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COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 1 of 97
Introduction: Many hazardous substances are used in the construction industry COSHH Assessments must be carried out with the aim of elimination,
substitution and reduction of exposure to hazardous substances.
COSHH Assessments 97 pages
Contents
01 Concreting, Grouts, Resins 01r Sikadur 52 05 Miscellaneous
01a Cement, Wet Concrete , Mortar 05a Welding Rods for Steel
01b Flowcable – Post-tensioning 05b Sipoxy Base - Repairs to DI pipes
01c Masterflow – Bridge Bearings 02 Waterproofing 05c Sipoxy Hardner - Repairs to DI pipes
01d Concure A – Curing Agent 02a Igasol EmulsionSG (F) by Sika 05d Bentonite - 132 KV Cables
01e Rheofinish 225D – Release Agent 02b Bituthene 8000 & Protection Board 05e Jotashield Concrete Paint
01f Sika 101 - Crack Injection 05f Jotashield Tex Ultra
01g Sika 210 - Crack Injection 03 Asphalt Paving 05g JOTUN SILOXANE A PRIMER
01 h Nitobond EP Base 03a Bitumen 05h Jotun Thinner No. 10
01 i Nitobond EP Hardener 03b Asphalt Release Agent 05j Transformer Oil
01 j Nitofill EPLV Base 03b Prime Coat MC 70 05k Paint for Kerbs
01 k Nitofill EPLV Hardener 03c Tack Coat SS1H 05 L Hydrochloric Solution 40%
01l Frosroc Solvent 102 05m Trichloroethylene
01m BASF Emaco R907 Plus Liquid 04 Plant & Equipment 05n Rockwool Thermal Panels
01n BASF Emaco R907 Plus Powder 04a Diesel 05o Welding Rod for HDPE
01o BASF Emaco S22NB 04b Lubricating Oil 05p Universal Powerwash Liquid
01p BASF Emaco S23 BC 04c Jet A1 Aircraft Fuel 05q Double Sided Butyl for Cladding System
01q Masterflow 928 05r Sealer’s Choice™ Gold for Terrazo
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 2 of 97
05 Miscellaneous Cont 07 Paints for Steel 11 Fireproofing
05s Thixothane Coating ( VJ Couplings) 07a Juton Penguard Express ZP 11a Cafco 300
05t Thixothane Hardener ( VJ Couplings) 07b Juton Steelmaster 60WB
05 u Thinner # 7 Juton 07c Pioner Topcoat 12 Epoxy Coating
05 v Thermoplastic Road Paint 12a Nitocote EPU Base
05w HEMPADUR MASTIC 45889 Base O8 Sealants for Pavement Concrete 12b Nitocote EPU Hardener
05X HEMPEL'S CURING AGENT 95881 08a Fisher Injection Mortar FIS EM 12c Nitomortar FC (B) Base
05Y Road Marking Paint 08b Sure Anchor Grout J-50 12d Nitomortar FC (B) Hardener
05z Galvafroid 08c Igas 1h (Cold Sealant)
05ab CRC Galva Brite 08d Igas K ( Hot Sealant) 13 Tiling Mortar Adhesives
13a Sika Ceram 201
06 Plaster & Render 09 Chemical Adhesive 13b Marble, Granite& traventine Premium
bed mortar
06a Bonding Rush Coat BRC (Conmix) 09a Hilti Hit RE 500 13c Polyblend Non-sanded Grout
06b Premix CP2 (Conmix)
06c Premix SRC-1 (Mineralite) 10 Roof Waterproofing 14 Sundry
06d Premix SRC-2 (Mineralite) 10a IMI Concrete Primer 14a Juton Barrier 80
06e Premix Undercoat SP1 (Mineralite) 10b IMI Elastomeric Membrane 14b Juton Penguard
06f Mineralite Finish Coat (Mineralite) 10c IMI Ekoflash 14c Juton Hardtop XP
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 3 of 97
Hazardous Substance :- 01a Cement / Wet Concrete & Mortar
Cementitious Repair mortar
Suppliers name, :- CCCTAVJV Batching on site.
Use :- Wide variety of applications.
Storage Precautions :- No special storage requirements.
Disposal Procedure :- Dispose of as inert material, prevent dust generation.
Spillage Procedure :- Recover spilled material avoiding generating dust.
Health Effects Controls First aid measures & Emergencies
Eye contact - Eye contact with cement powder may cause
serious injury.
Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek
immediate medical attention.
Skin burns – cement may have an irritating effect on moist
skin and may cause serious burns.
Wear Gloves or barrier cream. Wear waterproof foot wear or
wellington boots. Clothing contaminated by cement should
be removed and washed thoroughly before use.
Wash with copious amounts of clean water.
Ingestion - May cause nausea, vomiting and diarrhoea Wash hands before eating or smoking. Wash out mouth and drink plenty of water. Do
not induce vomiting. Seek medical advice if large
amount is swallowed.
Inhalation - Frequent inhalation of cement powder over a
long period of time increases the risk of developing lung
diseases.
Wear mask (respirator) rated for cement dust, at all times
when mixing cement.
If irritation occurs, move to fresh air. If nose or
airways become inflamed seek medical advice.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 4 of 97
Hazardous Substance :- 01b Flowcable
Suppliers name, :- BASF
Use :- Grout expanding agent
Storage Precautions :- No special storage requirements.
Disposal Procedure :- Dispose of as inert material, prevent dust generation.
Spillage Procedure :- Recover spilled material avoiding generating dust.
Health Effects Controls First aid measures & Emergencies
Eye contact - The dust is abrasive and irritating to the eyes
and may be capable of causing corneal scarring.
Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek
immediate medical attention.
Skin – Slight irritant and may cause dermatitis. In the
presence of moisture such as perspiration it can dry skin and
cause alkali burns.
Wear Gloves or barrier cream. Clothing contaminated by
cement should be removed and washed thoroughly before
use.
Wash with copious amounts of clean water.
Ingestion - May result in irritation and burns to mouth and
stomach
Wash hands before eating or smoking. Wash out mouth and drink a glass of water.
Inhalation – The dust is harmful and irritating to the upper
respiratory tract and lungs. The materials present a hazard
from repeated exposures over long periods.
Wear dust mask at all times when mixing with cement. If irritation occurs, move to fresh air.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 5 of 97
Hazardous Substance :- 01c Masterflow 410
Manufacturer’s name, :- BASF Constructional Chemicals UAE LLC
Use :- Grouting Bridge Bearings
Storage Precautions :- Store in cool,dry place with ventilation and away from food stuff.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain spilled material & remove with inert absorbent material.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Causes irritation
Do not get in eyes. Solvent resistant safety eyewear
recommended. MSDS on site & with site clinic
Flush immediately with large amounts of water.
Get medical attention. Refer to MSDS
Skin burns –
Causes irritation. May develop sensitisation through shin
contact.
Wear appropriate chemical resistant protective gloves and
protective wear. MSDS on site & with site clinic
Wash affected area with soap water. Remove
soiled clothing. Get medical attention if irritation
persists Refer to MSDS
Ingestion –
Stomach / intestinal irritation nausea vomiting diarrhea.
Wash hands before eating or smoking MSDS on site & with
site clinic
Rince out mouth and consult site doctor
immediately.. Refer to MSDS
Inhalation –
Harmful . Long term exposure can result in progressive
symptoms & impaired pulmonary function.
Use appropriate dust mask / respirator. MSDS on site & with
site clinic
Leave the area to obtain fresh air. If continued
difficulty in breathing persists get medical
attention.. Refer to MSDS
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 6 of 97
Hazardous Substance :- 01d Concure A
Suppliers name, :- Fosroc UAE
Use :- Curing compound for concrete
Storage Precautions :- Store away from sources of ignition, keep containers dry and tightly closed.
Disposal Procedure :- Dispose of through an authorised waste contractor
Spillage Procedure :- Recover spilled material.
Fire Data & Extinguishing Media :- Flammable, gives off toxic fumes. Extinguish media: carbon dioxide, powder, foam or water fog – do not use water
jets. Use Self-contained breathing apparatus.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Vapour may cause irritation.
Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek
immediate medical attention.
Skin burns –
May be absorbed through the skin. May defat the skin.
Wear Gloves or barrier cream. Clothing contaminated by
cement should be removed and washed thoroughly before
use.
Wash with copious amounts of clean water and
soap.
Ingestion -
May cause nausea, vomiting and diarrhoea
Wash hands before eating or smoking. Do not induve vomiting, obtain medical attention
Inhalation –
Mist and vapour may cause irritation to nose and respiratory
tract.
Use in well vented areas Remove from exposure, rest and keep warm and
obtain medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 7 of 97
Hazardous Substance :- 01e Rheofinish 225D – Release Agent
Suppliers name, :- BASF
Use :- Relase agent for formwork
Storage Precautions :- Store under cover
Disposal Procedure :- Dispose of through an authorised waste contractor
Spillage Procedure :- Recover spilled material.
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
Particulates may cause irritation, which is typically
characterized by redness and excessive tear production.
Safety glasses with side shields. In processes where the
product is in contact with hot materials a face shield should be
worn.
Flush eye with clear water for several minutes. Remove
contact lens if worn. If irritation persists seek medical
attention.
Skin burns
Rheofinish may have an irritating effect on moist skin and
may cause serious burns..
Cloth or leather work gloves. In processes where the product
is in contact with hot materials thermal protection gloves,
apron and arm protection should be worn.
Seek medical attention immediately
Ingestion
May cause nausea, vomiting and diarrhoea.
Wash hands before eating or smoking. First aid is not normally required.
Inhalation
Frequent inhalation of Rheofinish over a long period of time
increases the risk of developing lung diseases.
Wear mask when applying Rheofinish Remove affected person to fresh air. If irritation persists
then seek medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 8 of 97
Hazardous Substance :- 01f Sika Injection 101
Manufacturer’s name, :- Sika Limited, Hertfordshire, England
Use :- Injecting cracks in concrete.
Storage Precautions :- Store in the original container securely closed. Keep away from foodstuffs.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain and absorb with inert absorbent material. Transfer into container for recovery or disposal.
Health Effects Controls First aid measures & Emergencies
Eye contact -
May causes eye irritation
Do not get in eyes. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids.
Get medical attention.
Skin contact –
May cause skin irritation.
Use barrier skin cream or gloves Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes. Obtain
medical attention if symptoms occur.
Ingestion –
Can cause gastronintestinal disturbance
Wash hands, forearms and face thoroughhlyafter handling,
before eating, smoking and using the lavatory and at the end
of the work period.
Do not induce vomiting unless directed to do so by
medical personnel. Mainyain an open airway. Seek
medical attention.
Inhalation –
May causes irritation
Good general ventilation should be sufficient to control
worker exposure to airborne contaminants.
Obtain medical attention if symptoms occur.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 9 of 97
Hazardous Substance :- 01g Sika Injection 201
Manufacturer’s name, :- Sika Limited, Hertfordshire, England
Use :- Injecting cracks in concrete.
Storage Precautions :- Store in the original container securely closed. Keep away from foodstuffs.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain and absorb with inert absorbent material. Transfer into container for recovery or disposal.
Health Effects Controls First aid measures & Emergencies
Eye contact -
May causes eye irritation
Do not get in eyes. Immediately flush eyes with plenty of water,
occasionally lifting the upper and lower eyelids.
Get medical attention.
Skin contact –
May cause skin irritation.
Use barrier skin cream or gloves Flush contaminated skin with plenty of water.
Remove contaminated clothing and shoes. Obtain
medical attention if symptoms occur.
Ingestion –
Harmful if swallowed
Wash hands, forearms and face thoroughhlyafter handling,
before eating, smoking and using the lavatory and at the end
of the work period.
Do not induce vomiting unless directed to do so by
medical personnel. Mainyain an open airway. Seek
medical attention.
Inhalation –
May causes irritation
Good general ventilation should be sufficient to control
worker exposure to airborne contaminants.
Obtain medical attention if adverse health effects
persit or are severe.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
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Hazardous Substance :- 01h Nitobond EP Base
Manufacturer’s name, :- Fosroc
Use :- Epoxy Bonding Agent
Storage Precautions :- Keep containers dry and tightly closed
Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site.
Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means
Health Effects Controls First aid measures & Emergencies
Eye contact -
Causes transient irration
Avoid eye contact. Irrigate immediately with copious quantities of
water for several minutes. Obtain medical attention
if irritation persists.
Skin contact –
Irritation. May cause sensitisation.
Avoid skin contact. Maintain good standards of personal
hygiene.
Wash thoroughly with soap and water or suitable
skin cleanser as soon as possible. Obtain medical
advise if skin discorders develop.
Inhalation –
May cause respiratory irritation
Ensure adequate ventilation. Remove from exposure
Ingestion –
May cause irritation of mouth, throat and digestive tract.
Do not eat, drink or smoke whilst using this product. Obtain medical attention. Do not induce vomiting.
Beware of aspiration if vomiting occurs.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
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Hazardous Substance :- 01i Nitobond EP Hardener
Manufacturer’s name, :- Fosroc
Use :- Epoxy Bonding Agent
Storage Precautions :- Store in cool, dry areas. Keep away from foodstuffs and food containers. Store in original container.
................................................Never transfer to a unlabelled container
Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site.
Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Irritating and may injure eye tissue if not removed promptly.
Avoid eye contact. Wear goggles conforming to EN 166 Irrigate immediately with copious quantities of
water for several minutes. Obtain medical attention
if irritation urgently
Skin contact –
Harmful by absorption through the skin. Moderately
irritating. May cause sensitisation.
Avoid skin contact. Maintain good standards of personal
hygiene. Wear impervious gloves e.g. PVC
Wash immediately with soap and water or suitable
skin cleanser. Obtain medical advise if skin
discorders develop. Remove contaminated clothing
immediately.
Inhalation –
Toxic by inhalation. May cause respiratory irritation
Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure, rest and keep warm and
obtain medical attention urgently.
Ingestion –
Toxic if swallowed. May cause nausea, vomiting and
diarrhoea.
Do not eat, drink or smoke whilst using this product. Wash out mouth with water and give sips of cold
water to soothe the affected parts. Do not induce
vomiting. Obtain medical attention urgently.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 12 of 97
Hazardous Substance :- 01j Nitofill EPLV Base
Manufacturer’s name, :- Fosroc
Use :- Concrete Crack Repair
Storage Precautions :- Keep containers dry and tightly closed.
Handling :- Maintain good standards of personal hygiene. Avoid shin and eye contact. Do not eat, drink or smoke
..................................................whilst using this product. Ensure adequate ventilation.
Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site.
Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers.
......................................................................................Dispose of as waste.
Fire Hazard Details :- Flash point >150*C. Use carbon dioxide, power, foam or water fog – do not use water jets to extinguish a fire
Health Effects Controls First aid measures & Emergencies
Eye contact -
Irritation
Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of
water for several minutes. Obtain medical attention
if irritation persists.
Skin contact –
Irritation. May cause sensitisation.
Avoid skin contact. Maintain good standards of personal
hygiene. Wear impervious gloves e.g. PVC. Change
contaminated clothing immediately and clean before re-use.
Wash thoroughly with soap and water or suitable
skin cleanser as soon as possible. Obtain medical
advise if skin discorders develop.
Inhalation –
May cause respiratory irritation
Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure.
Ingestion –
May cause irritation of mouth, throat and dijestive tract.
Do not eat, drink or smoke whilst using this product. Obtain medical attention urgently. Do Not induce
vomiting. Beware of aspiration if vomiting occurs.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 13 of 97
Hazardous Substance :- 01k Nitofill EPLV Hardener
Manufacturer’s name, :- Fosroc
Use :- Concrete Crack Repair
Storage Precautions :- Store in cool, dry area. Store only in original container. Neverleave a container unsealed.
Handling :- Maintain good standards of personal hygiene. Avoid shin and eye contact. Do not eat, drink or smoke
..................................................whilst using this product. Ensure adequate ventilation.
Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site.
Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers.
......................................................................................Dispose of as waste.
Fire Hazard Details :- Flash point 110*C. Use carbon dioxide, power, foam or water fog – do not use water jets to extinguish a fire
Health Effects Controls First aid measures & Emergencies
Eye contact -
Severe irritation. Causes irreversible damage to eye tissue if
not removed promptly.
Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of
water for several minutes. Obtain medical attention
if irritation persists.
Skin contact –
Corrosive – causes burns. May cause sensitisation.
Avoid skin contact. Maintain good standards of personal
hygiene. Wear impervious gloves e.g. PVC. Change
contaminated clothing immediately and clean before re-use.
Wash thoroughly with soap and water or suitable
skin cleanser as soon as possible. Remove
contaminated clothing immediately.
Inhalation –
Irritating to respiratory system.
Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure.
Ingestion –
Corrosive – causes severe damage to mouth, throat and
dijestive tract.
Do not eat, drink or smoke whilst using this product. Wash mouth with water. Obtain medical attention
urgently.. Do Not induce vomiting. Beware of
aspiration if vomiting occurs.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 14 of 97
Hazardous Substance :- 01l Fosroc Solvent 102
Manufacturer’s name, :- Fosroc
Use :- Solvent cleaning
Storage Precautions :- Store away from sources of ignition. Store out of direct sunlight.
Handling :- Do not use near sources of ignition. Use only in well ventilated areas. Avoid breathing vapours. Avoid
.................................................skin and eye contact.
Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site.
Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Dispose of as waste.
Fire Hazard Detail :- Avoid any source of ignition. Direct sunlight. Temperatures avove 30*C. To extinguish use carbon dioxide, power,
foam or water fog do not use water jets.
Health Effects Controls First Aid Measures & Emergencies
Eye contact -
Irritating, but does not injure eye tissue. Vapour may cause
irritation.
Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of
water for several minutes. Obtain medical attention
if irritation persists.
Skin contact –
May be absorbed through the skin. May defat the skin.
Avoid skin contact. Maintain good standards of personal
hygiene.
Wash thoroughly with soap and water or suitable
skin cleanser as soon as possible. Remove
contaminated clothing immediately.
Inhalation –
Mist and vapours may cause irritation to nose and respiratory
tract.
Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure, rest and keep warm and
obtain medical attention urgently.
Ingestion –
May cause nausea, vomiting and diarrhoea. Aspiration of
liquid during ingestion or from vomiting may cause severe
chemical pneumonitis.
Do not eat, drink or smoke whilst using this product. Obtain medical attention urgently. Do Not induce
vomiting. Beware of aspiration if vomiting occurs.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 15 of 97
Hazardous Substance : 01m Emaco R907 Plus Liquid
Manufacturer’s name : BASF
Description :- :
Storage Precautions : Store in shaded areas and away from direct sunlight
Disposal Procedure :
Spillage Procedure : Absorb with suitable material e.g. sand & earth, seal in plastic bag & bury in landfill.
Fire Fighting Measures
Extinguishing media : Non-flammable material.
Recommendations :
Personal Precautions :
Health Effects Controls First aid measures & Emergencies
Eye contact -
N/A
Safety goggles
Flush immediately with plenty of water for at least
15 minutes. Get
medical attention if irritation persists.
Skin –
N/A
Impervious gloves
Remove contaminated clothes immediately. Wash
affected area
with soap and plenty of water.
Ingestion –
N/A
Wash hands before breaks and after finishing work. Do not eat,
drink or smoke at workplace.
Inhalation -
N/A
Provide for good ventilation
Remove affected person to fresh air. If symptoms
persist obtain
medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 16 of 97
Hazardous Substance : 01n Emaco R907 Plus Powder
Manufacturer’s name : BASF
Description :- : Blend of cementitious powder and mineral fillers.
Storage Precautions : Powder product. Must be protected from dampness and water.
Disposal Procedure :
Spillage Procedure : Reuse if possible OR Sweep up powder as soon as possible, andnbury in the landfill.
Fire Fighting Measures
Extinguishing media : Non-flammable material.
Recommendations :
Personal Precautions :
Health Effects Controls First aid measures & Emergencies
Eye contact -
Irritating to eyes.
Safety goggles
Flush immediately with plenty of water for at least
15 minutes. Get medical attention if irritation
persists.
Skin –
Irritating to skin.
Impervious gloves
Remove contaminated clothes immediately. Wash
affected area with soap and plenty of water.
Ingestion –
No data available
Wash hands before breaks and after finishing work. Do not eat,
drink or smoke at workplace.
If swallowed obtain medical attention. Do not induce
vomiting. Give water to drink.
Inhalation -
Irritating to respiratory system.
Dust Mask.
Powder product – take care when handling. Remove
affected person to fresh air. If symptoms persist obtain
medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 17 of 97
Hazardous Substance : 01o Emaco S22NB
Manufacturer’s name : BASF
Description :- : Blend of cementitious powder and mineral fillers
Storage Precautions : Store out of direct sunlight, clear of ground on pallets protected from rainfall. Avoid excessive compaction
Disposal Procedure :
Spillage Procedure : Reuse if possible. OR Mix with water and allow to harden, and dispose in landfill.
Fire Fighting Measures
Extinguishing media : Non-flammable material.
Recommendations :
Personal Precautions :
Health Effects Controls First aid measures & Emergencies
Eye contact -
N/A
Safety goggles
Flush immediately with plenty of water for at least 15
minutes. Get medical attention.
Skin –
Prolonged exposure may cause skin sensitization.
Impervious gloves. Observe the usual precautions when handling
chemicals
Remove contaminated clothes immediately. Wash
affected area with soap and plenty of water.
Ingestion –
N/A
Wash hands before breaks and after finishing work. Do not eat,
drink or smoke at workplace.
If swallowed obtain medical attention. Do not induce
vomiting.
Inhalation -
Prolonged exposure may cause irritation to respiratory system.
Dust Mask
Remove affected person to fresh air. If symptoms
persist obtain medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
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Hazardous Substance : 01p Emaco S23NB
Manufacturer’s name : BASF
Description :- : Blend of cementitious powder and mineral fillers
Storage Precautions : Store out of direct sunlight, clear of ground on pallets protected from rainfall. Avoid excessive compaction
Disposal Procedure :
Spillage Procedure : Reuse if possible. OR Mix with water and allow to harden, and dispose in landfill.
Fire Fighting Measures
Extinguishing media : Non-flammable material.
Recommendations :
Personal Precautions :
Health Effects Controls First aid measures & Emergencies
Eye contact -
Irritating to eyes
Safety goggles
Flush immediately with plenty of water for at least 15
minutes. Get medical attention.
Skin –
Irritating to skin
Impervious gloves. Observe the usual precautions when handling
chemicals
Remove contaminated clothes immediately. Wash
affected area with soap and plenty of water.
Ingestion –
N/A
Wash hands before breaks and after finishing work. Do not eat,
drink or smoke at workplace.
If swallowed obtain medical attention. Do not induce
vomiting.
Inhalation -
Irritating to respiratory system.
Dust Mask
Remove affected person to fresh air. If symptoms
persist obtain medical attention.
Hazardous Substance : 01q Masterflow 928
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 19 of 97
Manufacturer’s name : Degussa Building Systems
Storage Precautions : In an area that is ventilated
Disposal Procedure :
Spillage Procedure : Clean up promptly by sweeping or vacuum.
Description :- : Grout
Fire Fighting Measures
Extinguishing media : Water fog, carbon dioxide, dry chemical.
Recommendations :
Personal Precautions : Wear full protective gear
Health Effects Controls First aid measures & Emergencies
Eye contact -
Can cause severe irritation, redness, tearning and blurred vision. Wear as appropriate: safety glasses with side shields.
Flush eyes with water, lifting upper and lower lids
occasionally for 15 minutes. Seek medical attention.
Skin –
Can cause slight to moderate irritation due to abrasive action. In
combination with water, repeated or prolonged exposure can
cause moderate to severe alkali burns.
Wear as appropriate; gloves
Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water. Seek medical
advice.
Ingestion –
Irritating to mouth, throat and stomach.
Wash hands before meal breaks.
Do not induce vomitingwithout medical advice. If
conscious drink plenty of water. Seek medical advice.
Inhalation –
Inhalation of dust may cause coughing and laboured breathing
and possible temporary but irresible irritation on mucous
membranes and respiratory tract.
In case of insufficient ventilation wear respirator
Remove victim from exposure. If difficulty with breathing
administer oxygen.
Hazardous Substance : 01r Sikadur 52 Part A
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 20 of 97
Manufacturer’s name : Sika Ltd
Description :- : 2-component epoxy resin for crack injection and stabilising.
Storage Precautions :
Storage area should be: cool. dry. Storage temperature should be controlled to between 5 and 25 °C.
Store in the original container securely closed . Keep away from foodstuffs
Disposal Procedure : Dispose of as Special Waste. Arrange for disposal via a licensed waste contractor.
Spillage Procedure : Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal.
Fire Fighting Measures
Extinguishing media : Use foam, dry chemical or carbon dioxide.
Recommendations :
Personal Precautions : Wear full protective clothing and self-contained breathing apparatus.
Health Effects Controls First aid measures & Emergencies
Eye contact - Irritating to the eyes.
Wear chemical goggles.
Immediately flood the eye with plenty of water for at
least 15
minutes, holding the eye open.
Obtain medical attention urgently.
Skin – Frequent or prolonged skin contact may cause
some local short term skin irritation.
Wear suitable impervious gloves. (butyl / nitrile type)
The insides of gloves must be kept scrupulously clean.
Wipe off as much as possible with a clean dry
cloth. Wash skin
thoroughly with soap and water.
Solvents should not be used to clean skin because
they may
increase the penetration of the material.
Ingestion – Use of the basic principles of Industrial Hygiene will enable this
material to be used safely.
Wash out mouth with water. Obtain medical
attention.
Inhalation - Respiratory protection not normally required.
Remove from exposure. In cases of possible
respiratory irritation or if feeling unwell in cases of
prolonged exposure,obtain medical attention.
Hazardous Substance : 01r Sikadur 52 Part B
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 21 of 97
Manufacturer’s name : Sika Ltd
Description :- : 2-component epoxy resin for crack injection and stabilising.
Storage Precautions :
Storage area should be: cool. dry. Storage temperature should be controlled to between 5 and 25 °C.
Store in the original container securely closed . Keep away from foodstuffs
Disposal Procedure : Dispose of as Special Waste. Arrange for disposal via a licensed waste contractor.
Spillage Procedure : Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal.
Fire Fighting Measures
Extinguishing media : Use foam, dry chemical or carbon dioxide.
Recommendations :
Personal Precautions : Wear full protective clothing and self-contained breathing apparatus.
Health Effects Controls First aid measures & Emergencies
Eye contact - Causes burns. This material is corrosive to
the eye.
Wear chemical goggles.
Immediately flood the eye with plenty of water for at
least 15 minutes, holding the eye open.
Obtain medical attention urgently.
Skin – This material is corrosive to the skin. The
possibility of allergic sensitisation should be considered
Wear suitable impervious gloves. (butyl / nitrile type)
The insides of gloves must be kept scrupulously clean.
Wipe off as much as possible with a clean dry
cloth. Wash skin thoroughly with soap and water.
Solvents should not be used to clean skin because
they may increase the penetration of the material.
Ingestion – Harmful if swallowed.
Use of the basic principles of Industrial Hygiene will enable this
material to be used safely.
Do not induce vomiting.
Obtain medical attention.
Inhalation - Harmful by inhalation,
Respiratory protection not normally required.
Remove from exposure. In cases of possible
respiratory irritation or if feeling unwell in cases of
prolonged exposure,obtain medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 22 of 97
Hazardous Substance :- 02a Igasol Emulsion SG (F)by Sika
Description - Aqueous Bitumen Emulsion for Waterproofing buried concrete
Suppliers name, :- Sika
Storage Procedures :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Use spill kit
Fire Data & Extinguishing Media :- Flash Point N.A. Extinguish media: Water. Foam carbon dioxide, dry powder
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
May cause irritation
Wear eye protection Irrigate immediately with copious quantities of
water for 15 minutes. Summon site doctor
immediately
Skin
May cause irritation
Wear gloves and overalls, remove soiled clothing
immediately
Wash off immediately with soap and water Consult
doctor if skin irritation persists.
Ingestion
May cause irritation
Do not eat, drink or smoke during work time. Wash hands
before eating.
Do not induce vomiting. Summon a doctor
immediately.
Inhalation
May cause health disorders
Ensure adequate ventilation. In the event of symptoms take medical treatment
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 23 of 97
Hazardous Substance :- 02b Bituthene 8000& Protection Board
Description - Bituthene membrane 1.5mm thick, grey in colour. Self adhesive, comes in rolls and has a
protectice release paper. For waterproofing buried concrete.
Suppliers name, :- W.R.Grace
Storage Procedures :- N special requirement
Disposal Procedure :- Product is classified as non hazardous for disposal purposes.
Spillage Procedure :- Due to physical nature, spills not possible.
Fire Data & Extinguishing Media :- Flash Point > 210*C In case of fire, use water spray, dry chemical, Carbon dioxide or foam.
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
May cause irritation
Wear eye protection Flush with water for 15 minutes
Skin
Not applicable
Wash with water remove residue with clearing
cream
Ingestion
Not applicable
Not applicable
Inhalation
Not applicable
Unlikely to occur in quantites sufficient to cause
any effects.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 24 of 97
Hazardous Substance :- 03a Bitumen
Description :- Bitumen product for road building.
Suppliers name, :- Shell
Use :- Paving material
Storage Precautions :- Store away from moisture and sources of ignition
Disposal Procedure :- Dispose of via an authorised person / licence waste disposal contractor.
Spillage Procedure :- Contain and recover liquid using sand or other inert absorbent.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Hot product may cause severe eye burns and/or blindness.
For normal operations with hot material wear safety hat with
visor.
• Hot product - If contact with hot product, cool
the burn area by flushing with large amounts of
water for twenty minutes.
• Do not attempt to remove anything from the
burn area or apply burn creams or ointments.
• Cover the burn area loosely with a sterile
dressing, if available. Transport to the nearest
medical facility
• for additional treatment.
• All burns should receive medical attention.
• Cold product - Flush eye with copious quantities
of water. If persistent irritation occurs, obtain
medical attention.
Skin burns –
Contact with hot material can cause thermal
burns which may result in permanent skin damage.
For normal operations with hot material wear heat resistant
coveralls, (with cuffs over gloves and legs over boots), and
heavy-duty boots, e.g. leather for heat resistance. The use of
a neck apron is recommended.
• If contact with hot product, cool the burn area by
flushing with large amounts of water.
• Do not attempt to remove anything from the
burn area or apply burn creams or ointments.
Cover
• the burn area loosely with a sterile dressing, if
available.
• Transport to the nearest medical facility for
additional
• treatment. It should be noted this product
contracts on cooling.
• Where a limb is encased, care should be taken
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 25 of 97
to avoid the
• development of a tourniquet effect. In the event
of this
• occurring the adhering product must be
softened and/or split to
• prevent restriction of blood flow. All burns
should receive medical attention.
Ingestion –
Under normal conditions of use, this is not expected to
be a primary route of exposure.
Wash hand thoroughly before eating, drinking, smoking,
and use rest room after contact.
• If contamination of mouth occurs, wash out
thoroughly with water. Do not induce
vomiting, obtain medical advise.
Inhalation –
Inhalation of vapours or mists may cause irritation to the
respiratory system.
No respiratory protection is ordinarily required under
normal conditions of use. Use self contained breathing
apparatus in places where hydrogen sulphide vapours
may accumulate.
• If inhalation of mists, fumes or vapour
causes irritation to the nose or throat,
remove to fresh air.
• If rapid recovery does not occur, obtain
medical attention.
• Casualties suffering ill effects as a result of
exposure
• to hydrogen sulphide should be removed to
fresh air.
• Do not attempt to rescue the victim unless
proper respiratory protection is worn.
• If the victim has difficulty breathing or
tightness of the chest, is dizzy, vomiting, or
unresponsive, give 100% oxygen with
rescue breathing or Cardiopulmonary
Resuscitation (CPR) as required and
transport to the
• nearest medical facility.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 26 of 97
Hazardous Substance :- 03b LIESEN Separating Agent TM-BA1( Emulsion)
Description :- Asphalt release / cleaning agent
Suppliers Name :- LIESEN
Storage Procedures :- Store above freezing point.
Disposal Procedure :- Use approved waste disposal facility
Spillage Procedure :- Use absorbent and don’t allow to enter watercourse
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact –
May be painful and irritating
- Person using chemical to be briefed on the correct use of
chemical.
- Personnel not involved in the use of the chemical to be
removed from area.
- Goggles or helmet with viser to be worn when spraying
Black Magic Chemical
- Eye wash kit to be available in work location
- First aider to be in batching plant are whenever work is
being carried out.
- First aid box eye wash
Flush with eye wash kit for fifteen minutes
Inform the onsite first aider
Go to the on site clinic for check up
Skin Contact-
Prolonged contact may cause irritation
- Person using chemical to be briefed on the correct use of
chemical.
- Personnel not involved in the use of the chemical to be
removed from area.
- Coveralls and rubber gloves to be worn at all times when
using the chemical.
- Clean running water and soap to be available for personnel.
- Clean coveralls to be available if ones been used get
contaminated.
Wash with mild soap and wash off with clean
water.
Inform onsite first aided
If problem occurs go straight to the onsite clinic
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 27 of 97
Ingestion –
May cause nausea
- Chemical not to be used in a confined space.
- Personnel not involved in the use of the chemical to be
removed from area.
- 3M style mask to be worn when using the chemical
Inform the onsite first aider and go to site clinic.
Inhalation –
May irritate nose, throat or chest.
- Chemical not to be used in a confined space.
- Personnel not involved in the use of the chemical to be
removed from area.
- 3M style mask to be worn when using the chemical
Remove person effected to fresh air and contact the
onsite first aider.
If the effected person does not feel better after 15
minutes in the fresh air, take them to site clinic.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 28 of 97
Hazardous Substance :- 03b Prime Coat MC-70
Description :- Mediumm curing cutback asphalt
Suppliers Name :- Horizon energy Ltd, Dubai
Storage Procedures :- Keep far from food or drink.
Disposal Procedure :- Use approved waste disposal facility
Spillage Procedure :- Use absorbent and don’t allow to enter watercourse
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
May cause mild eye irritation including stringing, watering,
and redness.
Wear eye face protection
First aid box
Rince with water till disappearance of the
irritation, in case of persistence go to sit clinic.
Skin
May cause redness, itching, burning and severe skin damage.
Use oleo resistant gloves and suitable protective clothing. Wash with water and soap, take off contaminated
clothes and wash before using.
Ingestion
Low degrees of toxicity by ingestion.
Wash hand thoroughly before eating, drinking, smoking, and
use rest room after contact.
Don’t induce vomiting and seek medical attention.
Inhalation
low degree of toxicity by inhalation
When the product concentration in the air is high use
protective masks
The product doesn’t emit vapours
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 29 of 97
Hazardous Substance :- 03c Tack Coat SS1H
Description :- Anionic emulsified asphalt
Suppliers Name :- CYTECH, DUBAI
Storage Procedures :- Keep far from food or drink.
