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Sustainable Minerals Manufacturing
Overview
Frank A. Karbarz
President
713-893-5003
fkarbarz@corexmaterials.com
Copyright2015CoreXMaterials,Inc.AllRightsReserved
Copyright2016CoreXMaterials,Inc.AllRightsReserved
Founded in 2011. Corporate Office in Texas.
CoreX’s globally patented process enables coal ash and residual
slag fines to be upgraded into more valuable co-products.
CoreX produces PCC and fine aggregates.
PCC is Precipitated Calcium Carbonate:
a manufactured mineral with high
performance and cost-saving benefits
for diverse manufacturers with a
$4B global market
Fine aggregate is a component in Portland
cement concrete and other construction
applications
About Us
2
Copyright2015CoreXMaterials,Inc.AllRightsReserved
3
Executive Summary
Precipitated Calcium Carbonate
“PCC”
• PCC is the fastest growing component of the functional filler
minerals segment
• PCC exhibits superior particle shapes and size distributions
when compared to alternatives such as talc, kaolin, titanium
dioxide, or ground calcium carbonate
•World PCC market doubled in 10 years to 17 million tons in 2012
and is expected to grow at a CAGR of 3.9% though 2019
•Filler grade CaCO3 (both PCC and GCC) > 76 million tons in
2012
•PCC price ranges: $150/ton for pulp/paper - $1,500/ton for
pharma
Pulp Paper – Whiter, brighter, better ink absorption
Extruded Plastics (PVC) – stiffness, strength
Injected Plastics –flowability, fire resistance
Adhesives –viscosity
Coatings – pigment base extender
Rubber – abrasion resistance, stiffness
Water Treatment – corrosion control, remineralization
Pharmaceuticals – mild abrasive, tablet delivery, anti-acid
Food – mineral fortification, animal feed
Air Emissions – acid rain prevention
Oil & Gas - well drilling fluid, proppant
Why make PCC?
Global Demand for:
Copyright2016CoreXMaterials,Inc.AllRightsReserved
4
Copyright2016CoreXMaterials,Inc.AllRightsReserved
Performance Fillers Overview
PCC market has doubled in volume over 10 years
PCC captures wide performance / value spot between TiO2 and GCC
Paper
39%
Plastics
18%
Paint
7%
Rubber
6%
Adhesives/
Sealants
10%
Other
20%
PCC & GCC Applications
Kaolin, 26
GCC, 89
PCC, 19
Talc, 7.2TiO2, 7.2
Volume (mm tons)
Sources: USGS, Roskill, GIA, CoreX
5
Copyright2012CoreXMaterials,Inc.AllRightsReserved
• CoreX reduces the $100/ton manufacturing cost to $15/ton
• PCC price ranges: $150/ton for pulp/paper - $1,500/ton for pharma
• PCC is the fastest growing segment of the functional filler market
• PCC has superior particle shapes and size distributions vs. talc,
kaolin, titanium dioxide, or ground calcium carbonate
6
The Corex Clean Manufacturing Process
Produces PCC at 80% Lower Cost
We convert coal ash and slag into useful materials
Two feedstocks - Coal ash or Steel slag and CO2
Two products - Precipitated Calcium Carbonate (PCC)
- Fine cement aggregate or formed goods
Advantages for coal ash & slag management
• Low Energy - Ambient Temperature/Pressure
• Low Cost - Catalytic
• High Throughput
• Clean manufacturing processes
• Reduce ash & slag inventory
• Direct emissions reductions
7
Corex Process Highlights
Copyright2015CoreXMaterials,Inc.AllRightsReserved
• Traditional PCC uses a ‘dirty’, energy intensive
manufacturing process
MINE
Limestone
CRUSH HEAT
1700 F
Calcium
+ CO2
DRY
CoreX eliminates these steps with lower
operating cost, proprietary processes, &
coal ash and slag clean-up.
8
Prevailing PCC Production Process
Copyright2015CoreXMaterials,Inc.AllRightsReserved
Copyright2016CoreXMaterials,Inc.AllRightsReserved Slag and Coal Ash can be very Carbon-Friendly
Limestone supports Steel and Power Production
CoreX separates lime from the ash and/or slag and then
adds CO2 to produce PCC
Coal Ash
and/or
Steel Slag
9
Copyright2015CoreXMaterials,Inc.AllRightsReserved
CoreX SSS* Process
10
• Ph-swing chemistry
• Liquid/solid separation
• High throughput, filterless
• Rapid, Catalytic reaction
• Ambient pressure, temp
• Commercial pilot ready
• Flexible
• Modular
• Scalable
• Mobile
* Sequential Separation and Sequestration
Carbon Dioxide
20,000 tons annually
1. Reduce mineral inventory problems
2. Sell value to pulp, cement, & plastic factories
3. Offer potential to recover residual iron in slag
4. Exceed environmental goals
Estimated Direct Benefits
For a two million ton p.a. Steel Mill
11
High-calcium slag
200,000 tons annually
from converter-type
steel slag
PCC
Copyright2016CoreXMaterials,Inc.AllRightsReserved
Cement/
Aggregate
Metals
CO2
Credits
1. Reduce ash inventory
2. Enable marketable product streams
3. Potential to create a limestone loop
4. Realize low-cost carbon reductions
12
Estimated Direct Benefits
For a 600 Megawatt Circulating Fluidized Bed Plant
Cement
Aggregate
Carbon co-product
122,000 tons annually
CO2
Credits
Mineral co-product
750,000 tons annual top
and bottom ash
PCC
Copyright2015CoreXMaterials,Inc.AllRightsReserved

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Why Corex - Coal Ash and Steel Slag

