Thermal conductivity measurements were taken on lightly Sr- and Zn-doped La2CuO4 single crystals from 2-300 K. It was found that even very low doping levels significantly suppressed the low-temperature phonon peak in thermal conductivity. The suppression of the phonon peak was greater in the c-axis than the ab-plane for Sr doping, but the opposite was true for Zn doping. Comparison with undoped La2CuO4 suggests the static spin stripes present in lightly doped La2CuO4 are playing an important role in damping the phonon heat transport, particularly for the c-axis.
Morphological study of aluminum tris(8 hydroxyquinoline) thin films using inf...John Clarkson
R.J. Curry, W.P. Gillin, J. Clarkson & D.N. Batchelder, “Morphological study of aluminum tris(8-hydroxyquinoline) thin films using infrared and Raman spectroscopy”, J. Appl. Phys., 92 (4), 1902-1905, 2002.
Dynamic Stereochemistry and What role does conformation plays on stereochemistry is being exemplified in this presentation. Useful for the Undergraduate and Postgraduates students of Pharmacy, Pharmaceutical Chemistry and Chemical Sciences
Morphological study of aluminum tris(8 hydroxyquinoline) thin films using inf...John Clarkson
R.J. Curry, W.P. Gillin, J. Clarkson & D.N. Batchelder, “Morphological study of aluminum tris(8-hydroxyquinoline) thin films using infrared and Raman spectroscopy”, J. Appl. Phys., 92 (4), 1902-1905, 2002.
Dynamic Stereochemistry and What role does conformation plays on stereochemistry is being exemplified in this presentation. Useful for the Undergraduate and Postgraduates students of Pharmacy, Pharmaceutical Chemistry and Chemical Sciences
The industry of ultrafine and nanopowder materials requires new methods for their production and hardware equipment for engineering processes. Among them there is plasmachemical synthesis of powder materials with the use of electric arc generators of low-temperature plasma. Plasma heating of initial inputs allows evaporation of almost any material and performance of the required chemical reactions in the gas phase with following vapor condensation to the nanodisperse solid phase. Considering the capacities of plasma generators and plasmachemical reactors achieved for today (many hundreds of kilowatts), we can expect that productivity by the desired product can be hundreds of kilograms per hour. Moreover, the plasma equipment demonstrates high universality relative to the initial materials, possible synthesis of complex powders and continuous conditions of operatingprocedure. The developed electric-arc plasmatrons and reactors allow different high-temperature processes, including powder processing in plasma flows . Now the most common constructions ofplasma reactors are the direct-flow ones with co-axial plasmatron and the three-jet ones with three plasmatrons tilted at 30–45° relative to the reactor axis and located in 120° intervals on the water-cooled upper lid. The plasmatron with sectioned inter-electrode insertion and shaped outlet nozzle-electrode ensure diffuse glow of the anode region of the arc discharge, what leads to the uniform temperature field and flow velocity at the nozzle edge. These parameters of the plasma jet have a good impact on reproducibility of powder processing, high coefficient of initial material use and production of powder with the given physical-chemical properties. Application of the three-jet plasmachemical reactor ensures the uniform temperature field along the reaction zone, allows easy control of productivity due
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
The Balmer series of the hydrogen spectrumSaiKalyani11
Balmer is well renowned for his research on the hydrogen spectral series. The part of the hydrogen emission spectrum that corresponds to electron transitions from higher orbicular states n>2 to the energy level with principal quantum number n=2 is a series of spectral lines known as the Balmer series. And the Balmer series consists of a sequence of spectral emissions in both ultraviolet and visible regions of the electromagnetic spectrum.
Modes of Heat Transfer - An Experimental ApproachNoaman Ahmed
Comparison of theoretical and steady-state temperature profiles in metallic rods of Copper, Aluminum, and Iron including the determination of net heat transfer in each metallic rod and the comparison of rate of heat transfer due to conduction, convection, and radiation.
mercury analysis in AAS, by fayaz hussain chandio, Introduction of Atomic Absorption Spectroscopy
Mercury-Element information, properties and uses
Mercury contamination and Human health
Analytical methods for mercury analysis
Determination of mercury by Cold-vapor Atomic absorption spectroscopy
Conclusion
Acknowledgment
Atomic Spectroscopy
Atomic-absorption (AA) spectroscopy uses the absorption of light to measure the concentration of gas-phase atoms.
samples are usually liquids or solids
Analyte atoms or ions must be vaporized in a flame or graphite furnace
The atoms absorb ultraviolet or visible light and make transitions to higher electronic energy levels.
Discovered approximately 1500 BC
Group 12, Period 6, Block d, Atomic number 80, Boiling point 356.619 ℃.
Mercury is an element and a transition metal that is found in air, water, and soil.
It is liquid at room temperature
Mercury has long been known as quicksilver.
Elemental mercury is liquid at room temperature. (Hg)
Inorganic mercury compounds are formed when mercury combines with other elements, such as sulfur or oxygen, to form compounds or salts. inorganic Hg (Hg2+).
Organic mercury compounds are formed when mercury combines with carbon. (MMHg, CH3Hg+), (DMHg, CH3HgCH3).
Mercury is also used in dental applications.
Coatings for mirrors.
The most important use of mercury is in the preparation of chlorine.
Mercury thermometers
and barometers.
Mercuric arsenate used
as waterproofing paints.