Disposal Procedure :- Use approved waste disposal facility
Spillage Procedure :- Use absorbent and don’t allow to enter watercourse
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
May cause mild eye irritation including stringing, watering,
and redness.
Wear eye face protection Rince with water till disappearance of the
irritation, in case of persistence go to sit clinic.
Skin
May cause redness, itching, burning and severe skin damage.
Use oleo resistant gloves and suitable protective clothing. Wash with water and soap, take off contaminated
clothes and wash before using.
Ingestion
Low degrees of toxicity by ingestion.
Wash hand thoroughly before eating, drinking, smoking, and
use rest room after contact.
Don’t induce vomiting and seek medical attention.
Inhalation
Low degree of toxicity by inhalation
When the product concentration in the air is high use
protective masks
The product doesn’t emit vapours
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 30 of 97
Hazardous Substance :- 04a Diesel
Suppliers name, :- Shell
Storage Procedures :- Store in approved containers protected from physical damage away from sources of ignition
Disposal Procedure :- Use approved waste disposal facility
Spillage Procedure :- Clean up spills with absorbent material and isolate hazard area.
Hazardous Substance & Health Effects Controls First aid measures & Emergencies
Eye contact
May cause mild eye irritation including stringing, watering,
and redness.
Wear googles and Safety glasses with side shields as good
industrial practice. First aid box with eye wash.
If irritation or redness develops, move victim away
from exposure and into fresh air. Flush eyes with
clean water. If symptoms persist, seek medical
attention.
Skin
May cause redness, itching, burning and severe skin damage.
Prolonged or repeated contact can worsened irritation by
causing drying and cracking of the skin leading to dermatitis.
Not actually toxic by skin absorption but prolonged or
repeated skin contact maybe harmful.
Use oil-resistant gloves and apron if needed. Immediately removed contaminated shoes,
clothing and constrictive jewelry and flush affected
area with large amount of water. If skin surface is
damaged, apply a clean dressing and seek
immediate medical attention.
Ingestion
Low degrees of toxicity by ingestion can enter to the lungs
during swallowing and cause lung inflammation and damage.
Wash hand thoroughly before eating, drinking, smoking, and
use rest room after contact.
Do not leave the victim unattended and observe
closely for adequacy of breathing and seek medical
attention.
Inhalation
low degree of toxicity by inhalation
Carry out refuelling in fresh air situations. If breathing difficulties develops, administer
oxygene by medical personnel.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 31 of 97
Hazardous Substance :- 04b Lubrication Oil
Suppliers name, :- Shell
Storage Procedures :- Do not store near heat, sparks, flames or strong oxidants. Store in cool place
Disposal Procedure :- Use approved waste disposal facility.
Spillage Procedure :- Use absorbent and don’t allow to enter watercourse.
Health Effects Controls First aid measures & Emergencies
Eye contact
Eye contact may result in irritation.
Wear googles and Safety glasses with side shields as good
industrial practice. First aid with eye washing facility
In case of contact, flush eyes with plenty nof water
for atleast 15 minutes or until irritation subsides.
Physician should be contacted should irritation
persist.
Skin burns
Prolonged or repeated skin contact may cause skin irritation
Use oil-resistant gloves and apron if needed. Removed any contaminated clothing and wash skin
with soap and warm water.
Ingestion
Minute amounts aspirated into the lungs during ingestion
may cause mild to severe pulmonary injury.
Wash hand thoroughly before eating, drinking, smoking, and
use rest room after contact.
If ingested call a physician immediately. Do not
induce vomiting.
Inhalation
Vapor pressure is very low and inhillation at room
temperature is not a problem. If overcome by vapour from a
hot product mild to severe pulmonary injury may occur.
Respiratory protection normally not needed. If overcome by vapor from hot product, Immediately
removed from exposure and call a physician.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 32 of 97
Hazardous Substance : 04c Jet A1 Aircraft fuel
Manufacturer’s name : Shell
Description :- : Fuel for aviation turbine engines fitted to aircraft.
Storage Precautions : Tanks must be specifically designed for use with this product.
Disposal Procedure : Disposal methods in compliance with applicable regulations
Spillage Procedure :
Evacuate the area of all nonessential personnel. Ventilate contaminated area thoroughly. For small liquid spills (< 1 drum), transfer
by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up
with an appropriate absorbent material and dispose of safely
Fire Fighting Measures
Extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only.
Recommendations :
Keep adjacent containers cool by spraying with water. If possible remove containers from the danger zone. If the fire cannot be
extinguished the only course of action is to evacuate immediately.
Personal Precautions : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space
Health Effects Controls First aid measures & Emergencies
Eye contact - Slightly irritating.
Chemical splash goggles (chemical monogoggles).
Flush eyes with water while holding eyelids open. Rest
eyes for 30 minutes. If redness, burning, blurred vision,
or swelling persist, transport to the nearest medical
facility for additional treatment
Skin – Irritating to skin.
Personal hygiene is a key element of effective hand
care.
Gloves must only be worn on clean hands.
Remove contaminated clothing. Immediately flush skin
with large amounts of water for at least 15 minutes, and
follow by washing with soap and water if available. If
redness, swelling, pain and/or blisters occur, transport to
the nearest medical facility for additional treatment
Ingestion – Low toxicity:LD50 >2000 mg/kg Wash hand thoroughly before eating, drinking, smoking,
and use rest room after contact
If swallowed, do not induce vomiting: transport to
nearest medical facility for additional treatment. If
vomiting occurs spontaneously, keep head below hips to
prevent aspiration.
Inhalation - Slightly irritating
.
Ventilation, If engineering controls do not maintain
airborne concentrations to a level which is adequate to
protect worker health, select respiratory protection
equipment
Remove to fresh air. If rapid recovery does not occur,
transport to nearest medical facility for additional
treatment.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 33 of 97
Hazardous Substance :- 05a Welding Rods
Manufacturer’s name, :- Various
Use :- Welding steel
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Health Effects Controls First aid measures & Emergencies
Eye contact -
Hazardous
Use helmets with suitable shielding glass Dampen with fresh water
Skin –
Burns
Cover exposed areas with appropriate clothing. For hands and
arms use welding gauntlets.
Seek medical attention
Hearing –
Minor
Use ear protectors and/or ear plugs Seek medical assistance.
Inhalation –
Hazardous in case of inhalation.
Avoid inhaling fumes / gases, be sure there is enough
ventilationand / or fumes extractors are available.
Remove to ventilated place. Seek medical
assistance if symptoms persist.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 34 of 97
Hazardous Substance :- 05b Sipoxy Shield 266 Base
Manufacturer’s name, :- Saudi Industrials Paint Co. Ltd
Use :- For repairs to DI Pipes
Storage Precautions :- Keep away from heat, spark, flame.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain spilled material & remove with inert absorbent material.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Causes irritation
Do not get in eyes. Solvent resistant safety eyewear
recommended.
Flush immediately with large amounts of water.
Get medical attention.
Skin burns –
Causes irritation, may be harmful if absorbed through skin.
Wear protective gloves and protective wear. Wash affected area with soap water. Remove
soiled clothing. Get medical attention if irritation
persists
Ingestion –
Stomach / intestinal irritation nausea vomiting diarrhea.
Wash hands before eating or smoking Consult a physician immediately. Do not induce
vomiting.
Inhalation –
Irritation of repiratory tract, headache, nausea, dizziness.
Extream exposure can cause unconsciousness ans even
respiratory arrest.
Use dust / vapour mask. Leave the area to obtain fresh air. If continued
difficulty in breathing persists get medical
attention. If breathing ceases restore using CPR
techniques.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 35 of 97
Hazardous Substance :- 05c Sipoxy Shield 266 Hardener
Manufacturer’s name, :- Saudi Industrials Paint Co. Ltd
Use :- For repairs to DI Pipes
Storage Precautions :- Keep away from heat, spark, flame.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain spilled material & remove with inert absorbent material.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Causes irritation
Do not get in eyes. Solvent resistant safety eyewear
recommended.
Flush immediately with large amounts of water. Get
medical attention.
Skin burns –
Causes irritation, may be harmful if absorbed through skin.
Wear protective gloves and protective wear. Wash affected area with soap water. Remove soiled
clothing. Get medical attention if irritation persists
Ingestion –
Stomach / intestinal irritation nausea vomiting diarrhea.
Wash hands before eating or smoking Consult a physician immediately. Do not induce
vomiting.
Inhalation –
Irritation of repiratory tract, headache, nausea, dizziness.
Extream exposure can cause unconsciousness ans even
respiratory arrest.
Use dust / vapour mask. Leave the area to obtain fresh air. If continued
difficulty in breathing persists get medical attention.
If breathing ceases restore using CPR techniques.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 36 of 97
Hazardous Substance :- 05d Bentonite
Manufacturer’s name, :- Mandaksh Exports India
Use :- Grouting Duct Annulus
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain spilled material & remove
Description :- :- Powder
Health Effects Controls First aid measures & Emergencies
Eye contact -
Hazardous in case of eye contact (irritant),
Avoid contact with eyes Check for and remove any contact lenses. In case of
contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. WARM water
MUST be used. Get medical attention.
Skin –
Slightly hazardous in case of skin contact (irritant),
Full suit. Gloves Wash with soap and water. Cover the irritated skin with an
emollient. Get medical attention if irritation develops
Ingestion –
Not available.
Wash hands before eating or smoking MSDS on site & with
site clinic
Do NOT induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are
swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Inhalation –
Hazardous in case of inhalation.
Do not breathe dust
In case of insufficient ventilation, wear suitable
respiratory equipment.
If you feel unwell, seek medical attention and show the
label when possible.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 37 of 97
Hazardous Substance :- 05e Jotashield (Concrete Paint)
Manufacturer’s name, :- Jotun India Pvt Ltd, India
Use :- Concrete Paint
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents.
Description :- :- Liquid
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate
breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from
fire to sewers or waterways.
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS.
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may
cause irritation and reversible damage.
Use safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses.
Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open.
Skin –
Harmful in contact with skin and if
swallowed.
May cause sensitisation by skin contact.
Personnel should wear antistatic clothing made of natural fibres or of
hightemperature-
resistant synthetic fibres.
Remove contaminated clothing and shoes.
Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do not
use solvents or thinners.
Ingestion –
Harmful in contact with skin and if
swallowed.
Eating, drinking and smoking should be prohibited in areas where this
material is handled, stored and processed.
If swallowed, seek medical advice
immediately and show the container or label.
Keep person warm and at rest. Do not induce
vomiting.
Inhalation –
Irritating to respiratory system.
If workers are exposed to concentrations above the exposure limit, they
must use appropriate, certified respirators. Use respiratory mask with
charcoal and dust filter when spraying this product.(as filter
combination A2-P2). In confined spaces, use compressed-air or fresh-
air respiratory equipment. When use of roller or brush, consider use of
charcoalfilter.
Remove to fresh air. Keep person warm and
at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide
artificial respiration or oxygen by
trained personnel.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 38 of 97
Hazardous Substance :- 05f Jotashield Tex Ultra (Concrete Paint)
Manufacturer’s name, :- Jotun India Pvt Ltd, India
Use :- Concrete Paint
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents.
Description :- :- Liquid
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate
breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from
fire to sewers or waterways.
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS.
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may cause
irritation and reversible damage.
Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately
flush eyes with running water for at least 15 minutes,
keeping eyelids open.
Skin –
Harmful in contact with skin and if swallowed.
May cause sensitisation by skin contact.
Personnel should wear anti-static clothing made of natural fibre. For prolonged or
repeated handling, use gloves : Neoprene or nitrile.
Barrier creams may help to protect the exposed areas of the skin, they
should however not be applied once exposure has occurred
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion –
Harmful in contact with skin and if swallowed.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
If swallowed, seek medical advice immediately and
show the container or label. Keep person warm and at
rest. Do not induce vomiting.
Inhalation –
Irritating to respiratory system.
If workers are exposed to concentrations above the exposure limit they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product (as filter combination) In confined spaces use compressed
air or fresh air respiratory equipment. When use of roller or brush,
consider use of Charcoal filter.
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial
respiration or oxygen by trained personnel. Give nothing
by mouth. If unconscious place in recovery position and
seek medical advice.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 39 of 97
Hazardous Substance :- 05g JOTUN SILOXANE A PRIMER (Concrete Paint)
Manufacturer’s name, :- Jotun U.A.E. Ltd. LLC.
Use :- Concrete Paint
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents.
Description :- :- Liquid
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate
breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from
fire to sewers or waterways.
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS.
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may cause
irritation and reversible damage.
Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately
flush eyes with running water for at least 15 minutes,
keeping eyelids open.
Skin –
Harmful in contact with skin and if swallowed.
May cause sensitisation by skin contact.
Personnel should wear anti-static clothing made of natural fibre. For prolonged or
repeated handling, use gloves : Neoprene or nitrile.
Barrier creams may help to protect the exposed areas of the skin, they
should however not be applied once exposure has occurred
Remove contaminated clothing and shoes. Wash skin
thoroughly withsoap and water or use recognized skin
cleanser. Do NOT use solvents orthinners.
Ingestion –
Harmful in contact with skin and if swallowed.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
If swallowed, seek medical advice immediately and
show the container or label. Keep person warm and at
rest. Do not induce vomiting.
Inhalation –
Irritating to respiratory system.
If workers are exposed to concentrations above the exposure limit they
must use appropriate, certified respirators.
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial
respiration or oxygen by trained personnel. Give nothing
by mouth. If unconscious place in recovery position and
seek medical advice.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 40 of 97
Hazardous Substance :- 05h Jotun Thinner No. 10
Manufacturer’s name, :- Jotun Paints (Europe) Ltd.
Use :- Concrete Paint
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents.
Description :- :- Liquid
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate
breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from
fire to sewers or waterways.
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS.
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may cause
irritation and reversible damage.
Use safety eyewear designed to protect against splash of liquids Check for and remove any contact lenses. Immediately
flush eyes with running water for at least 15 minutes,
keeping eyelids open.
Skin –
Harmful in contact with skin and if swallowed.
May cause sensitisation by skin contact.
Personnel should wear anti-static clothing made of natural fibre or of high temperature
resistant synthetic fibre.
For prolonged or repeated handling, use gloves: polyvinyl alcohol or nitrile. Barrier
creams may help to protect the exposed areas of the skin, they should however not be
applied once exposure has occurred.
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use recognised skin
cleanser. Do NOT use solvents or thinners.
Ingestion –
Harmful in contact with skin and if swallowed.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
If swallowed, seek medical advice immediately and
show the container or label. Keep person warm and at
rest.
Do not induce vomiting.
Inhalation –
Irritating to respiratory system.
If workers are exposed to concentrations above the exposure limit they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product (as filter combination A2-P2). In confined spaces use
compressed air or fresh air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter (A2).
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory
arrest
occurs, provide artificial respiration or oxygen by trained
personnel. Give nothing by mouth. If unconscious place
in recovery position and seek medical advice.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 41 of 97
Hazardous Substance :- 05j Transformer Oil
Suppliers name :- M/S. Savita Oil Technologies Ltd - India.,
Storage Procedures :- Do not store near heat, sparks, flames or strong oxidants. At ambient Temperature
Disposal Procedure :- Use approved waste disposal facility.
Spillage Procedure :- Absorbe large spillages in sand and don’t allow to enter watercourse.
Health Effects Controls First aid measures & Emergencies
Eye contact
Eye contact may result in irritation and redness.
Wear googles and Safety glasses with side shields as good
industrial practice. First aid with eye washing facility
In case of contact, flush eyes with plenty of water for
atleast 15 minutes or until irritation subsides.
Physician should be contacted should irritation
persist.
Skin burns
Prolonged or repeated skin contact may cause skin
irritation,dryness & dermatitis.
Use oil-resistant gloves and apron if needed.Wash
thoroughly with water.
Remove any contaminated clothing and wash skin
with soap and warm water.
Ingestion
Minute amounts aspirated into the lungs during ingestion
may cause stomach discomfort or nausea.
Wash hand thoroughly before eating, drinking, smoking, and
use rest room after contact.
If ingested call a physician immediately. Do not
induce vomiting.
Inhalation
Inhalation of vapour or mist may be irritating to respiratory
passages.Prolonged exposure may result in dizziness and
nausea.
Remove to fresh air.Assist breathing if necessary. If overcome by vapor from hot product, Immediately
removed from exposure and call a physician.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 42 of 97
Hazardous Substance :- 05k Jotun Road Marking Paint (Concrete Paint)
Manufacturer’s name, :- Jotun India Pvt Ltd, India
Use :- Road marking Paint
Storage Precautions :- Secure area
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain and collect spillage with non-combustible absorbent material.
Description :- :- Liquid in various colours
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray.
Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate
breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from
fire to sewers or waterways.
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS.
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may cause
irritation and reversible damage.
Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately
flush eyes with running water for at least 15 minutes,
keeping eyelids open.
Skin –
Harmful in contact with skin and if swallowed.
May cause sensitisation by skin contact.
Personnel should wear anti-static clothing made of natural fibre. For prolonged or
repeated handling, use gloves : Neoprene or nitrile.
Barrier creams may help to protect the exposed areas of the skin, they
should however not be applied once exposure has occurred
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion –
Harmful in contact with skin and if swallowed.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
If swallowed, seek medical advice immediately and
show the container or label. Keep person warm and at
rest. Do not induce vomiting.
Inhalation –
Irritating to respiratory system.
If workers are exposed to concentrations above the exposure limit they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product (as filter combination) In confined spaces use compressed
air or fresh air respiratory equipment. When use of roller or brush,
consider use of Charcoal filter.