  • 1. Sustainable Minerals Manufacturing Overview Frank A. Karbarz President 713-893-5003 fkarbarz@corexmaterials.com Copyright2015CoreXMaterials,Inc.AllRightsReserved
  • 2. Copyright2016CoreXMaterials,Inc.AllRightsReserved Founded in 2011. Corporate Office in Texas. CoreX’s globally patented process enables coal ash and residual slag fines to be upgraded into more valuable co-products. CoreX produces PCC and fine aggregates. PCC is Precipitated Calcium Carbonate: a manufactured mineral with high performance and cost-saving benefits for diverse manufacturers with a $4B global market Fine aggregate is a component in Portland cement concrete and other construction applications About Us 2
  • 3. Copyright2015CoreXMaterials,Inc.AllRightsReserved 3 Executive Summary Precipitated Calcium Carbonate “PCC” • PCC is the fastest growing component of the functional filler minerals segment • PCC exhibits superior particle shapes and size distributions when compared to alternatives such as talc, kaolin, titanium dioxide, or ground calcium carbonate •World PCC market doubled in 10 years to 17 million tons in 2012 and is expected to grow at a CAGR of 3.9% though 2019 •Filler grade CaCO3 (both PCC and GCC) > 76 million tons in 2012 •PCC price ranges: $150/ton for pulp/paper - $1,500/ton for pharma
  • 4. Pulp Paper – Whiter, brighter, better ink absorption Extruded Plastics (PVC) – stiffness, strength Injected Plastics –flowability, fire resistance Adhesives –viscosity Coatings – pigment base extender Rubber – abrasion resistance, stiffness Water Treatment – corrosion control, remineralization Pharmaceuticals – mild abrasive, tablet delivery, anti-acid Food – mineral fortification, animal feed Air Emissions – acid rain prevention Oil & Gas - well drilling fluid, proppant Why make PCC? Global Demand for: Copyright2016CoreXMaterials,Inc.AllRightsReserved 4
  • 5. Copyright2016CoreXMaterials,Inc.AllRightsReserved Performance Fillers Overview PCC market has doubled in volume over 10 years PCC captures wide performance / value spot between TiO2 and GCC Paper 39% Plastics 18% Paint 7% Rubber 6% Adhesives/ Sealants 10% Other 20% PCC & GCC Applications Kaolin, 26 GCC, 89 PCC, 19 Talc, 7.2TiO2, 7.2 Volume (mm tons) Sources: USGS, Roskill, GIA, CoreX 5
  • 6. Copyright2012CoreXMaterials,Inc.AllRightsReserved • CoreX reduces the $100/ton manufacturing cost to $15/ton • PCC price ranges: $150/ton for pulp/paper - $1,500/ton for pharma • PCC is the fastest growing segment of the functional filler market • PCC has superior particle shapes and size distributions vs. talc, kaolin, titanium dioxide, or ground calcium carbonate 6 The Corex Clean Manufacturing Process Produces PCC at 80% Lower Cost
  • 7. We convert coal ash and slag into useful materials Two feedstocks - Coal ash or Steel slag and CO2 Two products - Precipitated Calcium Carbonate (PCC) - Fine cement aggregate or formed goods Advantages for coal ash & slag management • Low Energy - Ambient Temperature/Pressure • Low Cost - Catalytic • High Throughput • Clean manufacturing processes • Reduce ash & slag inventory • Direct emissions reductions 7 Corex Process Highlights Copyright2015CoreXMaterials,Inc.AllRightsReserved
  • 8. • Traditional PCC uses a ‘dirty’, energy intensive manufacturing process MINE Limestone CRUSH HEAT 1700 F Calcium + CO2 DRY CoreX eliminates these steps with lower operating cost, proprietary processes, & coal ash and slag clean-up. 8 Prevailing PCC Production Process Copyright2015CoreXMaterials,Inc.AllRightsReserved
  • 9. Copyright2016CoreXMaterials,Inc.AllRightsReserved Slag and Coal Ash can be very Carbon-Friendly Limestone supports Steel and Power Production CoreX separates lime from the ash and/or slag and then adds CO2 to produce PCC Coal Ash and/or Steel Slag 9
  • 10. Copyright2015CoreXMaterials,Inc.AllRightsReserved CoreX SSS* Process 10 • Ph-swing chemistry • Liquid/solid separation • High throughput, filterless • Rapid, Catalytic reaction • Ambient pressure, temp • Commercial pilot ready • Flexible • Modular • Scalable • Mobile * Sequential Separation and Sequestration
  • 11. Carbon Dioxide 20,000 tons annually 1. Reduce mineral inventory problems 2. Sell value to pulp, cement, & plastic factories 3. Offer potential to recover residual iron in slag 4. Exceed environmental goals Estimated Direct Benefits For a two million ton p.a. Steel Mill 11 High-calcium slag 200,000 tons annually from converter-type steel slag PCC Copyright2016CoreXMaterials,Inc.AllRightsReserved Cement/ Aggregate Metals CO2 Credits
  • 12. 1. Reduce ash inventory 2. Enable marketable product streams 3. Potential to create a limestone loop 4. Realize low-cost carbon reductions 12 Estimated Direct Benefits For a 600 Megawatt Circulating Fluidized Bed Plant Cement Aggregate Carbon co-product 122,000 tons annually CO2 Credits Mineral co-product 750,000 tons annual top and bottom ash PCC Copyright2015CoreXMaterials,Inc.AllRightsReserved