Mercuric chloride, or
mercury bichloride, or corrosive sublimate (HgCl ):disinfectant, insecticide.
Vapors pass through the skin into the blood stream. Can also be inhaled, can also be swallowed.
Mercury chloride known as calomel was sometimes used as a poison to kill people.
Depression, nervousness, and personality changes.
Damage to the kidneys and muscles.
Most exposure to mercury comes from the ingestion of certain foods, such as fish, in which the mercury has accumulated at high levels.
According to US EPA, list of many of the regulatory methods that are available for use with today’s technologies.
Cold Vapour Atomic Absorption Spectroscopy (CVAAS):
Cold Vapour At omic Fluorescence Spectroscopy (CVAFS):
Direct Analysis by Thermal Decomposition:
ICP or ICP-MS:
SCOPE AND APPLICATION METHOD:
This procedure measures total mercury (organic + inorganic) in drinking, surface, ground, sea, brackish waters, industrial and domestic wastewater, fish and coal.
The range of the method is 0.2-10 μg Hg/L.
most modern CVAAS instruments are more sensitive, automated, smaller, faster, and less expensive than generic flame spectrometers with cold vapor devices attached.
Heating the sample in the presence of different combinations of mineral acids such as nitric, hydrochloric, sulfuric and per chloric acids and also other oxidizing agents such as hydrogen peroxide.
2016 rsc-advance-tc-c-qinggao wang - 6 pp 16197-16202Konstantin German
We analyze the formation of transition metal (TM) carbides, as determined by the strength of TM–TM and
TM–C bonds, as well as lattice distortions induced by C interstitials. With increasing filling of the d-band of
TMs, TM–C bonds become increasingly weak from the left of the periodic table to the right, with fewer and
fewer C atoms entering the TMs lattice. Technetium (Tc) turns out to be a critical point for the formation of
carbides, guiding us to resolve a long-standing dispute. The predicted Tc carbides, agreeing with measured
X-ray absorption spectra, should decompose to cubic Tc and graphite above 2000 K. Consequently, we
show that what has been claimed as TcC (with rocksalt structure) is actually a high-temperature cubic
phase of elemental technetium.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
The industry of ultrafine and nanopowder materials requires new methods for their production and hardware equipment for engineering processes. Among them there is plasmachemical synthesis of powder materials with the use of electric arc generators of low-temperature plasma. Plasma heating of initial inputs allows evaporation of almost any material and performance of the required chemical reactions in the gas phase with following vapor condensation to the nanodisperse solid phase. Considering the capacities of plasma generators and plasmachemical reactors achieved for today (many hundreds of kilowatts), we can expect that productivity by the desired product can be hundreds of kilograms per hour. Moreover, the plasma equipment demonstrates high universality relative to the initial materials, possible synthesis of complex powders and continuous conditions of operatingprocedure. The developed electric-arc plasmatrons and reactors allow different high-temperature processes, including powder processing in plasma flows . Now the most common constructions ofplasma reactors are the direct-flow ones with co-axial plasmatron and the three-jet ones with three plasmatrons tilted at 30–45° relative to the reactor axis and located in 120° intervals on the water-cooled upper lid. The plasmatron with sectioned inter-electrode insertion and shaped outlet nozzle-electrode ensure diffuse glow of the anode region of the arc discharge, what leads to the uniform temperature field and flow velocity at the nozzle edge. These parameters of the plasma jet have a good impact on reproducibility of powder processing, high coefficient of initial material use and production of powder with the given physical-chemical properties. Application of the three-jet plasmachemical reactor ensures the uniform temperature field along the reaction zone, allows easy control of productivity due
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
The Balmer series of the hydrogen spectrumSaiKalyani11
Balmer is well renowned for his research on the hydrogen spectral series. The part of the hydrogen emission spectrum that corresponds to electron transitions from higher orbicular states n>2 to the energy level with principal quantum number n=2 is a series of spectral lines known as the Balmer series. And the Balmer series consists of a sequence of spectral emissions in both ultraviolet and visible regions of the electromagnetic spectrum.
Modes of Heat Transfer - An Experimental ApproachNoaman Ahmed
Comparison of theoretical and steady-state temperature profiles in metallic rods of Copper, Aluminum, and Iron including the determination of net heat transfer in each metallic rod and the comparison of rate of heat transfer due to conduction, convection, and radiation.
mercury analysis in AAS, by fayaz hussain chandio, Introduction of Atomic Absorption Spectroscopy
Mercury-Element information, properties and uses
Mercury contamination and Human health
Analytical methods for mercury analysis
Determination of mercury by Cold-vapor Atomic absorption spectroscopy
Conclusion
Acknowledgment
Atomic Spectroscopy
Atomic-absorption (AA) spectroscopy uses the absorption of light to measure the concentration of gas-phase atoms.
samples are usually liquids or solids
Analyte atoms or ions must be vaporized in a flame or graphite furnace
The atoms absorb ultraviolet or visible light and make transitions to higher electronic energy levels.
Discovered approximately 1500 BC
Group 12, Period 6, Block d, Atomic number 80, Boiling point 356.619 ℃.
Mercury is an element and a transition metal that is found in air, water, and soil.
It is liquid at room temperature
Mercury has long been known as quicksilver.
