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IOSR Journal of Applied Physics (IOSR-JAP)
e-ISSN: 2278-4861.Volume 7, Issue 1 Ver. II (Jan.-Feb. 2015), PP 23-30
www.iosrjournals.org
DOI: 10.9790/4861-07122330 www.iosrjournals.org 23 | Page
Numerical Simulation of 𝐒𝐢 𝟏−𝐱 𝐆𝐞 𝐱 Thin Film Solar Cell Using
AMPS - 1D
A. K. Das
Department of Physics, P. K. College, Contai; Contai-721401, India.
Abstract: Crystalline silicon-germanium (Si1-xGex) alloy based single junction solar cells with graded Ge
fraction are simulated as intrinsic (i) layer between p-doped and n-doped hydrogenated amorphous Si (a-Si: H)
layers. In this paper, I have used the global air mass AM 1.5G (one sun) illumination (1 kW/m2
, 0.32 - 1.3 µm)
to calculate the optimum efficiency of single junction solar cells with different band gap energy by varying Ge
concentration with the help of one dimension simulation program AMPS-1D that was initially developed at the
Pennsylvania State University, USA. Alloys that have a lower band gap can extend infrared response of a
silicon cell and hence increase the current generation but simultaneously it will also cause the device to suffer
loss in voltage. The enhancement of efficiency with respect to pure Si by incorporating SiGe alloys into thin film
single and multilayer structures shows that such loss in voltage overcomes the increase of current within the
device of thickness less than 6 µm. The optimum efficiency is obtained by introducing multi (four) i-layers in the
step of 25% increasing Ge concentration including a germanium like Si1-xGex layer of 0.90 mole fraction (x)
towards the back surface of the device and shows better result to the efficiency with respect to pure Si cell.
Multilayer approach of single junction SiGe becomes insignificant in comparison to the pure Si as i-layer for
device thickness greater than about 6 µm. The whole range of Ge concentrations, p-layer thicknesses from 1 –
100 nm and surface recombination velocities from 10 – 107
cm.s-1
are explored. In the simulation, the current
density-voltage (J-V) characteristics are performed by varying Ge concentration and the quantum efficiency by
varying total device thickness from 1 to 60 µm.
Keywords: AMPS-1D simulation, conversion efficiency, SiGe thin film, solar cell, quantum efficiency.
I. Introduction
Solar energy can be used for multipurpose from among the various renewable energy sources
especially for solar cell. In future solar cell will take much important role in daily life for new generation at the
edge of finishing of conventional energy sources. Characteristic properties and abundances of silicon and
germanium inspire humankind to invent efficient solar cell. The thin film processing is one of the technologies
to make such cells with high efficiency, consuming less material, low process temperature and providing the
capability of large-area production [1, 2]. However, enhancement of efficiency in Si solar cell is one of the
methods to introduce a lower band gap material into the device. Germanium is such lower band gap material to
absorb the infrared wave in solar spectrum in addition to the efficient front surface light trapping of the cell and
hence increase the photo generation. Also Si and Ge are completely miscible in all respects like lattice matching,
vapour pressure etc. to construct graded solar cell of multi-layer structures [3].
Healy and Green have studied bulk devices using low Ge concentrations (x) using from 0 to 28% of Si-
Ge alloys [4]. Ruiz et al [5] have looked at mono crystalline devices and have determined the absorption
coefficients for photon energies of 0.6 to 1.5 eV and have concluded that a Ge concentration of 50% is optimal
for bulk devices. Chirstoffel et al [6] have modeled the bulk hetero-structures using germanium concentrations
about 30% with alloy layer of 10 to 40 µm and have predicted an efficiency gain of up to 0.7% without the use
of light trapping. Kochier et al [7] have used PC1D (a one-dimensional circuit simulation package) to simulate
the effect of incorporating a layer of Si1−xGex alloy into the multilayer structure and have shown the optimal
efficiency for high Ge concentration. Researchers have been performed much work on Si1−xGex alloy based
solar cells. However, improvement in the efficiency of the thin film based solar cells is a challenge for them.
II. Simulation Model with AMPS-1D
The theoretical calculations carried out using AMPS-1D (Analysis of Microelectronic and Photonic
Structures) for the analysis were based on Poisson’s equation and the first-principle continuity equations of
electrons and holes [8] and used to analyze the carriers transport behavior of semiconductor electronic and
optoelectronic device structures including solar cells.
In one dimension case, Poisson’s equation is written as;
d
dX
−ε X
dΨ
dX
= q ∗ [p X − n X + ND
+
X − NA
−
X + pt X − nt X ] (1)
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 24 | Page
where, the electrostatic potential Ψ, the free electron n , free hole p , trapped electron nt, and trapped hole pt as
well as the ionized donor-like doping ND
+
and ionized acceptor-like doping NA
−
concentrations are all functions
of the position co-ordinate X. Here, ε is the permittivity and q is the magnitude of charge of an electron. The
continuity equations for the free electrons and holes in the delocalized (band) states of the conduction band and
valence band, respectively, have the forms:
for electron ;
1
q
dJn
dX
= −Gop X + R(X) (2)
and for hole;
1
q
dJp
dX
= Gop X − R(X) (3)
where Jn and Jp are, respectively, the electron and hole current densities. The term R(X) is the net recombination
rate resulting from direct band-to-band recombination and indirect Shockley-Read-Hall (SRH) recombination
through gap (localized) states and the term Gop X is the optical generation rate as a function of X due to
externally imposed illumination.
The AMPS-1D can operate in two distinct modes: the density of state (DOS) mode or the lifetime
mode. The DOS mode allows the definition of multiple defect states using densities, energy distribution, and
capture cross-sections. The lifetime model does not allow the said recombination processes, where inputs are
given in the form of carrier life times, which are assumed constant, independent of light and voltage bias. In this
paper, a combination of crystalline Si and Ge semiconductors as intrinsic layers is employed to design a multi-
stacked hetero layer solar cell using the DOS mode.
