the EU: DORA and NIS 2 Directive's Global Impact
Beyond the EU: DORA and NIS 2 Directive's Global Impact
 
Mehran University Newsletter Vol-X, Issue-I, 2024
Mehran University Newsletter Vol-X, Issue-I, 2024Mehran University Newsletter Vol-X, Issue-I, 2024
Mehran University Newsletter Vol-X, Issue-I, 2024
 
Sports & Fitness Value Added Course FY..
Sports & Fitness Value Added Course FY..Sports & Fitness Value Added Course FY..
Sports & Fitness Value Added Course FY..
 
Introduction to Nonprofit Accounting: The Basics
Introduction to Nonprofit Accounting: The BasicsIntroduction to Nonprofit Accounting: The Basics
Introduction to Nonprofit Accounting: The Basics
 
APM Welcome, APM North West Network Conference, Synergies Across Sectors
APM Welcome, APM North West Network Conference, Synergies Across SectorsAPM Welcome, APM North West Network Conference, Synergies Across Sectors
APM Welcome, APM North West Network Conference, Synergies Across Sectors
 
Gardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch LetterGardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch Letter
 
Unit-IV- Pharma. Marketing Channels.pptx
Unit-IV- Pharma. Marketing Channels.pptxUnit-IV- Pharma. Marketing Channels.pptx
Unit-IV- Pharma. Marketing Channels.pptx
 
Mattingly "AI & Prompt Design: The Basics of Prompt Design"
Mattingly "AI & Prompt Design: The Basics of Prompt Design"Mattingly "AI & Prompt Design: The Basics of Prompt Design"
Mattingly "AI & Prompt Design: The Basics of Prompt Design"
 
Measures of Central Tendency: Mean, Median and Mode
Measures of Central Tendency: Mean, Median and ModeMeasures of Central Tendency: Mean, Median and Mode
Measures of Central Tendency: Mean, Median and Mode
 
Web & Social Media Analytics Previous Year Question Paper.pdf
Web & Social Media Analytics Previous Year Question Paper.pdfWeb & Social Media Analytics Previous Year Question Paper.pdf
Web & Social Media Analytics Previous Year Question Paper.pdf
 
Gardella_Mateo_IntellectualProperty.pdf.
Gardella_Mateo_IntellectualProperty.pdf.Gardella_Mateo_IntellectualProperty.pdf.
Gardella_Mateo_IntellectualProperty.pdf.
 
Código Creativo y Arte de Software | Unidad 1
Código Creativo y Arte de Software | Unidad 1Código Creativo y Arte de Software | Unidad 1
Código Creativo y Arte de Software | Unidad 1
 
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptxSOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
 
Making and Justifying Mathematical Decisions.pdf
Making and Justifying Mathematical Decisions.pdfMaking and Justifying Mathematical Decisions.pdf
Making and Justifying Mathematical Decisions.pdf
 
Key note speaker Neum_Admir Softic_ENG.pdf
Key note speaker Neum_Admir Softic_ENG.pdfKey note speaker Neum_Admir Softic_ENG.pdf
Key note speaker Neum_Admir Softic_ENG.pdf
 
Advanced Views - Calendar View in Odoo 17
Advanced Views - Calendar View in Odoo 17Advanced Views - Calendar View in Odoo 17
Advanced Views - Calendar View in Odoo 17
 
1029 - Danh muc Sach Giao Khoa 10 . pdf
1029 -  Danh muc Sach Giao Khoa 10 . pdf1029 -  Danh muc Sach Giao Khoa 10 . pdf
1029 - Danh muc Sach Giao Khoa 10 . pdf
 