Elemental mercury is liquid at room temperature. (Hg)
Inorganic mercury compounds are formed when mercury combines with other elements, such as sulfur or oxygen, to form compounds or salts. inorganic Hg (Hg2+).
Organic mercury compounds are formed when mercury combines with carbon. (MMHg, CH3Hg+), (DMHg, CH3HgCH3).
Mercury is also used in dental applications.
Coatings for mirrors.
The most important use of mercury is in the preparation of chlorine.
Mercury thermometers
and barometers.
Mercuric arsenate used
as waterproofing paints.
Mercuric chloride, or
mercury bichloride, or corrosive sublimate (HgCl ):disinfectant, insecticide.
Vapors pass through the skin into the blood stream. Can also be inhaled, can also be swallowed.
Mercury chloride known as calomel was sometimes used as a poison to kill people.
Depression, nervousness, and personality changes.
Damage to the kidneys and muscles.
Most exposure to mercury comes from the ingestion of certain foods, such as fish, in which the mercury has accumulated at high levels.
According to US EPA, list of many of the regulatory methods that are available for use with today’s technologies.
Cold Vapour Atomic Absorption Spectroscopy (CVAAS):
Cold Vapour At omic Fluorescence Spectroscopy (CVAFS):
Direct Analysis by Thermal Decomposition:
ICP or ICP-MS:
SCOPE AND APPLICATION METHOD:
This procedure measures total mercury (organic + inorganic) in drinking, surface, ground, sea, brackish waters, industrial and domestic wastewater, fish and coal.
The range of the method is 0.2-10 μg Hg/L.
most modern CVAAS instruments are more sensitive, automated, smaller, faster, and less expensive than generic flame spectrometers with cold vapor devices attached.
Heating the sample in the presence of different combinations of mineral acids such as nitric, hydrochloric, sulfuric and per chloric acids and also other oxidizing agents such as hydrogen peroxide.
2016 rsc-advance-tc-c-qinggao wang - 6 pp 16197-16202Konstantin German
We analyze the formation of transition metal (TM) carbides, as determined by the strength of TM–TM and
TM–C bonds, as well as lattice distortions induced by C interstitials. With increasing filling of the d-band of
TMs, TM–C bonds become increasingly weak from the left of the periodic table to the right, with fewer and
fewer C atoms entering the TMs lattice. Technetium (Tc) turns out to be a critical point for the formation of
carbides, guiding us to resolve a long-standing dispute. The predicted Tc carbides, agreeing with measured
X-ray absorption spectra, should decompose to cubic Tc and graphite above 2000 K. Consequently, we
show that what has been claimed as TcC (with rocksalt structure) is actually a high-temperature cubic
phase of elemental technetium.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
The heating of electrons and phonons, as well as thermal size effects in the Schottky barrier, are investigated. The dependence of the electron and phonon temperature is analyzed depending on the thermal boundary conditions and the sample size. It was found that in thin (ka << 1) diodes at the contacts, the electron temperature is much higher than the phonon temperature. When the condition of ideal heat transfer is satisfied in an ohmic contact, the temperatures of electrons and phonons coincide with the ambient temperature. In massive (ka >> 1) diodes in the volume, the temperatures of electrons and phonons coincide, and in an ohmic contact, the temperatures coincide with the ambient temperature. Gulomov Gafurjon, Kudiratulla Bekbaevich, & Umarov Kudiratulla Bekbaevich. (2020). THERMAL SIZE EFFECTS IN CONTACT METAL SEMICONDUCTOR. International Journal on Orange Technologies, 2(12), 34-37. https://doi.org/10.31149/ijot.v2i12.1060 Pdf Url: https://journals.researchparks.org/index.php/IJOT/article/view/1060/1005 Paper Url: https://journals.researchparks.org/index.php/IJOT/article/view/1060
An Overview of Superconductivity with Special Attention on Thermodynamic Aspe...Thomas Templin
Superconductors are special types of conductors that exhibit a variety of physical phenomena such as zero resistivity, the absence of thermoelectric effects, ideal diamagnetism, the existence of a Meissner effect, and flux quantization. The observed phenomena mean that superconductivity is a well-defined thermodynamic equilibrium state/phase that does not depend on a sample’s history. Changes of phase are entirely reversible, and once a substance has come to equilibrium with its surroundings, there is no memory of its past history.
A variety of theoretical approaches have been developed to explain superconductivity. These include the two-fluid model of superconductivity, the Ginzburg-Landau theory, and the BCS model. These models are most suitable to explain the phenomena associated with type-I superconductors, i.e., the types of superconductors that only exist when the external magnetic field is below a relatively low threshold value of Bc as well as below a transition temperature Tc close to 0 K. In the 1980s a new type of superconductors was discovered, called type-II superconductors. Type-II materials are characterized by the coexistence of normally conducting and superconducting states as well as relatively high values of the critical field and transition temperature. Type-II superconductors have been used in a variety of technological applications, such as superconducting electromagnets, MRI, particle accelerators, levitating trains, and superconducting quantum-interference devices (SQUIDs).
The superconducting state has a lower free energy than the normal state. The exclusion of the magnetic field from a superconductor leads to an increase in the free energy. The Meissner effect thus implies the existence of a thermodynamical critical field for which these two effects balance out. Knowing only the experimental temperature dependence of the critical field, the Gibbs free energy, the entropy, and the specific heat that characterize the superconducting phase can be determined.