III. Modeling Parameters
Band gap ( Eg ) : The stacked layers are formed by different band gaps of SiGe alloys which can be tailored
from 1.12 eV to 0.66 eV. Sant et al [9] have developed two equations by nonlinear spline and polynomial
interpolation methods in which one allows the fundamental band gap to be calculated for germanium contents of
less than 85% and another greater than 85%. The common understanding is that the band structure of Si1−xGex
alloys changes from silicon like to germanium like at a Ge percentage of around 85%. This change shows itself
as a rapid decrease in band gap of the alloys between 85 and 100%. The developed energy gap equations by
Sant et al with Ge mole fraction (x) in Si1−xGex alloy are as follows
Eg (eV) = 1.106 – 0.454x + 0.208x2
… … for x < 0.85 (4)
= 2.089 – 1.498x + 0.066x2
… … for x > 0.85 (5)
Absorption coefficient ( α ): Efficiency of solar cell depends on some factors including absorption coefficient
that plays a significant role as a function of energies of incident photons, band gap and phonon for indirect
transition. Braunstein et al [10] have shown the two-step phonon assisted transition for indirect band gap
semiconductor materials where both energy and momentum are conserved and the corresponding absorption
coefficient for SiGe solar cell can be determined from the following expression of Macfarlane and Robert as
α (cm−1
) = A[
hγ−Eg −Eph
2
1−exp −Eph kT
+
hγ−Eg+Eph
2
exp −Eph kT −1
] (6)
where, hγ and Eph are, respectively, the energy of incident photon and average energy of all contributed phonon
and A be the average weighing factor of the absorption coefficient. The first and second term in the right hand
side of above equation represents the phonon assisted emission and absorption process, respectively. For SiGe
alloys A and Eph are taken as 3200 and 50 meV, respectively [11]. Also other parametric equations as a function
of x are given by
Electron affinity ( 𝛘 ) : in eV χ(x) = 4.05 1 − x + 4.0x *
(7)
Electron mobility ( 𝛍 𝐧 ): in cm2
/V-s μn(x) = 1500 1 − x + 3900x *
(8)
Hole mobility ( 𝛍 𝐩 ): in cm2
/V-s μp(x) = 450 1 − x + 1900x *
(9)
The * marked equations are obtained from the linear approximation of the corresponding parameters of Si and
Ge.
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 25 | Page
Relative permittivity ( 𝛆 𝐫 )[12]: The relative permittivity or dielectric constant is a measure of optical
properties of SiGe alloy layers and is given by the following relation as a function of x
εr x = 11.8 + 4.2x (10)
Effective density of states (𝐍 𝐂, 𝐍 𝐕) : The electron and hole concentration in conduction and valence band in a
semiconductor can be written, respectively, as
n = NCe
(Ef−Ec )
kT , and p = NVe
(Ev−Ef)
kT (11)
where, NC , Ec and NV , Ev are the effective density of states and mobility edges in the conduction and valence
band, respectively. Ef is the Fermi level at absolute temperature T and k be the Boltzmann constant. The data of
intrinsic concentration (ni) of Si1−xGex solar cell for all Ge mole fractions has been taken from the graphical
representation by Kochier et al [7] from where NC can be calculated by knowing NV [12], ni and putting the
value of Eg from equations (4) and (5) in the following two relations, respectively.
NV (cm−3
) = [0.6x + 1.04 1 − x ] × 1019
(12)
, and ni
2
(cm−6
) = np = NCNVe−Eg kT
(13)
IV. Cell Structures
↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛
(a) (b)
↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛
(c) (d)
Figure 1: Schematic diagram of single junction solar cell structures with i-layer crystalline (a) Ge, (b) Si, (c)
Si0.10Ge0.90, and (d) multi 𝑆𝑖 𝑥 𝐺𝑒1−𝑥 layers for the total device thickness of 4.47 µm.
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 26 | Page
V. Parameters for the 𝑺𝒊 𝟏−𝒙 𝑮𝒆 𝒙 Solar Cells
Table: Model parameters used in the simulation for (a) p-layer a-Si: H, (b) n-layer a-Si: H and for crystalline i-
layers of (c) Ge, (d) Si, (e) Si0.75Ge0.25, (f) Si0.50Ge0.50, (g) Si0.25Ge0.75 and (h) Si0.10Ge0.90.
*Energy gap for p-a-Si: H and n-a-Si: H layers are taken same from intrinsic a-Si: H [13].
VI. Results and Discussions
In this paper, several 𝑆𝑖 𝑥 𝐺𝑒1−𝑥 single junction solar cells are designed by varying germanium
concentrations from 0 − 100% of intrinsic (i) layer between doped p-type and n-type hydrogenated amorphous
Si (a-Si:H). The photo-generated short-circuit current density (𝐽𝑆𝐶 ) and the open-circuit voltage (𝑉𝑂𝐶 ) of each
structure under 𝐴𝑀 1.5𝐺 (one sun) illumination (1kW/m2
, 0.32 - 1.30 µm) of photon flux from ASTM G173-03
[14] are simulated for different cell thickness varying from 1 to 60 µm. The fill factor (FF) in conjunction with
𝑉𝑂𝐶 and 𝐽𝑆𝐶 determines the maximum power (𝑉𝑚𝑝 𝐽 𝑚𝑝 ) per m2
from the solar cell which is defined as the ratio of
the product of 𝑉𝑚𝑝 𝑎𝑛𝑑 𝐽 𝑚𝑝 to the product of 𝑉𝑂𝐶 and 𝐽𝑆𝐶 of the cell i.e. 𝐹𝐹 =
𝑉 𝑚𝑝 𝐽 𝑚𝑝
𝑉𝑜𝑐 𝐽 𝑠𝑐
and in addition, the
conversion efficiency (η) =
𝑉 𝑚𝑝 𝐽 𝑚𝑝
𝑃 𝑖𝑛
, where 𝑃𝑖𝑛 be the incident power of photon per m2
on the solar cell.
Fig. 2 shows the variation of performances (𝜂, 𝐽𝑆𝐶, 𝑉𝑂𝐶 and 𝐹𝐹) as a function of Ge concentration of i-
layer of thickness of 4.45 µm between 10 nm of each p-a-Si:H and n-a-Si:H layers of the cell (Fig. 1). It is
observed that Voc decreases with decrease of band gap (Eg) as the germanium concentration increases. But this
decrease is quite small compared to the increase of Jsc leading to an overall optimum increase in 𝜂 (19.68%) at
90% concentration of Ge corresponding to Eg of 0.79 eV relative to pure Si solar cell. This leading performance
of efficiency for thin film SiGe alloy based solar cell continues to device thickness of about 6 µm (Fig. 3) and
then it becomes insignificant compared to the efficiency of crystalline Si cell. Similarly the FF decreases very
slowly with increase of germanium concentration and a sharp drop is observed at pure Ge. It is also observed
that except short-circuit current, the other parameters (𝜂, 𝑉𝑂𝐶 𝑎𝑛𝑑 𝐹𝐹) of pure Ge are not promising and
therefore is not suitable for single junction solar cell applications. Another notable observation is that from 85%
Ge concentration, the performances of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys have changed significantly from silicon like to
germanium like.