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial
respiration or oxygen by trained personnel. Give nothing
by mouth. If unconscious place in recovery position and
seek medical advice.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 43 of 97
Hazardous Substance :- 05l Hydrochloric Solution 40%
Manufacturer’s name, :- Cooper
Use :- Washing Mineralite Plasterwork
Description :- :- Liquid
Storage Precautions :- Secure and ventilated area, keep away from heat and flame. Keep out of direct sunlight.
Disposal Procedure :- To licenced facility
Spillage Procedure :- Contain and collect spillage with non-combustible absorbent material.
Fire Fighting Measures
Extinguishing media : Use extinguishing agents appropriate for surrounding fires.
Recommendations : In event of a fire, wear full protective clothing and full protective gear. Non flammable, but reacts with most metals to
form flammable hydrogen gas.
Personal Precautions : Keep unnecessary people away, isolate hazard area and deny entry.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Corrosive ! Vapour or mist may cause irritation
and severe burns and permanent eye damage.
May cause painful senitization to light. May
cause conjuncttivities
Use chemical safety goggles and/or a full face shield where splashing is possible.
Maintain eye wash fountain and quick-drench facilities in work area.
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower lids, Get medical
aid immediately. Do not allow victim to rub or keep eyes
closed.
Skin –
Corrosive ! May be absorbed through the skin in
harmful amounts. Contact with liquid is corrosive
and causes severe burns and ulceration. May
Rubber or neoprene gloves and additional protection including impervious boots,
apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact.
Get medical attention immediately. Rinse area with large
amounts of water for at least 15 minutes. Remove
contaminated clothing and shoes.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 44 of 97
cause photosensitization in certain individuals.
Ingestion –
Corrosive ! May cause circulatory system failure.
Causessevere digestive tract burns with
abdominal pain, vomiting, and possible death.
May cause permanent tissue destruction of the
esophagus and digestive tract.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed.
Do not induce vomiting. If the victim is conscious and
alert, give 2 to 4 cupfuls of milk or water. Get medical
attention immediately.
Inhalation –
Corrosive ! Causes severe irritation of upper
respiratory tract with coughing, burns,
breathingdifficulty and possible coma. May cause
pulmonary edema and severe respiratory
disturbances.
If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge
may be worn up to 50 times the exposure limit or the maximum use concentration
specified by the appropriate regulatory agency or respirator supplier, whichever is
lowest. For emergencies or instances where the exposure levels are not known, use a
full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying
respirators do not protect workers in oxygen-deficient atmospheres.
Remove to fresh air immediately. If not breathing., give
artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 45 of 97
Hazardous Substance : 05M Trichloroethylene (Asphalt Yard)
Manufacturer’s name : Various
Storage Precautions : Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Store protected from light.
Disposal Procedure : Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste
Spillage Procedure :
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection section). Remove all sources of ignition. Use a spark-proof tool. Do not let this chemical
enter the environment.
Description :- : Liquid - clear, colorless
Fire Fighting Measures
Extinguishing media : Use water spray, dry chemical, carbon dioxide, or chemical foam
Recommendations :
Personal Precautions : As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Causes eye irritation. Contact with trichloroethylene causes pain
but no permanent injury to the eyes.
Wear appropriate protective eyeglasses or chemical safety goggles as
described by OSHA's eye and face protection regulations in 29 CFR
1910.133 or European Standard EN166.
Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids.
Get medical aid.
Skin –
Causes skin irritation. May be harmful if absorbed through the
skin.
Wear appropriate protective gloves to prevent skin exposure. Wear
appropriate protective clothing to prevent skin exposure
Get medical aid. Immediately flush skin with plenty of
water for at least 15 minutes while removing
contaminated clothing and shoes.
Ingestion –
May cause irritation of the digestive tract. May be harmful if
swallowed. May cause central nervous system effects.
Do not ingest. Do not induce vomiting. Get medical aid.
Inhalation –
May cause respiratory tract irritation. May cause liver and kidney
damage. May be harmful if inhaled. May cause central nervous
system effects. The chief symptoms of TCE exposure were found
to be abnormal fatigue, irritability, headache, gastric disturbances,
and intolerance to alcohol
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149. Use a NIOSH/MSHA or European Standard
EN 149 approved respirator if exposure limits are exceeded or if irritation
or other symptoms are experienced.
Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 46 of 97
Hazardous Substance : 05n Rockwool Thermal panels
Manufacturer’s name : Saudi Rockwool
Description :- Insulation material consisting of stone wool based minerals
Storage Precautions : Keep materials in original packaging.
Disposal Procedure :
Spillage Procedure : Dispose empty packaging and surplus material to a place accepting builders waste.
Fire Fighting Measures
Extinguishing media : Is not flammable . Water, foam, carbon diodide or dry powder.
Recommendations :
Personal Precautions : Observe normal fire fighting procedures.
Health Effects Controls First aid measures & Emergencies
Eye contact - Can cause temporary self-fading effects e.g.
itching.
Normally not required.
If irritation occurs flush eyes with potable cold water. Do
not rub the eyes. Consult a doctor if irritation persists
Skin – There can be physical effects on skin. Hand protection not normally required but gloves can be worn.
If irritation occurs, wash off under cold running water prior
to washing with mild soap. Do not rub or scratch.
Ingestion – Do not ingest.
If irritation occurs clean throat by rinsing with cold, potable
water.
Inhalation - There can be physical effects on the upper respiratory
system
No problem when used externally
If respiratory irritation occurs, leave source of
contamination and get fresh air. Consult a doctor if
irritation persists
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 47 of 97
Hazardous Substance : 05o Welding Rod / granulate for HDPE
Manufacturer’s name : Various
Storage Precautions : No smoking, open flames or sources of ignition in handling and storage area.
Disposal Procedure : .
Spillage Procedure : Contain spilled material if possible. Sweep up. Collect in suitable and properly labelled containers
Description :- :
Fire Fighting Measures
Extinguishing media : Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam.
Recommendations : Keep people away. Isolate fire and deny unnecessary entry. Soak thoroughly with water to cool and prevent re-ignition.
Personal Precautions : Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing
Health Effects Controls First aid measures & Emergencies
Eye contact -
Solid or dust may cause irritation or corneal injury due to
mechanical action. Vapour may cause eye
irritation experienced as mild discomfort and redness.
Use safety glasses.
Flush eyes thoroughly with water for several minutes.
Remove contact lenses after the
initial 1-2 minutes and continue flushing for several
additional minutes. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin –
Prolonged contact is essentially non-irritating to skin. Mechanical
injury only. Under normal processing
conditions, material is heated to elevated temperatures; contact
with the material may cause thermal
burns.
No precautions other than clean body-covering clothing should be needed
If molten material comes in contact with the skin, do not
apply ice but cool under ice water
or running stream of water. DO NOT attempt to remove
the material from skin. Removal could result in
severe tissue damage. Seek medical attention
immediately.
Ingestion –
Very low toxicity if swallowed. Harmful effects not anticipated from
swallowing small amounts. May
cause choking if swallowed.
Use good personal hygiene. Do not consume or store food in the work
area. Wash hands before smoking or eating.
If swallowed, seek medical attention. May cause
gastrointestinal blockage. Do not give
laxatives. Do not induce vomiting unless directed to do so
by medical personnel
Inhalation –
No adverse effects are anticipated from single exposure to dust.
Vapours/fumes released during thermal processing may cause
respiratory irritation.
Provide force ventilation in confined spaces
Move person to fresh air; if effects occur, consult a
physician
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 48 of 97
Hazardous Substance : 05p Universal Powerwash Liquid
Manufacturer’s name : Arrow Chemicals Ltd
Storage Precautions : Store upright in container provided away from thoroughfares to prevent accidental damage.
Disposal Procedure : .Dispose in a safe way.
Spillage Procedure : Large spillages: absorbwith sand. Small spillage; hose away to foul sewer with plenty of water.
Description :- : A caustic alkaline cleaner degreaser
Fire Fighting Measures
Extinguishing media : This material is not Flammable
Recommendations :
Personal Precautions :
Health Effects Controls First aid measures & Emergencies
Eye contact -
Extreme irritation of eye and mucous membrane including burning
and tearing.
Use eye protection. Provide eye wash.
Promptly wash eyeswith plenty of waterwhile lifting the
eye lids. Get medical attention immediately . Continue to
rince.
Skin –
Severe skin irration
Protective gloves must be worn if there is a risk of contact or splash.
Rinse the skin immediately with lots of water. Get medical
attention immediately.
Ingestion –
Severe abdominal pain.
Do not ingest.
Do not induce vomiting. Get medial attention
immediately. Rinse mouth thouroughly.
Inhalation –
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 49 of 97
Hazardous Substance : 05q Double Sided Butyl for Roof Cladding System
Manufacturer’s name : Olin Etancheite Isolation
Storage Precautions : Store in a cool, dry, well ventilated area
Disposal Procedure :
This material and its container must be disposed of in a safe way. Dispose of in a manner consistent with federal, state and
local regulations
Spillage Procedure : Collect the product with a saptule.
Description :- :
Fire Fighting Measures
Extinguishing media : Water spray, carbon dioxide (CO2). Use water spray to cool fire exposed containers
Recommendations :
Personal Precautions : Wear self-contained breathing apparatus to prevent contact with thermal decomposition product (COx; NOx…)
Health Effects Controls First aid measures & Emergencies
Eye contact -
No known toxic effect
Wear appropriate protective eyeglasses when using
product
Wash eyes with plenty of water
Skin –
No known toxic effect
Wear appropriate protective gloves when using product Wash skin with plenty of soap and water
Ingestion –
No known toxic effect
Do not induce vomiting. Get medical aid
Inhalation –
No known toxic effect
Not necessary
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 50 of 97
Hazardous Substance : 05r Sealer’s Choice™ Gold for Terrazo
Manufacturer’s name : AQUA MIX INC.
Storage Precautions : Store in cool, dry location
Disposal Procedure : Dispose materials in accordance with all applicable local, state and federal regulations.
Spillage Procedure : Soak up with compatible absorbent material (sand, clay litter, diatomaceous earth).
Description :- :
Fire Fighting Measures
Extinguishing media : Use water fog, carbon dioxide, dry chemical or foam
Recommendations : None
Personal Precautions : None
Health Effects Controls First aid measures & Emergencies
Eye contact -
Contact may cause tearing or stinging Avoid eye contact. Wear safety glasses or goggles
Immediately flush eyes with copious amounts of
water. If irritation persists, seek medical attention
Skin –
Mild to moderate irritation such as drying, redness, or
tightness of skin may occur when liquid is allowed to
dry on skin.
Wear rubber, latex or nitrile gloves. Use as necessary to prevent skin
contact.
Wash with soap and water. If irritation persists
seek medical attention
Ingestion –
Ingestion may cause mild nausea, diarrhea, or some
discomfort of the digestive tract.
DO NOT INDUCE VOMITING! Drink 1 or 2
glasses of water. If spontaneous vomiting is
inevitable,
prevent aspiration by keeping the victim’s head
below knees. Seek immediate medical attention.
Inhalation –
If misting or atomized spraying, wear a NIOSH approved high-
efficiency respirator rated
for mists, dusts, and particulates
Not Applicable
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 51 of 97
Hazardous Substance : 05s Thixothane Coating ( VJ Couplings)
Manufacturer’s name : HMG PAINTS LTD.
Storage Precautions : Keep receptacles tightly sealed. Ensure good ventilation/extraction at the workplace.
Disposal Procedure : Must not be disposed together with household garbage. Do not allow product to reach sewage system
Spillage Procedure : Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Description :- : Coating compound/ Surface coating/ paint
Fire Fighting Measures
Extinguishing media : CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam
Recommendations :
Personal Precautions : Mount respiratory protective device.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Contact may cause tearing or stinging
Wear tightly sealed goggles. Avoid contact with the eyes
and skin.
Rinse opened eye for several minutes under
running water.
Skin –
Irritating to skin
Immediately remove all soiled and contaminated clothing
Wear suitable protective clothing and gloves.
Immediately wash with water and soap and
rinse thoroughly.
Ingestion –
Ingestion may cause mild nausea, diarrhea, or some
discomfort of the digestive tract.
Keep away from foodstuffs, beverages and feed. Wash
hands before breaks and at the end of work.
If symptoms persist consult doctor.
Inhalation –
Harmful by inhalation
In case of brief exposure or low pollution use respiratory
filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of
circulating air
Supply fresh air. If required, provide artificial
respiration. Keep patient warm. Consult doctor
if symptoms
persist.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 52 of 97
Hazardous Substance : 05t Thixothane Hardener ( VJ Couplings)
Manufacturer’s name : HMG PAINTS LTD.
Storage Precautions : Keep receptacles tightly sealed. Ensure good ventilation/extraction at the workplace.
Disposal Procedure : Must not be disposed together with household garbage. Do not allow product to reach sewage system
Spillage Procedure : Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Description :- : Coating compound/ Surface coating/ paint
Fire Fighting Measures
Extinguishing media : CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam
Recommendations :
Personal Precautions :
Mount respiratory protective device.
Health Effects Controls First aid measures & Emergencies
Eye contact -
No irritant effect. Wear tightly sealed goggles
Hold the eye open and rinse with
(preferably)luke warm water for a sufficiently
long period of time (at least
10 minutes). Contact a doctor or
opthalmologist.
Rinse opened eye for several minutes under
running water. Then consult a doctor.
Skin –
No irritant effect.
Immediately remove all soiled and contaminated clothing
Wear suitable protective clothing and gloves.
Immediately wash with water and soap and
rinse thoroughly.
Ingestion –
Ingestion may cause mild nausea, diarrhea, or some
discomfort of the digestive tract.
Keep away from foodstuffs, beverages and feed. Wash
hands before breaks and at the end of work.
DO NOT induce the patient to vomit, medical
advice is required.
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Control of Substances Hazardous to Health
Page 53 of 97
Inhalation –
Harmful by inhalation
In the case of hypersensitivity of the respiratory tract (e.g.
asthmatics and those who suffer from chronic
bronchitis)it is inadvisable to work with the product.
In case of brief exposure or low pollution use respiratory
filter device. In case of intensive or longer exposure
use respiratory protective device that is independent of
circulating air.
In case of unconsciousness place the patient
stably in side position for transportation. If the
aerosol or
vapour in inhaled in high concentrations, take
the person into fresh air, keep warm and let
rest. If there is
difficulty in breathing, medical advice is
required.
Supply fresh air and call for a doctor.
In case of unconsciousness place patient
stably in side position for transportation
Hazardous Substance : 05u Thinner # 7 Juton
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 54 of 97
Manufacturer’s name : Jotun Paints Co LLC,
Storage Precautions : Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used.
Disposal Procedure : According to local regulations
Spillage Procedure :
Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for
disposal according to local regulations
Description :- : Coatings: Solvent.
Fire Fighting Measures
Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Not to be used : water jet
Recommendations :
Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist
Health Effects Controls First aid measures & Emergencies
Eye contact -
If splashed in the eyes, the liquid may cause irritation and
reversible damage.
Use safety eyewear designed to protect against splash of liquids.
Check for and remove any contact lenses. Immediately
flush eyes with running water for at least 15 minutes,
keeping eyelids open.
Skin –
Irritating to skin.
Personnel should wear antistatic clothing made of natural fibres or of
high-temperature-resistant synthetic fibres
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use
recognised skin cleanser. Do not use solvents or
thinners.
Ingestion – Eating, drinking and smoking should be prohibited in area where this
material is handled, stored and processed.
If swallowed, seek medical advice immediately and
show the container or label. Keep person warm
and at rest. Do not induce vomiting.
Inhalation –
Harmful by inhalation
If workers are exposed to concentrations above the exposure limit,
they must use appropriate, certified respirators.
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or
oxygen by trained personnel. Give nothing by mouth. If
unconscious, place in recovery position and seek
medical advice.
Hazardous Substance : 05v Thermoplastic Road Paint
Manufacturer’s name : Various
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 55 of 97
Storage Precautions : Avoid heat, sparks open flames and other ignition sources.
Disposal Procedure : As per local regulations.
Spillage Procedure : Attempt to reclaim the free material.
Description :- : Liquid
Fire Fighting Measures
Extinguishing media : Dry Chemical. Carbon dioxide.
Recommendations :
Personal Precautions : Wear suitable protective equipment.
Health Effects Controls First aid measures & Emergencies
Eye contact
Powder state – may cause irritation
Molten state – causes serious injury to eyes due to its extreme
temperature.
Face mask or goggles to be worn by operatives working with material
when it is in molten state.
Only essential personnel allowed within vicinity of the material when it is in
a molten state.
First aider to be aware of the precautions and measures related to this
material.
Emergency contact details for site clinic to be available for first aider and
other operatives on site.
Clean water to be available for carrying out first aid measures.
Powder state – flush thoroughly with water immediately. If
irritation persists, consult site doctor.
Molten state – flush with large quantity of water
immediately. Do not attempt to remove any solid
thermoplastic material. Seek medical attention at site
clinic immediately.
Skin
Powder state – may cause irritation
Molten state – may cause burns due to high temperature
Potentially exposed skin such as hands should be covered using gloves
when in the vicinity of the molten material.
Only essential personnel allowed within vicinity of the material when it is in
a molten state.
First aider to be aware of the precautions and measures related to this
material.
Emergency contact details for site clinic to be available for first aider and
other operatives on site.
Clean water to be available for carrying out first aid measures.
Powder state – wash with soap and water
Molten state – immerse or flush the affected part with
copious amounts of sterile water to dissipate the heat and
limit injury. No attempt should be made to remove
thermoplastic or any clothing that may be fused to
damaged area. Seek medical attention showing the sheet.
