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Chemistry of Food
Composition
Chapter 3
Lecture Topics
• Water
• Carbohydrates
• Lipids
• Proteins
• Vitamins
• Minerals
• Nonnutritive food components
Basic Food Chemistry
• All foods, including people, consist of one or more of six basic
nutrient groups (CHNOPS):
• Carbon
• Hydrogen
• Nitrogen
• Oxygen
• Phosphorus
• Sulfur
Elements combine to form molecules or compounds
• Molecule: a unit composed of one or more types of atoms held
together by chemical bonds
• Compound: a substance whose molecules consist of unlike
atoms
Basic Food Chemistry
Basic Food Chemistry
Click on the
movie Icon
Water
• Water content in foods
• Foods have water content of 0 to 95%
• Fruits and vegetables: 70 to 95% water
• Whole milk: 80% water
• Most meats: average just under 70%
• Least water: vegetable oils and dried foods such as grains and
beans
Water
Water
Water
• Freezing Point: The temperature at which a liquid changes to a
solid
• Solute: solid, liquid, or a gas compound dissolved in another
substance
• Melting Point: The temperature at which a solid changes to a
liquid state
• Boiling Point: The temperature at which a heated liquid begins to
boil and changes to a gas.
• The boiling point of water is 212°F
Water
Water – Hard vs. Soft
• Minerals in water determine whether it is hard or soft
• Hard water contains greater concentration of calcium and magnesium
compounds
• Soft water has a higher sodium concentration
• Transfer medium for heat
• Acts as a solvent
• Important agent in chemical reactions
• Factor in perishability and preservation of food
Functions of Water
• Food preservation decreases microorganisms
• Dehydration occurs in warm temperatures; hydration in cool
temperatures
• Water activity (aw) determines how quickly food decays
• More water means quicker decay
• Solutes reduce water activity via osmosis
Water
Carbohydrates
• Sugars, starches, and fibers of food
• Mostly found in plants
• Made in plants during photosynthesis
• Milk is an animal food that contains the carbohydrate “lactose”
• Made up of carbon, hydrogen, and oxygen
Carbohydrates
• Glucose: starch and sugar; called dextrose when refined
• Fructose (fruit sugar)
• Galactose: rare in nature; part of lactose
Carbohydrates: Monosacharides
• Sucrose: table sugar
• One glucose and one fructose molecule
• Lactose: milk sugar; not digestible by some
• One glucose and one galactose molecule
• Maltose: malt sugar; found in beer, cereal, some infant formulas
• Two glucose molecules linked together
Carbohydrates: Disaccharides
Carbohydrates
• Starch
• Amylose and amylopectin
• Stored energy for plants
• Digestible by humans
• Glycogen
• Stored energy for animals
• Digestible by humans
• Turned into lactic acid during slaughter
Carbohydrates: Polysaccharides
Carbohydrates
• Undigestible by humans
• Only found in plant-originated food
• Soluble fiber vs. insoluble fiber
• Cellulose
• Hemicelluloses
• Pectic substances
• Others (vegetable gums, inulin, lignin)
Carbohydrates: Fiber
Lipids: Fats vs. Oils
• Fats are solid at room temperature
• Oils are liquid at room temperature
• Fats are usually derived from animal sources
• Oils are derived predominantly from plants
• Animal sources include:
• Meats, poultry, and dairy products
• Plant food sources include:
• Nuts, seeds, avocado, olives, and coconut
Foods High in Lipids
Triglycerides
• Three fatty acids attached to a glycerol molecule
• 95% of lipids in foods
Fatty acids
• Length determined by number of carbon atoms
• Saturation determined by number of double bonds between carbon
atoms
• Saturation = no double bonds
Lipids (Fats)
Lipids (Fats)
• Contains phosphorus, which makes them water soluble
• Used as emulsifiers (e.g., lecithin)
• Emulsifier: compound that possesses both water-loving and
water-fearing properties so that it disperses in either water or oil
Phospholipids
Proteins
• Contain nitrogen
• Made from amino acids
• There are twenty-two amino acids
• Nine are essential (must be obtained by diet)
• Complete vs. incomplete proteins
• Most animal proteins are complete
• Most plant proteins are incomplete (protein complementation)
• Hydration
• Denaturation/coagulation
• Enzymatic reactions
• Buffering
• Browning
Functions of Proteins in Food
Vitamins and Minerals
• Vitamins
• Organic (carbon-containing)
• Can be destroyed by heat, light, or oxygen
• No kcalories
• Minerals
• Nonorganic; found on periodic table
• Cannot be destroyed by heat, light, or oxygen
• No kcalories
• Enrichment and fortification
• Enriched: modified by the addition of certain nutrients in order to
replace those lost during processing (refers to refined grain products)