Effect of Germanium Concentration on Performance of 𝑺𝒊 𝒙 𝑮𝒆 𝟏−𝒙 Solar Cells
Parameters Numerical values for
(a) (b) (c) (d) (e) (f) (g) (h)
Dielectric constant
Energy gap (eV)
Mobility of electron
(cm2
/V-s)
Mobility of hole (cm2
/V-
s)
Intrinsic carrier
concentration, ni (cm-3
)
Effective density of states
in conduction band, Nc
(cm-3
)
Effective density of states
in valence band, Nv (cm-3
)
Acceptor /Donor
concentration (cm-3
)
Electron affinity (eV)
11.9
1.72*
(1.82)
10
1
-
2.5×1020
1.5×1020
3×1019
/
3.8
11.9
1.72
20
2
-
2.5×1020
1×1020
/1×1019
3.8
16
0.66
3900
1900
2.40×1013
1.02×1019
6.0×1018
-
4.0
11.8
1.12
1500
450
1.0×1010
5.73×1019
1.04×1019
-
4.05
12.85
1.01
2100
812.5
8.70×1010
5.08×1019
9.30×1018
-
4.04
13.9
0.93
2700
1175
4.20×1011
7.65×1019
8.20×1018
-
4.03
14.95
0.88
3300
1537.5
1.33×1012
1.37×1020
7.10×1018
-
4.01
15.58
0.87
3660
1755
2.75×1012
3.41×1020
6.44×1018
-
4.0
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 27 | Page
Figure 2: Variations of 𝜂 and 𝐽𝑆𝐶 ; 𝑉𝑂𝐶 and 𝐹𝐹 as a function of germanium concentration.
A comparison of efficiency with i-layer thickness from 1 – 60 µm for crystalline Si, Si0.10Ge0.90 and
multi (four) 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloy layers is shown in Fig. 3. It is observed that the 𝜂 of single junction SiGe alloy
based thin film device (fig. 1c) of 0.90 Ge concentration and multi layer device (fig. 1d) predominate (e.g., by
1.29% at 1µm device thickness) with respect to pure Si for cell thickness less than 6.37 µm and after that they
change their dominancy leading to high efficiency for crystalline Si as absorbing layer. It is also shown from
Fig. 3 that the solar cell for multi (four) i-layers, the efficiency curve almost merges the curve of single i-layer
cell of 90% Ge concentration. When the model parameters within first bracket in Table are taken by remaining
other parameters same, then the dominancy of the efficiency (e.g., by 1.21% at 1µm) for SiGe alloy (fig. 1d)
remains within the same device thickness (~ 6.37 𝜇𝑚) compare to pure Si.
1 10 100
10
12
14
16
18
20
22
24
26

i - layer thickness ( m )
Si
Si0.10Ge0.90
4 i- layers
Si0.75Ge0.25
Si0.50Ge0.50
Si0.25Ge0.75
Si0.10Ge0.90
Figure 3: Comparison of efficiency with i-layer thickness for Si, Si0.10Ge0.90 and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys (four i-layers)
in thin film solar cells.
J-V Characteristics of the Solar Cells
Fig. 4 shows the current density (J) – voltage (V) characteristics of Si, Ge and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 solar cells for
total device thickness of 4.47 µm. It is observed that the curve for Ge cell shows higher 𝐽𝑆𝐶 that is a common
property of low band gap material with significantly low 𝑉𝑂𝐶 and hence lesser efficiency and fill factor than Si
and Si0.10Ge0.90 solar cells. The Jsc and Voc of SiGe cells compromise between those for Ge and Si cells and
ultimately give optimum 𝜂 (19.70%), for multi (four) i-layers of Ge concentration varying from 25 to 90% as
shown in the figure 1 (d).
Figure 4: J-V characteristics of Ge, Si and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys for i-layer(s) as a parameter of Ge concentration in
thin film of 4.47 µm device thickness.
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 28 | Page
1 10 100
26
28
30
32
34
36
38
JSC
(mA/cm
2
)
p-layer thickness ( nm )
1 10 100
14
15
16
17
18
19
20
21
(%)
1 10 100
0.768
0.769
0.770
FF
p-layer thickness ( nm )
1 10 100
0.707
0.714
0.721
VOC
(volt)
Figure 5: Variations of 𝐽𝑆𝐶 and 𝜂 ; 𝐹𝐹 and 𝑉𝑂𝐶 as a function of p-layer thickness.
Fig. 5 shows the variation of performances with thickness of p-layer (a-Si: H) for 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 solar cell.
The Jsc and Voc values decrease with increase of thickness (p-layer) resulting the decrease of efficiency. This
decrease is due to the enhancement of opportunity and time of photo generated carriers to recombine at surface
and in bulk as thickness increases before reaching into i-layer. Thus for fabrication of solar cell, in general, the
thickness of p-layer should be taken small so that maximum amount of incident light will reach the absorbing
layer.
Fig. 6 shows the variation of performances as a function of surface recombination velocity (SRV) from
10 to 107
cm/s by setting remaining parameters as constant for Si0.10Ge0.90 solar cell. In surface recombination Jsc
will be largely affected, and high recombination rates at the top surface have particularly detrimental impact on
the short circuit current, because top surface also corresponds to the highest generation region of carriers in the
solar cell and this impact can be shown in fig. 6 (a). When surface recombination increases then the carrier starts
to recombine at the defect surface which reduces the cell performance. Here the Voc remains almost constant and
the FF increases as shown in fig. 6(b) for germanium like 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 cell with the increase of surface
recombination by showing maximum efficiency at SRV of 103
cm/s. The 𝜂 value as shown in fig. 6(c) increases
sharply for lower SRV as fast as FF and then decreases without changing Voc and FF due to the decrement of
short circuit current for surface recombination.
10
0
10
1
10
2
10
3
10
4
10
5
10
6
10
7
17.5
18.0
18.5
19.0
19.5
20.0
Surface recombination velocity (cm/sec)

(%)
(c)
10
0
10
1
10
2
10
3
10
4
10
5
10
6
10
7
35.6
35.8
36.0
36.2
JSC
JSC
(mA/cm
2
)
(a) (b)
10
0
10
1
10
2
10
3
10
4
10
5
10
6
10
7
0.66
0.69
0.72
0.75
0.78
FF
VOC
FF&Voc(volt)
Surface recombination velocity (cm/sec)
Figure 6: Variations of (a) 𝐽𝑆𝐶 , (b) 𝐹𝐹 & 𝑉𝑂𝐶 and (c) 𝜂 , as a function of surface recombination.
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 29 | Page
Quantum Efficiency as a function of Cell Thickness
The term quantum efficiency (QE) of the solar cell is defined as the ratio of the number of minority
carriers collected by the cell to the number of photons of a given energy incident on the cell. If all photons of
certain energy are absorbed and the resulting minority carriers are collected, then the quantum efficiency at that
particular energy is unity. The quantum efficiency for photons with energy below the band gap is zero.
Fig. 7(a) shows the QE spectra of the 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 cell (𝑥 of 0.90) as a parameter of device thickness (1–
60 µm) by varying i-layer thickness for high SRV of 1.0×107
cm.s-1
of electrons and holes at the front and back
surfaces of the device. It can be observed that for higher thickness, the cell shows broader QE spectra due to the
absorption of more photons which improves the overall efficiency (Fig. 8) of the device. The QE spectra for
higher thicknesses of the cell, are not only broader but also closer, reveal the no significant change of the curves
and hence in the conversion efficiencies exceeding the cell thickness of about 30 µm. In addition, the QE is
about 99% for complete absorption of incident photon for wave length (𝜆) range from 0.66 to 1.1 𝜇𝑚 by using
efficient anti reflecting coating (ARC) on the front surface of the cell. There are also sharp decrements of QE for
lower and higher 𝜆 in solar spectrum, respectively, due to front surface recombination and rear surface
recombination as well as small absorptions of photons near the band edge (𝜆~1.30 𝜇𝑚).