Properties of superconductors, Effects of the magnetic field, variation of resistance with temperature, Meissner Effect, isotope effect, Energy Gap, Coherence Length, BCS Theory, Types of superconductors ,
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Similar to Thermal conductivity of lightly sr and zn-doped la2 cuo4 single crystals (20)
The Art of the Pitch: WordPress Relationships and SalesLaura Byrne
Clients don’t know what they don’t know. What web solutions are right for them? How does WordPress come into the picture? How do you make sure you understand scope and timeline? What do you do if sometime changes?
All these questions and more will be explored as we talk about matching clients’ needs with what your agency offers without pulling teeth or pulling your hair out. Practical tips, and strategies for successful relationship building that leads to closing the deal.
Climate Impact of Software Testing at Nordic Testing DaysKari Kakkonen
My slides at Nordic Testing Days 6.6.2024
Climate impact / sustainability of software testing discussed on the talk. ICT and testing must carry their part of global responsibility to help with the climat warming. We can minimize the carbon footprint but we can also have a carbon handprint, a positive impact on the climate. Quality characteristics can be added with sustainability, and then measured continuously. Test environments can be used less, and in smaller scale and on demand. Test techniques can be used in optimizing or minimizing number of tests. Test automation can be used to speed up testing.
GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using Deplo...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
A tale of scale & speed: How the US Navy is enabling software delivery from l...sonjaschweigert1
Rapid and secure feature delivery is a goal across every application team and every branch of the DoD. The Navy’s DevSecOps platform, Party Barge, has achieved:
- Reduction in onboarding time from 5 weeks to 1 day
- Improved developer experience and productivity through actionable findings and reduction of false positives
- Maintenance of superior security standards and inherent policy enforcement with Authorization to Operate (ATO)
Development teams can ship efficiently and ensure applications are cyber ready for Navy Authorizing Officials (AOs). In this webinar, Sigma Defense and Anchore will give attendees a look behind the scenes and demo secure pipeline automation and security artifacts that speed up application ATO and time to production.
We will cover:
- How to remove silos in DevSecOps
- How to build efficient development pipeline roles and component templates
- How to deliver security artifacts that matter for ATO’s (SBOMs, vulnerability reports, and policy evidence)
- How to streamline operations with automated policy checks on container images
Encryption in Microsoft 365 - ExpertsLive Netherlands 2024Albert Hoitingh
In this session I delve into the encryption technology used in Microsoft 365 and Microsoft Purview. Including the concepts of Customer Key and Double Key Encryption.
zkStudyClub - Reef: Fast Succinct Non-Interactive Zero-Knowledge Regex ProofsAlex Pruden
This paper presents Reef, a system for generating publicly verifiable succinct non-interactive zero-knowledge proofs that a committed document matches or does not match a regular expression. We describe applications such as proving the strength of passwords, the provenance of email despite redactions, the validity of oblivious DNS queries, and the existence of mutations in DNA. Reef supports the Perl Compatible Regular Expression syntax, including wildcards, alternation, ranges, capture groups, Kleene star, negations, and lookarounds. Reef introduces a new type of automata, Skipping Alternating Finite Automata (SAFA), that skips irrelevant parts of a document when producing proofs without undermining soundness, and instantiates SAFA with a lookup argument. Our experimental evaluation confirms that Reef can generate proofs for documents with 32M characters; the proofs are small and cheap to verify (under a second).
Paper: https://eprint.iacr.org/2023/1886
Observability Concepts EVERY Developer Should Know -- DeveloperWeek Europe.pdfPaige Cruz
Monitoring and observability aren’t traditionally found in software curriculums and many of us cobble this knowledge together from whatever vendor or ecosystem we were first introduced to and whatever is a part of your current company’s observability stack.
While the dev and ops silo continues to crumble….many organizations still relegate monitoring & observability as the purview of ops, infra and SRE teams. This is a mistake - achieving a highly observable system requires collaboration up and down the stack.
I, a former op, would like to extend an invitation to all application developers to join the observability party will share these foundational concepts to build on:
Unlocking Productivity: Leveraging the Potential of Copilot in Microsoft 365, a presentation by Christoforos Vlachos, Senior Solutions Manager – Modern Workplace, Uni Systems
Threats to mobile devices are more prevalent and increasing in scope and complexity. Users of mobile devices desire to take full advantage of the features
available on those devices, but many of the features provide convenience and capability but sacrifice security. This best practices guide outlines steps the users can take to better protect personal devices and information.
UiPath Test Automation using UiPath Test Suite series, part 6DianaGray10
Welcome to UiPath Test Automation using UiPath Test Suite series part 6. In this session, we will cover Test Automation with generative AI and Open AI.
UiPath Test Automation with generative AI and Open AI webinar offers an in-depth exploration of leveraging cutting-edge technologies for test automation within the UiPath platform. Attendees will delve into the integration of generative AI, a test automation solution, with Open AI advanced natural language processing capabilities.
Throughout the session, participants will discover how this synergy empowers testers to automate repetitive tasks, enhance testing accuracy, and expedite the software testing life cycle. Topics covered include the seamless integration process, practical use cases, and the benefits of harnessing AI-driven automation for UiPath testing initiatives. By attending this webinar, testers, and automation professionals can gain valuable insights into harnessing the power of AI to optimize their test automation workflows within the UiPath ecosystem, ultimately driving efficiency and quality in software development processes.
