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17 June 2016
1
 Types of Power Plants
(1)SUBCRITICAL
(2)SUPERCRITICAL
(3)ULTRA SUPERCRITICAL
17 June 2016 2
 Water/steam circulation systems are divided
into two main classifications:
(1) Drum-Type Boiler
(2) Once-Through Boiler
17 June 2016 3
 Use less coal per unit of production compared
with subcritical boilers.
 Lower pollution levels.
 Better efficiency.
 A next step in the development of coal-based
power production technologies would be
carbon capture.
17 June 2016 4
17 June 2016 5
 The main technical challenge with
supercritical plants is that the higher steam
pressure and temperature require
components (superheaters, headers, water
tubes, steam chests, rotors and turbine
casings) which are produced from nickel-
based alloys.
17 June 2016 6
 Nickel is an expensive commodity so that for
an increased use of SPF at lower costs further
developments are needed in new steels for
water and boiler tubes and high-alloy steels
that minimize corrosion.
 Another operational aspect which would
support the market penetration of
supercritical and ultra-supercritical plants is
the development of advanced control
equipment and procedures (i.e. expert
systems, condition monitoring) to operate a
plant more flexibly.
17 June 2016 7
 With respect to developing countries with a
high coal consumption, such as China and
India, SPF technology transfers could take
place by the sale of equipment, licensing, joint
ventures, co-operative production,
subcontracting of the manufacture of
components, and co-operative research and
development .
17 June 2016 8
 Approximately 97% of global coal-base power
production capacity is based on pulverised
coal combustion.
 Many conventional pulverised coal-fired
power plants have been improved by
upgrading the system so that emissions of
several pollutants could be reduced, but the
efficiency gains are minimal as the heat rates
can only be improved at existing plants by 3 to
5%-points at best.
17 June 2016 9
17 June 2016 10
Steam cycle Subcritical Supercritical Ultra-supercritical
(best available)
Ultra-supercritical
(AD700)
Steam
conditions
180 bar (540oC) 250 bar (560oC) 300 bar (600oC) 350 bar (700oC)
Net output (MW) 458 458 456 458
Net efficiency (%) 40.2 42.0 43.4 50.6
CO2 emissions
(t/MWh-net)
0.83 0.80 0.77 0.73
17 June 2016 11
 This analysis identifies optimized cycle
configurations and steam conditions for coal-
fired power project SC and USC designs that
will yield the best overall ST efficiency.
 For a predetermined plant net power output of
600 MW, nominal matrices of thermal
performance and differential costs
were developed by varying the main steam
pressure and the main/reheat steam
temperatures.
17 June 2016 12
 The pressure range was set from 3,500 psia
(240 bar) to 4,500 psia (310 bar), and main
steam/reheat temperatures from 1,000
°F/1,000°F (538 °C/538 °C) to 1,300 °F/1,300
°F (705°C/705 °C).
 The heat balances were developed for a
variety of pressure and temperature
combinations using commercially available
simulation programs.
17 June 2016 13
 As indicated in Figure 1, an increase in operating
pressure without a respective increase in
operating temperature is counterproductive.
 The best results are achieved at the highest
pressure and temperature , an improvement of
0.39 percent compared with the base case.
 The cycle optimization analysis indicates that the
higher the main steam throttle temperature,
when accompanied by a corresponding increase
in main steam pressure, thebetter the cycle
efficiency.
 An increase in reheat temperatures also improves
the cycle efficiency, but to a lesser degree.
17 June 2016 14
 The optimum approach is a thermal cycle
design that incorporates significant increases
in both main steam pressure and temperature.
A key aspect of the design is the determination
of the enthalpy end point (EEP) or moisture
level in the exhaust of the LP turbine.
 A thermal cycle design that incorporates
significant increases in the operating pressure
of the ST without comparable
increases in temperature can lead to an EEP in
the wet zone of the LP exhaust greater than
the average of 10–12 percent.
17 June 2016 15
 The high thermal efficiency of the SC and USC
steam power plants cannot be achieved without
the use of new alloys with higher creep strength
and improved oxidation resistance.
 Operation above 1,000 °F was possible due to the
continuous development effort to improve the 9–
12 percent ferritic steels (T91/P91, T92/P92,
T112/P122), as well as some advanced austenitic
alloys (TP347, HFG, Super 304).
17 June 2016 16
 It should be noted that the high temperature
strength of ferritic steels (P92, P122,E91) is
equal to that of the low-end austenitic alloys,
but their resistance to oxidation is lower.
