treatment of resin waste water

1. Under the guidance of
Dr. B. Prasad
Professor, Dept. of Chemical Engg.
IIT Roorkee
TREATMENT OF RESIN
MANUFACTURING INDUSTRY
WASTE WATER USING
COAGULATION FLOCCULATION
Presented by: Arvind kumar
E. No. 14515002

2. • Introduction
• Literature review
• Objectives
Contents

3. Resins
• Resins are natural or synthetic compound that begins in a highly viscous
state and hardens with treatment.
• It is soluble in alcohol, but insoluble in water.
• Synthetic resin are produce by polymerization and poly condensation
process.
TYPES OF RESINS AND THEIR USES : resin are two types
• Synthetic resin
• Natural resin
INTRODUCTION LITERATURE REVIEW OBJECTIVES

4. INTRODUCTION LITERATURE REVIEW OBJECTIVES
RESINS USES
Polyacrylonitrile resin Civil and military aircraft , Missiles, Pressure
vessels ,Tennis rackets, badminton rackets .
Epoxy resin Adhesives ,carbon fiber Fiberglass, vinyl ester .
Ion-exchange resin Water purification, metal separation
Sugar manufacturing, pharmaceuticals .
Phenol formaldehyde resin
(Bakelite resin)
Electrical insulators, Radio ,Telephone casings,
Kitchenware, Jewelry, Pipe stems .
Ebonite resin Bowling balls ,Electric plugs Smoking pipe
,Fountain pen bodies and nib feeds .

5. Coagulation
• Coagulation is the destabilization of colloidal by addition of chemical that
neutralize the negative charge .
• Chemical coagulant are higher valance cationic salt ( Al+3 , Fe+3 etc)
• Coagulant dose are used to reduce the electrostatic repulsive force .
• Electrostatic repulsive force reduce by the addition of counter charged ions.
• For determining the optimum coagulant dose jar test is to be done in
laboratory.
Flocculation
Flocculation is the agglomeration of destabilizing particles in to a large size
particle known as flocs .which can be remove by sedimentation or floatation .
INTRODUCTION LITERATURE REVIEW OBJECTIVES

6. Mechanism :
There are two major force acting on colloids
1. Electrostatic repulsion
2. Intermolecular or vander waals attraction force
INTRODUCTION LITERATURE REVIEW OBJECTIVES

7. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Industries Coagulant Remark Author
Sugar Industries (Al2(SO4)3+FeSO4) 77% COD
REDUCTION
Khan et al., 2003
Pulp and paper Polyaluminium Chloride
(PAC), Bagasse fly ash
(BFA)
COD and colour to
87 % and 95 %,
respectively
Srivastava et al., 2005
Textile Industry Polyaluminium Chloride
(PAC)
93.47% COD Sabur et al., 2012
Distillery Industries FeCl3, AlCl3 and PAC 55, 60 and 72% COD
reductions and about
83, 86 and 92%
colour reductions
Chaudhari et al., 2007
Application of different coagulant in industries

8. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Grease waste water Aluminum sulfate ferric
chloride and ferrous sulfate
Aluminium sulphate
=90% Ferric
chloride=88% Ferrous
sulphate=28%
Ghaly et al., 2006
Synthetic Wastewater Ferric Chloride dye removal 96.3% Moghaddam et al.,
2010
Dye waste water Polyferric chlorides (PFCs) COD 55% reduction Yu-li, et al., 2006
Municipal waste
water alum and ferric chloride 50% COD, 90%
phosphours
Tassoula et al., 2007
Tannery leather waste
water PACF/Ca(OH)2 76% COD and 98%
TSS
Lofrano et al., 2006
Petroleum waste
water
PACl, FeCl3 PAC= 885 Color and
72% COD, FeCl3=79
color and 67% COD
Farajnezhad, and
Gharbani, 2012
Industries Coagulant Dosing Remark Author

