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THERMOCHEMICAL EQUATION
CALORIMETRY
HESS’ LAW
THERMO
CHEMISTRYANJ CASTILLO // ST. AGATHA
HEATS OF FORMATION,
Hf, represents an equation in which one
mole of product is made from elements.
4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ
The equation shows the formation of
aluminum oxide from the pure elements. Re-
write it such that only one mole of
aluminum oxide is produced.
4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ_ __ __
2 2 2
2 Al (s) + 3/2 O2 (g) -> Al2O3 (s) q = -3400 kJ
Calculate the het of this new reaction and
restart is ass enthalpy, the energy
absorbed/released per mole of reaction.
2 Al (s) + 3/2 O2 (g) -> Al2O3 (s) q = -3400 kJ
4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ
Hf = -1700
Determine H 25 C for the reaction:
2 FeO2 (g) + ½ O2 -> Fe2O3 (S)
Fe (s) + ½ O2 (g) -> FeO H 25 C = -272.0 kJ
2 Fe (s) + 3/2 O2 (g) -> Fe2O3 H 25 C = -825 kJ
Eq. 1
Eq. 2
Eq. (1)’: 2 FeO (s) -> 2 Fe + O2 (g)
H 25 C = -[2(-272.0 kJ)] = 544 kJ
THANK
YOU

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Thermochemistry

  • 2.
  • 3.
  • 4.
  • 5. HEATS OF FORMATION, Hf, represents an equation in which one mole of product is made from elements. 4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ
  • 6. The equation shows the formation of aluminum oxide from the pure elements. Re- write it such that only one mole of aluminum oxide is produced. 4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ_ __ __ 2 2 2 2 Al (s) + 3/2 O2 (g) -> Al2O3 (s) q = -3400 kJ
  • 7. Calculate the het of this new reaction and restart is ass enthalpy, the energy absorbed/released per mole of reaction. 2 Al (s) + 3/2 O2 (g) -> Al2O3 (s) q = -3400 kJ 4 Al (s) + 3 O2 (g) -> 2 Al2O3 (s) q = -3400 kJ Hf = -1700
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15. Determine H 25 C for the reaction: 2 FeO2 (g) + ½ O2 -> Fe2O3 (S) Fe (s) + ½ O2 (g) -> FeO H 25 C = -272.0 kJ 2 Fe (s) + 3/2 O2 (g) -> Fe2O3 H 25 C = -825 kJ
  • 16. Eq. 1 Eq. 2 Eq. (1)’: 2 FeO (s) -> 2 Fe + O2 (g) H 25 C = -[2(-272.0 kJ)] = 544 kJ