This document discusses research on phononic crystals using photoelastic visualization techniques. Simulation results using FEM show negative refraction and focusing of waves passing through triangular arrangements of steel rods embedded in epoxy. The research aims to experimentally validate simulations by creating a solid-solid phononic crystal and using photoelastic methods to observe wave propagation. This will provide a better understanding of phononic crystal properties without limitations of computer simulation.
This document summarizes a seminar on magnetic nanocomposites. It discusses how nanocomposites have particles mixed at the nanoscale, including magnetic nanocomposites containing ferromagnetic particles. The history of magnetic nanocomposites is reviewed, from early amorphous alloys to developments in the 1980s-1990s of alloys like FINEMET, NANOPERM, and HITPERM. Recent developments discussed include core-shell nanoparticles, colloidal crystals, mesoporous nanocomposites, and functional polymers. Applications mentioned are using magnetic fields to destroy tumor cells, transformers, and DC-DC power converters. Challenges remaining are controlled synthesis, understanding mechanisms, cost, toxicity
Effects of Different Parameters in Enhancing the Efficiency of Plasmonic Thin...IJAMSE Journal
Efficiency of thin film solar cells are less comparing to thick film solar cells which can be enhanced by utilizing the metal nanoparticles near their localized Plasmon resonance. In this paper, we have reviewed the Plasmon resonance of metallic nanoparticles and its application in solar cell technology. Beside this, we have also reviewed about different parameters which dominate the nanoparticles to increase optical absorption. Thus a cost-effective model has been proposed.
This document provides an overview of magnetic nanocomposite materials. It discusses how nanocomposite materials with magnetic particles embedded in a matrix can have properties different from conventional composites due to interactions at the nanoscale. The document then reviews the history of magnetic nanocomposites, including early amorphous alloys and more recent developments like FINEMET, NANOPERM, and HITPERM which use crystalline nanoparticles embedded in an amorphous matrix. Recent advances in preparation of functional nanocomposites and hybrid materials are also summarized, including core-shell nanoparticles, colloidal crystals, mesoporous composites, and functional magnetic polymers.
This document discusses ferromagnetic nanomaterials. It introduces magnetic nanoparticles and their size requirements for various applications. It describes the magnetic properties of ferromagnetic materials and how temperature and magnetic fields affect them. Common ferromagnetic elements are iron, nickel and cobalt. Their magnetic domains can be aligned with external fields. Preparation methods like co-precipitation and thermal decomposition are discussed. Applications include nanomagnetism, targeted drug delivery, and using zero valent iron for groundwater remediation.
Effect of Milling Time on Co0.5Zn0.5Fe2O4 Microstructure and Particles Size E...Abubakar Yakubu
This document summarizes a study on the effect of milling time on the microstructure and particle size evolution of Co0.5Zn0.5Fe2O4 powder produced via mechanical alloying. Nanocrystalline CoZn-ferrite powder was fabricated by ball milling a mixture of Fe2O3, CoO, and ZnO for varying times. X-ray diffraction analysis showed the formation of a single phase CoZn-ferrite structure after 8 hours of milling with crystallite sizes ranging from 16-30 nm. Scanning electron microscopy revealed particle sizes of 19.5-24 nm after 12 hours of milling. Transmission electron microscopy images confirmed the nanosized particles produced had diameters
This document summarizes the synthesis and characterization of lithium substituted copper-manganese ferrite nanoparticles. Four samples of lithium ferrite nanoparticles with varying lithium content were prepared using an auto-combustion technique. Magnetic characterization using vibrating sample magnetometry showed that magnetization increased from 5.08 emu/g to 45.35 emu/g with increasing lithium content. Field emission scanning electron microscopy revealed that grain size also increased from 96 nm to 112 nm with higher lithium substitution levels. In conclusion, lithium substituted copper-manganese ferrite nanoparticles were successfully synthesized and exhibited ferromagnetic behavior and tunable properties based on the lithium content.
Nanotechnology involves creating and manipulating materials at the nanoscale, between 1-100 nanometers. At this scale, materials exhibit unique properties due to increased surface area to volume ratio and quantum mechanical effects. Some examples include enhanced chemical reactivity, color changes with particle size, and size-dependent melting points and conductivity. The document provides background on nanotechnology and an overview of how properties change at the nanoscale.
This document summarizes a seminar on magnetic nanocomposites. It discusses how nanocomposites have particles mixed at the nanoscale, including magnetic nanocomposites containing ferromagnetic particles. The history of magnetic nanocomposites is reviewed, from early amorphous alloys to developments in the 1980s-1990s of alloys like FINEMET, NANOPERM, and HITPERM. Recent developments discussed include core-shell nanoparticles, colloidal crystals, mesoporous nanocomposites, and functional polymers. Applications mentioned are using magnetic fields to destroy tumor cells, transformers, and DC-DC power converters. Challenges remaining are controlled synthesis, understanding mechanisms, cost, toxicity
Effects of Different Parameters in Enhancing the Efficiency of Plasmonic Thin...IJAMSE Journal
Efficiency of thin film solar cells are less comparing to thick film solar cells which can be enhanced by utilizing the metal nanoparticles near their localized Plasmon resonance. In this paper, we have reviewed the Plasmon resonance of metallic nanoparticles and its application in solar cell technology. Beside this, we have also reviewed about different parameters which dominate the nanoparticles to increase optical absorption. Thus a cost-effective model has been proposed.