Ingestion
Powder state – low toxicity, but may be harmful if swallowed
Molten state – harmful and must avoid swallowing
Personnel working with material to be made aware of the hazard of
swallowing the substance, especially when the material is molten
First aider to be aware of the precautions and measures related to this
material.
Emergency contact details for site clinic to be available for first aider and
other operatives on site.
Powder state – go and see the site doctor in the NDA
Molten state – seek medical attention immediately
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 56 of 97
Inhalation
Powder state – negligible hazard, over inhalation will cause some
irritation to throat.
Molten state – negligible hazard. However, over inhalation in a
confined space will cause choking.
Material is not going to be used in a confined space for road marking, but
personnel should be made aware of the hazards of being in a confined
space with the substance.
First aider to be aware of the precautions and measures related to this
material.
Powder state – first aid not normally required
Molten state – not going to be used in a confined space
Hazardous Substance : 05 W HEMPADUR MASTIC 45889 Base
Manufacturer’s name : HEMPEL A/S, Denmark
Storage Precautions : Always keep in containers made from the same material as the original one.
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 57 of 97
Disposal Procedure : Disposal according to local regulations
Spillage Procedure :
Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for
disposal
Description :- : Epoxy primer (base for multi-component product)
Fire Fighting Measures
Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: waterjet
Recommendations : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire
Personal Precautions :
Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of
protection for chemical incidents.
Health Effects Controls First aid measures & Emergencies
Eye contact -
Irritating to eyes.
Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure
to liquid splashes, mists or dusts.
Check for and remove any contact lenses.
Immediately flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower
eyelids. Seek immediate medical attention.
Skin –
Irritating to skin. May cause sensitization by skin contact
Wear chemical-resistant gloves (tested to EN374) in combination with
'basic' employee training
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion –
Irritating to mouth, throat and stomach.
Wash hands, forearms, and face thoroughly after handling
compounds and before eating, smoking, using lavatory, and at the
end of day.
If swallowed, seek medical advice immediately and
show this container or label. Keep person warm and
at rest. Do not induce vomiting unless directed to do
so by medical personnel. Lower the head so that
vomit will not re-enter the mouth and throat.
Inhalation –
Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
If working areas have insufficient ventilation: When the product is
applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P.
Remove to fresh air. Keep person warm and at rest. If
unconscious, place in recovery position and seek
medical advice.
Hazardous Substance : 05 x HEMPEL'S CURING AGENT 95881
Manufacturer’s name : HEMPEL A/S, Denmark
COSHH ASSESSMENTS
Control of Substances Hazardous to Health
Page 58 of 97
Storage Precautions :
Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and
ignition sources.
Disposal Procedure : In accordance with local egulations.
Spillage Procedure : Stop leak if without risk. Move containers from spill area. Approach release from upwind
Description :- : Curing agent
Fire Fighting Measures
Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: waterjet
Recommendations : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.
Personal Precautions :
Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.
Health Effects Controls First aid measures & Emergencies
Eye contact -
May cause eye irritation
Safety eyewear complying with an approved standard should be used
when a risk assessment indicates this is necessary to avoid exposure
to liquid splashes, mists or dusts.
Check for and remove any contact lenses.
Immediately flush eyes with plenty of water for at least
15 minutes, occasionally lifting the upper and lower
eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Skin –
Irritating to skin. May cause sensitization by skin contact.
Wear chemical-resistant gloves (tested to EN374) in combination with
'basic' employee training
Remove contaminated clothing and shoes. Wash skin
thoroughly with soap and water or use recognized skin
cleanser. Do NOT use solvents or thinners.
Ingestion –
Irritating to mouth, throat and stomach.
Wash hands, forearms, and face thoroughly after handling
compounds and before eating, smoking, using lavatory, and at the
end of day.
If swallowed, seek medical advice immediately and
show this container or label. Keep person warm and
at rest. Do not induce vomiting unless directed to do
so by medical personnel. Lower the head so that
vomit will not re-enter the mouth and throat.
Inhalation –
Harmful by inhalation
If working areas have insufficient ventilation: When the product is
applied by means that will not generate an aerosol such as, brush or
roller wear half or totally covering mask equipped with gas filter
of type A, when grinding use particle filter of type P.
Remove to fresh air. Keep person warm and at rest. If
not breathing, if breathing is irregular or if respiratory
arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If
unconscious, place in recovery position and get
medical attention immediately.
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages
Coshh  Assessments 97 pages

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Coshh Assessments 97 pages

  • 1. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 1 of 97 Introduction: Many hazardous substances are used in the construction industry COSHH Assessments must be carried out with the aim of elimination, substitution and reduction of exposure to hazardous substances. COSHH Assessments 97 pages Contents 01 Concreting, Grouts, Resins 01r Sikadur 52 05 Miscellaneous 01a Cement, Wet Concrete , Mortar 05a Welding Rods for Steel 01b Flowcable – Post-tensioning 05b Sipoxy Base - Repairs to DI pipes 01c Masterflow – Bridge Bearings 02 Waterproofing 05c Sipoxy Hardner - Repairs to DI pipes 01d Concure A – Curing Agent 02a Igasol EmulsionSG (F) by Sika 05d Bentonite - 132 KV Cables 01e Rheofinish 225D – Release Agent 02b Bituthene 8000 & Protection Board 05e Jotashield Concrete Paint 01f Sika 101 - Crack Injection 05f Jotashield Tex Ultra 01g Sika 210 - Crack Injection 03 Asphalt Paving 05g JOTUN SILOXANE A PRIMER 01 h Nitobond EP Base 03a Bitumen 05h Jotun Thinner No. 10 01 i Nitobond EP Hardener 03b Asphalt Release Agent 05j Transformer Oil 01 j Nitofill EPLV Base 03b Prime Coat MC 70 05k Paint for Kerbs 01 k Nitofill EPLV Hardener 03c Tack Coat SS1H 05 L Hydrochloric Solution 40% 01l Frosroc Solvent 102 05m Trichloroethylene 01m BASF Emaco R907 Plus Liquid 04 Plant & Equipment 05n Rockwool Thermal Panels 01n BASF Emaco R907 Plus Powder 04a Diesel 05o Welding Rod for HDPE 01o BASF Emaco S22NB 04b Lubricating Oil 05p Universal Powerwash Liquid 01p BASF Emaco S23 BC 04c Jet A1 Aircraft Fuel 05q Double Sided Butyl for Cladding System 01q Masterflow 928 05r Sealer’s Choice™ Gold for Terrazo
  • 2. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 2 of 97 05 Miscellaneous Cont 07 Paints for Steel 11 Fireproofing 05s Thixothane Coating ( VJ Couplings) 07a Juton Penguard Express ZP 11a Cafco 300 05t Thixothane Hardener ( VJ Couplings) 07b Juton Steelmaster 60WB 05 u Thinner # 7 Juton 07c Pioner Topcoat 12 Epoxy Coating 05 v Thermoplastic Road Paint 12a Nitocote EPU Base 05w HEMPADUR MASTIC 45889 Base O8 Sealants for Pavement Concrete 12b Nitocote EPU Hardener 05X HEMPEL'S CURING AGENT 95881 08a Fisher Injection Mortar FIS EM 12c Nitomortar FC (B) Base 05Y Road Marking Paint 08b Sure Anchor Grout J-50 12d Nitomortar FC (B) Hardener 05z Galvafroid 08c Igas 1h (Cold Sealant) 05ab CRC Galva Brite 08d Igas K ( Hot Sealant) 13 Tiling Mortar Adhesives 13a Sika Ceram 201 06 Plaster & Render 09 Chemical Adhesive 13b Marble, Granite& traventine Premium bed mortar 06a Bonding Rush Coat BRC (Conmix) 09a Hilti Hit RE 500 13c Polyblend Non-sanded Grout 06b Premix CP2 (Conmix) 06c Premix SRC-1 (Mineralite) 10 Roof Waterproofing 14 Sundry 06d Premix SRC-2 (Mineralite) 10a IMI Concrete Primer 14a Juton Barrier 80 06e Premix Undercoat SP1 (Mineralite) 10b IMI Elastomeric Membrane 14b Juton Penguard 06f Mineralite Finish Coat (Mineralite) 10c IMI Ekoflash 14c Juton Hardtop XP
  • 3. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 3 of 97 Hazardous Substance :- 01a Cement / Wet Concrete & Mortar Cementitious Repair mortar Suppliers name, :- CCCTAVJV Batching on site. Use :- Wide variety of applications. Storage Precautions :- No special storage requirements. Disposal Procedure :- Dispose of as inert material, prevent dust generation. Spillage Procedure :- Recover spilled material avoiding generating dust. Health Effects Controls First aid measures & Emergencies Eye contact - Eye contact with cement powder may cause serious injury. Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek immediate medical attention. Skin burns – cement may have an irritating effect on moist skin and may cause serious burns. Wear Gloves or barrier cream. Wear waterproof foot wear or wellington boots. Clothing contaminated by cement should be removed and washed thoroughly before use. Wash with copious amounts of clean water. Ingestion - May cause nausea, vomiting and diarrhoea Wash hands before eating or smoking. Wash out mouth and drink plenty of water. Do not induce vomiting. Seek medical advice if large amount is swallowed. Inhalation - Frequent inhalation of cement powder over a long period of time increases the risk of developing lung diseases. Wear mask (respirator) rated for cement dust, at all times when mixing cement. If irritation occurs, move to fresh air. If nose or airways become inflamed seek medical advice.
  • 4. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 4 of 97 Hazardous Substance :- 01b Flowcable Suppliers name, :- BASF Use :- Grout expanding agent Storage Precautions :- No special storage requirements. Disposal Procedure :- Dispose of as inert material, prevent dust generation. Spillage Procedure :- Recover spilled material avoiding generating dust. Health Effects Controls First aid measures & Emergencies Eye contact - The dust is abrasive and irritating to the eyes and may be capable of causing corneal scarring. Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek immediate medical attention. Skin – Slight irritant and may cause dermatitis. In the presence of moisture such as perspiration it can dry skin and cause alkali burns. Wear Gloves or barrier cream. Clothing contaminated by cement should be removed and washed thoroughly before use. Wash with copious amounts of clean water. Ingestion - May result in irritation and burns to mouth and stomach Wash hands before eating or smoking. Wash out mouth and drink a glass of water. Inhalation – The dust is harmful and irritating to the upper respiratory tract and lungs. The materials present a hazard from repeated exposures over long periods. Wear dust mask at all times when mixing with cement. If irritation occurs, move to fresh air.
  • 5. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 5 of 97 Hazardous Substance :- 01c Masterflow 410 Manufacturer’s name, :- BASF Constructional Chemicals UAE LLC Use :- Grouting Bridge Bearings Storage Precautions :- Store in cool,dry place with ventilation and away from food stuff. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain spilled material & remove with inert absorbent material. Health Effects Controls First aid measures & Emergencies Eye contact - Causes irritation Do not get in eyes. Solvent resistant safety eyewear recommended. MSDS on site & with site clinic Flush immediately with large amounts of water. Get medical attention. Refer to MSDS Skin burns – Causes irritation. May develop sensitisation through shin contact. Wear appropriate chemical resistant protective gloves and protective wear. MSDS on site & with site clinic Wash affected area with soap water. Remove soiled clothing. Get medical attention if irritation persists Refer to MSDS Ingestion – Stomach / intestinal irritation nausea vomiting diarrhea. Wash hands before eating or smoking MSDS on site & with site clinic Rince out mouth and consult site doctor immediately.. Refer to MSDS Inhalation – Harmful . Long term exposure can result in progressive symptoms & impaired pulmonary function. Use appropriate dust mask / respirator. MSDS on site & with site clinic Leave the area to obtain fresh air. If continued difficulty in breathing persists get medical attention.. Refer to MSDS
  • 6. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 6 of 97 Hazardous Substance :- 01d Concure A Suppliers name, :- Fosroc UAE Use :- Curing compound for concrete Storage Precautions :- Store away from sources of ignition, keep containers dry and tightly closed. Disposal Procedure :- Dispose of through an authorised waste contractor Spillage Procedure :- Recover spilled material. Fire Data & Extinguishing Media :- Flammable, gives off toxic fumes. Extinguish media: carbon dioxide, powder, foam or water fog – do not use water jets. Use Self-contained breathing apparatus. Health Effects Controls First aid measures & Emergencies Eye contact - Vapour may cause irritation. Wear Goggles where there is a danger of splashes. Irrigate with copious amounts of clean water. Seek immediate medical attention. Skin burns – May be absorbed through the skin. May defat the skin. Wear Gloves or barrier cream. Clothing contaminated by cement should be removed and washed thoroughly before use. Wash with copious amounts of clean water and soap. Ingestion - May cause nausea, vomiting and diarrhoea Wash hands before eating or smoking. Do not induve vomiting, obtain medical attention Inhalation – Mist and vapour may cause irritation to nose and respiratory tract. Use in well vented areas Remove from exposure, rest and keep warm and obtain medical attention.
  • 7. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 7 of 97 Hazardous Substance :- 01e Rheofinish 225D – Release Agent Suppliers name, :- BASF Use :- Relase agent for formwork Storage Precautions :- Store under cover Disposal Procedure :- Dispose of through an authorised waste contractor Spillage Procedure :- Recover spilled material. Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact Particulates may cause irritation, which is typically characterized by redness and excessive tear production. Safety glasses with side shields. In processes where the product is in contact with hot materials a face shield should be worn. Flush eye with clear water for several minutes. Remove contact lens if worn. If irritation persists seek medical attention. Skin burns Rheofinish may have an irritating effect on moist skin and may cause serious burns.. Cloth or leather work gloves. In processes where the product is in contact with hot materials thermal protection gloves, apron and arm protection should be worn. Seek medical attention immediately Ingestion May cause nausea, vomiting and diarrhoea. Wash hands before eating or smoking. First aid is not normally required. Inhalation Frequent inhalation of Rheofinish over a long period of time increases the risk of developing lung diseases. Wear mask when applying Rheofinish Remove affected person to fresh air. If irritation persists then seek medical attention.
  • 8. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 8 of 97 Hazardous Substance :- 01f Sika Injection 101 Manufacturer’s name, :- Sika Limited, Hertfordshire, England Use :- Injecting cracks in concrete. Storage Precautions :- Store in the original container securely closed. Keep away from foodstuffs. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain and absorb with inert absorbent material. Transfer into container for recovery or disposal. Health Effects Controls First aid measures & Emergencies Eye contact - May causes eye irritation Do not get in eyes. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Get medical attention. Skin contact – May cause skin irritation. Use barrier skin cream or gloves Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Obtain medical attention if symptoms occur. Ingestion – Can cause gastronintestinal disturbance Wash hands, forearms and face thoroughhlyafter handling, before eating, smoking and using the lavatory and at the end of the work period. Do not induce vomiting unless directed to do so by medical personnel. Mainyain an open airway. Seek medical attention. Inhalation – May causes irritation Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Obtain medical attention if symptoms occur.
  • 9. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 9 of 97 Hazardous Substance :- 01g Sika Injection 201 Manufacturer’s name, :- Sika Limited, Hertfordshire, England Use :- Injecting cracks in concrete. Storage Precautions :- Store in the original container securely closed. Keep away from foodstuffs. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain and absorb with inert absorbent material. Transfer into container for recovery or disposal. Health Effects Controls First aid measures & Emergencies Eye contact - May causes eye irritation Do not get in eyes. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Get medical attention. Skin contact – May cause skin irritation. Use barrier skin cream or gloves Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Obtain medical attention if symptoms occur. Ingestion – Harmful if swallowed Wash hands, forearms and face thoroughhlyafter handling, before eating, smoking and using the lavatory and at the end of the work period. Do not induce vomiting unless directed to do so by medical personnel. Mainyain an open airway. Seek medical attention. Inhalation – May causes irritation Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Obtain medical attention if adverse health effects persit or are severe.
  • 10. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 10 of 97 Hazardous Substance :- 01h Nitobond EP Base Manufacturer’s name, :- Fosroc Use :- Epoxy Bonding Agent Storage Precautions :- Keep containers dry and tightly closed Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site. Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means Health Effects Controls First aid measures & Emergencies Eye contact - Causes transient irration Avoid eye contact. Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation persists. Skin contact – Irritation. May cause sensitisation. Avoid skin contact. Maintain good standards of personal hygiene. Wash thoroughly with soap and water or suitable skin cleanser as soon as possible. Obtain medical advise if skin discorders develop. Inhalation – May cause respiratory irritation Ensure adequate ventilation. Remove from exposure Ingestion – May cause irritation of mouth, throat and digestive tract. Do not eat, drink or smoke whilst using this product. Obtain medical attention. Do not induce vomiting. Beware of aspiration if vomiting occurs.
  • 11. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 11 of 97 Hazardous Substance :- 01i Nitobond EP Hardener Manufacturer’s name, :- Fosroc Use :- Epoxy Bonding Agent Storage Precautions :- Store in cool, dry areas. Keep away from foodstuffs and food containers. Store in original container. ................................................Never transfer to a unlabelled container Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site. Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers. Health Effects Controls First aid measures & Emergencies Eye contact - Irritating and may injure eye tissue if not removed promptly. Avoid eye contact. Wear goggles conforming to EN 166 Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation urgently Skin contact – Harmful by absorption through the skin. Moderately irritating. May cause sensitisation. Avoid skin contact. Maintain good standards of personal hygiene. Wear impervious gloves e.g. PVC Wash immediately with soap and water or suitable skin cleanser. Obtain medical advise if skin discorders develop. Remove contaminated clothing immediately. Inhalation – Toxic by inhalation. May cause respiratory irritation Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure, rest and keep warm and obtain medical attention urgently. Ingestion – Toxic if swallowed. May cause nausea, vomiting and diarrhoea. Do not eat, drink or smoke whilst using this product. Wash out mouth with water and give sips of cold water to soothe the affected parts. Do not induce vomiting. Obtain medical attention urgently.
