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International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019
Available at www.ijsred.com
ISSN : 2581-7175 ©IJSRED:All Rights are Reserved Page 645
Electronic Waste impacting Health and Environment, It’s
Management -Global & Indian Perspective
----------------------------------------************************----------------------------------
Abstract:
Use of electronics equipment and their disposal is increasing exponentially with time. The disposal of
equipment is in proportion to obsolescence which in turn is linked with adoption of new technology. It
has attributed around 10 % growth in e-Waste in India. Recycling of e-Waste through environment
friendly means is utmost need of the day. Still in India, instead of using standardised technology based
methods in recycling, it is carried out by using primitive means which are extremely hazardous and
spoiling the environment. Development of an ecosystem comprising adequate legislation, restrictions on
hazardous substance (RoHS) , cost-effective technology based recycling solution, awareness to all
stakeholders & general public on electronic waste is to be ensured and full proof management practices
warrantying environment protection and eco-friendly manufacturing and recycling are to be adopted.
Keywords —e-Waste, WEEE, RoHS, Recycling, Extraction
----------------------------------------************************----------------------------------
I. INTRODUCTION
Discarded electronics and electrical equipment
appliances are considered widely Electronic Waste
(E-Waste). It is generally utilised for refurbishment,
recycling for material recovery for reuse. It
potentially contains toxic , hazardous, carcinogenic
substances such as mercury, lead and cadmium etc
and essentially is to be handled & disposed with
scientific & eco-friendly manner.
Annually , approx. 50 million tonnes of electronic
and electrical waste is generated globally which is
more than six kilograms per person per year. If it
keeps on increasing with current pace, it will be
doubled by 2050. Only 20 % e-Waste is recycled
through formal sector recyclers. Rest 80 % ,
majorly imported as well as locally generated in
developing countries, is largely ending up in
landfill contaminating soil and groundwater,
putting food supply systems and water sources at
risk or it is being informally recycled through
primitive methods exposing labours to hazardous
and carcinogenic substances leading to adverse
human health effects .
The substances found in e-waste which are toxic
and hazardous to human & environment include :
Lead and Cadmium in Cathode Ray Tubes (CRT),
Computers Batteries , Plating Metal Enclosures/
Metal Parts in sub-assemblies, Printed Circuit
Boards (PCBs), ; mercury in Switches, Flat Screen,
CFL etc ; Poly Chlorinated Biphenyls in
Capacitors, Transformers , retardant on Printed
Dr. Anju RatheeAhlawat, Assistant Professor,
Department of Applied Sciences, Maharaja Surajmal Institute of Technology, C-4, JanakPuri, New Delhi
Email:anu.ahlawat@gmail.com
RESEARCH ARTICLE OPEN ACCESS
International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019
Available at www.ijsred.com
ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 646
Circuit Boards, plastic casings, cables ; Poly Vinyl
Chloride (PVC) in cable sheathing ; PBD/PBDE in
plastic parts of electronics ; and various other
substances [6]
E-Waste contains around 7% of world’s gold. As
compared to gold ore, e-Waste have 100 times more
gold. Poor management of e-waste is ensuing in a
significant loss of rare, scarce and valuable raw
materials viz gold, platinum, cobalt, apart from
polluting the planet and effecting health adversely.
In India, ill effects of improper e-waste processing
- leaching of hazardous contents from landfills to
soil, contamination of rivers & underground water
sources, emission of gases to air, impacted human
through inhalation of gases emitted during
recycling and through contact with hazardous
substances used in recovery processes – is
substantially visible. With the support of
legislation which has been updated time to time,
Ministry of Environment and Forests, Government
of India along with agencies like Central Pollution
Control Board, State Pollution Control Board and
others are handling, managing, controlling the e-
Waste related affairs including Restriction of
Hazardous Substance (RoHS) directives in India.
Despite it, no formal data from Government is
readily available. However, by efforts of some Non
Government Organisations ( NGOs) , the
assimilated data is eye opener and informs that still
e-Waste collection, segregation, recycling is
majorly dealt by informal sector and labour health
& environment issues are grossly ignored.
