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pourbaix diagram of IRON

Engineering

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Crown ethers NOMENCLATURE GENERAL SYNTHESIS OF CROWN ETHER AZA CROWN CRYPTAND APPLICATIONS 1. SYNTHETIC APPLICTION Esterification Saponification Anhydride formation Potassium permanganate oxidation Aromatic substitution reactions Elimination reactions Displacement reaction Generation of carbenes Superoxide anion Alkylations – 1. o-alkylations 2. c-alkylations 3. n-alkylations 2. ANALYTICAL APPLICATION Determination of gold in geological samples Super critical fluid extraction of trace metal from solid and liquid materials Application of ionic liquids in analytical chemistry Oxidation and determination of aldehydes Crown ethers are used in the laboratory as phase transfer catalyst OTHER APPLICATION It is used in photocynation Resolution of racemic mixture Benzoin condensation Hetrocyclisation Synthesis of furanones Acetylation of secondary amines in presence of primary amine

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Organocopper compounds - Gilman reagent

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