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
QE
wave length (m )
1 m
2 ''
3 ''
4 ''
4.47 ''
6 ''
10 ''
20 ''
30 ''
40 ''
50 ''
60 ''
(a)
Similarly, the QE spectra for Si solar cell are shown in fig. 7(b) that explains the low efficiency of the
cell corresponding to small quantum efficiency in comparison with SiGe cell for device thickness lower than
6.37 µm. As an example for 1 µm of device thickness, the optimum QE of Si and SiGe (fig. 7a) cells are,
respectively, 0.76 and 0.83 for 𝜆 of 4597 Å. Therefore, the blue (shorter 𝜆) to infrared response of SiGe is more
than pure Si that increases the current generation and hence in the overall conversion efficiency for such smaller
device thickness.
0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1
0.0
0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
1.0
QE
wave length (m )
1 m
2 ''
3 ''
4 ''
10 ''
15 ''
20 ''
25 ''
30 ''
40 ''
50 ''
60 ''
(b)
Figure 7 QE spectra of solar cells (a) Si0.10Ge0.90 and (b) Si as i-layer for different device thickness shows that
higher thickness absorbs more photons which improves the overall efficiency of the cells.
Open Circuit Voltage, Fill Factor, Short Circuit Current and Efficiency as a function of Cell Thickness
Fig. 8 shows the variation of the VOC , FF and JSC including η as a function of Si0.10Ge0.90 cell thickness.
It indicates that below 6 µm thickness, the cell shows the very sharp decrease in the JSC compare to moderate
and slight increase of VOC and FF, respectively, and therefore decrease in the η.
Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D
DOI: 10.9790/4861-07122330 www.iosrjournals.org 30 | Page
-10 0 10 20 30 40 50 60 70
12
16
20
24
28
32
36
40
44
48
Jsc

FF
VOC
i-layer thickness (m)
(%)&Jsc(mA/cm
2
)
0.52
0.56
0.60
0.64
0.68
0.72
0.76
0.80
FF&Voc(volt)
Figure 8: Variations of η , JSC and FF, VOC as a function of device thickness.
VII. Conclusion
The optimum performance of the Si1−xGex single junction solar cell is simulated by AMPS-1D to study
the dependence on germanium concentration, absorber layer thickness, p-layer thickness and on surface
recombination. The best performance for single i-layer SiGe cell is verified at Ge concentration of 90% for thin
film of device thickness below 6.37 µm. Optimum efficiency is obtained as 19.70% for multi (four) i-layers of
Si1−xGex cell compare to the results of 19.68% and 19.25%, respectively, for single i-layer germanium like
Si0.10Ge0.90 cell and for pure Si cell at 4.47 µm device thickness. Another important conclusion is that SiGe cells
are significant only for thin film of device thickness less than about 6 µm compare to pure Si and after that only
pure Si is sufficient to make high efficient cells as absorbing layer. This work also looks that only for 1 nm
thickness of p-layer of amorphous hydrogenated Si and for surface recombination velocity of 103
cm-s-1
of
electrons and holes, the cells show optimum efficiency and for multi i-layers cell it is 20.589% for high surface
recombination velocity (~ 107
cm. s−1
). It is also observed that the conversion efficiency increases until the
device thickness reaches at around 30 µm for Si0.10Ge0.90 cell and 60 µm for Si cell. There are also very sharp
increase of Jsc compare to small decrease of Voc with thickness and hence increase in the efficiency below the
device thickness of 6 µm.
Acknowledgement
The author acknowledges the use of AMPS-1D program that was developed by Dr. Fonash’s group at Pennsylvania State
University.
References
[1]. S. Benagli et al., “High-efficiency amorphous silicon devices on LPCVD-ZnO TCO prepared industrial KAI-M R&D reactor,”
Proceedings of The 24th
European Photovoltaic Solar Energy Conference, Hamburg, Germany, 2009.
[2]. O Tuzun et al., “Properties of n-type poly-crystalline silicon solar cells formed by aluminum induced crystallization and CVD
thickening,” Solar Energy Materials and Solar Cells 94(II), 2010, 1869-1874.
[3]. D. V. Lang et al., “Measurement of the band gap of GexSi1-X/Si strained-layer heterostructures,” Appl. Phys. Lett., 47(12), 1985,
1333-1335.
[4]. S. A. Healy et al., “Efficiency enhancements in crystalline silicon solar cells by alloying with germanium,” Solar Energy Materials
and Solar Cell. 28, 1992, 273-284.
[5]. J. M. Ruiz et al., “Assessment of crystalline Si1-XGex infrared solar cells for dual band gap PV concepts,” 12th
European PVSEC,
Amsterdam, The Netherlands, 1994, 572-574.
[6]. E. Chirstoffel et al., “Modeling of thin-film Si-SiGe solar cells,” 14th European PV Conf. Exhib., Barcelona, Spain, 1997, 2097-
2100.
[7]. Linda. M. Koschier et al., “Modeling and optimization of thin-film devices with Si1-XGex alloys,” IEEE Transactions on Electron
Devices, 46(10), 1999, 2111-2115.
[8]. Fonash, S. et al., http://www.cneu.psu.edu/amps/.
[9]. Saurabh Sant et al., “Band gap bowing and band offsets in relaxed and strained Si1-XGex alloys by employing a new nonlinear
interpolation scheme,” J. Appl. Phys. 113, 2013, 033708.
[10]. R. Braunstein et al., “Intrinsic optical absorption in germanium silicon alloys,” Physical Review, 109(3), 1958, 695-770.
[11]. J. L. Polleux et al., “Optical absorption coefficient determination and physical modeling of strained SiGe/Si photo detectors,”
Proceedings of The 8th IEEE International Symposium on High Performance Electron Devices for Microwave and Optoelectronic
Application (EDMO’00), November 2000, 162-172.
[12]. Tarun Vir Singh et al., “Effect of the Ge mole fraction on the formation of a conduction path in cylindrical strained-silicon on SiGe
MOSFETs,” Superlattices and Microstructures 44, 2008, 79–85.
[13]. N. Hernandez -Como et al., “Simulation of hetero-junction silicon solar cells with AMPS-1D,” Solar Energy Materials and Solar
Cell. 94(1), 2010, 62-67.
[14]. ASTM G173-03 reference spectra derived from smarts V. 2.9.2, “Reference solar spectral irradiance: Air Mass 1.5 G”
http://www.rredc.nrel.gov /solar /spectra /am1.5/.

