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Physic Behavior of Materials 
During Reduction at High 
Temperature
Introduction 
 The behavior of materials from the time 
these are charged on is of direct interest in 
assessing the blast furnace operation. 
 During this process material may 
disintegrate by any one or more of the 
following; 
 Decrepitation 
 Low temperature breakdown under 
reducing condition
Introduction 
 Failure under overlying load at high 
temperature 
 Swelling at high temperature under reducing 
condition 
 premature softening of materials 
 Tests are developed to measure the tendency 
of burden materials to degradation
Decrepitation 
 When iron bearing materials are suddenly 
exposed to exhaust gas temperature on 
charging ,breakdown may occur due to thermal 
shocks. It is known as decrepitation. 
 In a typical test 500g of 20-40mm size undried 
ore is dropped in a furnace previously heated to 
400C and retained there for 30 mints under a 
flow rate of 5000L of nitrogen per hour. 
 The sample is then cooled and the %age of 
0.5mm and-506 + 0.5 in the product is 
determined by sieving.
Low Temperature Breakdown Test 
 It has been observed that iron bearing 
materials do disintegrate at low temperature 
under mildly reducing conditions ,it is due to 
the presence of micro cracks. 
 The consists of subjecting the charge to static 
bed reduction at low temperature in a 
rotating furnace for a fixed duration. 
 The %age of fines generated is quoted as L 
.T .B . T. index
Swelling 
 Pellets show a maxima in their volume change 
with increasing degree of reduction .It is due to 
swelling . It also troubles the furnace operation. 
 Swelling can be measured for individual particles 
but bulk swelling data is of practical use. 
 Their apparent volume is measured by 
immersion in mercury . then samples are 
reduced to different degrees of reduction in a 
static bed under following conditions;
Swelling 
 Temperature 1000C 
 Reducing gas 40% CO and 60% N2 
 Gas flow 1000 liters/min 
 Pre heating under nitrogen 
atmosphere 
 The %age reduction is ascertained from the 
%age weight loss or chemical analysis
Hot Compression Test 
 The compression strength of burden 
materials falls rapidly with increasing 
temperature. 
 Materials with low hot compression strength 
would breakdown under load in the lower 
part of the furnace stack and affect the 
permeability. 
 The hot compression strength can be 
measured in a compression testing machine
MUHAMMAD SHAFQAT 
MME-10M -11
MUHAMMAD SHAFQAT 
MME-10M -11

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Physical behavior of materials during reduction at high temperature

  • 1. Physic Behavior of Materials During Reduction at High Temperature
  • 2. Introduction  The behavior of materials from the time these are charged on is of direct interest in assessing the blast furnace operation.  During this process material may disintegrate by any one or more of the following;  Decrepitation  Low temperature breakdown under reducing condition
  • 3. Introduction  Failure under overlying load at high temperature  Swelling at high temperature under reducing condition  premature softening of materials  Tests are developed to measure the tendency of burden materials to degradation
  • 4. Decrepitation  When iron bearing materials are suddenly exposed to exhaust gas temperature on charging ,breakdown may occur due to thermal shocks. It is known as decrepitation.  In a typical test 500g of 20-40mm size undried ore is dropped in a furnace previously heated to 400C and retained there for 30 mints under a flow rate of 5000L of nitrogen per hour.  The sample is then cooled and the %age of 0.5mm and-506 + 0.5 in the product is determined by sieving.
  • 5. Low Temperature Breakdown Test  It has been observed that iron bearing materials do disintegrate at low temperature under mildly reducing conditions ,it is due to the presence of micro cracks.  The consists of subjecting the charge to static bed reduction at low temperature in a rotating furnace for a fixed duration.  The %age of fines generated is quoted as L .T .B . T. index
  • 6. Swelling  Pellets show a maxima in their volume change with increasing degree of reduction .It is due to swelling . It also troubles the furnace operation.  Swelling can be measured for individual particles but bulk swelling data is of practical use.  Their apparent volume is measured by immersion in mercury . then samples are reduced to different degrees of reduction in a static bed under following conditions;
  • 7. Swelling  Temperature 1000C  Reducing gas 40% CO and 60% N2  Gas flow 1000 liters/min  Pre heating under nitrogen atmosphere  The %age reduction is ascertained from the %age weight loss or chemical analysis
  • 8. Hot Compression Test  The compression strength of burden materials falls rapidly with increasing temperature.  Materials with low hot compression strength would breakdown under load in the lower part of the furnace stack and affect the permeability.  The hot compression strength can be measured in a compression testing machine