II. SIZE OF ELECTRONICS WASTE
E-waste today often consists of products from the
past. In year 2016, 44.7 Million Tonnes (MT) of e-
Waste was generated globally by adding in 16.8
MT small equipment, 9.1 MT large equipment, 7.6
MT temperature exchange equipment, 6.6 MT
screens, 3.9 MT small IT equipment, 0.7 MT lamps
[1]
.
Though forecasting the volumes of e-waste
generation is difficult, yet considering the current
pace and in the absence of some effective
controlling & managing mechanism, it is expected
that by 2021 the annual total volume may surpass
52 million tonnes.
Some other indicators - EE devices connected to the
internet at between 25-50 billion by 2020 i.e. three
times the world population; By 2040, carbon
emissions from production and use of electronics
including devices like PCs, laptops, monitors,
smartphones and tablets reaching 14% of total
emissions; By 2060, the world’s consumption of
raw materials is set to double - give insight that by
2050, the volume of e-waste, in the worst-case
scenario, could top 120 million tonnes annually.
India generates around two million tonnes of e-
waste per annum and is at fifth rank among e-waste
producing countries, after the US, China, Japan and
Germany. However, there is no government data on
e-waste generation in the country (ii)
.
However important indicators -rapid growth of
Mobile subscriber in India from 310 million in
2001 to 1.1 billion in 2016 which is nearly 4 times
that of United States and ranking second only to
China in the world, which has 1.3 billion
subscribers ; 57 million computers in use and
plethora of other gadgets and consumer electronics-
predict growth in domestic e-Waste generation in
India. 10 year ago, around 70 % of e-Waste
processed or disposed of in India was originated
from abroad. Afterward efforts to control the
inflow have been effective , but surge in domestic
consumption have overshoot it, leading to an over
all growth in e-Waste generation.
Computer equipment and mobile telephones as the
principal e-waste generators in India contributing
around 70 per cent of the total e-waste generated in
International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019
Available at www.ijsred.com
ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 647
India, while telecommunication equipment
attribution is about 12 per cent. Mumbai is first
among cities generating around 1,20,000 tonnes of
e-waste per annum, followed by Delhi and
Bengaluru with generation of 98,000 and 92,000
tonnes of e-waste per annum [4]
. About 70 per cent
of heavy metals in landfills is sourced from E-
waste.
III. ELEMENTS AND ECONOMIC VALUE:
There are so many elements which are scarcely
available in nature but available in e-Waste with
good recycling rates. Extraction of these scarce
elements from e-Waste is more economical than
their extraction from ore. Also extraction from ore
mines is also causing enormous pollution.
Availability in nature, pollution caused by mining
and recycling rates of some important elements
[1]
are which are available in e-Waste is depicted in
Tables 1:
TABLE1 :
CLASSIFICATION OF ELEMENTS PRESENT IN E-WASTE BASED UPON
PARAMETERS-THEIR AVAILABILITY IN NATURE, POLLUTION CAUSED DURING
MINING , AND RECYCLING RATES :
Availability in Nature:
Low < Scarcity in Nature > High
Available in
Nature
Limited
Availability,