What will you get from this session?
1. Insights into integrating generative AI.
2. Understanding how this integration enhances test automation within the UiPath platform
3. Practical demonstrations
4. Exploration of real-world use cases illustrating the benefits of AI-driven test automation for UiPath
Topics covered:
What is generative AI
Test Automation with generative AI and Open AI.
UiPath integration with generative AI
Speaker:
Deepak Rai, Automation Practice Lead, Boundaryless Group and UiPath MVP
GraphSummit Singapore | The Art of the Possible with Graph - Q2 2024Neo4j
Neha Bajwa, Vice President of Product Marketing, Neo4j
Join us as we explore breakthrough innovations enabled by interconnected data and AI. Discover firsthand how organizations use relationships in data to uncover contextual insights and solve our most pressing challenges – from optimizing supply chains, detecting fraud, and improving customer experiences to accelerating drug discoveries.
Securing your Kubernetes cluster_ a step-by-step guide to success !KatiaHIMEUR1
Today, after several years of existence, an extremely active community and an ultra-dynamic ecosystem, Kubernetes has established itself as the de facto standard in container orchestration. Thanks to a wide range of managed services, it has never been so easy to set up a ready-to-use Kubernetes cluster.
However, this ease of use means that the subject of security in Kubernetes is often left for later, or even neglected. This exposes companies to significant risks.
In this talk, I'll show you step-by-step how to secure your Kubernetes cluster for greater peace of mind and reliability.
Essentials of Automations: The Art of Triggers and Actions in FMESafe Software
In this second installment of our Essentials of Automations webinar series, we’ll explore the landscape of triggers and actions, guiding you through the nuances of authoring and adapting workspaces for seamless automations. Gain an understanding of the full spectrum of triggers and actions available in FME, empowering you to enhance your workspaces for efficient automation.
We’ll kick things off by showcasing the most commonly used event-based triggers, introducing you to various automation workflows like manual triggers, schedules, directory watchers, and more. Plus, see how these elements play out in real scenarios.
Whether you’re tweaking your current setup or building from the ground up, this session will arm you with the tools and insights needed to transform your FME usage into a powerhouse of productivity. Join us to discover effective strategies that simplify complex processes, enhancing your productivity and transforming your data management practices with FME. Let’s turn complexity into clarity and make your workspaces work wonders!
Alt. GDG Cloud Southlake #33: Boule & Rebala: Effective AppSec in SDLC using ...James Anderson
Effective Application Security in Software Delivery lifecycle using Deployment Firewall and DBOM
The modern software delivery process (or the CI/CD process) includes many tools, distributed teams, open-source code, and cloud platforms. Constant focus on speed to release software to market, along with the traditional slow and manual security checks has caused gaps in continuous security as an important piece in the software supply chain. Today organizations feel more susceptible to external and internal cyber threats due to the vast attack surface in their applications supply chain and the lack of end-to-end governance and risk management.
The software team must secure its software delivery process to avoid vulnerability and security breaches. This needs to be achieved with existing tool chains and without extensive rework of the delivery processes. This talk will present strategies and techniques for providing visibility into the true risk of the existing vulnerabilities, preventing the introduction of security issues in the software, resolving vulnerabilities in production environments quickly, and capturing the deployment bill of materials (DBOM).
Speakers:
Bob Boule
Robert Boule is a technology enthusiast with PASSION for technology and making things work along with a knack for helping others understand how things work. He comes with around 20 years of solution engineering experience in application security, software continuous delivery, and SaaS platforms. He is known for his dynamic presentations in CI/CD and application security integrated in software delivery lifecycle.
Gopinath Rebala
Gopinath Rebala is the CTO of OpsMx, where he has overall responsibility for the machine learning and data processing architectures for Secure Software Delivery. Gopi also has a strong connection with our customers, leading design and architecture for strategic implementations. Gopi is a frequent speaker and well-known leader in continuous delivery and integrating security into software delivery.
Dr. Sean Tan, Head of Data Science, Changi Airport Group
Discover how Changi Airport Group (CAG) leverages graph technologies and generative AI to revolutionize their search capabilities. This session delves into the unique search needs of CAG’s diverse passengers and customers, showcasing how graph data structures enhance the accuracy and relevance of AI-generated search results, mitigating the risk of “hallucinations” and improving the overall customer journey.
2. phonon transport significantly, while their role is minor in the
in-plane phonon transport.
II. EXPERIMENTS
The single crystals of LSCO and LCZO are grown by the
traveling-solvent floating-zone technique, and carefully an-
nealed in flowing pure He gas to remove the excess
oxygen.20
After the crystallographic axes are determined by
using an x-ray Laue analysis, the crystals are cut into rectan-
gular thin platelets with the typical sizes of 2.5ϫ0.5
ϫ0.15 mm3
, where the c axis is perpendicular or parallel to
the platelet with an accuracy of 1°. The thermal conductivity
is measured in the temperature range of 2–300 K using a
steady-state technique;21–23
above 150 K, a double thermal
shielding is employed to minimize the heat loss due to radia-
tion, and the residual radiation loss is corrected by using an
elaborate measurement configuration. The temperature dif-
ference ⌬T in the sample is measured by a differential
Chromel-Constantan thermocouple, which is glued to the
sample using GE vanish. The ⌬T varies between 0.5% and
2% of the sample temperature. To improve the accuracy of
the measurement at low temperatures, is also measured
with ‘‘one heater, two thermometer’’ method from 2 to 20 K
by using a chip heater and two Cernox chip sensors.21
The
errors in the thermal conductivity data are smaller than 10%,
which are mainly caused by the uncertainties in the geo-
metrical factors. Magnetization measurements are carried out
using a Quantum Design superconducting quantum interfer-
ence device magnetometer.
