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CERAMICS
Basic Industrial Processes
Aslı Erdiller
Outline
 Ceramics
 Nature and Structure
 Ceramic Products
 Design of a Ceramic
 Processing of a Ceramics
Ceramics
 Ceramics, by definition, comprise inorganic, non-
metallic, non-water-soluble compounds that show
ionic contributions in their chemical bonds.
 HIGH
 hardness, heat resistance, corrosion resistance
 LOW
 electrical and thermal conductivity, ductility,
fracture toughness
Ceramics
 Hard, brittle, high melting point materials
with low electrical and thermal
conductivity, low thermal expansion, good
chemical and thermal stability, good creep
resistance, high elastic modulus and high
compresive strengths.
Nature and Structure
 Compounds of metallic
and nonmetallic elements
(in forms of oxides,
carbides and nitrides)
 Exist in a wide variety of
compositions and forms
 Most have crystalline
structures (strong ionic or
covalent bonds)
Nature and Structure
 Absence of free electrons
makes ceramics poor
electrical conductors.
 High melting
temperatures.
 Noncrystalline structure
is also possible in solid
ceramics. This
amorphous condition is
called glassy state.
Sales
1993 sales
 glass and glass products 53%
 advanced ceramic materials 20%
 whiteware products 9%
 porcelain enameled products 9%
 refactories 6%
 structural clay products 2%
Ceramic Products
Clay and Whiteware
Products
 Ex: brick, roof and
structural tiles,
drainage and sewer
pipe, sanitory ware,
dinnerware, china,
decorative floor and
wall tile, pottery and
other artware.
Ceramic Products
Clay and Whiteware
Products
 Ex: brick, roof and
structural tiles,
drainage and sewer
pipe, sanitory ware,
dinnerware, china,
decorative floor and
wall tile, pottery and
other artware.
Ceramic Products
Refractory Materials
 are ceramics that have
been designed to provide
acceptable mechanical
and chemical properties
at high temperatures.
 Ex: bricks and shaped
products, bulk form for
coating, insulating
ceramic fibers.
Ceramic Products
Abrasives
(grinding)
Ceramics for
Electrical and
Magnetic
Applications
Ceramic Products
Glasses
 are amorphous solid form of
ceramics
 Ex: window glass,
containers, light bulbs, TV
and computer display tubes,
fiberglass insulation, glass
cookware, fiberoptic
communication.
Glass Ceramics
 recrystallite or vitrificated
glass
Ceramic Products
Cermets
 are combination of
metals and ceramics,
bonded together by
the procedures of
powder metallurgy.
Structural Ceramics
 mechanical
application
Advanced Ceramics
 This new class of ceramic materials will
have the high-temperature stability,
corrosion resistance, and toughness
necessary for a wide range of applications.
They also can provide substantial energy,
environmental, and economical benefits,
including lower maintenance, higher
efficiency, and decreased operating costs.
Advanced Ceramics
 Advanced ceramics can be used in the chemicals,
aluminum, metal casting, forest products, glass,
petroleum refining, and steel industries, to name a
few. Uses for advanced ceramic components
include: diesel engine exhaust valves; IR burners;
heat exchanger tubes; hot gas filters; gas turbine
combustor liners and shrouds; and combustion
components for small stationary gas turbines[10].
Design of a Ceramic
 Because of their properties - their inherent
brittleness; inability to yield, change shape, or
plastically deform; sensitivity to defects;
tendency to break at any point of high stress
concentration; microstructures, which possess
flaws that can cause failure without being
detected beforehand-ceramics require a design
model that calls for greater degrees of accuracy in
the design and manufacture of ceramic parts.
Design of a Ceramic
 Anyone who has experienced breaking a piece of
glass will know about the sensitivity of brittle
materials to defects. A slight scratch on the
surface of the glass and a small bending force to
produce a tensile stress are all that is needed to
break a relatively thick piece of glass. This flaw
sensitivity means that a ceramic cannot be
considered as having only one strength but rather,
a distribution of strengths, depending on the flaws
in the material that were added during processing,
final machining, or testing, or while in service.
Processing of a Ceramic
 Five main steps in the manual
production process:
1. Preparation , including Clay
Fermentation, Clay Kneading
2. Molding
Processing of a Ceramic
3. Making up that can be separated
into 3 kinds: Scratching, Fretwork,
and Molding with liquid clay.
4. Drying: Natural drying takes 15-30
days in Summer and more than 30
days in Rainy Season.
Processing of a Ceramic
5. Firing: It can be separated into 3
levels of fire: Low Fire (200-300ºC),
Middle Fire (300-900ºC), High Fire
(900-1,300ºC). After the pottery has
been sufficiently air-dried, it will be
fired in a kiln using the traditional
firewood method.
Processing of a Ceramic
A three-step firing method is applied
starting with a low firing of 400ºC for
12 hours, followed by a 900ºC
setting for another six hours, and
then a 1000ºC setting for another six
hours to achieve an antique finish. If
the buyer requires a dark red finish,
the final stage of firing will be
increased to 1280 ºC.
Processing of a Ceramic
 New processes and advances in forming
and manufacturing techniques introduced
in recent years have led to the development
of advanced ceramics with the properties
and application potential to solve what
were once regarded as seemingly
impossible technical and engineering
challenges.
Processing of a Ceramic
 compaction of powder
 firing - applying heat (below melting
temperature) to achieve bonding of
particles, (reducing pore size) called
densification
 sintering - removal of pores and addition of
strong bonding forces that provides added
strength, but reduced size
Processing of a Ceramic
 The process by which progression was
measured took quite a long time to evolve.
