Stereochemistry deals with the three-dimensional arrangements of atoms in molecules. There are different types of isomers including stereoisomers which have the same molecular formula but different spatial arrangements. Configurational isomers have fixed atomic arrangements while conformational isomers can rotate around bonds. Geometric isomers have different arrangements in space and optical isomers are mirror images that rotate plane-polarized light in opposite directions. The stability and reactivity of cyclic compounds is influenced by their conformations, with the chair form typically being most stable for cyclohexane. Chirality is important in biology as enantiomers can have different biological effects.