Future Risk of
Supply
Rising
Threats
from
increased
use
Serious
Threat in
Next 100
years
Na, K, Rb, Cs, Be,
Ca, Ba, LA, Ti,
Ta, Te, Fe, Al, Si,
Ce, Pr, Sm, Eu,
Gd, Tb, Ho, Er,
Yb
Li, Mg, Sr, Sc,
Y, Zr, Nb, Cr,
Mo, W, Mn,
Co, Ni, Pd,
Cu, Au, Cd,
Hg, Ti, Sn,
Pb, Sb, Bi, Se,
Nd
Pt
Ag, Zn,
Ga, In,
Ge, As,
Te
Pollution Caused by Mining of elements:
Low < Pollution Caused by Mining > High
Ca
Li,
Mg,
Sr, Ba,
Y, Ti,
Zr, Nb,
Mn,
Fe, Co,
Cd, Al,
Sn, Pb
Be,
Ni,
Bi
Sc, Hf,
Ta, Cr,
Mo, W,
Cu, Ag,
Zn, Ga,
In, Tl,
Ge, As,
Sb, Se,
Te
Pd
Re,
Pt,
Hg
Na, K,
Rb, Cs,
La, Si,
Ce, Pr,
Nd, Sm,
Eu, Gd,
Tb, Ho,
Er, Yb
Au
Recycling Rates of elements from e-Waste:
Low < Recycling Rate > High
<1% 1-10%
>10-
25%
> 25-
50%
>50 %
Li, Be, Sr, Ba, Sc,
Y, La, Zr, Hf, Ta,
Ga, In, Tl, Ge, As,
Bi, Se, Te, Ce, Pr,
Nd, Sm, Eu, Gd,
Tb, Ho, Er, Yb
Hg,
Sb
W,
Cd
Mg, Mo
Ti, Nb, Cr,
Mn, Re, Fe,
Co, Ni, Pd,
Pt, Cu, Ag,
Au, Zn, Al,
Sn, Pb
By seeing the elements in above table and analysing
pollution in their mining, scarcity in nature vis a vis
recycling rates gives an enormous clue that scarce
elements like Gold (Au) having high recycling rate
and polluting environment heavily during their
mining must be recycled as it adds enormous value
to e-Waste Economy Chain and in environment
protection.
Elements such as Iron, Aluminium, Copper
amounts around 40-50 % of weight of e-Waste
whereas valuable elements are found in lesser
amounts but are still of high importance.
TABLE 2: METAL COMPOSITION OF SOME COMMON ELECTRONIC APPLIANCES
[3]
e-Waste
Items
Weight (%) Weight (ppm)
Fe Cu Al Pb Ni Ag Au Pd
TV
Board
28 10 10 1 0.3 280 20 10
PC
Board
7 20 5 1.5 1 1000 250 110
Mobile
Phone
5 13 1 0.3 0.1 1380 350 210
Portable
Audio
System
23 21 1 0.14 0.03 150 10 44
International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019
Available at www.ijsred.com
ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 648
DVD
Player
62 5 2 0.1 0.05 115 15 4
Calculat
or
4 3 5 0.1 0.5 260 50 5
Printed
Circuit
Board
5.3 26.
8
1.9 NR 0.14 3300 80 NR
E-waste
Mixture
36 4.1 4.9 0.29 1.0 NR NR NR
Some precious metals like gold are contained in E-
Waste as large as around 7% of world’s gold and
100 times more available in as compared to gold
ore. 24 kg Gold is present in 148.4 tons (1 million
units) of Mobile phones and to extract the same
weight of Gold from gold ore, 23763.4 tons of gold
ore is to be processed.
IV. HEALTH & ENVIRONMENTAL IMPACT:
EEEs are manufactured with various components ,
some containing high value substances. Recycling
of these substances may be toxic and have an
adverse impact on human health and the
environment ,if not handled properly. It may affect
seriously human involved in recycling process
and/or living in proximity to places where e-waste
is recycled or burnt [5]
. A computer contains highly
toxic chemicals like Lead, Cadmium, Mercury,
Beryllium, BFR, Poly Vinyl Chloride and Phosphor
compounds.
TABLE 3 : HAZARDOUS OF PROCESSING OF WASTE COMPUTER ON HUMAN LIFE
AND ENVIRONMENT
e-Waste
Component
Process
Potential
Occupational
Hazards
Potential
Environmental
Hazards
Cathode
Ray Tubes
Breaking to
extract copper
and dumping
Silicosis, Cuts from
glass, Inhalation or
contact with toxic
phosphor containing
cadmium or other
metals
Lead, Barium
and other heavy
metals leaching
into ground
water and
release of toxic
phosphor in air.
