SlideShare a Scribd company logo
Vortex Polarization Instabilities
     in PbTiO3 Nanowires

       G. Pilania and R. Ramprasad

    Chemical, Materials and Biomolecular Engineering
              Institute of Materials Science
          University of Connecticut, Storrs, CT
Ferroelectricity in Nanostructures
   Critical Size & Polarization States
    Lateral Polarization in BaTiO3 nanowires
          Spanier et al, Nano Lett. 6, 735 (2006)




                                         0.8 nm
Ferroelectric Nanostructures
         Vortex (Non-rectilinear) Polarization
                 Computations indicate the presence of non-rectilinear
                      polarization in ferroelectric nanostructures

Prosendeev & Bellaiche                                               Aguado-Puente et al
     (PRB 2007)                                                         (PRL, 2008)




              PFM results indicate possible presence of non-rectilinear
                             polarization in PZT nanodots


   Rodriguez et al
 (Nanoletters, 2009)
BaTiO3 Nanowires – Our DFT Study



Axial polarization                                                 Vortex polarization
instability above                                                  instability above
1.2 nm                                                             1.6 nm

                paraelectric   ferroelectric




                                               Also see: Geneste et. al, APL 88, 112906 (2006);
                                                         Shimada et al, PRB 79, 024102 (2009)
PbTiO3 Nanowires – Our DFT Study
                         Vortex polarization at
                     equilibrium in TiO2-terminated
                       nanowires above 1.6 nm
Ground State Polarization & Atomic Configurations
          4x4 TiO2-terminated PbTiO3 Nanowire
PbTiO3 Nanowires vs. Terminations
Strain-induced phase transition: vortex  axial polarization




               Four possible switchable polarization states
     Vortex (clockwise/counter-clockwise), Axial (positive/negative)
Vortex Instability vs. “Soft-mode”

Atomic displacement vector                          Zone-center phonon
 with respect to reference                       eigenvectors of reference
     paraelectric state                              paraelectric state




                     “Vortex” modes: imaginary
Summary
PbTiO3 nanowires display switchable rectilinear (axial) and
    non-rectilinear (vortex) polarization configurations

More Related Content

What's hot

Mottphysics 2talk
Mottphysics   2talkMottphysics   2talk
Mottphysics 2talk
ABDERRAHMANE REGGAD
 
photoacoustics electroptical cell dr1
photoacoustics electroptical cell dr1photoacoustics electroptical cell dr1
photoacoustics electroptical cell dr1Vicente Torres
 
Burakh 040816
Burakh 040816Burakh 040816
Burakh 040816
Burak Himmetoglu
 
Thesis defense
Thesis defenseThesis defense
Thesis defense
Sidney Burks, Ph.D
 
Young Scientist Award in JPS (invited talk)
Young Scientist Award in JPS (invited talk)Young Scientist Award in JPS (invited talk)
Young Scientist Award in JPS (invited talk)
Alto Osada
 
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsadaProspects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
Alto Osada
 
Invisible excitations and the story of luminescence in hexagonal Boron Nitride
Invisible excitations and the story of luminescence in hexagonal Boron NitrideInvisible excitations and the story of luminescence in hexagonal Boron Nitride
Invisible excitations and the story of luminescence in hexagonal Boron Nitride
Claudio Attaccalite
 
Nonlinear optics
Nonlinear opticsNonlinear optics
Nonlinear optics
Gandhimathi Muthuselvam
 
Photoelectron Spectroscopy for Functional Oxides
Photoelectron Spectroscopy for Functional OxidesPhotoelectron Spectroscopy for Functional Oxides
Photoelectron Spectroscopy for Functional Oxides
nirupam12
 
Theory of phonon-assisted luminescence: application to h-BN
Theory of phonon-assisted luminescence: application to h-BNTheory of phonon-assisted luminescence: application to h-BN
Theory of phonon-assisted luminescence: application to h-BN
Claudio Attaccalite
 
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal MicrobalanceElectrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
Saurav Ch. Sarma
 
Phonon-assisted luminescence in hexagonal boron nitride
Phonon-assisted luminescence in hexagonal boron nitridePhonon-assisted luminescence in hexagonal boron nitride
Phonon-assisted luminescence in hexagonal boron nitride
Claudio Attaccalite
 
Impact of electronic correlation on the electron-phonon coupling
Impact of electronic correlation on the electron-phonon couplingImpact of electronic correlation on the electron-phonon coupling
Impact of electronic correlation on the electron-phonon coupling
Claudio Attaccalite
 