Ef coop meetingpres_01192012

  • 1. EAST FORK WATERSHED WATER QUALITY MONITORING AND MODELING COOPERATIVE (EFWCOOP): JANUARY 19 2012 MEETING. 1. January 20, 2011
  • 2. ATTENDEES Melody Draggo, Brown County Chuck Lane, USEPA Erich Emery, USACE Jade Young, USACE Matt Heberling, USEPA Lilit Yegahzarian, UC Balaji Ramakrishnan, Shaw Roy Martin, USEPA Tom Yeager, Clermont County Heather Golden, USEPA Eric Waits, USEPA John McManus, Clermont County Chris Nietch, USEPA Eric Heiser, Clermont County Don Brown, USEPA
  • 3. Recalling Some of Our Primary Objectives 1. Integration of natural and built systems 2. Coupled modeling and monitoring programs for decision support 3. BMP/GI performance to effectiveness linkages 4. Informational (data) architectures and required cooperation for sustainable total water management 5. Consider scaling and extrapolation within and across systems 6. Defining and modeling drinking water treatability translations 7. Evaluation of Water Quality Trading models 8. TMDL Development Support
  • 4. Discussion Topics  Update on Monitoring Program  Planning for 2012 w/ OEPA’s TMDL development effort  Update on DBP formation tests  Update on UEFW and GRT Modeling Projects  Update on Harsha WQ Modeling and Developing 2012 Remote Sensing Pilot Project  Update on watershed projects  CC-CIG  Tipping Points  Other Issues/Items to discuss.
  • 5. Large Midwestern watershed draining to a National Scenic River and then the Ohio River Agriculture Weekly field site grab sampling continues Added an additional Site at GRT outlet thanks to Hannah Picked-up weekly Monitoring at GRSSY0.3 as CC is in winter mode Added three Brown County Sites
  • 6. EFWCoop Monitoring Sites and Point Sources
  • 7. A flavor for the Nutrient DataBase 450 2500 400 350 2000 Nitrate-Nitrie (ppb) 300 1500 250 TP (ppb) 200 1000 150 100 500 50 0 0 EFG EFB DAM EFK EFC EFG EFB DAM EFK EFC
  • 8. 2011 & Proposed 2012 Monitoring  Demonstration Project CIG Monitoring  Cover Crop & Ag. Pond Effectiveness  Biweekly, year-round grabs at 3 sites  ~5 Wet weather events  TMDL/HUC 12 biweekly monitoring & D.O. profiles at 9 sites  Biological Monitoring Discharge, T, DO, sp.cond., pH, of small tributaries, < DOC, TOC, N-NH3, NO2-NO3, 5 mi2 TKN, P-TP, Ortho-P, E.coli, TSS, atrazine, simazine, alachlor
  • 9. Characterization of Monitoring Sites Site General Land Use POPLR2.1 Park land, Low dens. residential, Agriculture STEFLMR Low dens. residential, Agriculture BARNS1.9 Agriculture, Low dens. residential, EFRM9.1 WWTP, Residential EFRM15.6 Low density residential, East Fork Lake EFRM34.8 WWTP, Agriculture, Low dens. residential EFRM70.1 WWTP, Agriculture, Low dens. residential EFRM75.3 Agriculture, Low dens. residential DODSN1.4 Agriculture, EWH
  • 10. 1.7 1.6 Avg. Nutrient Conc. NO2NO3 10000 Avg. Nutrient Loads 1.5 May- Aug. May - Aug. NO2NO3 (ppm) 1.4 TKN 1.3 PTOT 1000 TKN (ppm) 1.2 1.1 WWH NO3-criteria PTOT 1.0 kg/day 0.9 mg/L 100 0.8 0.7 0.6 EWH NO0-criteria 0.5 0.4 10 0.3 0.2 EWH TP- 0.1 criteria 0.0 1 1400 Avg. Bacteria 45 Avg. Suspended Solids May- Aug. 40 May- Aug. 1200 E. coli SS 35 1000 30 800 mg/L mg/L 25 600 20 400 15 10 200 30 day avg. criteria = 126 (#/100mL) 5 0 0
  • 11. 11 3-day deployment, 10 Not all data collected during same time 9 period Dissolved Oxygen (mg/L) 8 7 6 EWH Dissolved Oxygen criteria = 5.0 mg/L 5 DODSN1.4 4 EFRM75.3 EFRM70.1 3 EFRM60.1 EFRM44.1 2 EFRM15.6 EFRM9.1
  • 12. 3-day deployment, 12 Not all data collected during same time 10 period Dissolved Oxygen (mg/L) 8 6 WWH criteria Min D.O. = 4.0 mg/L 4 BARNS1.9 2 CLOVE5.1 POPLR2.1 ST13.4 0 BRUSH0.3 ST5.7 Time STEFLMR