  • 12. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 12 of 97 Hazardous Substance :- 01j Nitofill EPLV Base Manufacturer’s name, :- Fosroc Use :- Concrete Crack Repair Storage Precautions :- Keep containers dry and tightly closed. Handling :- Maintain good standards of personal hygiene. Avoid shin and eye contact. Do not eat, drink or smoke ..................................................whilst using this product. Ensure adequate ventilation. Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site. Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers. ......................................................................................Dispose of as waste. Fire Hazard Details :- Flash point >150*C. Use carbon dioxide, power, foam or water fog – do not use water jets to extinguish a fire Health Effects Controls First aid measures & Emergencies Eye contact - Irritation Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation persists. Skin contact – Irritation. May cause sensitisation. Avoid skin contact. Maintain good standards of personal hygiene. Wear impervious gloves e.g. PVC. Change contaminated clothing immediately and clean before re-use. Wash thoroughly with soap and water or suitable skin cleanser as soon as possible. Obtain medical advise if skin discorders develop. Inhalation – May cause respiratory irritation Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure. Ingestion – May cause irritation of mouth, throat and dijestive tract. Do not eat, drink or smoke whilst using this product. Obtain medical attention urgently. Do Not induce vomiting. Beware of aspiration if vomiting occurs.
  • 13. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 13 of 97 Hazardous Substance :- 01k Nitofill EPLV Hardener Manufacturer’s name, :- Fosroc Use :- Concrete Crack Repair Storage Precautions :- Store in cool, dry area. Store only in original container. Neverleave a container unsealed. Handling :- Maintain good standards of personal hygiene. Avoid shin and eye contact. Do not eat, drink or smoke ..................................................whilst using this product. Ensure adequate ventilation. Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site. Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Gather into containers. ......................................................................................Dispose of as waste. Fire Hazard Details :- Flash point 110*C. Use carbon dioxide, power, foam or water fog – do not use water jets to extinguish a fire Health Effects Controls First aid measures & Emergencies Eye contact - Severe irritation. Causes irreversible damage to eye tissue if not removed promptly. Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation persists. Skin contact – Corrosive – causes burns. May cause sensitisation. Avoid skin contact. Maintain good standards of personal hygiene. Wear impervious gloves e.g. PVC. Change contaminated clothing immediately and clean before re-use. Wash thoroughly with soap and water or suitable skin cleanser as soon as possible. Remove contaminated clothing immediately. Inhalation – Irritating to respiratory system. Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure. Ingestion – Corrosive – causes severe damage to mouth, throat and dijestive tract. Do not eat, drink or smoke whilst using this product. Wash mouth with water. Obtain medical attention urgently.. Do Not induce vomiting. Beware of aspiration if vomiting occurs.
  • 14. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 14 of 97 Hazardous Substance :- 01l Fosroc Solvent 102 Manufacturer’s name, :- Fosroc Use :- Solvent cleaning Storage Precautions :- Store away from sources of ignition. Store out of direct sunlight. Handling :- Do not use near sources of ignition. Use only in well ventilated areas. Avoid breathing vapours. Avoid .................................................skin and eye contact. Disposal Procedure :- Dispose of through an authorised waste contractor to a licenced site. Spillage Procedure :- Soak up with inert absorbent or contain and remove by best available means. Dispose of as waste. Fire Hazard Detail :- Avoid any source of ignition. Direct sunlight. Temperatures avove 30*C. To extinguish use carbon dioxide, power, foam or water fog do not use water jets. Health Effects Controls First Aid Measures & Emergencies Eye contact - Irritating, but does not injure eye tissue. Vapour may cause irritation. Avoid eye contact. Wear safety goggles. Irrigate immediately with copious quantities of water for several minutes. Obtain medical attention if irritation persists. Skin contact – May be absorbed through the skin. May defat the skin. Avoid skin contact. Maintain good standards of personal hygiene. Wash thoroughly with soap and water or suitable skin cleanser as soon as possible. Remove contaminated clothing immediately. Inhalation – Mist and vapours may cause irritation to nose and respiratory tract. Ensure adequate ventilation. Avoid breathing vapours. Remove from exposure, rest and keep warm and obtain medical attention urgently. Ingestion – May cause nausea, vomiting and diarrhoea. Aspiration of liquid during ingestion or from vomiting may cause severe chemical pneumonitis. Do not eat, drink or smoke whilst using this product. Obtain medical attention urgently. Do Not induce vomiting. Beware of aspiration if vomiting occurs.
  • 15. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 15 of 97 Hazardous Substance : 01m Emaco R907 Plus Liquid Manufacturer’s name : BASF Description :- : Storage Precautions : Store in shaded areas and away from direct sunlight Disposal Procedure : Spillage Procedure : Absorb with suitable material e.g. sand & earth, seal in plastic bag & bury in landfill. Fire Fighting Measures Extinguishing media : Non-flammable material. Recommendations : Personal Precautions : Health Effects Controls First aid measures & Emergencies Eye contact - N/A Safety goggles Flush immediately with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Skin – N/A Impervious gloves Remove contaminated clothes immediately. Wash affected area with soap and plenty of water. Ingestion – N/A Wash hands before breaks and after finishing work. Do not eat, drink or smoke at workplace. Inhalation - N/A Provide for good ventilation Remove affected person to fresh air. If symptoms persist obtain medical attention.
  • 16. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 16 of 97 Hazardous Substance : 01n Emaco R907 Plus Powder Manufacturer’s name : BASF Description :- : Blend of cementitious powder and mineral fillers. Storage Precautions : Powder product. Must be protected from dampness and water. Disposal Procedure : Spillage Procedure : Reuse if possible OR Sweep up powder as soon as possible, andnbury in the landfill. Fire Fighting Measures Extinguishing media : Non-flammable material. Recommendations : Personal Precautions : Health Effects Controls First aid measures & Emergencies Eye contact - Irritating to eyes. Safety goggles Flush immediately with plenty of water for at least 15 minutes. Get medical attention if irritation persists. Skin – Irritating to skin. Impervious gloves Remove contaminated clothes immediately. Wash affected area with soap and plenty of water. Ingestion – No data available Wash hands before breaks and after finishing work. Do not eat, drink or smoke at workplace. If swallowed obtain medical attention. Do not induce vomiting. Give water to drink. Inhalation - Irritating to respiratory system. Dust Mask. Powder product – take care when handling. Remove affected person to fresh air. If symptoms persist obtain medical attention.
  • 17. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 17 of 97 Hazardous Substance : 01o Emaco S22NB Manufacturer’s name : BASF Description :- : Blend of cementitious powder and mineral fillers Storage Precautions : Store out of direct sunlight, clear of ground on pallets protected from rainfall. Avoid excessive compaction Disposal Procedure : Spillage Procedure : Reuse if possible. OR Mix with water and allow to harden, and dispose in landfill. Fire Fighting Measures Extinguishing media : Non-flammable material. Recommendations : Personal Precautions : Health Effects Controls First aid measures & Emergencies Eye contact - N/A Safety goggles Flush immediately with plenty of water for at least 15 minutes. Get medical attention. Skin – Prolonged exposure may cause skin sensitization. Impervious gloves. Observe the usual precautions when handling chemicals Remove contaminated clothes immediately. Wash affected area with soap and plenty of water. Ingestion – N/A Wash hands before breaks and after finishing work. Do not eat, drink or smoke at workplace. If swallowed obtain medical attention. Do not induce vomiting. Inhalation - Prolonged exposure may cause irritation to respiratory system. Dust Mask Remove affected person to fresh air. If symptoms persist obtain medical attention.
  • 18. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 18 of 97 Hazardous Substance : 01p Emaco S23NB Manufacturer’s name : BASF Description :- : Blend of cementitious powder and mineral fillers Storage Precautions : Store out of direct sunlight, clear of ground on pallets protected from rainfall. Avoid excessive compaction Disposal Procedure : Spillage Procedure : Reuse if possible. OR Mix with water and allow to harden, and dispose in landfill. Fire Fighting Measures Extinguishing media : Non-flammable material. Recommendations : Personal Precautions : Health Effects Controls First aid measures & Emergencies Eye contact - Irritating to eyes Safety goggles Flush immediately with plenty of water for at least 15 minutes. Get medical attention. Skin – Irritating to skin Impervious gloves. Observe the usual precautions when handling chemicals Remove contaminated clothes immediately. Wash affected area with soap and plenty of water. Ingestion – N/A Wash hands before breaks and after finishing work. Do not eat, drink or smoke at workplace. If swallowed obtain medical attention. Do not induce vomiting. Inhalation - Irritating to respiratory system. Dust Mask Remove affected person to fresh air. If symptoms persist obtain medical attention. Hazardous Substance : 01q Masterflow 928
  • 19. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 19 of 97 Manufacturer’s name : Degussa Building Systems Storage Precautions : In an area that is ventilated Disposal Procedure : Spillage Procedure : Clean up promptly by sweeping or vacuum. Description :- : Grout Fire Fighting Measures Extinguishing media : Water fog, carbon dioxide, dry chemical. Recommendations : Personal Precautions : Wear full protective gear Health Effects Controls First aid measures & Emergencies Eye contact - Can cause severe irritation, redness, tearning and blurred vision. Wear as appropriate: safety glasses with side shields. Flush eyes with water, lifting upper and lower lids occasionally for 15 minutes. Seek medical attention. Skin – Can cause slight to moderate irritation due to abrasive action. In combination with water, repeated or prolonged exposure can cause moderate to severe alkali burns. Wear as appropriate; gloves Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Seek medical advice. Ingestion – Irritating to mouth, throat and stomach. Wash hands before meal breaks. Do not induce vomitingwithout medical advice. If conscious drink plenty of water. Seek medical advice. Inhalation – Inhalation of dust may cause coughing and laboured breathing and possible temporary but irresible irritation on mucous membranes and respiratory tract. In case of insufficient ventilation wear respirator Remove victim from exposure. If difficulty with breathing administer oxygen. Hazardous Substance : 01r Sikadur 52 Part A
  • 20. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 20 of 97 Manufacturer’s name : Sika Ltd Description :- : 2-component epoxy resin for crack injection and stabilising. Storage Precautions : Storage area should be: cool. dry. Storage temperature should be controlled to between 5 and 25 °C. Store in the original container securely closed . Keep away from foodstuffs Disposal Procedure : Dispose of as Special Waste. Arrange for disposal via a licensed waste contractor. Spillage Procedure : Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Fire Fighting Measures Extinguishing media : Use foam, dry chemical or carbon dioxide. Recommendations : Personal Precautions : Wear full protective clothing and self-contained breathing apparatus. Health Effects Controls First aid measures & Emergencies Eye contact - Irritating to the eyes. Wear chemical goggles. Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention urgently. Skin – Frequent or prolonged skin contact may cause some local short term skin irritation. Wear suitable impervious gloves. (butyl / nitrile type) The insides of gloves must be kept scrupulously clean. Wipe off as much as possible with a clean dry cloth. Wash skin thoroughly with soap and water. Solvents should not be used to clean skin because they may increase the penetration of the material. Ingestion – Use of the basic principles of Industrial Hygiene will enable this material to be used safely. Wash out mouth with water. Obtain medical attention. Inhalation - Respiratory protection not normally required. Remove from exposure. In cases of possible respiratory irritation or if feeling unwell in cases of prolonged exposure,obtain medical attention. Hazardous Substance : 01r Sikadur 52 Part B
  • 21. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 21 of 97 Manufacturer’s name : Sika Ltd Description :- : 2-component epoxy resin for crack injection and stabilising. Storage Precautions : Storage area should be: cool. dry. Storage temperature should be controlled to between 5 and 25 °C. Store in the original container securely closed . Keep away from foodstuffs Disposal Procedure : Dispose of as Special Waste. Arrange for disposal via a licensed waste contractor. Spillage Procedure : Contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Fire Fighting Measures Extinguishing media : Use foam, dry chemical or carbon dioxide. Recommendations : Personal Precautions : Wear full protective clothing and self-contained breathing apparatus. Health Effects Controls First aid measures & Emergencies Eye contact - Causes burns. This material is corrosive to the eye. Wear chemical goggles. Immediately flood the eye with plenty of water for at least 15 minutes, holding the eye open. Obtain medical attention urgently. Skin – This material is corrosive to the skin. The possibility of allergic sensitisation should be considered Wear suitable impervious gloves. (butyl / nitrile type) The insides of gloves must be kept scrupulously clean. Wipe off as much as possible with a clean dry cloth. Wash skin thoroughly with soap and water. Solvents should not be used to clean skin because they may increase the penetration of the material. Ingestion – Harmful if swallowed. Use of the basic principles of Industrial Hygiene will enable this material to be used safely. Do not induce vomiting. Obtain medical attention. Inhalation - Harmful by inhalation, Respiratory protection not normally required. Remove from exposure. In cases of possible respiratory irritation or if feeling unwell in cases of prolonged exposure,obtain medical attention.
  • 22. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 22 of 97 Hazardous Substance :- 02a Igasol Emulsion SG (F)by Sika Description - Aqueous Bitumen Emulsion for Waterproofing buried concrete Suppliers name, :- Sika Storage Procedures :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Use spill kit Fire Data & Extinguishing Media :- Flash Point N.A. Extinguish media: Water. Foam carbon dioxide, dry powder Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact May cause irritation Wear eye protection Irrigate immediately with copious quantities of water for 15 minutes. Summon site doctor immediately Skin May cause irritation Wear gloves and overalls, remove soiled clothing immediately Wash off immediately with soap and water Consult doctor if skin irritation persists. Ingestion May cause irritation Do not eat, drink or smoke during work time. Wash hands before eating. Do not induce vomiting. Summon a doctor immediately. Inhalation May cause health disorders Ensure adequate ventilation. In the event of symptoms take medical treatment
  • 23. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 23 of 97 Hazardous Substance :- 02b Bituthene 8000& Protection Board Description - Bituthene membrane 1.5mm thick, grey in colour. Self adhesive, comes in rolls and has a protectice release paper. For waterproofing buried concrete. Suppliers name, :- W.R.Grace Storage Procedures :- N special requirement Disposal Procedure :- Product is classified as non hazardous for disposal purposes. Spillage Procedure :- Due to physical nature, spills not possible. Fire Data & Extinguishing Media :- Flash Point > 210*C In case of fire, use water spray, dry chemical, Carbon dioxide or foam. Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact May cause irritation Wear eye protection Flush with water for 15 minutes Skin Not applicable Wash with water remove residue with clearing cream Ingestion Not applicable Not applicable Inhalation Not applicable Unlikely to occur in quantites sufficient to cause any effects.
  • 24. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 24 of 97 Hazardous Substance :- 03a Bitumen Description :- Bitumen product for road building. Suppliers name, :- Shell Use :- Paving material Storage Precautions :- Store away from moisture and sources of ignition Disposal Procedure :- Dispose of via an authorised person / licence waste disposal contractor. Spillage Procedure :- Contain and recover liquid using sand or other inert absorbent. Health Effects Controls First aid measures & Emergencies Eye contact - Hot product may cause severe eye burns and/or blindness. For normal operations with hot material wear safety hat with visor. • Hot product - If contact with hot product, cool the burn area by flushing with large amounts of water for twenty minutes. • Do not attempt to remove anything from the burn area or apply burn creams or ointments. • Cover the burn area loosely with a sterile dressing, if available. Transport to the nearest medical facility • for additional treatment. • All burns should receive medical attention. • Cold product - Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Skin burns – Contact with hot material can cause thermal burns which may result in permanent skin damage. For normal operations with hot material wear heat resistant coveralls, (with cuffs over gloves and legs over boots), and heavy-duty boots, e.g. leather for heat resistance. The use of a neck apron is recommended. • If contact with hot product, cool the burn area by flushing with large amounts of water. • Do not attempt to remove anything from the burn area or apply burn creams or ointments. Cover • the burn area loosely with a sterile dressing, if available. • Transport to the nearest medical facility for additional • treatment. It should be noted this product contracts on cooling. • Where a limb is encased, care should be taken
  • 25. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 25 of 97 to avoid the • development of a tourniquet effect. In the event of this • occurring the adhering product must be softened and/or split to • prevent restriction of blood flow. All burns should receive medical attention. Ingestion – Under normal conditions of use, this is not expected to be a primary route of exposure. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. • If contamination of mouth occurs, wash out thoroughly with water. Do not induce vomiting, obtain medical advise. Inhalation – Inhalation of vapours or mists may cause irritation to the respiratory system. No respiratory protection is ordinarily required under normal conditions of use. Use self contained breathing apparatus in places where hydrogen sulphide vapours may accumulate. • If inhalation of mists, fumes or vapour causes irritation to the nose or throat, remove to fresh air. • If rapid recovery does not occur, obtain medical attention. • Casualties suffering ill effects as a result of exposure • to hydrogen sulphide should be removed to fresh air. • Do not attempt to rescue the victim unless proper respiratory protection is worn. • If the victim has difficulty breathing or tightness of the chest, is dizzy, vomiting, or unresponsive, give 100% oxygen with rescue breathing or Cardiopulmonary Resuscitation (CPR) as required and transport to the • nearest medical facility.