Entangled states of trapped atomic ions
Entangled states of trapped atomic ionsEntangled states of trapped atomic ions
Entangled states of trapped atomic ions
Gabriel O'Brien
 
Laser dental hard tissue interaction with possible applications (2)
Laser dental hard tissue interaction with possible applications (2)Laser dental hard tissue interaction with possible applications (2)
Laser dental hard tissue interaction with possible applications (2)Rana Tariq
 

What's hot (20)

Mottphysics 2talk
Mottphysics   2talkMottphysics   2talk
Mottphysics 2talk
 
photoacoustics electroptical cell dr1
photoacoustics electroptical cell dr1photoacoustics electroptical cell dr1
photoacoustics electroptical cell dr1
 
Burakh 040816
Burakh 040816Burakh 040816
Burakh 040816
 
Thesis defense
Thesis defenseThesis defense
Thesis defense
 
Terahertz vcsel
Terahertz vcselTerahertz vcsel
Terahertz vcsel
 
Young Scientist Award in JPS (invited talk)
Young Scientist Award in JPS (invited talk)Young Scientist Award in JPS (invited talk)
Young Scientist Award in JPS (invited talk)
 
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsadaProspects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
Prospects for Electron-Ion-Circuit Hybrid Quantum Systems_AltoOsada
 
Invisible excitations and the story of luminescence in hexagonal Boron Nitride
Invisible excitations and the story of luminescence in hexagonal Boron NitrideInvisible excitations and the story of luminescence in hexagonal Boron Nitride
Invisible excitations and the story of luminescence in hexagonal Boron Nitride
 
Nonlinear optics
Nonlinear opticsNonlinear optics
Nonlinear optics
 
Photoelectron Spectroscopy for Functional Oxides
Photoelectron Spectroscopy for Functional OxidesPhotoelectron Spectroscopy for Functional Oxides
Photoelectron Spectroscopy for Functional Oxides
 
Theory of phonon-assisted luminescence: application to h-BN
Theory of phonon-assisted luminescence: application to h-BNTheory of phonon-assisted luminescence: application to h-BN
Theory of phonon-assisted luminescence: application to h-BN
 
Electrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal MicrobalanceElectrochemical Quartz Crystal Microbalance
Electrochemical Quartz Crystal Microbalance
 
Ue-Li Pen - 21cm Cosmology
Ue-Li Pen - 21cm CosmologyUe-Li Pen - 21cm Cosmology
Ue-Li Pen - 21cm Cosmology
 
OSAPS Poster
OSAPS PosterOSAPS Poster
OSAPS Poster
 
Phonon-assisted luminescence in hexagonal boron nitride
Phonon-assisted luminescence in hexagonal boron nitridePhonon-assisted luminescence in hexagonal boron nitride
Phonon-assisted luminescence in hexagonal boron nitride
 
Impact of electronic correlation on the electron-phonon coupling
Impact of electronic correlation on the electron-phonon couplingImpact of electronic correlation on the electron-phonon coupling
Impact of electronic correlation on the electron-phonon coupling
 
Poster-EMRS-2014_finalo
Poster-EMRS-2014_finaloPoster-EMRS-2014_finalo
Poster-EMRS-2014_finalo
 
Entangled states of trapped atomic ions
Entangled states of trapped atomic ionsEntangled states of trapped atomic ions
Entangled states of trapped atomic ions
 
Poster-EMRS-2014_finalo
Poster-EMRS-2014_finaloPoster-EMRS-2014_finalo
Poster-EMRS-2014_finalo
 
Laser dental hard tissue interaction with possible applications (2)
Laser dental hard tissue interaction with possible applications (2)Laser dental hard tissue interaction with possible applications (2)
Laser dental hard tissue interaction with possible applications (2)
 

Viewers also liked

cBodanov emrs2012
cBodanov emrs2012cBodanov emrs2012
cBodanov emrs2012
bpnv38
 
Electric properties
Electric propertiesElectric properties
Electric properties
Joel Cornelio
 
The End of Growth- Preparing for a new normal
The End of Growth- Preparing for a new normalThe End of Growth- Preparing for a new normal
The End of Growth- Preparing for a new normal
Post Carbon Institute
 
Materials and their properties presentation
Materials and their properties presentationMaterials and their properties presentation
Materials and their properties presentationiesrpe
 