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Numerical Simulation of 퐒퐢ퟏ−퐱퐆퐞퐱 Thin Film Solar Cell Using AMPS - 1D

  • 1. IOSR Journal of Applied Physics (IOSR-JAP) e-ISSN: 2278-4861.Volume 7, Issue 1 Ver. II (Jan.-Feb. 2015), PP 23-30 www.iosrjournals.org DOI: 10.9790/4861-07122330 www.iosrjournals.org 23 | Page Numerical Simulation of 𝐒𝐢 𝟏−𝐱 𝐆𝐞 𝐱 Thin Film Solar Cell Using AMPS - 1D A. K. Das Department of Physics, P. K. College, Contai; Contai-721401, India. Abstract: Crystalline silicon-germanium (Si1-xGex) alloy based single junction solar cells with graded Ge fraction are simulated as intrinsic (i) layer between p-doped and n-doped hydrogenated amorphous Si (a-Si: H) layers. In this paper, I have used the global air mass AM 1.5G (one sun) illumination (1 kW/m2 , 0.32 - 1.3 µm) to calculate the optimum efficiency of single junction solar cells with different band gap energy by varying Ge concentration with the help of one dimension simulation program AMPS-1D that was initially developed at the Pennsylvania State University, USA. Alloys that have a lower band gap can extend infrared response of a silicon cell and hence increase the current generation but simultaneously it will also cause the device to suffer loss in voltage. The enhancement of efficiency with respect to pure Si by incorporating SiGe alloys into thin film single and multilayer structures shows that such loss in voltage overcomes the increase of current within the device of thickness less than 6 µm. The optimum efficiency is obtained by introducing multi (four) i-layers in the step of 25% increasing Ge concentration including a germanium like Si1-xGex layer of 0.90 mole fraction (x) towards the back surface of the device and shows better result to the efficiency with respect to pure Si cell. Multilayer approach of single junction SiGe becomes insignificant in comparison to the pure Si as i-layer for device thickness greater than about 6 µm. The whole range of Ge concentrations, p-layer thicknesses from 1 – 100 nm and surface recombination velocities from 10 – 107 cm.s-1 are explored. In the simulation, the current density-voltage (J-V) characteristics are performed by varying Ge concentration and the quantum efficiency by varying total device thickness from 1 to 60 µm. Keywords: AMPS-1D simulation, conversion efficiency, SiGe thin film, solar cell, quantum efficiency. I. Introduction Solar energy can be used for multipurpose from among the various renewable energy sources especially for solar cell. In future solar cell will take much important role in daily life for new generation at the edge of finishing of conventional energy sources. Characteristic properties and abundances of silicon and germanium inspire humankind to invent efficient solar cell. The thin film processing is one of the technologies to make such cells with high efficiency, consuming less material, low process temperature and providing the capability of large-area production [1, 2]. However, enhancement of efficiency in Si solar cell is one of the methods to introduce a lower band gap material into the device. Germanium is such lower band gap material to absorb the infrared wave in solar spectrum in addition to the efficient front surface light trapping of the cell and hence increase the photo generation. Also Si and Ge are completely miscible in all respects like lattice matching, vapour pressure etc. to construct graded solar cell of multi-layer structures [3]. Healy and Green have studied bulk devices using low Ge concentrations (x) using from 0 to 28% of Si- Ge alloys [4]. Ruiz et al [5] have looked at mono crystalline devices and have determined the absorption coefficients for photon energies of 0.6 to 1.5 eV and have concluded that a Ge concentration of 50% is optimal for bulk devices. Chirstoffel et al [6] have modeled the bulk hetero-structures using germanium concentrations about 30% with alloy layer of 10 to 40 µm and have predicted an efficiency gain of up to 0.7% without the use of light trapping. Kochier et al [7] have used PC1D (a one-dimensional circuit simulation package) to simulate the effect of incorporating a layer of Si1−xGex alloy into the multilayer structure and have shown the optimal efficiency for high Ge concentration. Researchers have been performed much work on Si1−xGex alloy based solar cells. However, improvement in the efficiency of the thin film based solar cells is a challenge for them. II. Simulation Model with AMPS-1D The theoretical calculations carried out using AMPS-1D (Analysis of Microelectronic and Photonic Structures) for the analysis were based on Poisson’s equation and the first-principle continuity equations of electrons and holes [8] and used to analyze the carriers transport behavior of semiconductor electronic and optoelectronic device structures including solar cells. In one dimension case, Poisson’s equation is written as; d dX −ε X dΨ dX = q ∗ [p X − n X + ND + X − NA − X + pt X − nt X ] (1)
  • 2. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 24 | Page where, the electrostatic potential Ψ, the free electron n , free hole p , trapped electron nt, and trapped hole pt as well as the ionized donor-like doping ND + and ionized acceptor-like doping NA − concentrations are all functions of the position co-ordinate X. Here, ε is the permittivity and q is the magnitude of charge of an electron. The continuity equations for the free electrons and holes in the delocalized (band) states of the conduction band and valence band, respectively, have the forms: for electron ; 1 q dJn dX = −Gop X + R(X) (2) and for hole; 1 q dJp dX = Gop X − R(X) (3) where Jn and Jp are, respectively, the electron and hole current densities. The term R(X) is the net recombination rate resulting from direct band-to-band recombination and indirect Shockley-Read-Hall (SRH) recombination through gap (localized) states and the term Gop X is the optical generation rate as a function of X due to externally imposed illumination. The AMPS-1D can operate in two distinct modes: the density of state (DOS) mode or the lifetime mode. The DOS mode allows the definition of multiple defect states using densities, energy distribution, and capture cross-sections. The lifetime model does not allow the said recombination processes, where inputs are given in the form of carrier life times, which are assumed constant, independent of light and voltage bias. In this paper, a combination of crystalline Si and Ge semiconductors as intrinsic layers is employed to design a multi- stacked hetero layer solar cell using the DOS mode. III. Modeling Parameters Band gap ( Eg ) : The stacked layers are formed by different band gaps of SiGe alloys which can be tailored from 1.12 eV to 0.66 eV. Sant et al [9] have developed two equations by nonlinear spline and polynomial interpolation methods in which one allows the fundamental band gap to be calculated for germanium contents of less than 85% and another greater than 85%. The common understanding is that the band structure of Si1−xGex alloys changes from silicon like to germanium like at a Ge percentage of around 85%. This change shows itself as a rapid decrease in band gap of the alloys between 85 and 100%. The developed energy gap equations by Sant et al with Ge mole fraction (x) in Si1−xGex alloy are as follows Eg (eV) = 1.106 – 0.454x + 0.208x2 … … for x < 0.85 (4) = 2.089 – 1.498x + 0.066x2 … … for x > 0.85 (5) Absorption coefficient ( α ): Efficiency of solar cell depends on some factors including absorption coefficient that plays a significant role as a function of energies of incident photons, band gap and phonon for indirect transition. Braunstein et al [10] have shown the two-step phonon assisted transition for indirect band gap semiconductor materials where both energy and momentum are conserved and the corresponding absorption coefficient for SiGe solar cell can be determined from the following expression of Macfarlane and Robert as α (cm−1 ) = A[ hγ−Eg −Eph 2 1−exp −Eph kT + hγ−Eg+Eph 2 exp −Eph kT −1 ] (6) where, hγ and Eph are, respectively, the energy of incident photon and average energy of all contributed phonon and A be the average weighing factor of the absorption coefficient. The first and second term in the right hand side of above equation represents the phonon assisted emission and absorption process, respectively. For SiGe alloys A and Eph are taken as 3200 and 50 meV, respectively [11]. Also other parametric equations as a function of x are given by Electron affinity ( 𝛘 ) : in eV χ(x) = 4.05 1 − x + 4.0x * (7) Electron mobility ( 𝛍 𝐧 ): in cm2 /V-s μn(x) = 1500 1 − x + 3900x * (8) Hole mobility ( 𝛍 𝐩 ): in cm2 /V-s μp(x) = 450 1 − x + 1900x * (9) The * marked equations are obtained from the linear approximation of the corresponding parameters of Si and Ge.