III. RESULTS
A. Anisotropic heat transport in La2CuO4
It is useful to first establish an understanding of the an-
isotropic heat transport in undoped crystals. The temperature
dependences of the thermal conductivity measured along the
ab plane and the c axis in pure La2CuO4 are shown in Fig. 1,
which also contains data for LSCO and LCZO single crys-
tals. For the undoped La2CuO4 sample, a sharp peak appears
at low temperature, at ϳ25 K in ab(T) and at ϳ20 K in
c(T), respectively. In the c direction, above the peak tem-
perature, c decreases with increasing T approximately fol-
lowing 1/T dependence, which is typical for phonon heat
transport.24
This phonon peak originates from the competi-
tion between the increase in the population of phonons and
the decrease in their mean free path ͑due to the phonon-
phonon umklapp scattering͒ with increasing temperature. In
contrast to the mainly phononic heat transport in the c direc-
tion, in the ab plane another large and broad peak develops
at higher temperature (ϳ270 K), which has been
FIG. 1. Thermal conductivity of lightly doped La2ϪxSrxCuO4 and La2Cu1ϪyZnyO4 single crystals along the ab plane and the c axis. The
dashed line in panel ͑a͒ is e,ab of La1.96Sr0.04CuO4 estimated from the Wiedemann-Franz law.
X. F. SUN, J. TAKEYA, SEIKI KOMIYA, AND YOICHI ANDO PHYSICAL REVIEW B 67, 104503 ͑2003͒
104503-2
3. attributed18
to the magnon transport in a long-range-ordered
AF state. The heat conduction due to magnetic excitations
has been observed in many low-dimensional quantum anti-
ferromagnets, such as one-dimensional spin systems
CuGeO3,21,23,25
Sr2CuO3,26
SrCuO2,27
and
(Sr,Ca)14Cu24O41 ,28
and also the two-dimensional antiferro-
magnet K2V3O8.29
The absence of this high-T peak in c(T)
is obviously due to the much weaker magnetic correlations in
the c direction compared to that in the CuO2 plane. All these
behaviors in undoped La2CuO4 are consistent with the pre-
viously reported data.18
It is worthwhile to note that the
phononic peak value of c ͑27 W/Km͒ is considerably larger
than that of ab ͑16 W/Km͒. One possible reason for this
difference is that the phonon heat transport is intrinsically
easier along the c axis, which is not so easy to conceive in
view of the layered crystal structure of La2CuO4. Another,
more likely, possibility is that there exists phonon-magnon
scattering in the ab plane that causes additional damping of
the phonon peak. Such scattering may also happen in the c
axis, however, it should be much weaker than in the ab plane
because it is well known that the magnons are good excita-
tions only for the in-plane physics in the La2CuO4 system.
B. Doping dependence of magnon peak and Ne´el transition
Upon Sr or Zn doping, there are strong doping depen-
dences in both ab and c . Let us first discuss the change of
the high-T magnon peak in ab(T) for different dopants.
This peak is suppressed very quickly upon Sr-doping and in
fact completely disappears at only 1% doping concentration.
On the other hand, the suppression of this peak is much
slower in the Zn-doped case, where the peak, though gradu-
ally suppressed, survives to yϭ0.04. To clarify the relation
between the high-T peak and the Ne´el order, the magnetic
susceptibility of LSCO and LCZO is measured from 5 to 350
K in the magnetic field of 0.5 T applied along the c axis.
Figure 2 shows the temperature dependences of the magnetic
susceptibility, where the peak corresponds to the Ne´el tran-
sition ͑no transition is observed in LSCO with xу0.02). It is
clear ͑as has been already reported30,31
͒ that Sr doping is
much stronger than Zn doping in destroying the AF long-
range order, where the former decreases the Ne´el tempera-
ture TN much more quickly. The reason is related to the fact
that holes introduced by Sr are mobile and have a 1/2 spin,
while Zn ͑zero spin͒ causes a static spin vacancy in the CuO2
plane. Figure 3 summarizes the doping dependences of the
size of the high-T peak in ab(T) ͓defined by the difference
between the peak value and ab(100 K)], as well as those of
the Ne´el temperature TN , for the two systems. This result
confirms that the magnon peak is quickly diminished as TN is
reduced. It is useful to note that the disorder in the Ne´el state
induced by Sr doping appears to be detrimental to the mag-
non heat transport, because the magnon peak completely dis-
appears at xϭ0.01 even though the Ne´el order is still estab-
lished at 240 K for this Sr doping.
C. Doping dependence of phonon peak
More interesting changes happen in the suppression of the
phonon peak at low temperatures. One can see in Fig. 1 that
FIG. 2. Magnetic susceptibility of ͑a͒ La2ϪxSrxCuO4 and ͑b͒
La2Cu1ϪyZnyO4 single crystals measured in a 0.5-T field applied
along the c axis.