9. INTRODUCTION LITERATURE REVIEW OBJECTIVES
S.No Characteristics Value
1 pH 7.4
2 Sulphate (mg/l) 60
3 Chloride (mg/l) 53
4 TDS (mg/l) 235
5 COD (mg/l) 487
6 BOD (mg/l) 60
7 Phenol (mg/l) 122
RESIN MANUFACTURING INDUSTRY WASTE WATER CHARECTARSTIC
Phenol formaldehyde resin industry waste water characteristics (Rengaraj et al. 2011)

10. INTRODUCTION LITERATURE REVIEW OBJECTIVES
RESIN MANUFACTURING INDUSTRY WASTE WATER CHARECTARSTIC
ABS resin industry waste water charactarstic (Chen, et al. 2000 )
SN. Characteristics Value
1 pH 7.01
2 Temperature 0C 40
3 DO (mg/l) 4.8
4 COD(mg/l) 4125.6-4896.2
5 Acrilonitrile (mg/l) 380.8-449.9
6 Acryleamide (mg/l) 65.7-76.3
7 Acrylic acid(mg/l) 154.1-180.1
8 Ammonia (mg/l) 51.6-53.9

11. LITERATURE REVIEW
Level in water (ppm) Length of exposure Description of effect
142 1day Death & nervous system
disorder
180 10 day Birth defect in rate
Level in water (ppm) Length of exposure Description of effect
35 2 year Premature death in rate
52 60 day Low sperm count
100 19 month Low red blood cell count
200 6 month Ulcer in the throat and
premature death
500 220 day Reduce reproductivity
capability in rate
Long turm exposure (Greater then 14 year)
EPA standerd for acrylonitrile on human exposure (short turm exposure )
OBJECTIVESINTRODUCTION

12. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of
Coagulant
Materials
Operating Conditions Efficiency
Song et al.2004
COD,
TSS ,
Chromium
Ferric
chloride
 pH 9.2
 COD 3300 mg/l
 TSS 15000 mg/l
Cr 16.8 mg/l
 TSS 38.46%
COD 30-37 %
Cr 74-99 %
Amuda et al.
2006
COD
TSS
Total
phosphorus
(TP)
FeCl3 .6 H2O
Poly
electrolyte
 pH 9
 COD 1750 mg/l
 TSS 1620 mg/l
 BOD 894 mg/l
TSS 97%
COD 93 %
TP 95 %

13. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of
Coagulant
Materials
Operating Conditions Efficiency
Wong et al.
2006
COD,
TSS ,
Turbidity
Sludge
value index
(SVI)
Polyacryl
amide cations
 pH 7.3- 8.3
 COD 3087 mg/l
 TSS 3240 mg/l
 Turbidity
 TSS 99 %
COD 93%
Turbidity 95 %
SVI 14 mg/l
Ahmad et al.
2006
COD
TSS
Turbidity
Alum +
Poly
aluminium
chloride
 pH 6.3-8.3
 COD 3087 mg/l
 TSS 5240 mg/l
 Turbidity
TSS 99.4%
COD 91 %
Turbidity 99.8%

14. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of
Coagulant
Materials
Operating Conditions Efficiency
Rodrigues et
al. 2008
COD,
Turbidity ,
Nitrate ,
Sulphate
Ferric
chloride ,
chitosan
 pH 6
 COD 1303 mg/l
 BOD 146 mg/l
 Nitrate
Phosphate
 Nitrate 90.3 %
Sulphate 49.63%
COD 58%
Turbidity 75 %
Suarez et al.
2009
Dichlorophan
ac (DCF),
Naproxen
(NPX),
Ibuprofen
(IBP)
Ferric
chloride ,
Aluminium
sulphate ,
Sodium
carbonate
 pH 7.9
 COD 2464 mg/l
 TSS 339 mg/l
TSS 92 %
 DCF 46%
IBP 23 %
NPX 42%

15. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of
Coagulant
Materials
Operating Conditions Efficiency
Verma et al.
2010
COD
Ferric
chloride
 pH 5.6
 COD 2776 mg/l
 BOD 480 mg/l
COD 75.5%
Ayoub et al.
2011
TSS ,
Total
phosphorus
(TP) ,
Cromium ,
Turbidity
Lime ,
Ferric
chloride ,
Aluminium
sulphate
 pH 7.28 TSS 97 %
TP 87 %
Cr 99.7 %
Turbidity 99%

16. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of Process used Operating Conditions Efficiency
Kenneth et al.
2008
Acrilonitrie
Acetonitrile
Acrylamide
Wet oxidation
process
Temp 315-372 0c
Pressure 1550-4500 psi
Air 50% O2
Residence time 30 min- 2hr
Acrilonitrie 2480 mg/l
Acetonitrile 2050 mg/l
Acrylamide 1053 mg/l
Acrilonitrile 99%
Acetonitrile 99.9%
Acrylamide 92.75
Dars et al.
2009
COD Adsorption
process
adsorbent use
Commercial activated
carbon (CAC),
Date pits (ADP),
Rice husks (ARH)
COD Remove by
CAC – 92.5 %
ADP - 90.5%
ARH - 89%
WORK DONE ON RESIN WASTE WATER

17. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Removal of Process used
Operating
Conditions
Efficiency
Lai et al.2012 COD ,
TOC,
Iminodipropionitrile
(ADN),
Oxydipropionitrile
(ODN) ,
Acetophenone (AP)
Boilogical
activated
carbon
 COD 1100-1300
mg/l
ADN 30-35 mg/l
ODN 67-75 mg/l
AP 16-20 mg/l
COD 80 %
TOC 80%
AND 94.4%
ODN 67%
AP 16-20 %
WORK DONE ON RESIN WASTE WATER

18. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Specific objectives of the work are:
• Characterization of waste water obtained from resin manufacturing industry.
• Preparation of composite coagulants and their characterization.
• Removal of acrylonitrile, BOD, COD, TSS and TDS from acrilonitrile
butadiene styrene (ABS) resin waste water employing composite coagulants.
• To study the effect of various parameters such as concentration, pH, reaction
time , temperature and effect of coagulant dose on acrylonitile.
• To optimize the process.
• To analyze the sludge obtained from treatment waste water .
• To carry out the economic evaluation of the process.

19. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Comparison of different systems performance in acrylonitrile-containing
wastewater treatment
Li et al. 2007 Adsorption onto poly
aluminium chloride
(PAC)
Acrylonitrile
Acrylic Acid
Removal rate= 0.0074
g. AN/g. VSS. h
Max. Ads. Cap.= 36.23
mg/g
Shin et al.2009 Super critical water
oxidation (SCWO)
Acrylonitrile,
Cooper
Enhanced oxidation of
AN due to the
formation of nano-
catalysts of copper
and/or copper oxides
Shin et al.2009 Super critical water
oxidation (SCWO) Acrylonitrile
TOC convertion of
AN= 97% within 15s at
552ºc
Authors Treatment system Pollutants Results

20. INTRODUCTION LITERATURE REVIEW OBJECTIVES
Authors Treatment system Pollutants Results
Shakerkhatibi et al.
( 2010 )
Aerated submerged
fixed film reactor
(ASFFR)
Acrylonitrile 99% AN removal at
HRT=4 h and
OLR= 2.4
kg.COD/m3.d
Chang et al. 2006 Aerated submerged
membrane bio reactor
(ASMBR)
COD > 92% removal at
HRT=18-30 h and
OLR= 2 kg.BOD/m3.d
Kumar et al. 2008 Adsorption onto bio
gas fly ash ( BFA)
Acrylonitrile Max. Ads. Cap.= 84.47
mg/g at 30ºc
Ramakrishna et al
1989
Powered activated
carbon (PAC-AS)
COD 95% CN removal at
CN in= 15-20 mg/L
88% COD removal at
COD in=25000mg/L
Comparison of different systems performance in acrylonitrile-containing
wastewater treatment