Printer
Circuit
Boards
De-soldering
to removing
computer
chips and
Tin and Lead
inhalation, Possible
Brominated Dioxin,
Beryllium, Cadmium
Air emission of
the same
substances
open burning and Mercury
inhalation
Chips and
other Gold-
plated items
Chemical
stripping
using nitric
and
hydrochloric
acid along
riverbanks
Acid contact with
eyes, skin may result
in permanent injury;
Inhalation of acids
fumes, chlorine and
sulfur dioxide gases
can cause respiratory
difficulty ,pulmonary
allergy, respiratory
failure and death
Hydrocarbons,
heavy metals,
brominated
substances etc.
discharged
directly into
river ;Acidifies
the river
destroying fish
and flora
Plastics
from the
computer
and
peripherals
Shredding and
low-
temperature
melting
Probable
hydrocarbon,
brominated dioxin
and PAH exposure
to workers and
people living in the
nearby area
Emission of
brominated
dioxins and
heavy metals
and
hydrocarbons
Steel,
Copper &
metal
smelting
Furnace
recovers steel
or copper
from waste
Exposure to dioxins
and heavy metals
Emission of
dioxins and
heavy metals
Wires
Open burning
to recover
copper
Brominated and
Chlorinated Dioxin
and PAH exposure
to workers and
people living in
nearby area
Hydrocarbon
and ashes
including PAHs
discharged into
air, water and
soil
V. REGULATION AND ECOSYSTEM DEVELOPMENT
With the new E-Waste Management Rules 2016,
responsibility of recycling now lies with equipment
manufacturers too to take up the task of recycling
the products they produce. Though anticipated
outcome is not feasible until & unless , society at
large is sensitised about its necessity to manage e-
Waste.
Taking measures by Government to turn the
informal sector into a well-managed system will not
be adequate. In most proposed sustainable e-waste
models , informal e-waste value chains are offered
no alternate livelihood options and ultimately they
will lose their livelihoods. Safe, low-cost or
intermediate e-waste recycling technology,
enabling appropriate finance mechanism, are the
International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019
Available at www.ijsred.com
ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 649
need of the day , so that some alternative livelihood
options are emerged for existing e-waste markets by
re-shaping value chain for the better instead only
imposing regulations.
It requires better cooperation and trust between
national and local governments, manufacturers and
retailers, and small informal businesses. An
ecosystem- where informal sector functions
alongside and with the formal, new innovative
&equitable models of functioning, with key
economic and non-economic incentives for
informal and formal, large and small-scale
stakeholders , with greater understanding of the
diversity, inequalities and vulnerabilities that exist
within the informal e-waste sector - is to be
developed in India for settling a balance among all
stakeholder to manage e-Waste better.
Improved scientific understanding of the different
environmental and health risks along the chain, and
the technologies that could mitigate risks, will also
serve to inform better targeted interventions.
VI. CONCLUSIONS
In India, significant size of manpower in informal
sector is involved recycling of e-Waste to extract
elements by using primitive means resulting in
health and environment hazards. Despite
regulations, the concerns of livelihood, & lack of
awareness are important constraints for managing
e-Waste in appropriate ways. A suitable model is to
be evolved including all stakeholders. One
approach could be to create an ecosystem having all
stakeholders in one value chain - unorganized
sector to concentrate on collection, dismantling,
segregation etc; whereas the metal extraction,
recycling and disposal could be done by the
organized sector ; setting responsibilities with
manufacturers to recycle their obsolete produce;
and awareness of masses - so that e-Waste can be
managed in a better way.
VII. REFERENCES
[1] A New Circular Vision for Electronics -Time for a Global Reboot, a
report in support of the United Nations e-Waste Coalition, Jan 2019 ,
published as part of the PACE.
[2] Clean and inclusive Recycling e-Waste in China and India by Kate
Lines Garside, with Satish Sinha and Irina Fedorenko , March 2016 -
published by International Institute for Environment & Development,
UK
[3] Status of E-Waste In India- A Review, IsraelCherukuri, Nazia Sultana
And SankaraPitchaiahPodila , IOSR Journal of Environmental Science,
Toxicology and Food Technology e-ISSN: 2319-2402, p- ISSN: 2319-
2399.Volume 12, Issue 11 Ver. I (November. 2018), PP 08-16
[4] Health hazards caused by unorganised e-waste disposal by V.