  • 26. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 26 of 97 Hazardous Substance :- 03b LIESEN Separating Agent TM-BA1( Emulsion) Description :- Asphalt release / cleaning agent Suppliers Name :- LIESEN Storage Procedures :- Store above freezing point. Disposal Procedure :- Use approved waste disposal facility Spillage Procedure :- Use absorbent and don’t allow to enter watercourse Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact – May be painful and irritating - Person using chemical to be briefed on the correct use of chemical. - Personnel not involved in the use of the chemical to be removed from area. - Goggles or helmet with viser to be worn when spraying Black Magic Chemical - Eye wash kit to be available in work location - First aider to be in batching plant are whenever work is being carried out. - First aid box eye wash Flush with eye wash kit for fifteen minutes Inform the onsite first aider Go to the on site clinic for check up Skin Contact- Prolonged contact may cause irritation - Person using chemical to be briefed on the correct use of chemical. - Personnel not involved in the use of the chemical to be removed from area. - Coveralls and rubber gloves to be worn at all times when using the chemical. - Clean running water and soap to be available for personnel. - Clean coveralls to be available if ones been used get contaminated. Wash with mild soap and wash off with clean water. Inform onsite first aided If problem occurs go straight to the onsite clinic
  • 27. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 27 of 97 Ingestion – May cause nausea - Chemical not to be used in a confined space. - Personnel not involved in the use of the chemical to be removed from area. - 3M style mask to be worn when using the chemical Inform the onsite first aider and go to site clinic. Inhalation – May irritate nose, throat or chest. - Chemical not to be used in a confined space. - Personnel not involved in the use of the chemical to be removed from area. - 3M style mask to be worn when using the chemical Remove person effected to fresh air and contact the onsite first aider. If the effected person does not feel better after 15 minutes in the fresh air, take them to site clinic.
  • 28. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 28 of 97 Hazardous Substance :- 03b Prime Coat MC-70 Description :- Mediumm curing cutback asphalt Suppliers Name :- Horizon energy Ltd, Dubai Storage Procedures :- Keep far from food or drink. Disposal Procedure :- Use approved waste disposal facility Spillage Procedure :- Use absorbent and don’t allow to enter watercourse Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact May cause mild eye irritation including stringing, watering, and redness. Wear eye face protection First aid box Rince with water till disappearance of the irritation, in case of persistence go to sit clinic. Skin May cause redness, itching, burning and severe skin damage. Use oleo resistant gloves and suitable protective clothing. Wash with water and soap, take off contaminated clothes and wash before using. Ingestion Low degrees of toxicity by ingestion. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. Don’t induce vomiting and seek medical attention. Inhalation low degree of toxicity by inhalation When the product concentration in the air is high use protective masks The product doesn’t emit vapours
  • 29. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 29 of 97 Hazardous Substance :- 03c Tack Coat SS1H Description :- Anionic emulsified asphalt Suppliers Name :- CYTECH, DUBAI Storage Procedures :- Keep far from food or drink. Disposal Procedure :- Use approved waste disposal facility Spillage Procedure :- Use absorbent and don’t allow to enter watercourse Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact May cause mild eye irritation including stringing, watering, and redness. Wear eye face protection Rince with water till disappearance of the irritation, in case of persistence go to sit clinic. Skin May cause redness, itching, burning and severe skin damage. Use oleo resistant gloves and suitable protective clothing. Wash with water and soap, take off contaminated clothes and wash before using. Ingestion Low degrees of toxicity by ingestion. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. Don’t induce vomiting and seek medical attention. Inhalation Low degree of toxicity by inhalation When the product concentration in the air is high use protective masks The product doesn’t emit vapours
  • 30. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 30 of 97 Hazardous Substance :- 04a Diesel Suppliers name, :- Shell Storage Procedures :- Store in approved containers protected from physical damage away from sources of ignition Disposal Procedure :- Use approved waste disposal facility Spillage Procedure :- Clean up spills with absorbent material and isolate hazard area. Hazardous Substance & Health Effects Controls First aid measures & Emergencies Eye contact May cause mild eye irritation including stringing, watering, and redness. Wear googles and Safety glasses with side shields as good industrial practice. First aid box with eye wash. If irritation or redness develops, move victim away from exposure and into fresh air. Flush eyes with clean water. If symptoms persist, seek medical attention. Skin May cause redness, itching, burning and severe skin damage. Prolonged or repeated contact can worsened irritation by causing drying and cracking of the skin leading to dermatitis. Not actually toxic by skin absorption but prolonged or repeated skin contact maybe harmful. Use oil-resistant gloves and apron if needed. Immediately removed contaminated shoes, clothing and constrictive jewelry and flush affected area with large amount of water. If skin surface is damaged, apply a clean dressing and seek immediate medical attention. Ingestion Low degrees of toxicity by ingestion can enter to the lungs during swallowing and cause lung inflammation and damage. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. Do not leave the victim unattended and observe closely for adequacy of breathing and seek medical attention. Inhalation low degree of toxicity by inhalation Carry out refuelling in fresh air situations. If breathing difficulties develops, administer oxygene by medical personnel.
  • 31. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 31 of 97 Hazardous Substance :- 04b Lubrication Oil Suppliers name, :- Shell Storage Procedures :- Do not store near heat, sparks, flames or strong oxidants. Store in cool place Disposal Procedure :- Use approved waste disposal facility. Spillage Procedure :- Use absorbent and don’t allow to enter watercourse. Health Effects Controls First aid measures & Emergencies Eye contact Eye contact may result in irritation. Wear googles and Safety glasses with side shields as good industrial practice. First aid with eye washing facility In case of contact, flush eyes with plenty nof water for atleast 15 minutes or until irritation subsides. Physician should be contacted should irritation persist. Skin burns Prolonged or repeated skin contact may cause skin irritation Use oil-resistant gloves and apron if needed. Removed any contaminated clothing and wash skin with soap and warm water. Ingestion Minute amounts aspirated into the lungs during ingestion may cause mild to severe pulmonary injury. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. If ingested call a physician immediately. Do not induce vomiting. Inhalation Vapor pressure is very low and inhillation at room temperature is not a problem. If overcome by vapour from a hot product mild to severe pulmonary injury may occur. Respiratory protection normally not needed. If overcome by vapor from hot product, Immediately removed from exposure and call a physician.
  • 32. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 32 of 97 Hazardous Substance : 04c Jet A1 Aircraft fuel Manufacturer’s name : Shell Description :- : Fuel for aviation turbine engines fitted to aircraft. Storage Precautions : Tanks must be specifically designed for use with this product. Disposal Procedure : Disposal methods in compliance with applicable regulations Spillage Procedure : Evacuate the area of all nonessential personnel. Ventilate contaminated area thoroughly. For small liquid spills (< 1 drum), transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely Fire Fighting Measures Extinguishing media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Recommendations : Keep adjacent containers cool by spraying with water. If possible remove containers from the danger zone. If the fire cannot be extinguished the only course of action is to evacuate immediately. Personal Precautions : Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space Health Effects Controls First aid measures & Emergencies Eye contact - Slightly irritating. Chemical splash goggles (chemical monogoggles). Flush eyes with water while holding eyelids open. Rest eyes for 30 minutes. If redness, burning, blurred vision, or swelling persist, transport to the nearest medical facility for additional treatment Skin – Irritating to skin. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. Remove contaminated clothing. Immediately flush skin with large amounts of water for at least 15 minutes, and follow by washing with soap and water if available. If redness, swelling, pain and/or blisters occur, transport to the nearest medical facility for additional treatment Ingestion – Low toxicity:LD50 >2000 mg/kg Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact If swallowed, do not induce vomiting: transport to nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep head below hips to prevent aspiration. Inhalation - Slightly irritating . Ventilation, If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment.
  • 33. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 33 of 97 Hazardous Substance :- 05a Welding Rods Manufacturer’s name, :- Various Use :- Welding steel Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Health Effects Controls First aid measures & Emergencies Eye contact - Hazardous Use helmets with suitable shielding glass Dampen with fresh water Skin – Burns Cover exposed areas with appropriate clothing. For hands and arms use welding gauntlets. Seek medical attention Hearing – Minor Use ear protectors and/or ear plugs Seek medical assistance. Inhalation – Hazardous in case of inhalation. Avoid inhaling fumes / gases, be sure there is enough ventilationand / or fumes extractors are available. Remove to ventilated place. Seek medical assistance if symptoms persist.
  • 34. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 34 of 97 Hazardous Substance :- 05b Sipoxy Shield 266 Base Manufacturer’s name, :- Saudi Industrials Paint Co. Ltd Use :- For repairs to DI Pipes Storage Precautions :- Keep away from heat, spark, flame. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain spilled material & remove with inert absorbent material. Health Effects Controls First aid measures & Emergencies Eye contact - Causes irritation Do not get in eyes. Solvent resistant safety eyewear recommended. Flush immediately with large amounts of water. Get medical attention. Skin burns – Causes irritation, may be harmful if absorbed through skin. Wear protective gloves and protective wear. Wash affected area with soap water. Remove soiled clothing. Get medical attention if irritation persists Ingestion – Stomach / intestinal irritation nausea vomiting diarrhea. Wash hands before eating or smoking Consult a physician immediately. Do not induce vomiting. Inhalation – Irritation of repiratory tract, headache, nausea, dizziness. Extream exposure can cause unconsciousness ans even respiratory arrest. Use dust / vapour mask. Leave the area to obtain fresh air. If continued difficulty in breathing persists get medical attention. If breathing ceases restore using CPR techniques.
  • 35. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 35 of 97 Hazardous Substance :- 05c Sipoxy Shield 266 Hardener Manufacturer’s name, :- Saudi Industrials Paint Co. Ltd Use :- For repairs to DI Pipes Storage Precautions :- Keep away from heat, spark, flame. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain spilled material & remove with inert absorbent material. Health Effects Controls First aid measures & Emergencies Eye contact - Causes irritation Do not get in eyes. Solvent resistant safety eyewear recommended. Flush immediately with large amounts of water. Get medical attention. Skin burns – Causes irritation, may be harmful if absorbed through skin. Wear protective gloves and protective wear. Wash affected area with soap water. Remove soiled clothing. Get medical attention if irritation persists Ingestion – Stomach / intestinal irritation nausea vomiting diarrhea. Wash hands before eating or smoking Consult a physician immediately. Do not induce vomiting. Inhalation – Irritation of repiratory tract, headache, nausea, dizziness. Extream exposure can cause unconsciousness ans even respiratory arrest. Use dust / vapour mask. Leave the area to obtain fresh air. If continued difficulty in breathing persists get medical attention. If breathing ceases restore using CPR techniques.
  • 36. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 36 of 97 Hazardous Substance :- 05d Bentonite Manufacturer’s name, :- Mandaksh Exports India Use :- Grouting Duct Annulus Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Contain spilled material & remove Description :- :- Powder Health Effects Controls First aid measures & Emergencies Eye contact - Hazardous in case of eye contact (irritant), Avoid contact with eyes Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. WARM water MUST be used. Get medical attention. Skin – Slightly hazardous in case of skin contact (irritant), Full suit. Gloves Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops Ingestion – Not available. Wash hands before eating or smoking MSDS on site & with site clinic Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Inhalation – Hazardous in case of inhalation. Do not breathe dust In case of insufficient ventilation, wear suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible.
  • 37. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 37 of 97 Hazardous Substance :- 05e Jotashield (Concrete Paint) Manufacturer’s name, :- Jotun India Pvt Ltd, India Use :- Concrete Paint Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents. Description :- :- Liquid Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to sewers or waterways. Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS. Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Harmful in contact with skin and if swallowed. May cause sensitisation by skin contact. Personnel should wear antistatic clothing made of natural fibres or of hightemperature- resistant synthetic fibres. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do not use solvents or thinners. Ingestion – Harmful in contact with skin and if swallowed. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Irritating to respiratory system. If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product.(as filter combination A2-P2). In confined spaces, use compressed-air or fresh- air respiratory equipment. When use of roller or brush, consider use of charcoalfilter. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
  • 38. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 38 of 97 Hazardous Substance :- 05f Jotashield Tex Ultra (Concrete Paint) Manufacturer’s name, :- Jotun India Pvt Ltd, India Use :- Concrete Paint Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents. Description :- :- Liquid Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to sewers or waterways. Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS. Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Harmful in contact with skin and if swallowed. May cause sensitisation by skin contact. Personnel should wear anti-static clothing made of natural fibre. For prolonged or repeated handling, use gloves : Neoprene or nitrile. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Ingestion – Harmful in contact with skin and if swallowed. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Irritating to respiratory system. If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product (as filter combination) In confined spaces use compressed air or fresh air respiratory equipment. When use of roller or brush, consider use of Charcoal filter. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious place in recovery position and seek medical advice.
  • 39. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 39 of 97 Hazardous Substance :- 05g JOTUN SILOXANE A PRIMER (Concrete Paint) Manufacturer’s name, :- Jotun U.A.E. Ltd. LLC. Use :- Concrete Paint Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents. Description :- :- Liquid Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to sewers or waterways. Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS. Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Harmful in contact with skin and if swallowed. May cause sensitisation by skin contact. Personnel should wear anti-static clothing made of natural fibre. For prolonged or repeated handling, use gloves : Neoprene or nitrile. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred Remove contaminated clothing and shoes. Wash skin thoroughly withsoap and water or use recognized skin cleanser. Do NOT use solvents orthinners. Ingestion – Harmful in contact with skin and if swallowed. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Irritating to respiratory system. If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious place in recovery position and seek medical advice.
  • 40. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 40 of 97 Hazardous Substance :- 05h Jotun Thinner No. 10 Manufacturer’s name, :- Jotun Paints (Europe) Ltd. Use :- Concrete Paint Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Preferably clean with a detergent. Avoid using solvents. Description :- :- Liquid Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to sewers or waterways. Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS. Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use safety eyewear designed to protect against splash of liquids Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Harmful in contact with skin and if swallowed. May cause sensitisation by skin contact. Personnel should wear anti-static clothing made of natural fibre or of high temperature resistant synthetic fibre. For prolonged or repeated handling, use gloves: polyvinyl alcohol or nitrile. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred. Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do NOT use solvents or thinners. Ingestion – Harmful in contact with skin and if swallowed. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Irritating to respiratory system. If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product (as filter combination A2-P2). In confined spaces use compressed air or fresh air respiratory equipment. When use of roller or brush, consider use of charcoalfilter (A2). Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious place in recovery position and seek medical advice.
  • 41. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 41 of 97 Hazardous Substance :- 05j Transformer Oil Suppliers name :- M/S. Savita Oil Technologies Ltd - India., Storage Procedures :- Do not store near heat, sparks, flames or strong oxidants. At ambient Temperature Disposal Procedure :- Use approved waste disposal facility. Spillage Procedure :- Absorbe large spillages in sand and don’t allow to enter watercourse. Health Effects Controls First aid measures & Emergencies Eye contact Eye contact may result in irritation and redness. Wear googles and Safety glasses with side shields as good industrial practice. First aid with eye washing facility In case of contact, flush eyes with plenty of water for atleast 15 minutes or until irritation subsides. Physician should be contacted should irritation persist. Skin burns Prolonged or repeated skin contact may cause skin irritation,dryness & dermatitis. Use oil-resistant gloves and apron if needed.Wash thoroughly with water. Remove any contaminated clothing and wash skin with soap and warm water. Ingestion Minute amounts aspirated into the lungs during ingestion may cause stomach discomfort or nausea. Wash hand thoroughly before eating, drinking, smoking, and use rest room after contact. If ingested call a physician immediately. Do not induce vomiting. Inhalation Inhalation of vapour or mist may be irritating to respiratory passages.Prolonged exposure may result in dizziness and nausea. Remove to fresh air.Assist breathing if necessary. If overcome by vapor from hot product, Immediately removed from exposure and call a physician.
  • 42. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 42 of 97 Hazardous Substance :- 05k Jotun Road Marking Paint (Concrete Paint) Manufacturer’s name, :- Jotun India Pvt Ltd, India Use :- Road marking Paint Storage Precautions :- Secure area Disposal Procedure :- To licenced facility Spillage Procedure :- Contain and collect spillage with non-combustible absorbent material. Description :- :- Liquid in various colours Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Recommendations : Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard. Appropriate breathing apparatus may be required. Cool closed containers exposed to fire with water. Do not release runoff from fire to sewers or waterways. Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist, Refer to MSDS. Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use Safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Harmful in contact with skin and if swallowed. May cause sensitisation by skin contact. Personnel should wear anti-static clothing made of natural fibre. For prolonged or repeated handling, use gloves : Neoprene or nitrile. Barrier creams may help to protect the exposed areas of the skin, they should however not be applied once exposure has occurred Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Ingestion – Harmful in contact with skin and if swallowed. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Irritating to respiratory system. If workers are exposed to concentrations above the exposure limit they must use appropriate, certified respirators. Use respiratory mask with charcoal and dust filter when spraying this product (as filter combination) In confined spaces use compressed air or fresh air respiratory equipment. When use of roller or brush, consider use of Charcoal filter. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious place in recovery position and seek medical advice.
  • 43. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 43 of 97 Hazardous Substance :- 05l Hydrochloric Solution 40% Manufacturer’s name, :- Cooper Use :- Washing Mineralite Plasterwork Description :- :- Liquid Storage Precautions :- Secure and ventilated area, keep away from heat and flame. Keep out of direct sunlight. Disposal Procedure :- To licenced facility Spillage Procedure :- Contain and collect spillage with non-combustible absorbent material. Fire Fighting Measures Extinguishing media : Use extinguishing agents appropriate for surrounding fires. Recommendations : In event of a fire, wear full protective clothing and full protective gear. Non flammable, but reacts with most metals to form flammable hydrogen gas. Personal Precautions : Keep unnecessary people away, isolate hazard area and deny entry. Health Effects Controls First aid measures & Emergencies Eye contact - Corrosive ! Vapour or mist may cause irritation and severe burns and permanent eye damage. May cause painful senitization to light. May cause conjuncttivities Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids, Get medical aid immediately. Do not allow victim to rub or keep eyes closed. Skin – Corrosive ! May be absorbed through the skin in harmful amounts. Contact with liquid is corrosive and causes severe burns and ulceration. May Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact. Get medical attention immediately. Rinse area with large amounts of water for at least 15 minutes. Remove contaminated clothing and shoes.
