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WELDABILITY OF Ni & Ti ALLOYS
AND
SELECTION OF WELDING
PROCESS & PROCEDURE
Submitted by,
saroja.s
(ME , welding technology)
GCE,SALEM
 Nickel like copper, its FCC structure at all
temperature .
 Good corrosion resistance. its used food
processing plants ,chemical container and
other similar application.
 Nickel is used as alloying element to improve
mechanic properties.
 Resistant of oxidation in high temperature.
 Nickel melting point is 1453˚C.
 Nieq=%Ni+30*%C+0.5*%Mn.
Solid solution alloy:
 Ni-Cu=alloy 30-45%Cu its monel.
 Ni-Cr=16-20%Cr its nichrome.
 Ni-Fe-Cr=20-25%Ni,13-22%Cr,Fe-bal its INCONEL
 Ni-Mo=16-28%Mo,less % of Cr&Ni.
Precipitation hardening:
 Ni-cu.66.5%Ni,29.5%Cu monel
 Ni-Cr.76%Ni,19.5%Cr nichrome
 Ni-Fe-Cr. 73%Ni,15.5%Cr,7%Fe inconel
Solid Solution
Nickel - Copper
• Resistance to Sea Water
• Naval Application, Chlorination Plants, Water meter parts, pump
shafts, feed water heaters
Nickel-Chromium
• Corrosion Resistance at Elevated Temp
• Furnace muffles, heat treating equipment, nuclear steam tubing, heat
exchangers, aircraft engine components
Nickel-Iron-Chromium
• High Temp Strength, Resistance to Oxidation
• Heat exchangers, carburizing fixtures, pickling tank heaters, spent
nuclear fuel element recovery, hydrofluoric acid production
Nickel-Molybdenum
• Low temp corrosion resistance, some acids
• Cryogenic Service
Precipitation-hardening
Nickel-Copper Alloys
• Resistant to Sea Water, Chlorine
• Pump shafts, impellers, oil well drill collars, electronic components,
springs
•Sensitive to strain age cracking
Nickel-Chromium
• Good high temp oxidation
• Gas turbine components
Nickel-Iron-Chromium
• Forging applications
Phase diagram of Ni-Cu
MONEL AND INCONEL:
WELDING PROCESS:TIG,MIG,SMAW,elactron beam
PREHEAT: No
POST WELD: Necessary to avoid intergranular corrosion
REMARK: Good weldability
A=RECOMMENDED;C=POSSIBLY USABLE BUT NOT POPULAR
NO=NOT RECOMMENDED
proces
s
SMA
W
TIG PLAS
MA
SAW MIG FCAW
NICKEL A A A C A NO
INCON
EL
A A A NO A NO
MONEL A A A C A NO
GMAW techniques
 GMAW uses solid wires use for filler metal.
 The recommended polarity is DCEP with, normally,
constant-potential power sources.
 With a solid wire, the dominant mode of metal
transfer is spray transfer, but short circuiting and
globular welding are also widely employed
depending on the welding position and joint
thickness.
 For shielding the weld zone, shielding normally
use argon or argon mixed with helium.
 Ni & its alloy are used in coin.
 Chemical plant , heat exchanger , reaction
furnace are used
 Turbine blades,bumper , cutting tool
Imperfection:
Porosity
Lack of inter run fusion
Weld metal solidification cracking
Precaution:
Post weld heat treatment
 Pure Ti low tensile strength but excellent
ductility
 High strength to weight ratio compare to Al
 Suitable alloys added properties can
increased
 Above 650℃ reduce oxidation resistance
 Low thermal expansion & thermal
conductivity.
 Room temp , HCS called alpha phase. above
the 883℃ beta phase in BCC.
 Melting point is 1670 ℃
Ti phase diagram
Designation Commerically Medium
Pure Titanium Strength
Alloys
Alloy Type Alpha Alpha-Beta
0.2% Proof Stress MPa 345 - 480 480 – 550
Tensile Strength MPa 480 - 620 600 – 650
Elongation % 20 - 25 15 -20
Tensile Modulus GPa 103 104
Torosion Modulus Gpa 45 43
Hardness HV 160 - 220 200 - 280
Density kg/1 4.51 4.48 - 4.51
Thermal Expansion 10-6/ºC 8.9 8.3
Conductivity W/mK 22 8.0
Specific Heat J/kg/ºC 525 544
Properties of Ti
 i) commercially pure titanium
 Ii) alpha and near alpha alloy
 Iii) alpha- beta alloy
 Iv) beta alloy
 pure Ti 98.5 to 99 %Ti
 pure Ti has moderate strength but good
ductility. Its has good corrosion resistance,
formability , weldability
 Very important to maintain iron content
below 0.05%
 Use low iron content filler wire , avoid steel
brushes
 Weld in annealed condition . because stress
relieved , not need in after welding
Alpha Ti
 similar to pure Ti.
 alpha alloys and near alpha alloys have good
weldability because of there good ductility.
