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GAS LAWS
PREPARED BY,
JERIN.N.J
IDEAL GASES
Ideal gases are imaginary gases that perfectly
fit all of the assumptions of the kinetic
molecular theory.
Gases consist of tiny particles that are far
apart relative to their size.
Collisions between gas particles and
between particles and the walls of the
container are elastic collisions
No kinetic energy is lost in elastic collisions
IDEAL GASES (CONTINUED)
Gas particles are in constant, rapid motion.
They therefore possess kinetic energy, the
energy of motion
There are no forces of attraction between
gas particles
The average kinetic energy of gas particles
depends on temperature, not on the identity
of the particle.
REAL GASES DO NOT BEHAVE IDEALLY
Real gases DO experience inter-molecular
attractions
Real gases DO have volume
Real gases DO NOT have elastic collisions
DEVIATIONS FROM IDEAL BEHAVIOR
Likely to behave
nearly ideally
Gases at high
temperature and
low pressure
Small non-polar gas
molecules
Likely not to behave
ideally
Gases at low
temperature and high
pressure
Large, polar gas
molecules
THE COMBINED GAS LAW
The combined gas law expresses the relationship
between pressure, volume and temperature of a
fixed amount of gas.
2
22
1
11
T
VP
T
VP

BOYLE’S LAW
Pressure is inversely proportional to volume
when temperature is held constant.
2211 VPVP 
A GRAPH OF BOYLE’S LAW
CHARLES’S LAW
The volume of a gas is directly proportional to
temperature, and extrapolates to zero at zero Kelvin.
(P = constant)
Temperature MUST be in KELVINS!
2
2
1
1
T
V
T
V

A GRAPH OF CHARLES’ LAW
GAY LUSSAC’S LAW
The pressure and temperature of a gas are
directly related, provided that the volume
remains constant.
Temperature MUST be in KELVINS!
2
2
1
1
T
P
T
P

A GRAPH OF GAY-LUSSAC’S LAW
DALTON’S LAW OF PARTIAL PRESSURES
For a mixture of gases in a container,
PTotal = P1 + P2 + P3 + . . .
This is particularly useful in calculating the
pressure of gases collected over water.
THANK YOU

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Gas laws

  • 2. IDEAL GASES Ideal gases are imaginary gases that perfectly fit all of the assumptions of the kinetic molecular theory. Gases consist of tiny particles that are far apart relative to their size. Collisions between gas particles and between particles and the walls of the container are elastic collisions No kinetic energy is lost in elastic collisions
  • 3. IDEAL GASES (CONTINUED) Gas particles are in constant, rapid motion. They therefore possess kinetic energy, the energy of motion There are no forces of attraction between gas particles The average kinetic energy of gas particles depends on temperature, not on the identity of the particle.
  • 4. REAL GASES DO NOT BEHAVE IDEALLY Real gases DO experience inter-molecular attractions Real gases DO have volume Real gases DO NOT have elastic collisions
  • 5. DEVIATIONS FROM IDEAL BEHAVIOR Likely to behave nearly ideally Gases at high temperature and low pressure Small non-polar gas molecules Likely not to behave ideally Gases at low temperature and high pressure Large, polar gas molecules
  • 6. THE COMBINED GAS LAW The combined gas law expresses the relationship between pressure, volume and temperature of a fixed amount of gas. 2 22 1 11 T VP T VP 
  • 7. BOYLE’S LAW Pressure is inversely proportional to volume when temperature is held constant. 2211 VPVP 
  • 8. A GRAPH OF BOYLE’S LAW
  • 9. CHARLES’S LAW The volume of a gas is directly proportional to temperature, and extrapolates to zero at zero Kelvin. (P = constant) Temperature MUST be in KELVINS! 2 2 1 1 T V T V 
  • 10. A GRAPH OF CHARLES’ LAW
  • 11. GAY LUSSAC’S LAW The pressure and temperature of a gas are directly related, provided that the volume remains constant. Temperature MUST be in KELVINS! 2 2 1 1 T P T P 
  • 12. A GRAPH OF GAY-LUSSAC’S LAW
  • 13. DALTON’S LAW OF PARTIAL PRESSURES For a mixture of gases in a container, PTotal = P1 + P2 + P3 + . . . This is particularly useful in calculating the pressure of gases collected over water.