The 2015 Millennial Majority Workforce: Study Results
The 2015 Millennial Majority Workforce: Study ResultsThe 2015 Millennial Majority Workforce: Study Results
The 2015 Millennial Majority Workforce: Study Results
Elance-oDesk
 

Viewers also liked (6)

Global-13
Global-13Global-13
Global-13
 
cBodanov emrs2012
cBodanov emrs2012cBodanov emrs2012
cBodanov emrs2012
 
Electric properties
Electric propertiesElectric properties
Electric properties
 
The End of Growth- Preparing for a new normal
The End of Growth- Preparing for a new normalThe End of Growth- Preparing for a new normal
The End of Growth- Preparing for a new normal
 
Materials and their properties presentation
Materials and their properties presentationMaterials and their properties presentation
Materials and their properties presentation
 
The 2015 Millennial Majority Workforce: Study Results
The 2015 Millennial Majority Workforce: Study ResultsThe 2015 Millennial Majority Workforce: Study Results
The 2015 Millennial Majority Workforce: Study Results
 

Similar to Vortex Polarization Instabilities in PbTiO3 Nanowires

Neutron Refractometry - B Kreimer
Neutron Refractometry - B KreimerNeutron Refractometry - B Kreimer
Neutron Refractometry - B Kreimer
nirupam12
 
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
ABDERRAHMANE REGGAD
 
Seminor ansto-0730
Seminor ansto-0730Seminor ansto-0730
Seminor ansto-0730
Shinichiro Yano
 
Electronic structure of strongly correlated materials Part III V.Anisimov
 Electronic structure of strongly correlated materials Part III V.Anisimov Electronic structure of strongly correlated materials Part III V.Anisimov
Electronic structure of strongly correlated materials Part III V.Anisimov
ABDERRAHMANE REGGAD
 
Magnetic anisotropy in (III,Mn)V
Magnetic anisotropy in (III,Mn)VMagnetic anisotropy in (III,Mn)V
Magnetic anisotropy in (III,Mn)V
dziatkowski
 
Ferroelectric nanostructures and their processing issues
Ferroelectric nanostructures and their processing issuesFerroelectric nanostructures and their processing issues
Ferroelectric nanostructures and their processing issues♪♫•*¨ *•.¸¸
 
multiferroic materials.barium tatinate cobaltferrite
multiferroic materials.barium tatinate cobaltferritemultiferroic materials.barium tatinate cobaltferrite
multiferroic materials.barium tatinate cobaltferrite
NaSir566164
 
Properties of Nano-materials
Properties of Nano-materialsProperties of Nano-materials
Properties of Nano-materials
Partha P. Mishra
 
SpinFET
SpinFETSpinFET
SpinFET
IIT Bombay
 
Dierk Raabe D P Steel R X& G G 2010 Sheffield
Dierk  Raabe  D P  Steel  R X& G G 2010  SheffieldDierk  Raabe  D P  Steel  R X& G G 2010  Sheffield
Dierk Raabe D P Steel R X& G G 2010 Sheffield
Dierk Raabe
 
Magnetism and magnetic interactions in graphene and graphite
Magnetism and magnetic interactions in graphene and graphiteMagnetism and magnetic interactions in graphene and graphite
Magnetism and magnetic interactions in graphene and graphite
Oleg Yazyev
 
Photonic crystal and their application in details
Photonic crystal and their application in detailsPhotonic crystal and their application in details
Photonic crystal and their application in details
ANKITMAHTO11
 
Some of the application of photonic crystal by no means a complete overview
Some of the application of photonic crystal by no means a complete overviewSome of the application of photonic crystal by no means a complete overview
Some of the application of photonic crystal by no means a complete overview
ANKITMAHTO11
 
Sigma xishowcase
Sigma xishowcaseSigma xishowcase
Sigma xishowcasejyoung11509
 
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
Alexander Decker
 
Physical Models of LENR Processes Using the BSM-SG Atomic Models
Physical Models of LENR Processes Using the BSM-SG Atomic ModelsPhysical Models of LENR Processes Using the BSM-SG Atomic Models
Physical Models of LENR Processes Using the BSM-SG Atomic Models
Stoyan Sarg Sargoytchev
 
First Principles Calculation of Charge and Spin Transport in Tin-Monolayer
First Principles Calculation of Charge and Spin Transport in Tin-MonolayerFirst Principles Calculation of Charge and Spin Transport in Tin-Monolayer
First Principles Calculation of Charge and Spin Transport in Tin-Monolayer
Yuma Nakamura
 

Similar to Vortex Polarization Instabilities in PbTiO3 Nanowires (20)

Neutron Refractometry - B Kreimer
Neutron Refractometry - B KreimerNeutron Refractometry - B Kreimer
Neutron Refractometry - B Kreimer
 
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
Density Functional and Dynamical Mean-Field Theory (DFT+DMFT) method and its ...
 