 The strength of cold worked material in the HAZ
is decreased as a result of heating.
 Therefore alloy are normally weld in annealed
condition
 Its has higher strength at elevated temperature
 Near alpha alloy:
 Its excellent creep strength at elevated
temperature
 they are weldable but residual stress can be
high
 therefore stress relieving of weldment is
always recommended.
 Iron contamination degrades creep strength
and should be avoided
Beta +alpha Ti:
 Ti-6Al-4V alloy has the best weldability
 Ti-10V-2Fe-3Al has good weldability
because it is highly beta stabilized and fine
grain size during welding
 Annealing temp 750-790℃
Beta alloy:
 Beta alloy weldable in either annealed or the
heat treated condition
 Weld joints have good ductility but relatively
low strength.
α & pure Ti:
WELDING PROCESS:TIG,MIG, electron beam,resistance, flash
butt.
PREHEAT: weld in annealed condition
POST WELD: stress relief 400-650⁰ C
REMARK: highly reactive requires good shielding. No filler is
used below 2.5mm thickness, otherwise parent metal or
commercial purity titanium is used
(α+β)Ti:
WELDING PROCESS:TIG, electron beam, resistance, flash butt
PREHEAT: No
POSTWELD: 2hours at 538⁰ C complete aging during stress
relief
A=RECOMMENDED;C=POSSIBLY USABLE BUT NOT POPULAR
NO=NOT RECOMMENDED
PROCESS SMAW TIG PLASMA SMA MIG FCAW
Ti & its
alloy
NO A A NO A NO
Beta Ti:
Process : electron beam , resistance, flash butt
Preheat: weld in annealed condition
Post weld heat : -
Remark : not recommended
 major problem with Ti weldments Is porosity.
 It is a persistent problem and mostly it is caused
by gas bubbles formed during solidification of
weld metal.
 Oxidation form.
 Other variables affecting porosity in Ti welds:
 Heat input
 Cooling rare
 Welding speed
 Arc voltage
 Shielding gas flow rate
 i) ASM handbook vol 6A-welding fundamental
and process
 Ii) Nadkarni .S.V. modern arc welding
technology
 Iii)Dr.R.S.parmar: welding engineering and
technology
Weldability of ni & ti alloys

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Weldability of ni & ti alloys

  • 1. WELDABILITY OF Ni & Ti ALLOYS AND SELECTION OF WELDING PROCESS & PROCEDURE Submitted by, saroja.s (ME , welding technology) GCE,SALEM
  • 2.  Nickel like copper, its FCC structure at all temperature .  Good corrosion resistance. its used food processing plants ,chemical container and other similar application.  Nickel is used as alloying element to improve mechanic properties.  Resistant of oxidation in high temperature.  Nickel melting point is 1453˚C.  Nieq=%Ni+30*%C+0.5*%Mn.
  • 3.
  • 4.
  • 5.
  • 6. Solid solution alloy:  Ni-Cu=alloy 30-45%Cu its monel.  Ni-Cr=16-20%Cr its nichrome.  Ni-Fe-Cr=20-25%Ni,13-22%Cr,Fe-bal its INCONEL  Ni-Mo=16-28%Mo,less % of Cr&Ni. Precipitation hardening:  Ni-cu.66.5%Ni,29.5%Cu monel  Ni-Cr.76%Ni,19.5%Cr nichrome  Ni-Fe-Cr. 73%Ni,15.5%Cr,7%Fe inconel
  • 7. Solid Solution Nickel - Copper • Resistance to Sea Water • Naval Application, Chlorination Plants, Water meter parts, pump shafts, feed water heaters Nickel-Chromium • Corrosion Resistance at Elevated Temp • Furnace muffles, heat treating equipment, nuclear steam tubing, heat exchangers, aircraft engine components Nickel-Iron-Chromium • High Temp Strength, Resistance to Oxidation • Heat exchangers, carburizing fixtures, pickling tank heaters, spent nuclear fuel element recovery, hydrofluoric acid production Nickel-Molybdenum • Low temp corrosion resistance, some acids • Cryogenic Service
  • 8. Precipitation-hardening Nickel-Copper Alloys • Resistant to Sea Water, Chlorine • Pump shafts, impellers, oil well drill collars, electronic components, springs •Sensitive to strain age cracking Nickel-Chromium • Good high temp oxidation • Gas turbine components Nickel-Iron-Chromium • Forging applications
  • 10.
  • 11.
  • 12.