  • 3. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 25 | Page Relative permittivity ( 𝛆 𝐫 )[12]: The relative permittivity or dielectric constant is a measure of optical properties of SiGe alloy layers and is given by the following relation as a function of x εr x = 11.8 + 4.2x (10) Effective density of states (𝐍 𝐂, 𝐍 𝐕) : The electron and hole concentration in conduction and valence band in a semiconductor can be written, respectively, as n = NCe (Ef−Ec ) kT , and p = NVe (Ev−Ef) kT (11) where, NC , Ec and NV , Ev are the effective density of states and mobility edges in the conduction and valence band, respectively. Ef is the Fermi level at absolute temperature T and k be the Boltzmann constant. The data of intrinsic concentration (ni) of Si1−xGex solar cell for all Ge mole fractions has been taken from the graphical representation by Kochier et al [7] from where NC can be calculated by knowing NV [12], ni and putting the value of Eg from equations (4) and (5) in the following two relations, respectively. NV (cm−3 ) = [0.6x + 1.04 1 − x ] × 1019 (12) , and ni 2 (cm−6 ) = np = NCNVe−Eg kT (13) IV. Cell Structures ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 (a) (b) ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 ↓ ↓ ↓ ↓ ↓ ↓ 𝑜𝑛𝑒 𝑠𝑢𝑛 𝑖𝑙𝑙𝑢𝑚𝑖𝑛𝑎𝑡𝑖𝑜𝑛 (c) (d) Figure 1: Schematic diagram of single junction solar cell structures with i-layer crystalline (a) Ge, (b) Si, (c) Si0.10Ge0.90, and (d) multi 𝑆𝑖 𝑥 𝐺𝑒1−𝑥 layers for the total device thickness of 4.47 µm.
  • 4. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 26 | Page V. Parameters for the 𝑺𝒊 𝟏−𝒙 𝑮𝒆 𝒙 Solar Cells Table: Model parameters used in the simulation for (a) p-layer a-Si: H, (b) n-layer a-Si: H and for crystalline i- layers of (c) Ge, (d) Si, (e) Si0.75Ge0.25, (f) Si0.50Ge0.50, (g) Si0.25Ge0.75 and (h) Si0.10Ge0.90. *Energy gap for p-a-Si: H and n-a-Si: H layers are taken same from intrinsic a-Si: H [13]. VI. Results and Discussions In this paper, several 𝑆𝑖 𝑥 𝐺𝑒1−𝑥 single junction solar cells are designed by varying germanium concentrations from 0 − 100% of intrinsic (i) layer between doped p-type and n-type hydrogenated amorphous Si (a-Si:H). The photo-generated short-circuit current density (𝐽𝑆𝐶 ) and the open-circuit voltage (𝑉𝑂𝐶 ) of each structure under 𝐴𝑀 1.5𝐺 (one sun) illumination (1kW/m2 , 0.32 - 1.30 µm) of photon flux from ASTM G173-03 [14] are simulated for different cell thickness varying from 1 to 60 µm. The fill factor (FF) in conjunction with 𝑉𝑂𝐶 and 𝐽𝑆𝐶 determines the maximum power (𝑉𝑚𝑝 𝐽 𝑚𝑝 ) per m2 from the solar cell which is defined as the ratio of the product of 𝑉𝑚𝑝 𝑎𝑛𝑑 𝐽 𝑚𝑝 to the product of 𝑉𝑂𝐶 and 𝐽𝑆𝐶 of the cell i.e. 𝐹𝐹 = 𝑉 𝑚𝑝 𝐽 𝑚𝑝 𝑉𝑜𝑐 𝐽 𝑠𝑐 and in addition, the conversion efficiency (η) = 𝑉 𝑚𝑝 𝐽 𝑚𝑝 𝑃 𝑖𝑛 , where 𝑃𝑖𝑛 be the incident power of photon per m2 on the solar cell. Fig. 2 shows the variation of performances (𝜂, 𝐽𝑆𝐶, 𝑉𝑂𝐶 and 𝐹𝐹) as a function of Ge concentration of i- layer of thickness of 4.45 µm between 10 nm of each p-a-Si:H and n-a-Si:H layers of the cell (Fig. 1). It is observed that Voc decreases with decrease of band gap (Eg) as the germanium concentration increases. But this decrease is quite small compared to the increase of Jsc leading to an overall optimum increase in 𝜂 (19.68%) at 90% concentration of Ge corresponding to Eg of 0.79 eV relative to pure Si solar cell. This leading performance of efficiency for thin film SiGe alloy based solar cell continues to device thickness of about 6 µm (Fig. 3) and then it becomes insignificant compared to the efficiency of crystalline Si cell. Similarly the FF decreases very slowly with increase of germanium concentration and a sharp drop is observed at pure Ge. It is also observed that except short-circuit current, the other parameters (𝜂, 𝑉𝑂𝐶 𝑎𝑛𝑑 𝐹𝐹) of pure Ge are not promising and therefore is not suitable for single junction solar cell applications. Another notable observation is that from 85% Ge concentration, the performances of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys have changed significantly from silicon like to germanium like. Effect of Germanium Concentration on Performance of 𝑺𝒊 𝒙 𝑮𝒆 𝟏−𝒙 Solar Cells Parameters Numerical values for (a) (b) (c) (d) (e) (f) (g) (h) Dielectric constant Energy gap (eV) Mobility of electron (cm2 /V-s) Mobility of hole (cm2 /V- s) Intrinsic carrier concentration, ni (cm-3 ) Effective density of states in conduction band, Nc (cm-3 ) Effective density of states in valence band, Nv (cm-3 ) Acceptor /Donor concentration (cm-3 ) Electron affinity (eV) 11.9 1.72* (1.82) 10 1 - 2.5×1020 1.5×1020 3×1019 / 3.8 11.9 1.72 20 2 - 2.5×1020 1×1020 /1×1019 3.8 16 0.66 3900 1900 2.40×1013 1.02×1019 6.0×1018 - 4.0 11.8 1.12 1500 450 1.0×1010 5.73×1019 1.04×1019 - 4.05 12.85 1.01 2100 812.5 8.70×1010 5.08×1019 9.30×1018 - 4.04 13.9 0.93 2700 1175 4.20×1011 7.65×1019 8.20×1018 - 4.03 14.95 0.88 3300 1537.5 1.33×1012 1.37×1020 7.10×1018 - 4.01 15.58 0.87 3660 1755 2.75×1012 3.41×1020 6.44×1018 - 4.0