7633426.ppt
7633426.ppt7633426.ppt
7633426.ppt
 
Seminor ansto-0730
Seminor ansto-0730Seminor ansto-0730
Seminor ansto-0730
 
Electronic structure of strongly correlated materials Part III V.Anisimov
 Electronic structure of strongly correlated materials Part III V.Anisimov Electronic structure of strongly correlated materials Part III V.Anisimov
Electronic structure of strongly correlated materials Part III V.Anisimov
 
Magnetic anisotropy in (III,Mn)V
Magnetic anisotropy in (III,Mn)VMagnetic anisotropy in (III,Mn)V
Magnetic anisotropy in (III,Mn)V
 
Ferroelectric nanostructures and their processing issues
Ferroelectric nanostructures and their processing issuesFerroelectric nanostructures and their processing issues
Ferroelectric nanostructures and their processing issues
 
multiferroic materials.barium tatinate cobaltferrite
multiferroic materials.barium tatinate cobaltferritemultiferroic materials.barium tatinate cobaltferrite
multiferroic materials.barium tatinate cobaltferrite
 
Properties of Nano-materials
Properties of Nano-materialsProperties of Nano-materials
Properties of Nano-materials
 
SpinFET
SpinFETSpinFET
SpinFET
 
Dierk Raabe D P Steel R X& G G 2010 Sheffield
Dierk  Raabe  D P  Steel  R X& G G 2010  SheffieldDierk  Raabe  D P  Steel  R X& G G 2010  Sheffield
Dierk Raabe D P Steel R X& G G 2010 Sheffield
 
Ismanam 2011 fernandez seivane
Ismanam 2011 fernandez seivaneIsmanam 2011 fernandez seivane
Ismanam 2011 fernandez seivane
 
Magnetism and magnetic interactions in graphene and graphite
Magnetism and magnetic interactions in graphene and graphiteMagnetism and magnetic interactions in graphene and graphite
Magnetism and magnetic interactions in graphene and graphite
 
Photonic crystal and their application in details
Photonic crystal and their application in detailsPhotonic crystal and their application in details
Photonic crystal and their application in details
 
Some of the application of photonic crystal by no means a complete overview
Some of the application of photonic crystal by no means a complete overviewSome of the application of photonic crystal by no means a complete overview
Some of the application of photonic crystal by no means a complete overview
 
Sigma xishowcase
Sigma xishowcaseSigma xishowcase
Sigma xishowcase
 
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
Ferroelectric domains,tensor pairs and magnetoelectric polarisability propert...
 
Physical Models of LENR Processes Using the BSM-SG Atomic Models
Physical Models of LENR Processes Using the BSM-SG Atomic ModelsPhysical Models of LENR Processes Using the BSM-SG Atomic Models
Physical Models of LENR Processes Using the BSM-SG Atomic Models
 
First Principles Calculation of Charge and Spin Transport in Tin-Monolayer
First Principles Calculation of Charge and Spin Transport in Tin-MonolayerFirst Principles Calculation of Charge and Spin Transport in Tin-Monolayer
First Principles Calculation of Charge and Spin Transport in Tin-Monolayer
 
Spintronics
SpintronicsSpintronics
Spintronics
 

Recently uploaded

By Design, not by Accident - Agile Venture Bolzano 2024
By Design, not by Accident - Agile Venture Bolzano 2024By Design, not by Accident - Agile Venture Bolzano 2024
By Design, not by Accident - Agile Venture Bolzano 2024
Pierluigi Pugliese
 
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
DanBrown980551
 
Accelerate your Kubernetes clusters with Varnish Caching
Accelerate your Kubernetes clusters with Varnish CachingAccelerate your Kubernetes clusters with Varnish Caching
Accelerate your Kubernetes clusters with Varnish Caching
Thijs Feryn
 
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdfSmart TV Buyer Insights Survey 2024 by 91mobiles.pdf
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf
91mobiles
 