 The European material development program
AD 700 (named for its target of achieving
700°C [1,292 °F] as the MST)
includes research institutes and several major
ST manufacturers, including Siemens, Ansaldo,
and Alstom, which are actively collaborating
on this effort, despite being fierce commercial
competitors.
17 June 2016 17
 To minimize thermal and operational stresses,
HP sections of USC equipment use triple-shell
construction.
 With this type of arrangement, the outer
casing is not subject to elevated temperatures
and can be constructed of traditional CrMoV
material. The nozzle box is exposed to the
highest pressures
and temperatures and should be made of
forged 12CrMoVCbN steel.
17 June 2016 18
 The choice of material for bolting appears to
be relatively easy. The major requirements are
high resistance to stress relaxation, thermal
expansion compatibility, and low notch
sensitivity.
 As with ST rotating blades, the experience
accumulated from the use of identical
materials in large industrial gas turbines
operating at high temperatures is also relevant
for these applications.
 The status of material development for ST
parts used in various high pressure and high
temperature applications is given in Table .
17 June 2016 19
NICKEL:-
Optimum high-temperature
mechanical stability, Oxidation and Corrosion
Resistance . Excellent cyclic oxidation and
carburization resistance at 2000F, Good
stress ruptureproperties above 1800F.
17 June 2016 20
COBALT:-
Cobalt is resistant to stress and corrosion
at high temperatures.
CHROMIUM :-
Chromium is helpful in high corrosion
resistance and hardness.
TITANIUM :-
It optimizes special properties such as
fracture toughness, fatigue strength, and high-
temperature creep strength.
17 June 2016 21
Component 1,050 °F 1,150 °F 1,300 °F 1,400 °F
Casings
(shells, valves,
steam chests,
nozzles)
CrMoV (cast)
10CrMoVMb
9–10% Cr (W)
12CrW (Co)
CrMoWVNbN
CF8C-Plus
CCA617
Inconel 625
Nimonic 263
CCA617
Inconel 740
CF8C-Plus
Bolting 422
912%CrMoV
Nimonic80A
In 718
9–12% CrMoV
12
CrMoWVNbN
Nimonic 105
Nimonic 115
In 718
Waspaloy
Nimonic 105
Nimonic 115
U700,U710
U720
Rotors/Discs 1CrMoV
12CrMoVNbN
26NiCrMoV11
5
9–12 % CrWCo
12CrMoWVNb
N
CCA617
Inconel 625
Inconel 740
Hynes 230
CCA617
Inconel 740
Nozzles/Blades 422
10CrMoVNbN
9–12% CrWCo
10CrMoVCbN
Wrought
Ni-based
Wrought
Ni-based
Piping P22 P92 CCA617 Inconel 740
17 June 2016 22
Element
Material
Ni Cr Co Mo Other
INCONEL
625
63.5 21.5 0 9 Al,Ti,Mb
INCONEL
617
52 22 12 9.5 Al,Ti
INCONEL
263
51 20 20 6 Al,Ti
INCONEL
740
50 24 20 0.5 Al,Ti,Nm
Sanicro 25 25 22 1.5 0 W,Cu,Fe
17 June 2016 23
 The new AD700 technology of coal-fired
power plants supports the aim of the Kyoto-
protocol to reduce the CO2 emission in a mid-
term perspective under the target for a secure
and stable energy price.
17 June 2016 24
The previous graph shows that as efficiency
increases, specific carbon dioxide emissions
decrease from 1100g/kWh at 30% net plant
efficiency to 650g/kWh at 50% efficiency. This
equates to a reduction in carbon dioxide
emissions of 41%. Coal is similarly reduced
and clearly illustrates the benefits of efficiency
increase with regard to potential
environmental protection.
17 June 2016 25
17 June 2016 26
 In parallel with an ongoing R&D programme
aimed at the development of a high
temperature, solid solution nickel alloy (Alloy
617) for application to both pipe work and
superheater tubes, the AD700 programme
investigated precipitation-hardening nickel
alloys (Alloy 263 and Alloy 740).
17 June 2016 27
 The high cost of nickel, however, prohibits its
extensive use in tubes, and so the boiler
materials programme also set out to develop a
high temperature austenitic steel with average
stress rupture properties of 100MPa following
100,000 hours operation at 700°C.
 The austenitic material developed, Sanicro 25,
has been successfully produced in commercial
quantities and is has undergone extensive
testing as part of the phase 3 programme.
17 June 2016 28
 Nickel-based Alloys 617 and 625
were the main candidates for many turbine
components and their characterization in
terms of creep, creep/fatigue crack growth,
low cycle fatigue for castings, forgings and
welds was successfully completed.