21. INTRODUCTION LITERATURE REVIEW REFERENCES
•Ahmadia, Amiric, Martinezd, Treatment of phenol-formaldehyde resin manufacturing wastewater by the
electrocoagulation process a Environmental Technology Research Center, Ahvaz Jundishapur University
of Medical Sciences, Ahvaz, Iran
• Amuda and Ibrahim, “Industrial wastewater treatment using natural material as adsorbent”, African
Journal of Biotechnology vol 5, 2006.
• Arutchelvan, Kanakasabai , Nagarajan , Muralikrishnan ,Isolation and identification of novel high
strength phenol degrading bacterial strains from phenol-formaldehyde resin manufacturing industrial
wastewater Journal of Hazardous Materials (2005)
• Akyol, “Treatment of paint manufacturing wastewater by electrocoagulation”, Desalination 2012.
•Amokrane, A., Comel, C. and Veron, J., Landfill Leachates Pre-Treatment by Coagulation Flocculation.
Water Res., (1997).
• Aghaie, khani and Choobeh, “Utilization Soya Bean Fatty Acid for Synthesis of Alkyd Resin and
Comparation of Properties with Other Vegetable Oils”, Journal of Nano Chemical Agriculture (JNCA),
Islamic Azad University, Saveh Branch, 2012.
• Dars, Bakr, Adel M. E. Gabre , Reduction of COD in Resin Production Wastewater Using Three Types of
Activated Carbon Enviro. Treat. Tech. ISSN: 2309-1185
• Hassan, Souabi, Yaacoubi and Baudu, “Improvement of paint effluents coagulation using natural and
synthetic coagulant aids”, J. Hazard. Mater. 2006
• Hanafy and Elbary , Effluent waste water treatment for a resin based paint plant (case study) Ninth
International Water Technology Conference, IWTC9 2005, Sharm El-Sheikh, Egypt
• Hassan, Li, and Noor, coagulation and flocculation treatment of wastewater in textile industry using
chitosan. J. Chem. Nat. Resour. Eng.(2009).
• Katal and Pahlavanzadeh, Influence of different combinations of aluminum and iron electrode on
electrocoagulation efficiency, Application to the treatment of paper mill wastewater, Desalination, (2011).

22. INTRODUCTION LITERATURE REVIEW REFERENCES
•Koohestanian, Hosseini, and Abbasian, The Separation Method for Removing of Colloidal Particles from Raw
Water. American-Eurasian J. Agric. & Environ. Sci.(2008).
• Lai, Zhou, and Yanga, Treatment of wastewater from acrylonitrile butadiene- styrene (ABS) resin
manufacturing by biological activated carbon (BAC) (2013)
•Luenloi, Chalermsinsuwan, Sreethawong and Hinchiranan, Photodegradation of phenol catalyzed by TiO2
coated on acrylic sheets: Kinetics and factorial design analysis, Desalination, (2011)
•Malakootian, Almasi and Hossaini, “Pb and Co removal from paint industries effluent using wood ash”, Int. J.
Environ. Sci. Tech. Vol 5(2), 2008.
•Prado , Veiga, and Kennes , Removal of formaldehyde, methanol, dimethyl ether and carbon monoxide from
waste gases of synthetic resin-producing industries University of La Coruna, Alejandro Sota, La Coruna, Spain
•Pan, Huang, Chen, and Chung, Evaluation of a Modified Chitosan Biopolymer for Coagulation of Colloidal
Particles. Colloids and Surfaces (1999).
•Rajkumar and Palanivelu, Electrochemical treatment of industrial wastewater, J. Hazard. Mater., (2004) .
•Rengaraj , Moona, Sivabalan , Arabindoo , Murugesan Removal of phenol from aqueous solution and resin
manufacturing industry wastewater using an agricultural waste: rubber seed coat Oryong dong, Puk-gu,
Kwangju 500712, South Korea
•Tahar and Savall, Electrochemical degradation of phenol in aqueous solution on bismuth doped lead dioxide: a
comparison of the activities of various electrode formulations, J. Appl. Electrochem(1999) .
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Acrylonitrile International Biodeterioration & Biodegradation (1995) .
OBJECTIVES

23. THANKS