Monitoring Java Application Security with JDK Tools and JFR Events
Monitoring Java Application Security with JDK Tools and JFR EventsMonitoring Java Application Security with JDK Tools and JFR Events
Monitoring Java Application Security with JDK Tools and JFR Events
Ana-Maria Mihalceanu
 
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
UiPathCommunity
 
Climate Impact of Software Testing at Nordic Testing Days
Climate Impact of Software Testing at Nordic Testing DaysClimate Impact of Software Testing at Nordic Testing Days
Climate Impact of Software Testing at Nordic Testing Days
Kari Kakkonen
 
Leading Change strategies and insights for effective change management pdf 1.pdf
Leading Change strategies and insights for effective change management pdf 1.pdfLeading Change strategies and insights for effective change management pdf 1.pdf
Leading Change strategies and insights for effective change management pdf 1.pdf
OnBoard
 
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdfSAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
Peter Spielvogel
 
Video Streaming: Then, Now, and in the Future
Video Streaming: Then, Now, and in the FutureVideo Streaming: Then, Now, and in the Future
Video Streaming: Then, Now, and in the Future
Alpen-Adria-Universität
 
Elizabeth Buie - Older adults: Are we really designing for our future selves?
Elizabeth Buie - Older adults: Are we really designing for our future selves?Elizabeth Buie - Older adults: Are we really designing for our future selves?
Elizabeth Buie - Older adults: Are we really designing for our future selves?
Nexer Digital
 
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdfFIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
FIDO Alliance
 
The Future of Platform Engineering
The Future of Platform EngineeringThe Future of Platform Engineering
The Future of Platform Engineering
Jemma Hussein Allen
 
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdfFIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
FIDO Alliance
 
PHP Frameworks: I want to break free (IPC Berlin 2024)
PHP Frameworks: I want to break free (IPC Berlin 2024)PHP Frameworks: I want to break free (IPC Berlin 2024)
PHP Frameworks: I want to break free (IPC Berlin 2024)
Ralf Eggert
 
UiPath Test Automation using UiPath Test Suite series, part 4
UiPath Test Automation using UiPath Test Suite series, part 4UiPath Test Automation using UiPath Test Suite series, part 4
UiPath Test Automation using UiPath Test Suite series, part 4
DianaGray10
 
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdfFIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
FIDO Alliance
 
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
UiPathCommunity
 
RESUME BUILDER APPLICATION Project for students
RESUME BUILDER APPLICATION Project for studentsRESUME BUILDER APPLICATION Project for students
RESUME BUILDER APPLICATION Project for students
KAMESHS29
 
State of ICS and IoT Cyber Threat Landscape Report 2024 preview
State of ICS and IoT Cyber Threat Landscape Report 2024 previewState of ICS and IoT Cyber Threat Landscape Report 2024 preview
State of ICS and IoT Cyber Threat Landscape Report 2024 preview
Prayukth K V
 

Recently uploaded (20)

By Design, not by Accident - Agile Venture Bolzano 2024
By Design, not by Accident - Agile Venture Bolzano 2024By Design, not by Accident - Agile Venture Bolzano 2024
By Design, not by Accident - Agile Venture Bolzano 2024
 
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
LF Energy Webinar: Electrical Grid Modelling and Simulation Through PowSyBl -...
 
Accelerate your Kubernetes clusters with Varnish Caching
Accelerate your Kubernetes clusters with Varnish CachingAccelerate your Kubernetes clusters with Varnish Caching
Accelerate your Kubernetes clusters with Varnish Caching
 
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdfSmart TV Buyer Insights Survey 2024 by 91mobiles.pdf
Smart TV Buyer Insights Survey 2024 by 91mobiles.pdf
 
Monitoring Java Application Security with JDK Tools and JFR Events
Monitoring Java Application Security with JDK Tools and JFR EventsMonitoring Java Application Security with JDK Tools and JFR Events
Monitoring Java Application Security with JDK Tools and JFR Events
 
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
Le nuove frontiere dell'AI nell'RPA con UiPath Autopilot™
 
Climate Impact of Software Testing at Nordic Testing Days
Climate Impact of Software Testing at Nordic Testing DaysClimate Impact of Software Testing at Nordic Testing Days
Climate Impact of Software Testing at Nordic Testing Days
 