17 June 2016 29
 Due to difficulties experienced with the
castability of Alloy 617, most of the effort has
been focussed on the casting of Alloy 625.
 Both 617 and Alloy 625 have been successfully
forged and considered suitable for HP and IP
rotor forgings.
 Welded rotor will be a key feature of AD700
turbine technology. Prototype joints have been
manufactured successfully by welding 10%
Chrome steel to the nickel-based alloy.
17 June 2016 30
17 June 2016 31
 TURBINE INLET VALVE:The Component Test
Facility (including the Goodwin alloy 625
valve) is installed in the coalfired
power plant “Scholven F” located in
Gelsenkirchen (Germany). The valve casting
has been in service operating at 705’C
17 June 2016 32
 The AD700 Programme Phase 2 project
participants are listed below:
# Tech-wise A/s
# ALSTOM (Switzerland) Ltd
# ALSTOM Power Boiler GmbH
# ALSTOM Power Ltd
# ALSTOM Power
# Ansaldo Caldei
# Ansaldo Ricerche
17 June 2016 33
# Babcock-Hitachi Europe GmbH
# BOHLER Edelstahl GmbH & Co KG
# Burmeister & Wain Energy A/S
# Cantro Sviluppo Materiali S.p.A
# CESI Spa
# Doncasters FVC Ltd
# EDF R&D
# EDF-SEPTEN
# Eindhoven University of Technology
# ENEA CRF
# Energi E2 A/S
# EPPSA
# Fortum Power and Heat Oy
# Goodwin Steel Castings Ltd
# GRUPO EDP - Electricidade de Portugal
17 June 2016 34
 Development of an AD700 power plant
supports the European commitments for
emission reduction made in the Kyoto Treaty.
The resources are protected through more
efficient utilisation of the fuel coal. The
competitive situation of the energy industry
will be strengthened and secured with regard
to both operators and manufacturers.
17 June 2016 35
 These technologies can combust pulverised
coal and produce steam at higher
temperatures and under a higher pressure, so
that an efficiency level of 50% can be reached
(ultra-supercritical plants). Supercritical and
ultra supercritical power plants have become
the system of choice in most industrialised
countries.
17 June 2016 36
 We must
# Adopt Super Critical technology and work for
Ultra Super Critical Technology.
# Put efforts for inducting Clean Technologies
# Revise its energy mix by including non-fossil
fuel based generation such as those from
hydro, nuclear and renewable energy in its
portfolio.
17 June 2016 37
17 June 2016 38

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THE USE OF 700 C FOR CARBON FREE

  • 2.  Types of Power Plants (1)SUBCRITICAL (2)SUPERCRITICAL (3)ULTRA SUPERCRITICAL 17 June 2016 2
  • 3.  Water/steam circulation systems are divided into two main classifications: (1) Drum-Type Boiler (2) Once-Through Boiler 17 June 2016 3
  • 4.  Use less coal per unit of production compared with subcritical boilers.  Lower pollution levels.  Better efficiency.  A next step in the development of coal-based power production technologies would be carbon capture. 17 June 2016 4
  • 6.  The main technical challenge with supercritical plants is that the higher steam pressure and temperature require components (superheaters, headers, water tubes, steam chests, rotors and turbine casings) which are produced from nickel- based alloys. 17 June 2016 6
  • 7.  Nickel is an expensive commodity so that for an increased use of SPF at lower costs further developments are needed in new steels for water and boiler tubes and high-alloy steels that minimize corrosion.  Another operational aspect which would support the market penetration of supercritical and ultra-supercritical plants is the development of advanced control equipment and procedures (i.e. expert systems, condition monitoring) to operate a plant more flexibly. 17 June 2016 7
  • 8.  With respect to developing countries with a high coal consumption, such as China and India, SPF technology transfers could take place by the sale of equipment, licensing, joint ventures, co-operative production, subcontracting of the manufacture of components, and co-operative research and development . 17 June 2016 8
  • 9.  Approximately 97% of global coal-base power production capacity is based on pulverised coal combustion.  Many conventional pulverised coal-fired power plants have been improved by upgrading the system so that emissions of several pollutants could be reduced, but the efficiency gains are minimal as the heat rates can only be improved at existing plants by 3 to 5%-points at best. 17 June 2016 9
  • 11. Steam cycle Subcritical Supercritical Ultra-supercritical (best available) Ultra-supercritical (AD700) Steam conditions 180 bar (540oC) 250 bar (560oC) 300 bar (600oC) 350 bar (700oC) Net output (MW) 458 458 456 458 Net efficiency (%) 40.2 42.0 43.4 50.6 CO2 emissions (t/MWh-net) 0.83 0.80 0.77 0.73 17 June 2016 11