  • 13. MONEL AND INCONEL: WELDING PROCESS:TIG,MIG,SMAW,elactron beam PREHEAT: No POST WELD: Necessary to avoid intergranular corrosion REMARK: Good weldability A=RECOMMENDED;C=POSSIBLY USABLE BUT NOT POPULAR NO=NOT RECOMMENDED proces s SMA W TIG PLAS MA SAW MIG FCAW NICKEL A A A C A NO INCON EL A A A NO A NO MONEL A A A C A NO
  • 14. GMAW techniques  GMAW uses solid wires use for filler metal.  The recommended polarity is DCEP with, normally, constant-potential power sources.  With a solid wire, the dominant mode of metal transfer is spray transfer, but short circuiting and globular welding are also widely employed depending on the welding position and joint thickness.  For shielding the weld zone, shielding normally use argon or argon mixed with helium.
  • 15.
  • 16.
  • 17.  Ni & its alloy are used in coin.  Chemical plant , heat exchanger , reaction furnace are used  Turbine blades,bumper , cutting tool Imperfection: Porosity Lack of inter run fusion Weld metal solidification cracking Precaution: Post weld heat treatment
  • 18.  Pure Ti low tensile strength but excellent ductility  High strength to weight ratio compare to Al  Suitable alloys added properties can increased  Above 650℃ reduce oxidation resistance  Low thermal expansion & thermal conductivity.  Room temp , HCS called alpha phase. above the 883℃ beta phase in BCC.  Melting point is 1670 ℃
  • 19.
  • 21. Designation Commerically Medium Pure Titanium Strength Alloys Alloy Type Alpha Alpha-Beta 0.2% Proof Stress MPa 345 - 480 480 – 550 Tensile Strength MPa 480 - 620 600 – 650 Elongation % 20 - 25 15 -20 Tensile Modulus GPa 103 104 Torosion Modulus Gpa 45 43 Hardness HV 160 - 220 200 - 280 Density kg/1 4.51 4.48 - 4.51 Thermal Expansion 10-6/ºC 8.9 8.3 Conductivity W/mK 22 8.0 Specific Heat J/kg/ºC 525 544 Properties of Ti
  • 22.  i) commercially pure titanium  Ii) alpha and near alpha alloy  Iii) alpha- beta alloy  Iv) beta alloy
  • 23.  pure Ti 98.5 to 99 %Ti  pure Ti has moderate strength but good ductility. Its has good corrosion resistance, formability , weldability  Very important to maintain iron content below 0.05%  Use low iron content filler wire , avoid steel brushes  Weld in annealed condition . because stress relieved , not need in after welding
  • 24. Alpha Ti  similar to pure Ti.  alpha alloys and near alpha alloys have good weldability because of there good ductility.  The strength of cold worked material in the HAZ is decreased as a result of heating.  Therefore alloy are normally weld in annealed condition  Its has higher strength at elevated temperature
  • 25.  Near alpha alloy:  Its excellent creep strength at elevated temperature  they are weldable but residual stress can be high  therefore stress relieving of weldment is always recommended.  Iron contamination degrades creep strength and should be avoided
  • 26. Beta +alpha Ti:  Ti-6Al-4V alloy has the best weldability  Ti-10V-2Fe-3Al has good weldability because it is highly beta stabilized and fine grain size during welding  Annealing temp 750-790℃ Beta alloy:  Beta alloy weldable in either annealed or the heat treated condition  Weld joints have good ductility but relatively low strength.
  • 27. α & pure Ti: WELDING PROCESS:TIG,MIG, electron beam,resistance, flash butt. PREHEAT: weld in annealed condition POST WELD: stress relief 400-650⁰ C REMARK: highly reactive requires good shielding. No filler is used below 2.5mm thickness, otherwise parent metal or commercial purity titanium is used (α+β)Ti: WELDING PROCESS:TIG, electron beam, resistance, flash butt PREHEAT: No POSTWELD: 2hours at 538⁰ C complete aging during stress relief
  • 28. A=RECOMMENDED;C=POSSIBLY USABLE BUT NOT POPULAR NO=NOT RECOMMENDED PROCESS SMAW TIG PLASMA SMA MIG FCAW Ti & its alloy NO A A NO A NO Beta Ti: Process : electron beam , resistance, flash butt Preheat: weld in annealed condition Post weld heat : - Remark : not recommended
  • 29.
  • 30.  major problem with Ti weldments Is porosity.  It is a persistent problem and mostly it is caused by gas bubbles formed during solidification of weld metal.  Oxidation form.  Other variables affecting porosity in Ti welds:  Heat input  Cooling rare  Welding speed  Arc voltage  Shielding gas flow rate
  • 31.  i) ASM handbook vol 6A-welding fundamental and process  Ii) Nadkarni .S.V. modern arc welding technology  Iii)Dr.R.S.parmar: welding engineering and technology