Leading Change strategies and insights for effective change management pdf 1.pdf
Leading Change strategies and insights for effective change management pdf 1.pdfLeading Change strategies and insights for effective change management pdf 1.pdf
Leading Change strategies and insights for effective change management pdf 1.pdf
 
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdfSAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
SAP Sapphire 2024 - ASUG301 building better apps with SAP Fiori.pdf
 
Video Streaming: Then, Now, and in the Future
Video Streaming: Then, Now, and in the FutureVideo Streaming: Then, Now, and in the Future
Video Streaming: Then, Now, and in the Future
 
Elizabeth Buie - Older adults: Are we really designing for our future selves?
Elizabeth Buie - Older adults: Are we really designing for our future selves?Elizabeth Buie - Older adults: Are we really designing for our future selves?
Elizabeth Buie - Older adults: Are we really designing for our future selves?
 
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdfFIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
FIDO Alliance Osaka Seminar: The WebAuthn API and Discoverable Credentials.pdf
 
The Future of Platform Engineering
The Future of Platform EngineeringThe Future of Platform Engineering
The Future of Platform Engineering
 
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdfFIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
FIDO Alliance Osaka Seminar: Passkeys at Amazon.pdf
 
PHP Frameworks: I want to break free (IPC Berlin 2024)
PHP Frameworks: I want to break free (IPC Berlin 2024)PHP Frameworks: I want to break free (IPC Berlin 2024)
PHP Frameworks: I want to break free (IPC Berlin 2024)
 
UiPath Test Automation using UiPath Test Suite series, part 4
UiPath Test Automation using UiPath Test Suite series, part 4UiPath Test Automation using UiPath Test Suite series, part 4
UiPath Test Automation using UiPath Test Suite series, part 4
 
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdfFIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
FIDO Alliance Osaka Seminar: FIDO Security Aspects.pdf
 
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
Dev Dives: Train smarter, not harder – active learning and UiPath LLMs for do...
 
RESUME BUILDER APPLICATION Project for students
RESUME BUILDER APPLICATION Project for studentsRESUME BUILDER APPLICATION Project for students
RESUME BUILDER APPLICATION Project for students
 
State of ICS and IoT Cyber Threat Landscape Report 2024 preview
State of ICS and IoT Cyber Threat Landscape Report 2024 previewState of ICS and IoT Cyber Threat Landscape Report 2024 preview
State of ICS and IoT Cyber Threat Landscape Report 2024 preview
 

Vortex Polarization Instabilities in PbTiO3 Nanowires

  • 1. Vortex Polarization Instabilities in PbTiO3 Nanowires G. Pilania and R. Ramprasad Chemical, Materials and Biomolecular Engineering Institute of Materials Science University of Connecticut, Storrs, CT
  • 2. Ferroelectricity in Nanostructures Critical Size & Polarization States Lateral Polarization in BaTiO3 nanowires Spanier et al, Nano Lett. 6, 735 (2006) 0.8 nm
  • 3. Ferroelectric Nanostructures Vortex (Non-rectilinear) Polarization Computations indicate the presence of non-rectilinear polarization in ferroelectric nanostructures Prosendeev & Bellaiche Aguado-Puente et al (PRB 2007) (PRL, 2008) PFM results indicate possible presence of non-rectilinear polarization in PZT nanodots Rodriguez et al (Nanoletters, 2009)
  • 4. BaTiO3 Nanowires – Our DFT Study Axial polarization Vortex polarization instability above instability above 1.2 nm 1.6 nm paraelectric ferroelectric Also see: Geneste et. al, APL 88, 112906 (2006); Shimada et al, PRB 79, 024102 (2009)
  • 5. PbTiO3 Nanowires – Our DFT Study Vortex polarization at equilibrium in TiO2-terminated nanowires above 1.6 nm
  • 6. Ground State Polarization & Atomic Configurations 4x4 TiO2-terminated PbTiO3 Nanowire
  • 7. PbTiO3 Nanowires vs. Terminations Strain-induced phase transition: vortex  axial polarization Four possible switchable polarization states Vortex (clockwise/counter-clockwise), Axial (positive/negative)
  • 8. Vortex Instability vs. “Soft-mode” Atomic displacement vector Zone-center phonon with respect to reference eigenvectors of reference paraelectric state paraelectric state “Vortex” modes: imaginary
  • 9. Summary PbTiO3 nanowires display switchable rectilinear (axial) and non-rectilinear (vortex) polarization configurations