  • 12.  This analysis identifies optimized cycle configurations and steam conditions for coal- fired power project SC and USC designs that will yield the best overall ST efficiency.  For a predetermined plant net power output of 600 MW, nominal matrices of thermal performance and differential costs were developed by varying the main steam pressure and the main/reheat steam temperatures. 17 June 2016 12
  • 13.  The pressure range was set from 3,500 psia (240 bar) to 4,500 psia (310 bar), and main steam/reheat temperatures from 1,000 °F/1,000°F (538 °C/538 °C) to 1,300 °F/1,300 °F (705°C/705 °C).  The heat balances were developed for a variety of pressure and temperature combinations using commercially available simulation programs. 17 June 2016 13
  • 14.  As indicated in Figure 1, an increase in operating pressure without a respective increase in operating temperature is counterproductive.  The best results are achieved at the highest pressure and temperature , an improvement of 0.39 percent compared with the base case.  The cycle optimization analysis indicates that the higher the main steam throttle temperature, when accompanied by a corresponding increase in main steam pressure, thebetter the cycle efficiency.  An increase in reheat temperatures also improves the cycle efficiency, but to a lesser degree. 17 June 2016 14
  • 15.  The optimum approach is a thermal cycle design that incorporates significant increases in both main steam pressure and temperature. A key aspect of the design is the determination of the enthalpy end point (EEP) or moisture level in the exhaust of the LP turbine.  A thermal cycle design that incorporates significant increases in the operating pressure of the ST without comparable increases in temperature can lead to an EEP in the wet zone of the LP exhaust greater than the average of 10–12 percent. 17 June 2016 15
  • 16.  The high thermal efficiency of the SC and USC steam power plants cannot be achieved without the use of new alloys with higher creep strength and improved oxidation resistance.  Operation above 1,000 °F was possible due to the continuous development effort to improve the 9– 12 percent ferritic steels (T91/P91, T92/P92, T112/P122), as well as some advanced austenitic alloys (TP347, HFG, Super 304). 17 June 2016 16
  • 17.  It should be noted that the high temperature strength of ferritic steels (P92, P122,E91) is equal to that of the low-end austenitic alloys, but their resistance to oxidation is lower.  The European material development program AD 700 (named for its target of achieving 700°C [1,292 °F] as the MST) includes research institutes and several major ST manufacturers, including Siemens, Ansaldo, and Alstom, which are actively collaborating on this effort, despite being fierce commercial competitors. 17 June 2016 17
  • 18.  To minimize thermal and operational stresses, HP sections of USC equipment use triple-shell construction.  With this type of arrangement, the outer casing is not subject to elevated temperatures and can be constructed of traditional CrMoV material. The nozzle box is exposed to the highest pressures and temperatures and should be made of forged 12CrMoVCbN steel. 17 June 2016 18
  • 19.  The choice of material for bolting appears to be relatively easy. The major requirements are high resistance to stress relaxation, thermal expansion compatibility, and low notch sensitivity.  As with ST rotating blades, the experience accumulated from the use of identical materials in large industrial gas turbines operating at high temperatures is also relevant for these applications.  The status of material development for ST parts used in various high pressure and high temperature applications is given in Table . 17 June 2016 19
  • 20. NICKEL:- Optimum high-temperature mechanical stability, Oxidation and Corrosion Resistance . Excellent cyclic oxidation and carburization resistance at 2000F, Good stress ruptureproperties above 1800F. 17 June 2016 20
  • 21. COBALT:- Cobalt is resistant to stress and corrosion at high temperatures. CHROMIUM :- Chromium is helpful in high corrosion resistance and hardness. TITANIUM :- It optimizes special properties such as fracture toughness, fatigue strength, and high- temperature creep strength. 17 June 2016 21