  • 5. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 27 | Page Figure 2: Variations of 𝜂 and 𝐽𝑆𝐶 ; 𝑉𝑂𝐶 and 𝐹𝐹 as a function of germanium concentration. A comparison of efficiency with i-layer thickness from 1 – 60 µm for crystalline Si, Si0.10Ge0.90 and multi (four) 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloy layers is shown in Fig. 3. It is observed that the 𝜂 of single junction SiGe alloy based thin film device (fig. 1c) of 0.90 Ge concentration and multi layer device (fig. 1d) predominate (e.g., by 1.29% at 1µm device thickness) with respect to pure Si for cell thickness less than 6.37 µm and after that they change their dominancy leading to high efficiency for crystalline Si as absorbing layer. It is also shown from Fig. 3 that the solar cell for multi (four) i-layers, the efficiency curve almost merges the curve of single i-layer cell of 90% Ge concentration. When the model parameters within first bracket in Table are taken by remaining other parameters same, then the dominancy of the efficiency (e.g., by 1.21% at 1µm) for SiGe alloy (fig. 1d) remains within the same device thickness (~ 6.37 𝜇𝑚) compare to pure Si. 1 10 100 10 12 14 16 18 20 22 24 26  i - layer thickness ( m ) Si Si0.10Ge0.90 4 i- layers Si0.75Ge0.25 Si0.50Ge0.50 Si0.25Ge0.75 Si0.10Ge0.90 Figure 3: Comparison of efficiency with i-layer thickness for Si, Si0.10Ge0.90 and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys (four i-layers) in thin film solar cells. J-V Characteristics of the Solar Cells Fig. 4 shows the current density (J) – voltage (V) characteristics of Si, Ge and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 solar cells for total device thickness of 4.47 µm. It is observed that the curve for Ge cell shows higher 𝐽𝑆𝐶 that is a common property of low band gap material with significantly low 𝑉𝑂𝐶 and hence lesser efficiency and fill factor than Si and Si0.10Ge0.90 solar cells. The Jsc and Voc of SiGe cells compromise between those for Ge and Si cells and ultimately give optimum 𝜂 (19.70%), for multi (four) i-layers of Ge concentration varying from 25 to 90% as shown in the figure 1 (d). Figure 4: J-V characteristics of Ge, Si and 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 alloys for i-layer(s) as a parameter of Ge concentration in thin film of 4.47 µm device thickness.
  • 6. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 28 | Page 1 10 100 26 28 30 32 34 36 38 JSC (mA/cm 2 ) p-layer thickness ( nm ) 1 10 100 14 15 16 17 18 19 20 21 (%) 1 10 100 0.768 0.769 0.770 FF p-layer thickness ( nm ) 1 10 100 0.707 0.714 0.721 VOC (volt) Figure 5: Variations of 𝐽𝑆𝐶 and 𝜂 ; 𝐹𝐹 and 𝑉𝑂𝐶 as a function of p-layer thickness. Fig. 5 shows the variation of performances with thickness of p-layer (a-Si: H) for 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 solar cell. The Jsc and Voc values decrease with increase of thickness (p-layer) resulting the decrease of efficiency. This decrease is due to the enhancement of opportunity and time of photo generated carriers to recombine at surface and in bulk as thickness increases before reaching into i-layer. Thus for fabrication of solar cell, in general, the thickness of p-layer should be taken small so that maximum amount of incident light will reach the absorbing layer. Fig. 6 shows the variation of performances as a function of surface recombination velocity (SRV) from 10 to 107 cm/s by setting remaining parameters as constant for Si0.10Ge0.90 solar cell. In surface recombination Jsc will be largely affected, and high recombination rates at the top surface have particularly detrimental impact on the short circuit current, because top surface also corresponds to the highest generation region of carriers in the solar cell and this impact can be shown in fig. 6 (a). When surface recombination increases then the carrier starts to recombine at the defect surface which reduces the cell performance. Here the Voc remains almost constant and the FF increases as shown in fig. 6(b) for germanium like 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 cell with the increase of surface recombination by showing maximum efficiency at SRV of 103 cm/s. The 𝜂 value as shown in fig. 6(c) increases sharply for lower SRV as fast as FF and then decreases without changing Voc and FF due to the decrement of short circuit current for surface recombination. 10 0 10 1 10 2 10 3 10 4 10 5 10 6 10 7 17.5 18.0 18.5 19.0 19.5 20.0 Surface recombination velocity (cm/sec)  (%) (c) 10 0 10 1 10 2 10 3 10 4 10 5 10 6 10 7 35.6 35.8 36.0 36.2 JSC JSC (mA/cm 2 ) (a) (b) 10 0 10 1 10 2 10 3 10 4 10 5 10 6 10 7 0.66 0.69 0.72 0.75 0.78 FF VOC FF&Voc(volt) Surface recombination velocity (cm/sec) Figure 6: Variations of (a) 𝐽𝑆𝐶 , (b) 𝐹𝐹 & 𝑉𝑂𝐶 and (c) 𝜂 , as a function of surface recombination.