In the beginning, the production was done
completely by hand. Today, that is no
longer so.
Thank you!

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Ceramics Industry.ppt

  • 2. Outline  Ceramics  Nature and Structure  Ceramic Products  Design of a Ceramic  Processing of a Ceramics
  • 3. Ceramics  Ceramics, by definition, comprise inorganic, non- metallic, non-water-soluble compounds that show ionic contributions in their chemical bonds.  HIGH  hardness, heat resistance, corrosion resistance  LOW  electrical and thermal conductivity, ductility, fracture toughness
  • 4. Ceramics  Hard, brittle, high melting point materials with low electrical and thermal conductivity, low thermal expansion, good chemical and thermal stability, good creep resistance, high elastic modulus and high compresive strengths.
  • 5. Nature and Structure  Compounds of metallic and nonmetallic elements (in forms of oxides, carbides and nitrides)  Exist in a wide variety of compositions and forms  Most have crystalline structures (strong ionic or covalent bonds)
  • 6. Nature and Structure  Absence of free electrons makes ceramics poor electrical conductors.  High melting temperatures.  Noncrystalline structure is also possible in solid ceramics. This amorphous condition is called glassy state.
  • 7. Sales 1993 sales  glass and glass products 53%  advanced ceramic materials 20%  whiteware products 9%  porcelain enameled products 9%  refactories 6%  structural clay products 2%
  • 8. Ceramic Products Clay and Whiteware Products  Ex: brick, roof and structural tiles, drainage and sewer pipe, sanitory ware, dinnerware, china, decorative floor and wall tile, pottery and other artware.
  • 9. Ceramic Products Clay and Whiteware Products  Ex: brick, roof and structural tiles, drainage and sewer pipe, sanitory ware, dinnerware, china, decorative floor and wall tile, pottery and other artware.
  • 10. Ceramic Products Refractory Materials  are ceramics that have been designed to provide acceptable mechanical and chemical properties at high temperatures.  Ex: bricks and shaped products, bulk form for coating, insulating ceramic fibers.
  • 12. Ceramic Products Glasses  are amorphous solid form of ceramics  Ex: window glass, containers, light bulbs, TV and computer display tubes, fiberglass insulation, glass cookware, fiberoptic communication. Glass Ceramics  recrystallite or vitrificated glass
  • 13. Ceramic Products Cermets  are combination of metals and ceramics, bonded together by the procedures of powder metallurgy. Structural Ceramics  mechanical application
  • 14. Advanced Ceramics  This new class of ceramic materials will have the high-temperature stability, corrosion resistance, and toughness necessary for a wide range of applications. They also can provide substantial energy, environmental, and economical benefits, including lower maintenance, higher efficiency, and decreased operating costs.
  • 15. Advanced Ceramics  Advanced ceramics can be used in the chemicals, aluminum, metal casting, forest products, glass, petroleum refining, and steel industries, to name a few. Uses for advanced ceramic components include: diesel engine exhaust valves; IR burners; heat exchanger tubes; hot gas filters; gas turbine combustor liners and shrouds; and combustion components for small stationary gas turbines[10].
  • 16.
  • 17. Design of a Ceramic  Because of their properties - their inherent brittleness; inability to yield, change shape, or plastically deform; sensitivity to defects; tendency to break at any point of high stress concentration; microstructures, which possess flaws that can cause failure without being detected beforehand-ceramics require a design model that calls for greater degrees of accuracy in the design and manufacture of ceramic parts.
  • 18. Design of a Ceramic  Anyone who has experienced breaking a piece of glass will know about the sensitivity of brittle materials to defects. A slight scratch on the surface of the glass and a small bending force to produce a tensile stress are all that is needed to break a relatively thick piece of glass. This flaw sensitivity means that a ceramic cannot be considered as having only one strength but rather, a distribution of strengths, depending on the flaws in the material that were added during processing, final machining, or testing, or while in service.
  • 19. Processing of a Ceramic  Five main steps in the manual production process: 1. Preparation , including Clay Fermentation, Clay Kneading 2. Molding
  • 20. Processing of a Ceramic 3. Making up that can be separated into 3 kinds: Scratching, Fretwork, and Molding with liquid clay. 4. Drying: Natural drying takes 15-30 days in Summer and more than 30 days in Rainy Season.
  • 21. Processing of a Ceramic 5. Firing: It can be separated into 3 levels of fire: Low Fire (200-300ºC), Middle Fire (300-900ºC), High Fire (900-1,300ºC). After the pottery has been sufficiently air-dried, it will be fired in a kiln using the traditional firewood method.
  • 22. Processing of a Ceramic A three-step firing method is applied starting with a low firing of 400ºC for 12 hours, followed by a 900ºC setting for another six hours, and then a 1000ºC setting for another six hours to achieve an antique finish. If the buyer requires a dark red finish, the final stage of firing will be increased to 1280 ºC.
  • 23. Processing of a Ceramic  New processes and advances in forming and manufacturing techniques introduced in recent years have led to the development of advanced ceramics with the properties and application potential to solve what were once regarded as seemingly impossible technical and engineering challenges.
  • 24. Processing of a Ceramic  compaction of powder  firing - applying heat (below melting temperature) to achieve bonding of particles, (reducing pore size) called densification  sintering - removal of pores and addition of strong bonding forces that provides added strength, but reduced size
  • 25. Processing of a Ceramic  The process by which progression was measured took quite a long time to evolve. In the beginning, the production was done completely by hand. Today, that is no longer so.
  • 26.
  • 27.
  • 28.
  • 29.