Ranganathan – web article at link
https://yourstory.com/2018/06/unorganised-e-waste-disposal-dangers
[5] E-waste: From Toxic to Green India, web article at United Nations-
Climate Change
[6] Electronic Waste and India by Dr. S. Chatterjee, an article on website
of Ministry of Electronics & Information Technology, Government of
India

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Electronic Waste impacting Health And Environment, Its Management -Global & Indian Perspective

  • 1. International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019 Available at www.ijsred.com ISSN : 2581-7175 ©IJSRED:All Rights are Reserved Page 645 Electronic Waste impacting Health and Environment, It’s Management -Global & Indian Perspective ----------------------------------------************************---------------------------------- Abstract: Use of electronics equipment and their disposal is increasing exponentially with time. The disposal of equipment is in proportion to obsolescence which in turn is linked with adoption of new technology. It has attributed around 10 % growth in e-Waste in India. Recycling of e-Waste through environment friendly means is utmost need of the day. Still in India, instead of using standardised technology based methods in recycling, it is carried out by using primitive means which are extremely hazardous and spoiling the environment. Development of an ecosystem comprising adequate legislation, restrictions on hazardous substance (RoHS) , cost-effective technology based recycling solution, awareness to all stakeholders & general public on electronic waste is to be ensured and full proof management practices warrantying environment protection and eco-friendly manufacturing and recycling are to be adopted. Keywords —e-Waste, WEEE, RoHS, Recycling, Extraction ----------------------------------------************************---------------------------------- I. INTRODUCTION Discarded electronics and electrical equipment appliances are considered widely Electronic Waste (E-Waste). It is generally utilised for refurbishment, recycling for material recovery for reuse. It potentially contains toxic , hazardous, carcinogenic substances such as mercury, lead and cadmium etc and essentially is to be handled & disposed with scientific & eco-friendly manner. Annually , approx. 50 million tonnes of electronic and electrical waste is generated globally which is more than six kilograms per person per year. If it keeps on increasing with current pace, it will be doubled by 2050. Only 20 % e-Waste is recycled through formal sector recyclers. Rest 80 % , majorly imported as well as locally generated in developing countries, is largely ending up in landfill contaminating soil and groundwater, putting food supply systems and water sources at risk or it is being informally recycled through primitive methods exposing labours to hazardous and carcinogenic substances leading to adverse human health effects . The substances found in e-waste which are toxic and hazardous to human & environment include : Lead and Cadmium in Cathode Ray Tubes (CRT), Computers Batteries , Plating Metal Enclosures/ Metal Parts in sub-assemblies, Printed Circuit Boards (PCBs), ; mercury in Switches, Flat Screen, CFL etc ; Poly Chlorinated Biphenyls in Capacitors, Transformers , retardant on Printed Dr. Anju RatheeAhlawat, Assistant Professor, Department of Applied Sciences, Maharaja Surajmal Institute of Technology, C-4, JanakPuri, New Delhi Email:anu.ahlawat@gmail.com RESEARCH ARTICLE OPEN ACCESS
  • 2. International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019 Available at www.ijsred.com ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 646 Circuit Boards, plastic casings, cables ; Poly Vinyl Chloride (PVC) in cable sheathing ; PBD/PBDE in plastic parts of electronics ; and various other substances [6] E-Waste contains around 7% of world’s gold. As compared to gold ore, e-Waste have 100 times more gold. Poor management of e-waste is ensuing in a significant loss of rare, scarce and valuable raw materials viz gold, platinum, cobalt, apart from polluting the planet and effecting health adversely. In India, ill effects of improper e-waste processing - leaching of hazardous contents