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RECENT TRENDS IN CHEMICAL ENGG.
AEROGEL
WHAT IS AN AEROGEL ? ? ?
• AEROGEL is essentially the solid
framework of a gel
• A class of porous, solid materials that
exhibit extreme material properties
• A Nanostructured Material with Fascinating
Properties and Unlimited Applications
HISTORY OF AEROGEL
 Aerogel was first created by Samuel
Stephens Kistler in 1931.
 The first aerogels were produced from silica
gels. Kistler's later work involved aerogels
based on alumina, chromia and tin dioxide.
Carbon aerogels were first developed in the
late 1980s.
PROPERTIES:
 Extremely low density
 Very good thermal
insulator
 High specific surface
area
 Lowest dielectric
constant
PROPERTIES:
 ultimate compressive
strength, compressive
modulus.
 flexibility, modulus of
flexure.
 Water proof material.
TYPES OF AEROGEL
 On basis of Material
 Silica
 Metal oxide
 Carbon
 On basis of
temperature
 Cryogel - for low-
temperature applications
(-200°C - 90°C);
 Spaceloft - for mid-
temperature applications
(-200°C – 200°C);
 Pyrogel - for high-
temperature applications
( up to 650°C
SILICA AEROGEL
• high specific surface area (500–1200 m2/g)
• high porosity (80–99.8%)
• low density (∼0.003 g/cm3)
• high thermal insulation value (0.005 W/mK)
• ultra low dielectric constant (k= 1.0–2.0)
• low index of refraction (∼1.05)
METAL OXIDE AEROGEL
• Density 0.070 g cm-3
• Surface area 340 m2 g-1
• Pore volume 1.25 cm3 g-1
• Average pore diameter 12 nm
CARBON AEROGEL
 Carbon aerogels are
composed of particles
with sizes in the
nanometer range.
 covalently bonded
together with pore
diameter under 100
nm.
APPLICATION IN SPACE RESEARCH
 Thermal insulation for
planetary landers and
rovers
 Insulation of cryogenic
propulstion system
AEROGEL AS STAR DUST COLLECTOR
 a section of aerogel as
part of its Stardust
probe to collect
samples of material
from the tail of comet;
GENERAL FIELDS OF APPLICATION
 Hydrogen storage
 Magnetic media
 An excellent sound
insulator
GENERAL FIELDS OF APPLICATION
 daylight panels.
 Insulation of windows
and sections of the
roof.
 As water proofing
agent.
REFERENCE
 www.aerogel.com
 John F. Poco, Joe H. Satcher , and Lawrence ,
Synthesis of high porosity, monolithic alumina
aerogels, Journal of Non-Crystalline Solids, 285,
57-63 (2001).
THANK YOU

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AEROGEL

  • 1. RECENT TRENDS IN CHEMICAL ENGG. AEROGEL
  • 2. WHAT IS AN AEROGEL ? ? ? • AEROGEL is essentially the solid framework of a gel • A class of porous, solid materials that exhibit extreme material properties • A Nanostructured Material with Fascinating Properties and Unlimited Applications
  • 3. HISTORY OF AEROGEL  Aerogel was first created by Samuel Stephens Kistler in 1931.  The first aerogels were produced from silica gels. Kistler's later work involved aerogels based on alumina, chromia and tin dioxide. Carbon aerogels were first developed in the late 1980s.
  • 4. PROPERTIES:  Extremely low density  Very good thermal insulator  High specific surface area  Lowest dielectric constant
  • 5. PROPERTIES:  ultimate compressive strength, compressive modulus.  flexibility, modulus of flexure.  Water proof material.
  • 6. TYPES OF AEROGEL  On basis of Material  Silica  Metal oxide  Carbon  On basis of temperature  Cryogel - for low- temperature applications (-200°C - 90°C);  Spaceloft - for mid- temperature applications (-200°C – 200°C);  Pyrogel - for high- temperature applications ( up to 650°C
  • 7. SILICA AEROGEL • high specific surface area (500–1200 m2/g) • high porosity (80–99.8%) • low density (∼0.003 g/cm3) • high thermal insulation value (0.005 W/mK) • ultra low dielectric constant (k= 1.0–2.0) • low index of refraction (∼1.05)
  • 8. METAL OXIDE AEROGEL • Density 0.070 g cm-3 • Surface area 340 m2 g-1 • Pore volume 1.25 cm3 g-1 • Average pore diameter 12 nm
  • 9. CARBON AEROGEL  Carbon aerogels are composed of particles with sizes in the nanometer range.  covalently bonded together with pore diameter under 100 nm.
  • 10. APPLICATION IN SPACE RESEARCH  Thermal insulation for planetary landers and rovers  Insulation of cryogenic propulstion system
  • 11. AEROGEL AS STAR DUST COLLECTOR  a section of aerogel as part of its Stardust probe to collect samples of material from the tail of comet;
  • 12. GENERAL FIELDS OF APPLICATION  Hydrogen storage  Magnetic media  An excellent sound insulator
  • 13. GENERAL FIELDS OF APPLICATION  daylight panels.  Insulation of windows and sections of the roof.  As water proofing agent.
  • 14. REFERENCE  www.aerogel.com  John F. Poco, Joe H. Satcher , and Lawrence , Synthesis of high porosity, monolithic alumina aerogels, Journal of Non-Crystalline Solids, 285, 57-63 (2001).