FIG. 3. ͑a͒ Doping dependences of the size of high-T peak in
ab(T) ͓defined by the difference between the peak value and
ab(100 K)] of La2ϪxSrxCuO4 and La2Cu1ϪyZnyO4 single crys-
tals. ͑b͒ Doping dependences of the Ne´el temperature TN for the
two cases.
THERMAL CONDUCTIVITY OF LIGHTLY Sr- AND Zn- . . . PHYSICAL REVIEW B 67, 104503 ͑2003͒
104503-3
4. in ab(T) the peak magnitude decreases more quickly with
Zn doping than with Sr doping; on the contrary, the peak
value in c decreases much more quickly with Sr doping
than with Zn doping. It should be noted that those peculiar
differences between Sr and Zn dopings cannot be due to the
additional electronic thermal conductivity in the Sr-doped
samples: The electronic thermal conductivity e can roughly
be estimated by the Wiedemann-Franz law eϭL0T/,
where is the electrical resistivity and L0 is the Lorenz
number ͑which can be approximated by the Sommerfeld
value, 2.44ϫ10Ϫ8
W⍀/K2
). Using the resistivity data for
our crystals,32
the contribution e,ab for La1.96Sr0.04CuO4 can
be estimated to be smaller than 0.25 W/Km in the whole
temperature region ͓dashed line in Fig. 1͑a͔͒, and samples
with lower Sr doping should have smaller e,ab than this
estimate for xϭ0.04; clearly, the electronic contribution can
be safely neglected in the lightly Sr doped region in the
discussion of the ab(T) behavior, not to mention the c(T)
behavior. Thus, the changes in the low-temperature peak
upon doping must be due to the changes in the phonon trans-
port properties, that is, the scattering process that determines
the phonon mean free path.
D. Reappearance of the phonon peak in RE-doped LSCO
Although both the phonon-impurity scattering and the
phonon-carrier scattering can contribute to the suppression of
the phonon peak, these scattering processes cannot be the
only mechanisms to determine the Sr-doping dependence of
the phonon heat transport, because the phonon peak re-
appears in overdoped LSCO and in RE-doped LSCO.18,19
Figure 4 shows our data for the re-appearance of the phonon
peak in RE-doped samples ͑both Nd- and Eu-doped cases͒
for xϭ0.12; these data are taken on single crystals, and es-
sentially confirms the polycrystalline data reported by Bab-
erski et al.19
The single crystal data of Fig. 4 allow us to
compare the absolute values of ab and c of the RE-doped
samples to those of the RE-free LSCO; such a comparison
tells us that the low-T peak values of ab and c of the
RE-doped crystals at xϭ0.12 are similar to those of the RE-
free LSCO crystals at xϭ0.04, despite the factor of 3 differ-
ence in the Sr concentrations. This result clearly indicates
that the phonon-impurity scattering and the phonon-carrier
scattering are not the only scattering mechanisms to deter-
mine the phonon mean free path.
IV. DISCUSSION
A. Magnetic scattering of phonons in the ab plane of LCZO
Based on the apparent similarity of the doping depen-
dence of the phonon peak in ab , shown in Figs. 1͑a͒ and
1͑b͒, one might naively conclude that the lattice disorders
induced by Zn and Sr in the ab plane are very similar and
that the ab(T) behavior is essentially explained only by the
lattice disorder; however, this is not likely to be the case,
which can be understood by considering the nature of the
impurity scattering and the additional charge carriers intro-
duced in LSCO. First, it is important to notice that the low-
T phonon peak in ab is suppressed slightly more quickly by
Zn doping than by Sr doping. In the impurity-scattering
scenario,24
it is difficult to conceive that the phonons are
scattered more strongly in LCZO than in LSCO, because the
atomic mass difference between Cu and Zn is much smaller
than that between La and Sr. In addition, the contribution of
the phonon-carrier scattering, which exists only in LSCO,
would cause the phonon peak in LSCO to be suppressed
more quickly than in LCZO. Thus the difference between the
Sr-doping dependence and the Zn-doping dependence in
ab(T) at low temperature, which is opposite to the naturally
expected trend, suggests that there are additional scatterers of
phonons in the Zn doped samples. It is most likely that the
additional scatterers in LCZO are of magnetic origin; mag-
nons, which cause the high-temperature peak in LCZO, are
an obvious candidate, and the magnetic disordering around
Zn atoms may also cause some scattering of phonons
through magnetoelastic coupling.33
It is useful to note that,
as we mentioned in Sec. III A, magnons are likely to be
already responsible for the relatively small phonon peak in
ab ͑compared to that in c) in pure La2CuO4.
B. Scattering of phonons by static spin stripes in LSCO
Contrary to the relatively small difference in the phonon
peak of ab between LSCO and LCZO, the suppression of
the phonon peak of c is much quicker in LSCO than in
LCZO; in particular, the sharp suppression of the phonon
peak from xϭ0 to 0.01 is quite surprising and is the most
striking observation of this work. Apart from the impurity
FIG. 4. Comparison of the low-temperature thermal conductiv-
ity of LSCO (xϭ0.12) single crystals to that of Nd- and Eu-doped
crystals, in which the phonon peak reappears. The data for both ͑a͒
ab(T) and ͑b͒ c(T) are shown.