  • 13. in-situ monitoring continues at the Lake DWTP intake River and/or Reservoir Treatment Plant Processes chlorophyll a Ecology Processes coagulation, settling, filtration, chlorination, activated carbon, membrane phycocyanin (cyanobact. pigment) biogeochemistry, hydrology, ecology filtration DO pH ORP turbidity Conductivity UV absorbance (DOM) In Plant Data Reservoir Modeling Source Modeling Data - Water Finished fate and Treatment Water various Data - transport Processes Data depths 1_depth Grab sampling chlorophyll a phycocyanin (cyano bact. pigment) algal taxonomy (species level counting) Grab sampling nutrients DBPs -THMs, HAAs pH UV absorbance (DOM) turbidity/sechi fluorescence EEMs (DOM) DOC/TOC, UV absorbance (DOM) Chlorine demand, etc. fluorescence EEMs (DOM) DBP (THMs) formation potential
  • 14. Controlled DBP Formation Tests 90 ppb CFE 2.5 UFC example 80 2 y = 0.0077x 2 + 0.592x - 2.5576 70 R² = 0.9961 60 chlorine residual (ppm) 1.5 Cl3 50 BrCl2 Br2Cl 40 1 Br3 30 THM4(ppb) 0.5 Series2 20 Poly. (Series2) 10 0 4.5 5 5.5 6 6.5 7 7.5 0 Kinetics Example chlorine dose (ppm) 4.5 5 5.5 6 6.5 7 7.5 Chlorine dose rxn Temp Final final TOT- rxn pH (20) FAC dose FAC Cl THMs always 8 always 20 6 diff measured measured measured
  • 15. Mike's constant temp THM reactions More DOC = more Cl2 demand24 Poor relationship with Cl2 demand 24 5.0 4.5 120.0 and THMs 4.0 100.0 24 hour Cl2 demand 3.5 3.0 80.0 2.5 THMs 60.0 2.0 1.5 y = 2.5519x - 4.2233 40.0 1.0 R² = 0.8025 y = 7.5476x + 45.724 0.5 20.0 R² = 0.1109 0.0 0.0 2 2.2 2.4 2.6 2.8 3 3.2 3.4 3.6 2.00 2.50 3.00 3.50 4.00 4.50 5.00 DOC Cl2demand24 120.0 Some trend with DOC and THMs 100.0 80.0 THMs 60.0 40.0 y = 45.871x - 67.129 R² = 0.5856 20.0 0.0 2 2.5 3 3.5 4 DOC
  • 16. UEFW SWAT MODELING UPDATE AND WQT CASE STUDY – LARGE SCALE MODELING
  • 17. Upper EFW SWAT Model  Final Descretization Achieved (shown here)  NexRad rain file compiled for watershed.  Still Working on a Land Use Layer using hierarchical ordering rules and ArcGIS zonal statistics function.  Almost have septic coverages for areas withoiut GIS coverage. Next will need to parameterize  Starting to address how to parameterize agBMPs, including Wetlands
  • 18. PRECIPITATION EVENT CENTROIDS DERIVED 90 EFK precipitation (event total, mm) 80 CWL 70 60 50 40 30 20 10 0
  • 19. Land Use in SWAT Model • Developed a set of rules for establishing land use based on the NHD, NLCD, and NASS- CDL. • Trying to capture temporal changes (crop rotations) in one spatial layer. Have identified approximately 50 rotation patterns. • Having some problems identifying parcels with septic systems when a septic layer is not available.
  • 20. Septics in Land Use Layer  The septic rule: if the centroid of a parcel is not classified as water, wetland, or urban, put a septic at the centroid of the parcel.  Using the Clermont County septic layer, we looked at how the rules performed.  Note in the following figure that green parcels are those that are labeled on the county layer as having a septic, red dots are rule based septic locations. The rules are clearly overestimating septics. There are several reasons why the rules are overestimating, but these reasons are not easily addressed by changing the rules (for example, one house sits on two parcels).  Also note that the right side of the map is Brown County.
  • 23. The Septic System Model in SWAT
  • 24. CIG effort Update -SOME COVER CROPS PLANTED -PREP FOR BASIN DESIGN -SMALL-SCALE MODELING CONTINUES -GRT SITE ESTABLISHED -BROWN COUNTY 319 CC MONITORING -COVER CROP WORKSHOP SET FOR 3/2/2012
  • 25. GRT Modeling -Fully Parameterized -Moving into Calibration Phase id season n mtp mtrp mtn mtno23 mtnh4 mturea mdoc mtoc CWL Fall 14 451 364 1334 130 47 84 14650 13570 CWL Spring 14 422 146 3647 788 348 186 12285 12985 CWL Summer 10 306 184 2063 824 86 45 16400 17150 CWL Winter 2 228 128 2780 213 34 96 15420 14280
