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EFFECT OF RESIN ACIDS AND OTHER
  EXTRACTIVES ON DIMENSIONAL
      STABILITY AND DECAY
SUSCEPTABILITY OF SYP LUMBER IN
    ABOVE GROUND EXPOSURE

 Tor P. Schultz, Joseph
  Dahlen and Darrel
        Nicholas
   Mississippi State
      University
1. Examine effect of resin acids on dimensional
   stability of outdoor SYP decking
2.Examine effect of resin acids and other
   extractives on decay susceptibility of SYP in
   two above ground exposures
1st Study – RESIN
    ACIDS/DIMENSIONAL STABILITY

•TOR is the common acronym for resin acids that
are isolated from Tall Oil, obtained by the Kraft
pulping of pines
•Safe – modified TOR is chewing gum base,
GRAS for paper in food contact
•Inexpensive - $0.25 to 0.40/lb, bulk
•Other folks have examined potential of
solventborne TOR in Wood Preservation, so-so
results
•We developed a waterborne system
Materials & Methods
 Defect free sapwood            Roof, MSU Campus,
                                  slanted towards sun, very
 5/4 Flatsawn Decking            hot in summer, ~165F
   • Untreated control           Δ MC%: Rain: before & after,
   • 3% waterborne resin acid    plus other times
 Laminated Quartersawn          Flatsawn: checking
   • Untreated control           Quartersawn: cupping
   • 3% waterborne resin acid
   • 3% paraffin wax, toluene
Flatsawn
Quartersawn
Flatsawn


             Control      TOR



 ΔMC%       26.1% (A)   18.9% (B)



Checking    3.17 (A)     2.1(B)
Quartersawn


           Control      TOR         Wax



ΔMC%      33.4% (A)   26.2% (B)   5.2% (C)



Cupping   4.17 (A)     3.41(A)    1.25 (B)
Materials and Methods

   KD sapwood 5/4 flatsawn decking
   Two Above Ground Exposures
AWPA Gnd Prox, E-18,
Saucier, AWPA 5 Decay Hazard
Roof Setup
   Starkville: AWPA 4 Decay Hazard, very hot
Regression Factors & Results
   Extractives
    • Fatty and resin acids
   Initial water permeability Avg. Decay Ratings,
   Moisture content averages 21 months’ exposure
    before/after rain          • Roof = 7.85
   Checking                   • Ground = 7.35
   Relative density
   Growth rate
   Mold
   Gnd Prox vs. Roof
   Simple sugars
Ground Prox Decay
                                               Predicted vs Actual Ground Decay
                                                           r2 = 0.41

                         12

                                  + = less decay
                         10
                                  Palmitic -
Predicted Ground Decay




                         8        Dehydroabietic +
                                  Neoabietic -
                         6


                         4


                         2


                         0
                              0      1     2        3     4       5      6     7   8   9   10
                                                         Actual Ground Decay
Roof Decay
                                              Predicted vs Actual Roof Decay
                                                         r2 = 0.76

                       12
                                + = less decay
                       10
                                Permeability +
Predicted Roof Decay




                       8        Rain Absorption –
                                 C=87%, collinear -
                       6
                                Check Rating +
                       4        Dehydroabietic +

                       2


                       0
                            0       1     2       3     4       5      6       7   8   9   10
                                                        Actual Roof Decay
   Decay is complex
   Both tests above ground and had about the
    same extent of decay [which was not expected]
    – but different results as should be anticipated
   Roof Test – Decay extent appears related to
    moisture availability
   Ground Prox Test – decay appears related to
    extractives which inhibit decay

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Session 15 ic2011 schultz

  • 1. EFFECT OF RESIN ACIDS AND OTHER EXTRACTIVES ON DIMENSIONAL STABILITY AND DECAY SUSCEPTABILITY OF SYP LUMBER IN ABOVE GROUND EXPOSURE Tor P. Schultz, Joseph Dahlen and Darrel Nicholas Mississippi State University
  • 2. 1. Examine effect of resin acids on dimensional stability of outdoor SYP decking 2.Examine effect of resin acids and other extractives on decay susceptibility of SYP in two above ground exposures
  • 3. 1st Study – RESIN ACIDS/DIMENSIONAL STABILITY •TOR is the common acronym for resin acids that are isolated from Tall Oil, obtained by the Kraft pulping of pines •Safe – modified TOR is chewing gum base, GRAS for paper in food contact •Inexpensive - $0.25 to 0.40/lb, bulk •Other folks have examined potential of solventborne TOR in Wood Preservation, so-so results •We developed a waterborne system
  • 4.
  • 5. Materials & Methods  Defect free sapwood  Roof, MSU Campus, slanted towards sun, very  5/4 Flatsawn Decking hot in summer, ~165F • Untreated control  Δ MC%: Rain: before & after, • 3% waterborne resin acid plus other times  Laminated Quartersawn  Flatsawn: checking • Untreated control  Quartersawn: cupping • 3% waterborne resin acid • 3% paraffin wax, toluene
  • 8. Flatsawn Control TOR ΔMC% 26.1% (A) 18.9% (B) Checking 3.17 (A) 2.1(B)
  • 9. Quartersawn Control TOR Wax ΔMC% 33.4% (A) 26.2% (B) 5.2% (C) Cupping 4.17 (A) 3.41(A) 1.25 (B)
  • 10.
  • 11. Materials and Methods  KD sapwood 5/4 flatsawn decking  Two Above Ground Exposures
  • 12. AWPA Gnd Prox, E-18, Saucier, AWPA 5 Decay Hazard
  • 13. Roof Setup  Starkville: AWPA 4 Decay Hazard, very hot
  • 14. Regression Factors & Results  Extractives • Fatty and resin acids  Initial water permeability Avg. Decay Ratings,  Moisture content averages 21 months’ exposure before/after rain • Roof = 7.85  Checking • Ground = 7.35  Relative density  Growth rate  Mold  Gnd Prox vs. Roof  Simple sugars
  • 15. Ground Prox Decay Predicted vs Actual Ground Decay r2 = 0.41 12 + = less decay 10 Palmitic - Predicted Ground Decay 8 Dehydroabietic + Neoabietic - 6 4 2 0 0 1 2 3 4 5 6 7 8 9 10 Actual Ground Decay
  • 16. Roof Decay Predicted vs Actual Roof Decay r2 = 0.76 12 + = less decay 10 Permeability + Predicted Roof Decay 8 Rain Absorption – C=87%, collinear - 6 Check Rating + 4 Dehydroabietic + 2 0 0 1 2 3 4 5 6 7 8 9 10 Actual Roof Decay
  • 17. Decay is complex  Both tests above ground and had about the same extent of decay [which was not expected] – but different results as should be anticipated  Roof Test – Decay extent appears related to moisture availability  Ground Prox Test – decay appears related to extractives which inhibit decay