from landfills to soil, contamination of rivers & underground water sources, emission of gases to air, impacted human through inhalation of gases emitted during recycling and through contact with hazardous substances used in recovery processes – is substantially visible. With the support of legislation which has been updated time to time, Ministry of Environment and Forests, Government of India along with agencies like Central Pollution Control Board, State Pollution Control Board and others are handling, managing, controlling the e- Waste related affairs including Restriction of Hazardous Substance (RoHS) directives in India. Despite it, no formal data from Government is readily available. However, by efforts of some Non Government Organisations ( NGOs) , the assimilated data is eye opener and informs that still e-Waste collection, segregation, recycling is majorly dealt by informal sector and labour health & environment issues are grossly ignored. II. SIZE OF ELECTRONICS WASTE E-waste today often consists of products from the past. In year 2016, 44.7 Million Tonnes (MT) of e- Waste was generated globally by adding in 16.8 MT small equipment, 9.1 MT large equipment, 7.6 MT temperature exchange equipment, 6.6 MT screens, 3.9 MT small IT equipment, 0.7 MT lamps [1] . Though forecasting the volumes of e-waste generation is difficult, yet considering the current pace and in the absence of some effective controlling & managing mechanism, it is expected that by 2021 the annual total volume may surpass 52 million tonnes. Some other indicators - EE devices connected to the internet at between 25-50 billion by 2020 i.e. three times the world population; By 2040, carbon emissions from production and use of electronics including devices like PCs, laptops, monitors, smartphones and tablets reaching 14% of total emissions; By 2060, the world’s consumption of raw materials is set to double - give insight that by 2050, the volume of e-waste, in the worst-case scenario, could top 120 million tonnes annually. India generates around two million tonnes of e- waste per annum and is at fifth rank among e-waste producing countries, after the US, China, Japan and Germany. However, there is no government data on e-waste generation in the country (ii) . However important indicators -rapid growth of Mobile subscriber in India from 310 million in 2001 to 1.1 billion in 2016 which is nearly 4 times that of United States and ranking second only to China in the world, which has 1.3 billion subscribers ; 57 million computers in use and plethora of other gadgets and consumer electronics- predict growth in domestic e-Waste generation in India. 10 year ago, around 70 % of e-Waste processed or disposed of in India was originated from abroad. Afterward efforts to control the inflow have been effective , but surge in domestic consumption have overshoot it, leading to an over all growth in e-Waste generation. Computer equipment and mobile telephones as the principal e-waste generators in India contributing around 70 per cent of the total e-waste generated in
  • 3. International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019 Available at www.ijsred.com ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 647 India, while telecommunication equipment attribution is about 12 per cent. Mumbai is first among cities generating around 1,20,000 tonnes of e-waste per annum, followed by Delhi and Bengaluru with generation of 98,000 and 92,000 tonnes of e-waste per annum [4] . About 70 per cent of heavy metals in landfills is sourced from E- waste. III. ELEMENTS AND ECONOMIC VALUE: There are so many elements which are scarcely available in nature but available in e-Waste with good recycling rates. Extraction of these scarce elements from e-Waste is more economical than their extraction from ore. Also extraction from ore mines is also causing enormous pollution. Availability in nature, pollution caused by mining and recycling rates of some important elements [1] are which are available in e-Waste is depicted in Tables 1: TABLE1 : CLASSIFICATION OF ELEMENTS PRESENT IN E-WASTE BASED UPON PARAMETERS-THEIR AVAILABILITY IN NATURE, POLLUTION CAUSED DURING MINING , AND RECYCLING RATES : Availability in Nature: Low < Scarcity in Nature > High Available in Nature Limited Availability, Future Risk of Supply Rising Threats from increased use Serious Threat in Next 100 years Na, K, Rb, Cs, Be, Ca, Ba, LA, Ti, Ta, Te, Fe, Al, Si, Ce, Pr, Sm, Eu, Gd, Tb, Ho, Er, Yb Li, Mg, Sr, Sc, Y, Zr, Nb, Cr, Mo, W, Mn, Co, Ni, Pd, Cu, Au, Cd, Hg, Ti, Sn, Pb, Sb, Bi, Se, Nd Pt Ag, Zn, Ga, In, Ge, As, Te Pollution Caused by Mining of elements: Low < Pollution Caused by Mining > High Ca Li, Mg, Sr, Ba, Y, Ti, Zr, Nb, Mn, Fe, Co, Cd, Al, Sn, Pb Be, Ni, Bi Sc, Hf, Ta, Cr, Mo, W, Cu, Ag, Zn, Ga, In, Tl, Ge, As, Sb, Se, Te Pd Re, Pt, Hg Na, K, Rb, Cs, La, Si, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er, Yb Au Recycling Rates of elements from e-Waste: Low < Recycling Rate > High <1% 1-10% >10- 25% > 25- 50% >50 % Li, Be, Sr, Ba, Sc, Y, La, Zr, Hf, Ta, Ga, In, Tl, Ge, As, Bi, Se, Te, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Ho, Er, Yb Hg, Sb W, Cd Mg, Mo Ti, Nb, Cr, Mn, Re, Fe, Co, Ni, Pd, Pt, Cu, Ag, Au, Zn, Al, Sn, Pb By seeing the elements in above table and analysing pollution in their mining, scarcity in nature vis a vis recycling rates gives an enormous clue that scarce elements like Gold (Au) having high recycling rate and polluting environment heavily during their mining must be recycled as it adds enormous value to e-Waste Economy Chain and in environment protection. Elements such as Iron, Aluminium, Copper amounts around 40-50 % of weight of e-Waste whereas valuable elements are found in lesser amounts but are still of high importance. TABLE 2: METAL COMPOSITION OF SOME COMMON ELECTRONIC APPLIANCES [3] e-Waste Items Weight (%) Weight (ppm) Fe Cu Al Pb Ni Ag Au Pd TV Board 28 10 10 1 0.3 280 20 10 PC Board 7 20 5 1.5 1 1000 250 110 Mobile Phone 5 13 1 0.3 0.1 1380 350 210 Portable Audio System 23 21 1 0.14 0.03 150 10 44
  • 4. International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019 Available at www.ijsred.com ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 648 DVD Player 62 5 2 0.1 0.05 115 15 4 Calculat or 4 3 5 0.1 0.5 260 50 5 Printed Circuit Board 5.3 26. 8 1.9 NR 0.14 3300 80 NR E-waste Mixture 36 4.1 4.9 0.29 1.0 NR NR NR Some precious metals like gold are contained in E- Waste as large as around 7% of world’s gold and 100 times more available in as compared to gold ore. 24 kg Gold is present in 148.4 tons (1 million units) of Mobile phones and to extract the same weight of Gold from gold ore, 23763.4 tons of gold ore is to be processed. IV. HEALTH & ENVIRONMENTAL IMPACT: EEEs are manufactured with various components , some containing high value substances. Recycling of these substances may be toxic and have an adverse impact on human health and the environment ,if not handled properly. It may affect seriously human involved in recycling process and/or living in proximity to places where e-waste is recycled or burnt [5] . A computer contains highly toxic chemicals like Lead, Cadmium, Mercury, Beryllium, BFR, Poly Vinyl Chloride and Phosphor compounds. TABLE 3 : HAZARDOUS OF PROCESSING OF WASTE COMPUTER ON HUMAN LIFE AND ENVIRONMENT e-Waste Component Process Potential Occupational Hazards Potential Environmental Hazards Cathode Ray Tubes Breaking to extract copper and dumping Silicosis, Cuts from glass, Inhalation or contact with toxic phosphor containing cadmium or other metals Lead, Barium and other heavy metals leaching into ground water and release of toxic phosphor in air. Printer Circuit Boards De-soldering to removing computer chips and Tin and Lead inhalation, Possible Brominated Dioxin, Beryllium, Cadmium Air emission of the same substances open burning and Mercury inhalation Chips and other Gold- plated items Chemical stripping using nitric and hydrochloric acid along riverbanks Acid contact with eyes, skin may result in permanent injury; Inhalation of acids fumes, chlorine and sulfur dioxide gases can cause respiratory difficulty ,pulmonary allergy, respiratory failure and death Hydrocarbons, heavy metals, brominated substances etc. discharged directly into river ;Acidifies the river destroying fish and flora Plastics from the computer and peripherals Shredding and low- temperature melting Probable hydrocarbon, brominated dioxin and PAH exposure