  • 26. Brown County Cover Crop Sheds added to AgBMP experimental effort – Melody Dragoo
  • 27. Remote Sensing Pilot Study PURPOSE. Demonstrate the use of remote sensing to estimate water quality parameters in inland reservoirs and lakes to enhance Corps water quality management practices as described in ERDC/EL TR-11-13 (Reif, 2011).
  • 28. Draft SOW Prepared-Objectives  1) examine remote sensing imagery assets and analytical capabilities for interpreting water quality parameters in inland lakes and reservoirs  2) demonstrate and use the best available image types and interpretation techniques for a study area (i.e. Corps reservoir) in the Great Lakes and Ohio River Division  Examine and select a lake, reservoir or series of lakes/reservoirs in the LRD AO (e.g. Harsha Lake) representing a variety of environmental conditions, including water bodies with potential nutrient loading that may be vulnerable to Harmful Algal Blooms (HABs) and will provide an appropriate study site for development and demonstration of water quality interpretation using remote sensing  Should we consider adding a 2nd site – are there any lakes/reservoirs nearby to Harsha that may have different/worse water quality conditions?  Is Harsha big enough to be covered by MERIS?
  • 29. CE-QUAL-W2 Modeling  Update Submitted by Jeff last time, no new info.  Inflow discrepancy issue unresolved
  • 30. DO Temperature Recovery Hypothesis. Date Year Days since Avg. temp. Avg. DO 11/4/2002 2002 0 14.1 0 11/12/2002 8 13.1 3.2 11/19/2002 15 11.9 3.9 11/26/2002 22 10.6 3.9 12/4/2002 30 8.6 5.7 16 No new developments y = -0.1825x + 14.397  14 12 10 DO or Temp Avg. temp. 8 Avg. DO 6 Linear (Avg. temp.) 4 Linear (Avg. DO) 2 0 y = 0.165x + 0.8655 0 10 20 30 40 Days since turnover Low DO Duration Hypothesis  No new developments
  • 31. Low DO Duration Hypothesis  No new developments data testDO4; set testDO1; title "MixedModel"; if yr<2001 then delete; if julD < 125 then delete; if julD > 250 then delete; If depth1 < 20 then delete; proc mixed data=testDO4; class yr depth1 julD; model mlnDO= yr julD yr*juld/outp=Mone; random depth1(yr); repeated julD/sub= depth1(yr); lsmeans yr*julD; run; proc print; run;
  • 32. January Sampling of GHG and nutrients at the lake
  • 33. FALL AND WINTER SAMPLING RESULTS- GHG CH4 Emission Variations Across FLUXES the Lake 250 10 μmol CH4 min-1 m-2 1 0.1 Below detection 0.01 0 5 10 15 km from mouth of stream N2O Emission Variations Across 150 the Lake μg N2O-N m-2 h-1 100 October December 50 0 0 5 10 15 km from mouth of stream Sampling shows that just after fall CO2 Emission Variations Across turnover, GHG fluxes were very high 600 the Lake and detected at all points on the lake. μg CO2-N m-2 h-1 500 October 400 In the winter, GHG fluxes were still December 300 200 detected but at overall lower levels. 100 0 0 5 10 15 km from mouth of stream
  • 34. TIPPING POINT RESEARCH – CHUCK, HEATHER, ERIC, ROY’S WORK Trying to establish good sites for using metagenomic approaches to fish population health indicators, Looking for sites to represent significant gradients for ecological tipping point analyses/research.
  • 35.
  • 36.
  • 37.
  • 39. Next Meeting Date: January 19th, 2012 (Provided that Hannah can get us a place and be in attendance,) We’ll focus on 2012 monitoring program adjustments. I’ll try to have 2011 loading estimates compiled, please send me update materials for inclusion in the meeting slidedeck by COB Tuesday before the meeting. *The ideas and opinions expressed herein are those of the primary author and do not reflect official EPA position or policy. January 19, 2011