• Fortified: modified by the addition of nutrients that were not present in
the original food
• Antioxidants
• Sodium: preservation, flavoring
Functions of Vitamins and Minerals
Vitamins
Water Soluble Fat Soluble
B complex: Vitamin A
Thiamin (B1) Vitamin D
Riboflavin (B2) Vitamin E
Vitamin B6(pyridoxine) Vitamin K
Vitamin B12(cobalamin)
Niacin
Folate
Pantothenic acid
Biotin
Ascorbic acid (vitamin C)
TABLE 3-6 Major Vitamins and Minerals in Foods Vitamins
Minerals
Macrominerals (minerals present in the
body in relatively large amounts)
Microminerals (minerals present in the
body in relatively small amounts)
Calcium (Ca) Iron (Fe)
Phosphorous (P) Zinc (Zn)
Potassium (P) Selenium (Se)
Sulfur (S) Manganese (Mn)
Sodium (Na) Copper (Cu)
Chlorine (Cl) Iodine (I)
Magnesium (Mg) Molybdenum (Mo)
Chromium (Cr)
Fluorine (F)
TABLE 3-6 Major Minerals in Foods
• Food additive: any substance added to foods
• Over 3,000 food additives, including:
• Sugar
• Salt
• Corn syrup
Nonnutritive Food Components
• Improve appeal
• Color compounds, natural colors, flavor compounds, texture
compounds
• Extend storage life
• BHA and BHT
• Maximize performance
• Protect nutrient value
Purpose of Food Additives
Plant compounds:
• Beneficial
• Phytochemicals: a nonnutritive “chemical” in plants that is considered
beneficial to health
• Harmful
• Natural toxins
• Caffeine in excess
• Caffeine
• Natural stimulant
Nonnutritive Food Components
Nonnutritive Food Components
Phytochemical Family Major Food Sources
Allyl sulfides Onions, garlic, leeks, chives
Carotenoids Yellow and orange vegetables and fruits; dark green, leafy vegetables
Flavonoids Most fruits and vegetables
Indoles Cruciferous vegetables (broccoli, cabbage, kale, cauliflower, etc.)
Isoflavones Soybeans (tofu, soy milk)
Isothiocyanates Cruciferous vegetables
Limonoids Citrus fruits
Lycopene Tomatoes, red grapefruit
Phenols Nearly all fruits and vegetables
Phenolic acids Tomatoes, citrus fruits, carrots, whole grains, nuts
Plant sterols Broccoli, cabbage, cucumbers, squash, yams, tomatoes, eggplant, peppers, soy products, whole grains
Polyphenols Green tea, grapes, wine
Saponins Beans and legumes
Terpenes Cherries, citrus fruit pee
TABLE 3-8 Phytochemicals: Potential Cancer Protectors
End of Chapter 3
Chemistry of Food

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Chemistry of food 3

  • 2. Lecture Topics • Water • Carbohydrates • Lipids • Proteins • Vitamins • Minerals • Nonnutritive food components
  • 3. Basic Food Chemistry • All foods, including people, consist of one or more of six basic nutrient groups (CHNOPS): • Carbon • Hydrogen • Nitrogen • Oxygen • Phosphorus • Sulfur
  • 4. Elements combine to form molecules or compounds • Molecule: a unit composed of one or more types of atoms held together by chemical bonds • Compound: a substance whose molecules consist of unlike atoms Basic Food Chemistry
  • 6. Click on the movie Icon Water
  • 7. • Water content in foods • Foods have water content of 0 to 95% • Fruits and vegetables: 70 to 95% water • Whole milk: 80% water • Most meats: average just under 70% • Least water: vegetable oils and dried foods such as grains and beans Water
  • 10. • Freezing Point: The temperature at which a liquid changes to a solid • Solute: solid, liquid, or a gas compound dissolved in another substance • Melting Point: The temperature at which a solid changes to a liquid state • Boiling Point: The temperature at which a heated liquid begins to boil and changes to a gas. • The boiling point of water is 212°F Water
  • 11. Water – Hard vs. Soft • Minerals in water determine whether it is hard or soft • Hard water contains greater concentration of calcium and magnesium compounds • Soft water has a higher sodium concentration
  • 12. • Transfer medium for heat • Acts as a solvent • Important agent in chemical reactions • Factor in perishability and preservation of food Functions of Water
  • 13. • Food preservation decreases microorganisms • Dehydration occurs in warm temperatures; hydration in cool temperatures • Water activity (aw) determines how quickly food decays • More water means quicker decay • Solutes reduce water activity via osmosis Water
  • 14. Carbohydrates • Sugars, starches, and fibers of food • Mostly found in plants • Made in plants during photosynthesis • Milk is an animal food that contains the carbohydrate “lactose” • Made up of carbon, hydrogen, and oxygen
  • 16. • Glucose: starch and sugar; called dextrose when refined • Fructose (fruit sugar) • Galactose: rare in nature; part of lactose Carbohydrates: Monosacharides