to workers and people living in the nearby area Emission of brominated dioxins and heavy metals and hydrocarbons Steel, Copper & metal smelting Furnace recovers steel or copper from waste Exposure to dioxins and heavy metals Emission of dioxins and heavy metals Wires Open burning to recover copper Brominated and Chlorinated Dioxin and PAH exposure to workers and people living in nearby area Hydrocarbon and ashes including PAHs discharged into air, water and soil V. REGULATION AND ECOSYSTEM DEVELOPMENT With the new E-Waste Management Rules 2016, responsibility of recycling now lies with equipment manufacturers too to take up the task of recycling the products they produce. Though anticipated outcome is not feasible until & unless , society at large is sensitised about its necessity to manage e- Waste. Taking measures by Government to turn the informal sector into a well-managed system will not be adequate. In most proposed sustainable e-waste models , informal e-waste value chains are offered no alternate livelihood options and ultimately they will lose their livelihoods. Safe, low-cost or intermediate e-waste recycling technology, enabling appropriate finance mechanism, are the
  • 5. International Journal of Scientific Research and Engineering Development-– Volume 2 Issue 5, Sep – Oct 2019 Available at www.ijsred.com ISSN : 2581-7175 ©IJSRED: All Rights are Reserved Page 649 need of the day , so that some alternative livelihood options are emerged for existing e-waste markets by re-shaping value chain for the better instead only imposing regulations. It requires better cooperation and trust between national and local governments, manufacturers and retailers, and small informal businesses. An ecosystem- where informal sector functions alongside and with the formal, new innovative &equitable models of functioning, with key economic and non-economic incentives for informal and formal, large and small-scale stakeholders , with greater understanding of the diversity, inequalities and vulnerabilities that exist within the informal e-waste sector - is to be developed in India for settling a balance among all stakeholder to manage e-Waste better. Improved scientific understanding of the different environmental and health risks along the chain, and the technologies that could mitigate risks, will also serve to inform better targeted interventions. VI. CONCLUSIONS In India, significant size of manpower in informal sector is involved recycling of e-Waste to extract elements by using primitive means resulting in health and environment hazards. Despite regulations, the concerns of livelihood, & lack of awareness are important constraints for managing e-Waste in appropriate ways. A suitable model is to be evolved including all stakeholders. One approach could be to create an ecosystem having all stakeholders in one value chain - unorganized sector to concentrate on collection, dismantling, segregation etc; whereas the metal extraction, recycling and disposal could be done by the organized sector ; setting responsibilities with manufacturers to recycle their obsolete produce; and awareness of masses - so that e-Waste can be managed in a better way. VII. REFERENCES [1] A New Circular Vision for Electronics -Time for a Global Reboot, a report in support of the United Nations e-Waste Coalition, Jan 2019 , published as part of the PACE. [2] Clean and inclusive Recycling e-Waste in China and India by Kate Lines Garside, with Satish Sinha and Irina Fedorenko , March 2016 - published by International Institute for Environment & Development, UK [3] Status of E-Waste In India- A Review, IsraelCherukuri, Nazia Sultana And SankaraPitchaiahPodila , IOSR Journal of Environmental Science, Toxicology and Food Technology e-ISSN: 2319-2402, p- ISSN: 2319- 2399.Volume 12, Issue 11 Ver. I (November. 2018), PP 08-16 [4] Health hazards caused by unorganised e-waste disposal by V. Ranganathan – web article at link https://yourstory.com/2018/06/unorganised-e-waste-disposal-dangers [5] E-waste: From Toxic to Green India, web article at United Nations- Climate Change [6] Electronic Waste and India by Dr. S. Chatterjee, an article on website of Ministry of Electronics & Information Technology, Government of India