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BINITA RANI
ASSOCIATE PROFESSOR (DAIRY CHEMISTRY)
FACULTY OF DAIRY TECHNOLOGY
S.G.I.D.T., BVC CAMPUS,
P.O.- BVC, DIST.-PATNA-800014
FOOD CHEMISTRY
DTC-321 Credit hours- 3(2+1)
Minerals in Foods
 Term mineral  elements other than C, H, O, and N  present
in foods.
 No universally accepted definition of “mineral”
 Four non mineral elements (C, H, O, and N)  present in organic
molecules and water  constitute 99%  total number of atoms
in living systems.
 Minerals  remain as ash  combustion of plant and animal
tissues.
 Present  relatively low conc in foods  key functional roles .
 Mineral supply depends  intake  bioavailability  related
to composition of food.
 Food constituents, e. g., amino acids, proteins, peptides, sugars,
polysaccharides, phytin, lignin, and organic acids  bind
minerals  enhance / inhibit  absorption.
 affect  texture of food.
 contribute  food flavor.
 activate / inhibit  enzyme-catalyzed and other reactions
Three classes:
MAIN ELEMENTS:
human beings in amounts > 50 mg/day
e.g., Ca, Cl, K, Mg, Na, P, S .
TRACE ELEMENTS:
concentrations < 50 mg/day
e.g.,Fe, F, Co, Cu, Cr, I, Zn, Se, Mn, Mo, Ni.
ULTRA-TRACE ELEMENTS:
vital elements
e.g.,Al, As, B, Ba, Bi, Br, Cs, Cd, Ge, Hg, Li, Pb, Rb, Si, Sn, Sb, Sr,
Ti, W.
NUTRITIONALAND FUNCTIONAL ROLES
Minerals have important nutritional and physiological functions .
MAIN ELEMENTS
Sodium:
 Sodium absorption is rapid.
 activates  some enzymes, such as amylase.
 excessive intake  hypertension.
 low intake of sodium  a non-salty diet or by using diet salt
(common salt substitutes).
Potassium:
 regulates osmotic pressure within the cell.
 involved in cell membrane transport.
 deficiency  potassium-deficient foods, e.g., white
bread, fat or oil.
 Potatoes and molasses  sources.
Magnesium:
 constituent and activator  many enzymes.
 associated  conversion of energy-rich phosphate
compounds
 Stabilizer  plasma membranes, intracellular
membranes, and nucleic acids.
Calcium:
 skeleton and in some body tissues.
 controls essential processes  activity of brain cells and
cell growth, blood clotting, muscle contraction
(heartbeat).
 source  milk and milk products, fruit and vegetables,
cereal products, meat, fish and eggs.
Chloride:
 serves as counter ion for sodium in extracellular fluid and
 for hydrogen ions in gastric juice.
 absorption is as rapid as its excretion  urine.
Phosphorus:
 essential nutrient.
 in the form of phosphate, free or bound as an ester or present as
an anhydride, plays imp role  metabolism
TRACE ELEMENTS
Iron:
 essential ingredient of daily diet
 present  hemoglobin (blood) and myoglobin (muscle tissue)
pigments.
 present  enzymes (peroxidase, catalase, hydroxylases and
flavine enzymes)
 Two food processing problems  iron fortification :
1. increased probability  oxidation
2. wheat flour  decreased baking quality.
 undesirable element  food processing
 catalyzes oxidation of fat / oil,
 increases turbidity of wine,
 supports growth of iron-requiring bacteria.
Copper:
 component of oxidoreductase enzymes (amine oxidase,
cytochrome oxidase, superoxide dismutase, tyrosinase,
uricase ).
 less desirable than iron  food processing and storage 
catalyzes many unwanted reactions.
 Cu2+-Ions are taste bearing.
 Threshold value 2.4 – 3.8mg/l was determined with
aqueous solutions of CuSO4 or CuCl2.
Zinc:
 component  enzymes (e.g., alcohol dehydrogenase, carbonic
anhydrase, carboxypeptidases A and B, glutamate dehydrogenase,
lactate dehydrogenase and malate dehydrogenase,,).
 Other enzymes, e.g., alkaline phosphatase, dipeptidases, enolase
and lecithinase are activated by zinc.
 deficiency in animals  serious disorders.
 high zinc intake  toxic.
Manganese:
 metal activator for pyruvate carboxylase .
 activates various enzymes  alkaline phosphatase,
amino peptidase, arginase, lecithinase or enolase.
 even in higher amounts  relatively nontoxic.
Cobalt:
 Essential element  Vitamin B12 contains cobalt as its
central atom.
 Its requirement  met by normal nutrition.
Chromium:
 important  utilization of glucose.
 activates  enzyme phosphoglucomutase and increases 
activity of insulin
 deficiency  a decrease in glucose tolerance.
Selenium:
 vary greatly  varying content of selenium in the soil 
depending on the region.
 antioxidant and can enhance tocopherol activity.
 Enzyme glutathione peroxidase contains selenium.