  • 17. • Sucrose: table sugar • One glucose and one fructose molecule • Lactose: milk sugar; not digestible by some • One glucose and one galactose molecule • Maltose: malt sugar; found in beer, cereal, some infant formulas • Two glucose molecules linked together Carbohydrates: Disaccharides
  • 19. • Starch • Amylose and amylopectin • Stored energy for plants • Digestible by humans • Glycogen • Stored energy for animals • Digestible by humans • Turned into lactic acid during slaughter Carbohydrates: Polysaccharides
  • 21. • Undigestible by humans • Only found in plant-originated food • Soluble fiber vs. insoluble fiber • Cellulose • Hemicelluloses • Pectic substances • Others (vegetable gums, inulin, lignin) Carbohydrates: Fiber
  • 22. Lipids: Fats vs. Oils • Fats are solid at room temperature • Oils are liquid at room temperature • Fats are usually derived from animal sources • Oils are derived predominantly from plants
  • 23. • Animal sources include: • Meats, poultry, and dairy products • Plant food sources include: • Nuts, seeds, avocado, olives, and coconut Foods High in Lipids
  • 24. Triglycerides • Three fatty acids attached to a glycerol molecule • 95% of lipids in foods Fatty acids • Length determined by number of carbon atoms • Saturation determined by number of double bonds between carbon atoms • Saturation = no double bonds Lipids (Fats)
  • 26. • Contains phosphorus, which makes them water soluble • Used as emulsifiers (e.g., lecithin) • Emulsifier: compound that possesses both water-loving and water-fearing properties so that it disperses in either water or oil Phospholipids
  • 27. Proteins • Contain nitrogen • Made from amino acids • There are twenty-two amino acids • Nine are essential (must be obtained by diet) • Complete vs. incomplete proteins • Most animal proteins are complete • Most plant proteins are incomplete (protein complementation)
  • 28. • Hydration • Denaturation/coagulation • Enzymatic reactions • Buffering • Browning Functions of Proteins in Food
  • 29. Vitamins and Minerals • Vitamins • Organic (carbon-containing) • Can be destroyed by heat, light, or oxygen • No kcalories • Minerals • Nonorganic; found on periodic table • Cannot be destroyed by heat, light, or oxygen • No kcalories
  • 30. • Enrichment and fortification • Enriched: modified by the addition of certain nutrients in order to replace those lost during processing (refers to refined grain products) • Fortified: modified by the addition of nutrients that were not present in the original food • Antioxidants • Sodium: preservation, flavoring Functions of Vitamins and Minerals
  • 31. Vitamins Water Soluble Fat Soluble B complex: Vitamin A Thiamin (B1) Vitamin D Riboflavin (B2) Vitamin E Vitamin B6(pyridoxine) Vitamin K Vitamin B12(cobalamin) Niacin Folate Pantothenic acid Biotin Ascorbic acid (vitamin C) TABLE 3-6 Major Vitamins and Minerals in Foods Vitamins
  • 32. Minerals Macrominerals (minerals present in the body in relatively large amounts) Microminerals (minerals present in the body in relatively small amounts) Calcium (Ca) Iron (Fe) Phosphorous (P) Zinc (Zn) Potassium (P) Selenium (Se) Sulfur (S) Manganese (Mn) Sodium (Na) Copper (Cu) Chlorine (Cl) Iodine (I) Magnesium (Mg) Molybdenum (Mo) Chromium (Cr) Fluorine (F) TABLE 3-6 Major Minerals in Foods
  • 33. • Food additive: any substance added to foods • Over 3,000 food additives, including: • Sugar • Salt • Corn syrup Nonnutritive Food Components
  • 34. • Improve appeal • Color compounds, natural colors, flavor compounds, texture compounds • Extend storage life • BHA and BHT • Maximize performance • Protect nutrient value Purpose of Food Additives
  • 35. Plant compounds: • Beneficial • Phytochemicals: a nonnutritive “chemical” in plants that is considered beneficial to health • Harmful • Natural toxins • Caffeine in excess • Caffeine • Natural stimulant Nonnutritive Food Components
  • 36. Nonnutritive Food Components Phytochemical Family Major Food Sources Allyl sulfides Onions, garlic, leeks, chives Carotenoids Yellow and orange vegetables and fruits; dark green, leafy vegetables Flavonoids Most fruits and vegetables Indoles Cruciferous vegetables (broccoli, cabbage, kale, cauliflower, etc.) Isoflavones Soybeans (tofu, soy milk) Isothiocyanates Cruciferous vegetables Limonoids Citrus fruits Lycopene Tomatoes, red grapefruit Phenols Nearly all fruits and vegetables Phenolic acids Tomatoes, citrus fruits, carrots, whole grains, nuts Plant sterols Broccoli, cabbage, cucumbers, squash, yams, tomatoes, eggplant, peppers, soy products, whole grains Polyphenols Green tea, grapes, wine Saponins Beans and legumes Terpenes Cherries, citrus fruit pee TABLE 3-8 Phytochemicals: Potential Cancer Protectors
  • 37. End of Chapter 3 Chemistry of Food