X. F. SUN, J. TAKEYA, SEIKI KOMIYA, AND YOICHI ANDO PHYSICAL REVIEW B 67, 104503 ͑2003͒
104503-4
5. scattering, two different scattering processes of phonons are
possibly responsible for the suppression of the c-axis phonon
heat transport. The first possibility is the magnon-phonon
scattering. This may partly play a role ͑particularly in
samples where the long-range Ne´el order is established͒ in
the c-axis phonon heat transport, although their role is ex-
pected to be minor because of the essentially two-
dimensional nature of the magnons in the LCO system,
which means that the magnons cannot effectively change the
wave vector of the c-axis phonons. The second possibility is
the scattering of phonons caused by the static stripes that
exist only in LSCO. In the following, we elaborate on this
possibility.
It is known that static spin stripes are formed at low tem-
peratures in lightly doped LSCO.5–8
If the charges also form
static stripes together with the spins, they certainly cause
local lattice distortions. Even if the charges do not conform
to the static stripe potentials set by the spins, the spin stripes
themselves may well cause local lattice distortions due to the
magnetoelastic coupling;33
this direct coupling between the
spin stripes and the local lattice distortions is in fact very
likely, because recently Lavrov et al. found that the spin-
lattice coupling is very strong in lightly doped LSCO.34
It
should be noted that local lattice distortions due to static
stripes are not expected to scatter phonons when the stripes
induce only static and periodic modulation of the lattice
͑which is in fact a kind of superlattice͒; however, possible
disordering of stripes in the c direction can introduce rather
strong scattering of phonons in this direction. In fact, be-
cause of the weak magnetic correlations along the c axis, the
stripes in neighboring CuO2 planes are only weakly corre-
lated or even uncorrelated, which is best evidenced by the
very short magnetic correlation length c in the stripe phase
͑usually smaller than the distance between neighboring CuO2
planes͒ in the lightly doped LSCO.6,7
We can further discuss the possible role of static stripes in
the suppression of the phonon peak in ab of lightly doped
LSCO. Although the stripes are much better ordered in the
ab plane than in the c direction,6,7
there are two reasons that
phonons in the ab plane are possibly scattered by the stripes.
First, the static spin stripes were reported to be established at
about 30–17 K for xϭ0.01–0.04 by neutron
measurements.5,7
These temperatures are very close to the
position of the phonon peak ͑20–25 K͒. Near the stripe
freezing temperature, local lattice distortions are expected to
be well developed and yet are slowly fluctuating ͑or disor-
dered͒, which would tend to scatter phonons. Second, there
is no evidence until today that well periodically ordered
static charge stripes are formed in lightly doped LSCO; in-
stead, our charge transport data strongly suggest17,32,35
that
charge stripes exist in a liquid ͑or nematic͒ state.14
Such
disordered state of charge stripes would tend to scatter
phonons. Thus, it is possible that the static stripes also con-
tribute to the scattering of phonons in the in-plane heat trans-
port in LSCO, although their effect appears to be much
weaker than that in the c direction.
V. SUMMARY
We have measured the ab-plane and c-axis thermal con-
ductivities of lightly doped LSCO and LCZO single crystals.
It is found that the low-temperature phonon peak is signifi-
cantly suppressed upon Sr or Zn doping even at very low
doping levels, and that the doping dependences show clear
differences between the Sr and Zn dopants, and between ab
and c . The experimental observations can be summarized
as follows: ͑i͒ The phonon peak in c decreases much more
quickly with Sr doping than with Zn doping. ͑ii͒ On the other
hand, the phonon peak in ab is suppressed slightly more
quickly with Zn doping than with Sr doping. ͑iii͒ At high
temperature, the magnon peak in ab(T) decreases much
more quickly with Sr doping than with Zn doping; in fact,
the magnon peak completely disappears in LSCO with x
ϭ0.01, while it is still observable in LCZO with yϭ0.04.
͑iv͒ Rare-earth ͑Nd or Eu͒ doping for LSCO (xϭ0.12) en-
hances the phonon heat transport in both ab and c , and
this is manifested in the reappearance of the low temperature
phonon peak, whose height is similar to that of rare-earth-
free LSCO with xϭ0.04.
Based on the peculiar doping dependences of the low-
temperature phonon peak, we can deduce the following con-
clusions for the phonon heat transport at low temperatures:
͑i͒ In the in-plane direction, disordered static stripes are
probably working as scatterers of phonon ͑in addition to the
Sr impurities and the holes͒ in LSCO, while in LCZO mag-
netic scatterings cause strong damping of the phonon trans-
port, which overcompensates the absence of the stripe scat-
tering. ͑ii͒ In the c-axis heat transport, besides the possible
contribution of the magnon-phonon scattering, the strong
disorder of the stripe arrangement along the c axis is mainly
responsible for the scattering of phonons. The latter scatter-
ing mechanism naturally explains the strong damping of the
phonon peak in LSCO, while allowing a much slower sup-
pression of the phonon peak in LCZO where there is no
stripe. Therefore, the effect of static spin stripes, which are
formed in the lightly doped LSCO, appears to be most dra-
matically observed in the c-axis phonon heat transport.
ACKNOWLEDGMENTS
We thank A. N. Lavrov and I. Tsukada for helpful discus-
sions. X.F.S. acknowledges support from JISTEC.
*Email address: ko-xfsun@criepi.denken.or.jp
†
Email address: ando@criepi.denken.or.jp
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