Molybdenum:
 component of aldehyde oxidase and xanthine oxidase.
 bacterial nitrate reductase involved in meat curing and
pickling processes contains molybdenum
Nickel:
 activator of enzymes, e.g., alkaline phosphatase and
oxaloacetate decarboxylase, which can also be
activated by other divalent metal ions.
 enhances insulin activity.
Fluorine:
 Addition  drinking water 0.5–1.5 ppm fluorine in the form of
NaF  inhibits tooth decay.
 beneficial effect  retarding solubilization of tooth enamel and
inhibiting the enzymes involved  development of caries.
 Toxic effects  at a level of 2 ppm.
 beneficial effects of fluoridating drinking water  disputed by
some and  controversial topic of mineral nutrition.
Iodine:
 absorption  as iodide .
 utilized in thyroid gland  biosynthesis of  hormone thyroxine
(tetraiodothyronine) and its less iodized form, triiodothyronine.
 deficiency  enlargement of the thyroid gland (iodine-deficiency
induced goiter).
 most food  little iodine.
 Good sources  milk, eggs and seafood.
 Drinking water  little iodine supply.
 To avoid deficiency diseases  iodization of common salt is done
in which potassium iodate, with 100 μg iodine added to 1–10 g
NaCl..
 Higher amounts of iodine  toxic.
ULTRA-TRACE ELEMENTS
Tin:
 natural level of tin in food  very low.
 can be increased  foods canned in tinplate cans.
 Very acidic foods  dissolve substantial amounts of tin.
 concentration of tin in pineapple and grapefruit juice transported
in poorly tin plated cans  2 g/l.
 tin content of foods in tinplate cans  generally below 50mg/kg
and
 should not exceed 250 mg/kg.
Aluminum:
 resorbed in only negligible amounts by gastrointestinal
tract.
 largest portion is eliminated in feces.
 not secreted in milk.
Boron:
 essential nutrient.
 promotes bone formation by interaction with calcium,
magnesium and vitamin D.
 involved in hydroxylation of steroids, e.g., in the synthesis
testosterone.
 sources include wine and water.
Silicon:
 rapidly absorbed as soluble silicic acid.
 source is cereal products.
 promotes growth and thus has a biological role.
 toxicity of silicic acid is apparent only at
concentrations ≥ 100 mg/kg.
Arsenic:
 main source is fish.
 metabolic role is not yet understood.
 appears to be involved in the metabolism of methionine.
 Choline can be replaced by arseno choline in some of its
functions.
MINERAL CONTENT OF EGGS , CEREALS AND CEREAL PRODUCTS, FRUITS AND VEGETABLES
NUTRITIONAL AND FUNCTIONAL ROLE OF MINERALS AND MINERAL SALTS IN FOODS

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MINERALS-IN-FOODS.pptx

  • 1. BINITA RANI ASSOCIATE PROFESSOR (DAIRY CHEMISTRY) FACULTY OF DAIRY TECHNOLOGY S.G.I.D.T., BVC CAMPUS, P.O.- BVC, DIST.-PATNA-800014 FOOD CHEMISTRY DTC-321 Credit hours- 3(2+1) Minerals in Foods
  • 2.  Term mineral  elements other than C, H, O, and N  present in foods.  No universally accepted definition of “mineral”  Four non mineral elements (C, H, O, and N)  present in organic molecules and water  constitute 99%  total number of atoms in living systems.  Minerals  remain as ash  combustion of plant and animal tissues.  Present  relatively low conc in foods  key functional roles .
  • 3.  Mineral supply depends  intake  bioavailability  related to composition of food.  Food constituents, e. g., amino acids, proteins, peptides, sugars, polysaccharides, phytin, lignin, and organic acids  bind minerals  enhance / inhibit  absorption.  affect  texture of food.  contribute  food flavor.  activate / inhibit  enzyme-catalyzed and other reactions
  • 4. Three classes: MAIN ELEMENTS: human beings in amounts > 50 mg/day e.g., Ca, Cl, K, Mg, Na, P, S . TRACE ELEMENTS: concentrations < 50 mg/day e.g.,Fe, F, Co, Cu, Cr, I, Zn, Se, Mn, Mo, Ni. ULTRA-TRACE ELEMENTS: vital elements e.g.,Al, As, B, Ba, Bi, Br, Cs, Cd, Ge, Hg, Li, Pb, Rb, Si, Sn, Sb, Sr, Ti, W.
  • 5. NUTRITIONALAND FUNCTIONAL ROLES Minerals have important nutritional and physiological functions . MAIN ELEMENTS Sodium:  Sodium absorption is rapid.  activates  some enzymes, such as amylase.  excessive intake  hypertension.  low intake of sodium  a non-salty diet or by using diet salt (common salt substitutes).
  • 6. Potassium:  regulates osmotic pressure within the cell.  involved in cell membrane transport.  deficiency  potassium-deficient foods, e.g., white bread, fat or oil.  Potatoes and molasses  sources.
  • 7. Magnesium:  constituent and activator  many enzymes.  associated  conversion of energy-rich phosphate compounds  Stabilizer  plasma membranes, intracellular membranes, and nucleic acids.
  • 8. Calcium:  skeleton and in some body tissues.  controls essential processes  activity of brain cells and cell growth, blood clotting, muscle contraction (heartbeat).  source  milk and milk products, fruit and vegetables, cereal products, meat, fish and eggs.