  • 7. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 29 | Page Quantum Efficiency as a function of Cell Thickness The term quantum efficiency (QE) of the solar cell is defined as the ratio of the number of minority carriers collected by the cell to the number of photons of a given energy incident on the cell. If all photons of certain energy are absorbed and the resulting minority carriers are collected, then the quantum efficiency at that particular energy is unity. The quantum efficiency for photons with energy below the band gap is zero. Fig. 7(a) shows the QE spectra of the 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 cell (𝑥 of 0.90) as a parameter of device thickness (1– 60 µm) by varying i-layer thickness for high SRV of 1.0×107 cm.s-1 of electrons and holes at the front and back surfaces of the device. It can be observed that for higher thickness, the cell shows broader QE spectra due to the absorption of more photons which improves the overall efficiency (Fig. 8) of the device. The QE spectra for higher thicknesses of the cell, are not only broader but also closer, reveal the no significant change of the curves and hence in the conversion efficiencies exceeding the cell thickness of about 30 µm. In addition, the QE is about 99% for complete absorption of incident photon for wave length (𝜆) range from 0.66 to 1.1 𝜇𝑚 by using efficient anti reflecting coating (ARC) on the front surface of the cell. There are also sharp decrements of QE for lower and higher 𝜆 in solar spectrum, respectively, due to front surface recombination and rear surface recombination as well as small absorptions of photons near the band edge (𝜆~1.30 𝜇𝑚). 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 QE wave length (m ) 1 m 2 '' 3 '' 4 '' 4.47 '' 6 '' 10 '' 20 '' 30 '' 40 '' 50 '' 60 '' (a) Similarly, the QE spectra for Si solar cell are shown in fig. 7(b) that explains the low efficiency of the cell corresponding to small quantum efficiency in comparison with SiGe cell for device thickness lower than 6.37 µm. As an example for 1 µm of device thickness, the optimum QE of Si and SiGe (fig. 7a) cells are, respectively, 0.76 and 0.83 for 𝜆 of 4597 Å. Therefore, the blue (shorter 𝜆) to infrared response of SiGe is more than pure Si that increases the current generation and hence in the overall conversion efficiency for such smaller device thickness. 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 QE wave length (m ) 1 m 2 '' 3 '' 4 '' 10 '' 15 '' 20 '' 25 '' 30 '' 40 '' 50 '' 60 '' (b) Figure 7 QE spectra of solar cells (a) Si0.10Ge0.90 and (b) Si as i-layer for different device thickness shows that higher thickness absorbs more photons which improves the overall efficiency of the cells. Open Circuit Voltage, Fill Factor, Short Circuit Current and Efficiency as a function of Cell Thickness Fig. 8 shows the variation of the VOC , FF and JSC including η as a function of Si0.10Ge0.90 cell thickness. It indicates that below 6 µm thickness, the cell shows the very sharp decrease in the JSC compare to moderate and slight increase of VOC and FF, respectively, and therefore decrease in the η.
  • 8. Numerical simulation of 𝑆𝑖1−𝑥 𝐺𝑒 𝑥 thin film solar cell using AMPS - 1D DOI: 10.9790/4861-07122330 www.iosrjournals.org 30 | Page -10 0 10 20 30 40 50 60 70 12 16 20 24 28 32 36 40 44 48 Jsc  FF VOC i-layer thickness (m) (%)&Jsc(mA/cm 2 ) 0.52 0.56 0.60 0.64 0.68 0.72 0.76 0.80 FF&Voc(volt) Figure 8: Variations of η , JSC and FF, VOC as a function of device thickness. VII. Conclusion The optimum performance of the Si1−xGex single junction solar cell is simulated by AMPS-1D to study the dependence on germanium concentration, absorber layer thickness, p-layer thickness and on surface recombination. The best performance for single i-layer SiGe cell is verified at Ge concentration of 90% for thin film of device thickness below 6.37 µm. Optimum efficiency is obtained as 19.70% for multi (four) i-layers of Si1−xGex cell compare to the results of 19.68% and 19.25%, respectively, for single i-layer germanium like Si0.10Ge0.90 cell and for pure Si cell at 4.47 µm device thickness. Another important conclusion is that SiGe cells are significant only for thin film of device thickness less than about 6 µm compare to pure Si and after that only pure Si is sufficient to make high efficient cells as absorbing layer. This work also looks that only for 1 nm thickness of p-layer of amorphous hydrogenated Si and for surface recombination velocity of 103 cm-s-1 of electrons and holes, the cells show optimum efficiency and for multi i-layers cell it is 20.589% for high surface recombination velocity (~ 107 cm. s−1 ). It is also observed that the conversion efficiency increases until the device thickness reaches at around 30 µm for Si0.10Ge0.90 cell and 60 µm for Si cell. There are also very sharp increase of Jsc compare to small decrease of Voc with thickness and hence increase in the efficiency below the device thickness of 6 µm. Acknowledgement The author acknowledges the use of AMPS-1D program that was developed by Dr. Fonash’s group at Pennsylvania State University. References [1]. S. Benagli et al., “High-efficiency amorphous silicon devices on LPCVD-ZnO TCO prepared industrial KAI-M R&D reactor,” Proceedings of The 24th European Photovoltaic Solar Energy Conference, Hamburg, Germany, 2009. [2]. O Tuzun et al., “Properties of n-type poly-crystalline silicon solar cells formed by aluminum induced crystallization and CVD thickening,” Solar Energy Materials and Solar Cells 94(II), 2010, 1869-1874. [3]. D. V. Lang et al., “Measurement of the band gap of GexSi1-X/Si strained-layer heterostructures,” Appl. Phys. Lett., 47(12), 1985, 1333-1335. [4]. S. A. Healy et al., “Efficiency enhancements in crystalline silicon solar cells by alloying with germanium,” Solar Energy Materials and Solar Cell. 28, 1992, 273-284. [5]. J. M. Ruiz et al., “Assessment of crystalline Si1-XGex infrared solar cells for dual band gap PV concepts,” 12th European PVSEC, Amsterdam, The Netherlands, 1994, 572-574. [6]. E. Chirstoffel et al., “Modeling of thin-film Si-SiGe solar cells,” 14th European PV Conf. Exhib., Barcelona, Spain, 1997, 2097- 2100. [7]. Linda. M. Koschier et al., “Modeling and optimization of thin-film devices with Si1-XGex alloys,” IEEE Transactions on Electron Devices, 46(10), 1999, 2111-2115. [8]. Fonash, S. et al., http://www.cneu.psu.edu/amps/. [9]. Saurabh Sant et al., “Band gap bowing and band offsets in relaxed and strained Si1-XGex alloys by employing a new nonlinear interpolation scheme,” J. Appl. Phys. 113, 2013, 033708. [10]. R. Braunstein et al., “Intrinsic optical absorption in germanium silicon alloys,” Physical Review, 109(3), 1958, 695-770. [11]. J. L. Polleux et al., “Optical absorption coefficient determination and physical modeling of strained SiGe/Si photo detectors,” Proceedings of The 8th IEEE International Symposium on High Performance Electron Devices for Microwave and Optoelectronic Application (EDMO’00), November 2000, 162-172. [12]. Tarun Vir Singh et al., “Effect of the Ge mole fraction on the formation of a conduction path in cylindrical strained-silicon on SiGe MOSFETs,” Superlattices and Microstructures 44, 2008, 79–85. [13]. N. Hernandez -Como et al., “Simulation of hetero-junction silicon solar cells with AMPS-1D,” Solar Energy Materials and Solar Cell. 94(1), 2010, 62-67. [14]. ASTM G173-03 reference spectra derived from smarts V. 2.9.2, “Reference solar spectral irradiance: Air Mass 1.5 G” http://www.rredc.nrel.gov /solar /spectra /am1.5/.