  • 44. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 44 of 97 cause photosensitization in certain individuals. Ingestion – Corrosive ! May cause circulatory system failure. Causessevere digestive tract burns with abdominal pain, vomiting, and possible death. May cause permanent tissue destruction of the esophagus and digestive tract. Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Do not induce vomiting. If the victim is conscious and alert, give 2 to 4 cupfuls of milk or water. Get medical attention immediately. Inhalation – Corrosive ! Causes severe irritation of upper respiratory tract with coughing, burns, breathingdifficulty and possible coma. May cause pulmonary edema and severe respiratory disturbances. If the exposure limit is exceeded, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres. Remove to fresh air immediately. If not breathing., give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
  • 45. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 45 of 97 Hazardous Substance : 05M Trichloroethylene (Asphalt Yard) Manufacturer’s name : Various Storage Precautions : Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Store protected from light. Disposal Procedure : Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste Spillage Procedure : Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Remove all sources of ignition. Use a spark-proof tool. Do not let this chemical enter the environment. Description :- : Liquid - clear, colorless Fire Fighting Measures Extinguishing media : Use water spray, dry chemical, carbon dioxide, or chemical foam Recommendations : Personal Precautions : As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Health Effects Controls First aid measures & Emergencies Eye contact - Causes eye irritation. Contact with trichloroethylene causes pain but no permanent injury to the eyes. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin – Causes skin irritation. May be harmful if absorbed through the skin. Wear appropriate protective gloves to prevent skin exposure. Wear appropriate protective clothing to prevent skin exposure Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion – May cause irritation of the digestive tract. May be harmful if swallowed. May cause central nervous system effects. Do not ingest. Do not induce vomiting. Get medical aid. Inhalation – May cause respiratory tract irritation. May cause liver and kidney damage. May be harmful if inhaled. May cause central nervous system effects. The chief symptoms of TCE exposure were found to be abnormal fatigue, irritability, headache, gastric disturbances, and intolerance to alcohol Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
  • 46. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 46 of 97 Hazardous Substance : 05n Rockwool Thermal panels Manufacturer’s name : Saudi Rockwool Description :- Insulation material consisting of stone wool based minerals Storage Precautions : Keep materials in original packaging. Disposal Procedure : Spillage Procedure : Dispose empty packaging and surplus material to a place accepting builders waste. Fire Fighting Measures Extinguishing media : Is not flammable . Water, foam, carbon diodide or dry powder. Recommendations : Personal Precautions : Observe normal fire fighting procedures. Health Effects Controls First aid measures & Emergencies Eye contact - Can cause temporary self-fading effects e.g. itching. Normally not required. If irritation occurs flush eyes with potable cold water. Do not rub the eyes. Consult a doctor if irritation persists Skin – There can be physical effects on skin. Hand protection not normally required but gloves can be worn. If irritation occurs, wash off under cold running water prior to washing with mild soap. Do not rub or scratch. Ingestion – Do not ingest. If irritation occurs clean throat by rinsing with cold, potable water. Inhalation - There can be physical effects on the upper respiratory system No problem when used externally If respiratory irritation occurs, leave source of contamination and get fresh air. Consult a doctor if irritation persists
  • 47. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 47 of 97 Hazardous Substance : 05o Welding Rod / granulate for HDPE Manufacturer’s name : Various Storage Precautions : No smoking, open flames or sources of ignition in handling and storage area. Disposal Procedure : . Spillage Procedure : Contain spilled material if possible. Sweep up. Collect in suitable and properly labelled containers Description :- : Fire Fighting Measures Extinguishing media : Water fog or fine spray. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers. Foam. Recommendations : Keep people away. Isolate fire and deny unnecessary entry. Soak thoroughly with water to cool and prevent re-ignition. Personal Precautions : Wear positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing Health Effects Controls First aid measures & Emergencies Eye contact - Solid or dust may cause irritation or corneal injury due to mechanical action. Vapour may cause eye irritation experienced as mild discomfort and redness. Use safety glasses. Flush eyes thoroughly with water for several minutes. Remove contact lenses after the initial 1-2 minutes and continue flushing for several additional minutes. If effects occur, consult a physician, preferably an ophthalmologist. Skin – Prolonged contact is essentially non-irritating to skin. Mechanical injury only. Under normal processing conditions, material is heated to elevated temperatures; contact with the material may cause thermal burns. No precautions other than clean body-covering clothing should be needed If molten material comes in contact with the skin, do not apply ice but cool under ice water or running stream of water. DO NOT attempt to remove the material from skin. Removal could result in severe tissue damage. Seek medical attention immediately. Ingestion – Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small amounts. May cause choking if swallowed. Use good personal hygiene. Do not consume or store food in the work area. Wash hands before smoking or eating. If swallowed, seek medical attention. May cause gastrointestinal blockage. Do not give laxatives. Do not induce vomiting unless directed to do so by medical personnel Inhalation – No adverse effects are anticipated from single exposure to dust. Vapours/fumes released during thermal processing may cause respiratory irritation. Provide force ventilation in confined spaces Move person to fresh air; if effects occur, consult a physician
  • 48. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 48 of 97 Hazardous Substance : 05p Universal Powerwash Liquid Manufacturer’s name : Arrow Chemicals Ltd Storage Precautions : Store upright in container provided away from thoroughfares to prevent accidental damage. Disposal Procedure : .Dispose in a safe way. Spillage Procedure : Large spillages: absorbwith sand. Small spillage; hose away to foul sewer with plenty of water. Description :- : A caustic alkaline cleaner degreaser Fire Fighting Measures Extinguishing media : This material is not Flammable Recommendations : Personal Precautions : Health Effects Controls First aid measures & Emergencies Eye contact - Extreme irritation of eye and mucous membrane including burning and tearing. Use eye protection. Provide eye wash. Promptly wash eyeswith plenty of waterwhile lifting the eye lids. Get medical attention immediately . Continue to rince. Skin – Severe skin irration Protective gloves must be worn if there is a risk of contact or splash. Rinse the skin immediately with lots of water. Get medical attention immediately. Ingestion – Severe abdominal pain. Do not ingest. Do not induce vomiting. Get medial attention immediately. Rinse mouth thouroughly. Inhalation –
  • 49. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 49 of 97 Hazardous Substance : 05q Double Sided Butyl for Roof Cladding System Manufacturer’s name : Olin Etancheite Isolation Storage Precautions : Store in a cool, dry, well ventilated area Disposal Procedure : This material and its container must be disposed of in a safe way. Dispose of in a manner consistent with federal, state and local regulations Spillage Procedure : Collect the product with a saptule. Description :- : Fire Fighting Measures Extinguishing media : Water spray, carbon dioxide (CO2). Use water spray to cool fire exposed containers Recommendations : Personal Precautions : Wear self-contained breathing apparatus to prevent contact with thermal decomposition product (COx; NOx…) Health Effects Controls First aid measures & Emergencies Eye contact - No known toxic effect Wear appropriate protective eyeglasses when using product Wash eyes with plenty of water Skin – No known toxic effect Wear appropriate protective gloves when using product Wash skin with plenty of soap and water Ingestion – No known toxic effect Do not induce vomiting. Get medical aid Inhalation – No known toxic effect Not necessary
  • 50. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 50 of 97 Hazardous Substance : 05r Sealer’s Choice™ Gold for Terrazo Manufacturer’s name : AQUA MIX INC. Storage Precautions : Store in cool, dry location Disposal Procedure : Dispose materials in accordance with all applicable local, state and federal regulations. Spillage Procedure : Soak up with compatible absorbent material (sand, clay litter, diatomaceous earth). Description :- : Fire Fighting Measures Extinguishing media : Use water fog, carbon dioxide, dry chemical or foam Recommendations : None Personal Precautions : None Health Effects Controls First aid measures & Emergencies Eye contact - Contact may cause tearing or stinging Avoid eye contact. Wear safety glasses or goggles Immediately flush eyes with copious amounts of water. If irritation persists, seek medical attention Skin – Mild to moderate irritation such as drying, redness, or tightness of skin may occur when liquid is allowed to dry on skin. Wear rubber, latex or nitrile gloves. Use as necessary to prevent skin contact. Wash with soap and water. If irritation persists seek medical attention Ingestion – Ingestion may cause mild nausea, diarrhea, or some discomfort of the digestive tract. DO NOT INDUCE VOMITING! Drink 1 or 2 glasses of water. If spontaneous vomiting is inevitable, prevent aspiration by keeping the victim’s head below knees. Seek immediate medical attention. Inhalation – If misting or atomized spraying, wear a NIOSH approved high- efficiency respirator rated for mists, dusts, and particulates Not Applicable
  • 51. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 51 of 97 Hazardous Substance : 05s Thixothane Coating ( VJ Couplings) Manufacturer’s name : HMG PAINTS LTD. Storage Precautions : Keep receptacles tightly sealed. Ensure good ventilation/extraction at the workplace. Disposal Procedure : Must not be disposed together with household garbage. Do not allow product to reach sewage system Spillage Procedure : Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Description :- : Coating compound/ Surface coating/ paint Fire Fighting Measures Extinguishing media : CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam Recommendations : Personal Precautions : Mount respiratory protective device. Health Effects Controls First aid measures & Emergencies Eye contact - Contact may cause tearing or stinging Wear tightly sealed goggles. Avoid contact with the eyes and skin. Rinse opened eye for several minutes under running water. Skin – Irritating to skin Immediately remove all soiled and contaminated clothing Wear suitable protective clothing and gloves. Immediately wash with water and soap and rinse thoroughly. Ingestion – Ingestion may cause mild nausea, diarrhea, or some discomfort of the digestive tract. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. If symptoms persist consult doctor. Inhalation – Harmful by inhalation In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist.
  • 52. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 52 of 97 Hazardous Substance : 05t Thixothane Hardener ( VJ Couplings) Manufacturer’s name : HMG PAINTS LTD. Storage Precautions : Keep receptacles tightly sealed. Ensure good ventilation/extraction at the workplace. Disposal Procedure : Must not be disposed together with household garbage. Do not allow product to reach sewage system Spillage Procedure : Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Description :- : Coating compound/ Surface coating/ paint Fire Fighting Measures Extinguishing media : CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam Recommendations : Personal Precautions : Mount respiratory protective device. Health Effects Controls First aid measures & Emergencies Eye contact - No irritant effect. Wear tightly sealed goggles Hold the eye open and rinse with (preferably)luke warm water for a sufficiently long period of time (at least 10 minutes). Contact a doctor or opthalmologist. Rinse opened eye for several minutes under running water. Then consult a doctor. Skin – No irritant effect. Immediately remove all soiled and contaminated clothing Wear suitable protective clothing and gloves. Immediately wash with water and soap and rinse thoroughly. Ingestion – Ingestion may cause mild nausea, diarrhea, or some discomfort of the digestive tract. Keep away from foodstuffs, beverages and feed. Wash hands before breaks and at the end of work. DO NOT induce the patient to vomit, medical advice is required.
  • 53. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 53 of 97 Inhalation – Harmful by inhalation In the case of hypersensitivity of the respiratory tract (e.g. asthmatics and those who suffer from chronic bronchitis)it is inadvisable to work with the product. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. In case of unconsciousness place the patient stably in side position for transportation. If the aerosol or vapour in inhaled in high concentrations, take the person into fresh air, keep warm and let rest. If there is difficulty in breathing, medical advice is required. Supply fresh air and call for a doctor. In case of unconsciousness place patient stably in side position for transportation Hazardous Substance : 05u Thinner # 7 Juton
  • 54. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 54 of 97 Manufacturer’s name : Jotun Paints Co LLC, Storage Precautions : Keep container tightly closed. Keep away from heat, sparks and flame. No sparking tools should be used. Disposal Procedure : According to local regulations Spillage Procedure : Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations Description :- : Coatings: Solvent. Fire Fighting Measures Extinguishing media : Recommended: alcohol-resistant foam, CO2, powders, water spray. Not to be used : water jet Recommendations : Personal Precautions : Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist Health Effects Controls First aid measures & Emergencies Eye contact - If splashed in the eyes, the liquid may cause irritation and reversible damage. Use safety eyewear designed to protect against splash of liquids. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Skin – Irritating to skin. Personnel should wear antistatic clothing made of natural fibres or of high-temperature-resistant synthetic fibres Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognised skin cleanser. Do not use solvents or thinners. Ingestion – Eating, drinking and smoking should be prohibited in area where this material is handled, stored and processed. If swallowed, seek medical advice immediately and show the container or label. Keep person warm and at rest. Do not induce vomiting. Inhalation – Harmful by inhalation If workers are exposed to concentrations above the exposure limit, they must use appropriate, certified respirators. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious, place in recovery position and seek medical advice. Hazardous Substance : 05v Thermoplastic Road Paint Manufacturer’s name : Various
  • 55. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 55 of 97 Storage Precautions : Avoid heat, sparks open flames and other ignition sources. Disposal Procedure : As per local regulations. Spillage Procedure : Attempt to reclaim the free material. Description :- : Liquid Fire Fighting Measures Extinguishing media : Dry Chemical. Carbon dioxide. Recommendations : Personal Precautions : Wear suitable protective equipment. Health Effects Controls First aid measures & Emergencies Eye contact Powder state – may cause irritation Molten state – causes serious injury to eyes due to its extreme temperature. Face mask or goggles to be worn by operatives working with material when it is in molten state. Only essential personnel allowed within vicinity of the material when it is in a molten state. First aider to be aware of the precautions and measures related to this material. Emergency contact details for site clinic to be available for first aider and other operatives on site. Clean water to be available for carrying out first aid measures. Powder state – flush thoroughly with water immediately. If irritation persists, consult site doctor. Molten state – flush with large quantity of water immediately. Do not attempt to remove any solid thermoplastic material. Seek medical attention at site clinic immediately. Skin Powder state – may cause irritation Molten state – may cause burns due to high temperature Potentially exposed skin such as hands should be covered using gloves when in the vicinity of the molten material. Only essential personnel allowed within vicinity of the material when it is in a molten state. First aider to be aware of the precautions and measures related to this material. Emergency contact details for site clinic to be available for first aider and other operatives on site. Clean water to be available for carrying out first aid measures. Powder state – wash with soap and water Molten state – immerse or flush the affected part with copious amounts of sterile water to dissipate the heat and limit injury. No attempt should be made to remove thermoplastic or any clothing that may be fused to damaged area. Seek medical attention showing the sheet. Ingestion Powder state – low toxicity, but may be harmful if swallowed Molten state – harmful and must avoid swallowing Personnel working with material to be made aware of the hazard of swallowing the substance, especially when the material is molten First aider to be aware of the precautions and measures related to this material. Emergency contact details for site clinic to be available for first aider and other operatives on site. Powder state – go and see the site doctor in the NDA Molten state – seek medical attention immediately
  • 56. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 56 of 97 Inhalation Powder state – negligible hazard, over inhalation will cause some irritation to throat. Molten state – negligible hazard. However, over inhalation in a confined space will cause choking. Material is not going to be used in a confined space for road marking, but personnel should be made aware of the hazards of being in a confined space with the substance. First aider to be aware of the precautions and measures related to this material. Powder state – first aid not normally required Molten state – not going to be used in a confined space Hazardous Substance : 05 W HEMPADUR MASTIC 45889 Base Manufacturer’s name : HEMPEL A/S, Denmark Storage Precautions : Always keep in containers made from the same material as the original one.
  • 57. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 57 of 97 Disposal Procedure : Disposal according to local regulations Spillage Procedure : Contain and collect spillage with noncombustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal Description :- : Epoxy primer (base for multi-component product) Fire Fighting Measures Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: waterjet Recommendations : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire Personal Precautions : Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Health Effects Controls First aid measures & Emergencies Eye contact - Irritating to eyes. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Seek immediate medical attention. Skin – Irritating to skin. May cause sensitization by skin contact Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Ingestion – Irritating to mouth, throat and stomach. Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat. Inhalation – Exposure to decomposition products may cause a health hazard. Serious effects may be delayed following exposure. If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. Remove to fresh air. Keep person warm and at rest. If unconscious, place in recovery position and seek medical advice. Hazardous Substance : 05 x HEMPEL'S CURING AGENT 95881 Manufacturer’s name : HEMPEL A/S, Denmark
  • 58. COSHH ASSESSMENTS Control of Substances Hazardous to Health Page 58 of 97 Storage Precautions : Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and ignition sources. Disposal Procedure : In accordance with local egulations. Spillage Procedure : Stop leak if without risk. Move containers from spill area. Approach release from upwind Description :- : Curing agent Fire Fighting Measures Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray. Not to be used: waterjet Recommendations : Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. Personal Precautions : Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents. Health Effects Controls First aid measures & Emergencies Eye contact - May cause eye irritation Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms persist, seek medical attention. Skin – Irritating to skin. May cause sensitization by skin contact. Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use recognized skin cleanser. Do NOT use solvents or thinners. Ingestion – Irritating to mouth, throat and stomach. Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking, using lavatory, and at the end of day. If swallowed, seek medical advice immediately and show this container or label. Keep person warm and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so that vomit will not re-enter the mouth and throat. Inhalation – Harmful by inhalation If working areas have insufficient ventilation: When the product is applied by means that will not generate an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A, when grinding use particle filter of type P. Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by mouth. If unconscious, place in recovery position and get medical attention immediately.