  • 9. Chloride:  serves as counter ion for sodium in extracellular fluid and  for hydrogen ions in gastric juice.  absorption is as rapid as its excretion  urine. Phosphorus:  essential nutrient.  in the form of phosphate, free or bound as an ester or present as an anhydride, plays imp role  metabolism
  • 10. TRACE ELEMENTS Iron:  essential ingredient of daily diet  present  hemoglobin (blood) and myoglobin (muscle tissue) pigments.  present  enzymes (peroxidase, catalase, hydroxylases and flavine enzymes)  Two food processing problems  iron fortification : 1. increased probability  oxidation 2. wheat flour  decreased baking quality.  undesirable element  food processing  catalyzes oxidation of fat / oil,  increases turbidity of wine,  supports growth of iron-requiring bacteria.
  • 11. Copper:  component of oxidoreductase enzymes (amine oxidase, cytochrome oxidase, superoxide dismutase, tyrosinase, uricase ).  less desirable than iron  food processing and storage  catalyzes many unwanted reactions.  Cu2+-Ions are taste bearing.  Threshold value 2.4 – 3.8mg/l was determined with aqueous solutions of CuSO4 or CuCl2.
  • 12. Zinc:  component  enzymes (e.g., alcohol dehydrogenase, carbonic anhydrase, carboxypeptidases A and B, glutamate dehydrogenase, lactate dehydrogenase and malate dehydrogenase,,).  Other enzymes, e.g., alkaline phosphatase, dipeptidases, enolase and lecithinase are activated by zinc.  deficiency in animals  serious disorders.  high zinc intake  toxic.
  • 13. Manganese:  metal activator for pyruvate carboxylase .  activates various enzymes  alkaline phosphatase, amino peptidase, arginase, lecithinase or enolase.  even in higher amounts  relatively nontoxic.
  • 14. Cobalt:  Essential element  Vitamin B12 contains cobalt as its central atom.  Its requirement  met by normal nutrition.
  • 15. Chromium:  important  utilization of glucose.  activates  enzyme phosphoglucomutase and increases  activity of insulin  deficiency  a decrease in glucose tolerance.
  • 16. Selenium:  vary greatly  varying content of selenium in the soil  depending on the region.  antioxidant and can enhance tocopherol activity.  Enzyme glutathione peroxidase contains selenium.
  • 17. Molybdenum:  component of aldehyde oxidase and xanthine oxidase.  bacterial nitrate reductase involved in meat curing and pickling processes contains molybdenum
  • 18. Nickel:  activator of enzymes, e.g., alkaline phosphatase and oxaloacetate decarboxylase, which can also be activated by other divalent metal ions.  enhances insulin activity.
  • 19. Fluorine:  Addition  drinking water 0.5–1.5 ppm fluorine in the form of NaF  inhibits tooth decay.  beneficial effect  retarding solubilization of tooth enamel and inhibiting the enzymes involved  development of caries.  Toxic effects  at a level of 2 ppm.  beneficial effects of fluoridating drinking water  disputed by some and  controversial topic of mineral nutrition.
  • 20. Iodine:  absorption  as iodide .  utilized in thyroid gland  biosynthesis of  hormone thyroxine (tetraiodothyronine) and its less iodized form, triiodothyronine.  deficiency  enlargement of the thyroid gland (iodine-deficiency induced goiter).  most food  little iodine.  Good sources  milk, eggs and seafood.  Drinking water  little iodine supply.  To avoid deficiency diseases  iodization of common salt is done in which potassium iodate, with 100 μg iodine added to 1–10 g NaCl..  Higher amounts of iodine  toxic.
  • 21. ULTRA-TRACE ELEMENTS Tin:  natural level of tin in food  very low.  can be increased  foods canned in tinplate cans.  Very acidic foods  dissolve substantial amounts of tin.  concentration of tin in pineapple and grapefruit juice transported in poorly tin plated cans  2 g/l.  tin content of foods in tinplate cans  generally below 50mg/kg and  should not exceed 250 mg/kg.
  • 22. Aluminum:  resorbed in only negligible amounts by gastrointestinal tract.  largest portion is eliminated in feces.  not secreted in milk.
  • 23. Boron:  essential nutrient.  promotes bone formation by interaction with calcium, magnesium and vitamin D.  involved in hydroxylation of steroids, e.g., in the synthesis testosterone.  sources include wine and water.
  • 24. Silicon:  rapidly absorbed as soluble silicic acid.  source is cereal products.  promotes growth and thus has a biological role.  toxicity of silicic acid is apparent only at concentrations ≥ 100 mg/kg.
  • 25. Arsenic:  main source is fish.  metabolic role is not yet understood.  appears to be involved in the metabolism of methionine.  Choline can be replaced by arseno choline in some of its functions.
  • 26. MINERAL CONTENT OF EGGS , CEREALS AND CEREAL PRODUCTS, FRUITS AND VEGETABLES
  • 27. NUTRITIONAL AND FUNCTIONAL ROLE OF MINERALS AND MINERAL SALTS IN FOODS