  • 22. Component 1,050 °F 1,150 °F 1,300 °F 1,400 °F Casings (shells, valves, steam chests, nozzles) CrMoV (cast) 10CrMoVMb 9–10% Cr (W) 12CrW (Co) CrMoWVNbN CF8C-Plus CCA617 Inconel 625 Nimonic 263 CCA617 Inconel 740 CF8C-Plus Bolting 422 912%CrMoV Nimonic80A In 718 9–12% CrMoV 12 CrMoWVNbN Nimonic 105 Nimonic 115 In 718 Waspaloy Nimonic 105 Nimonic 115 U700,U710 U720 Rotors/Discs 1CrMoV 12CrMoVNbN 26NiCrMoV11 5 9–12 % CrWCo 12CrMoWVNb N CCA617 Inconel 625 Inconel 740 Hynes 230 CCA617 Inconel 740 Nozzles/Blades 422 10CrMoVNbN 9–12% CrWCo 10CrMoVCbN Wrought Ni-based Wrought Ni-based Piping P22 P92 CCA617 Inconel 740 17 June 2016 22
  • 23. Element Material Ni Cr Co Mo Other INCONEL 625 63.5 21.5 0 9 Al,Ti,Mb INCONEL 617 52 22 12 9.5 Al,Ti INCONEL 263 51 20 20 6 Al,Ti INCONEL 740 50 24 20 0.5 Al,Ti,Nm Sanicro 25 25 22 1.5 0 W,Cu,Fe 17 June 2016 23
  • 24.  The new AD700 technology of coal-fired power plants supports the aim of the Kyoto- protocol to reduce the CO2 emission in a mid- term perspective under the target for a secure and stable energy price. 17 June 2016 24
  • 25. The previous graph shows that as efficiency increases, specific carbon dioxide emissions decrease from 1100g/kWh at 30% net plant efficiency to 650g/kWh at 50% efficiency. This equates to a reduction in carbon dioxide emissions of 41%. Coal is similarly reduced and clearly illustrates the benefits of efficiency increase with regard to potential environmental protection. 17 June 2016 25
  • 27.  In parallel with an ongoing R&D programme aimed at the development of a high temperature, solid solution nickel alloy (Alloy 617) for application to both pipe work and superheater tubes, the AD700 programme investigated precipitation-hardening nickel alloys (Alloy 263 and Alloy 740). 17 June 2016 27
  • 28.  The high cost of nickel, however, prohibits its extensive use in tubes, and so the boiler materials programme also set out to develop a high temperature austenitic steel with average stress rupture properties of 100MPa following 100,000 hours operation at 700°C.  The austenitic material developed, Sanicro 25, has been successfully produced in commercial quantities and is has undergone extensive testing as part of the phase 3 programme. 17 June 2016 28
  • 29.  Nickel-based Alloys 617 and 625 were the main candidates for many turbine components and their characterization in terms of creep, creep/fatigue crack growth, low cycle fatigue for castings, forgings and welds was successfully completed. 17 June 2016 29
  • 30.  Due to difficulties experienced with the castability of Alloy 617, most of the effort has been focussed on the casting of Alloy 625.  Both 617 and Alloy 625 have been successfully forged and considered suitable for HP and IP rotor forgings.  Welded rotor will be a key feature of AD700 turbine technology. Prototype joints have been manufactured successfully by welding 10% Chrome steel to the nickel-based alloy. 17 June 2016 30
  • 32.  TURBINE INLET VALVE:The Component Test Facility (including the Goodwin alloy 625 valve) is installed in the coalfired power plant “Scholven F” located in Gelsenkirchen (Germany). The valve casting has been in service operating at 705’C 17 June 2016 32
  • 33.  The AD700 Programme Phase 2 project participants are listed below: # Tech-wise A/s # ALSTOM (Switzerland) Ltd # ALSTOM Power Boiler GmbH # ALSTOM Power Ltd # ALSTOM Power # Ansaldo Caldei # Ansaldo Ricerche 17 June 2016 33
  • 34. # Babcock-Hitachi Europe GmbH # BOHLER Edelstahl GmbH & Co KG # Burmeister & Wain Energy A/S # Cantro Sviluppo Materiali S.p.A # CESI Spa # Doncasters FVC Ltd # EDF R&D # EDF-SEPTEN # Eindhoven University of Technology # ENEA CRF # Energi E2 A/S # EPPSA # Fortum Power and Heat Oy # Goodwin Steel Castings Ltd # GRUPO EDP - Electricidade de Portugal 17 June 2016 34
  • 35.  Development of an AD700 power plant supports the European commitments for emission reduction made in the Kyoto Treaty. The resources are protected through more efficient utilisation of the fuel coal. The competitive situation of the energy industry will be strengthened and secured with regard to both operators and manufacturers. 17 June 2016 35
  • 36.  These technologies can combust pulverised coal and produce steam at higher temperatures and under a higher pressure, so that an efficiency level of 50% can be reached (ultra-supercritical plants). Supercritical and ultra supercritical power plants have become the system of choice in most industrialised countries. 17 June 2016 36
  • 37.  We must # Adopt Super Critical technology and work for Ultra Super Critical Technology. # Put efforts for inducting Clean Technologies # Revise its energy mix by including non-fossil fuel based generation such as those from hydro, nuclear and renewable energy in its portfolio. 17 June 2016 37