This document provides an overview of magnetic nanocomposite materials. It discusses how nanocomposite materials with magnetic particles embedded in a matrix can have properties different from conventional composites due to interactions at the nanoscale. The document then reviews the history of magnetic nanocomposites, including early amorphous alloys and more recent developments like FINEMET, NANOPERM, and HITPERM which use crystalline nanoparticles embedded in an amorphous matrix. Recent advances in preparation of functional nanocomposites and hybrid materials are also summarized, including core-shell nanoparticles, colloidal crystals, mesoporous composites, and functional magnetic polymers.
This document discusses ferromagnetic nanomaterials. It introduces magnetic nanoparticles and their size requirements for various applications. It describes the magnetic properties of ferromagnetic materials and how temperature and magnetic fields affect them. Common ferromagnetic elements are iron, nickel and cobalt. Their magnetic domains can be aligned with external fields. Preparation methods like co-precipitation and thermal decomposition are discussed. Applications include nanomagnetism, targeted drug delivery, and using zero valent iron for groundwater remediation.
Effect of Milling Time on Co0.5Zn0.5Fe2O4 Microstructure and Particles Size E...Abubakar Yakubu
This document summarizes a study on the effect of milling time on the microstructure and particle size evolution of Co0.5Zn0.5Fe2O4 powder produced via mechanical alloying. Nanocrystalline CoZn-ferrite powder was fabricated by ball milling a mixture of Fe2O3, CoO, and ZnO for varying times. X-ray diffraction analysis showed the formation of a single phase CoZn-ferrite structure after 8 hours of milling with crystallite sizes ranging from 16-30 nm. Scanning electron microscopy revealed particle sizes of 19.5-24 nm after 12 hours of milling. Transmission electron microscopy images confirmed the nanosized particles produced had diameters
This document summarizes the synthesis and characterization of lithium substituted copper-manganese ferrite nanoparticles. Four samples of lithium ferrite nanoparticles with varying lithium content were prepared using an auto-combustion technique. Magnetic characterization using vibrating sample magnetometry showed that magnetization increased from 5.08 emu/g to 45.35 emu/g with increasing lithium content. Field emission scanning electron microscopy revealed that grain size also increased from 96 nm to 112 nm with higher lithium substitution levels. In conclusion, lithium substituted copper-manganese ferrite nanoparticles were successfully synthesized and exhibited ferromagnetic behavior and tunable properties based on the lithium content.
Nanotechnology involves creating and manipulating materials at the nanoscale, between 1-100 nanometers. At this scale, materials exhibit unique properties due to increased surface area to volume ratio and quantum mechanical effects. Some examples include enhanced chemical reactivity, color changes with particle size, and size-dependent melting points and conductivity. The document provides background on nanotechnology and an overview of how properties change at the nanoscale.
This document summarizes a seminar presentation about irradiation effects in high melting oxides and the synthesis of new luminescent composite materials. The presentation covered self-introduction of the speaker, introduction to the topic, purpose of the study which was to investigate irradiation effects in oxides like MgAl2O4 and α-Al2O3 as well as synthesize luminescent composites. Experimental methods used included irradiation of samples using neutrons and electrons followed by measurement techniques like photoluminescence spectroscopy. Results showed irradiation induced defects in oxides and conversion of Sm3+ to Sm2+ in Na2SO4 under irradiation. In conclusion, irradiation was found to modify optical and structural properties of materials.
Bismuth ferrite is a multiferroic material with rhombohedral crystal structure and Curie and Neel temperatures of 825°C and 360°C respectively. It exhibits ferroelectricity and ferromagnetism simultaneously. Bismuth ferrite nanoparticles were synthesized using a sol-gel method, which is a bottom-up approach involving hydrolysis and condensation of bismuth nitrate, iron nitrate, and citric acid precursors. The nanoparticles were characterized using X-ray diffraction, which confirmed the hexagonal crystal structure and an average crystalline size of 33.87 nm. Nanoparticle-based technologies are important for developing advanced applications in areas such as memory devices, telecommunications, and
Synthesis Of Nanostructured TiO2 Thin Films By Pulsed Laser Deposition (PLD) ...sarmad
Sarmad Sabih Al-Obaidi
Ali Ahmed Yousif
Abstract
In this work, nanostructured TiO2 thin films were grown by pulsed laser deposition (PLD) technique on glass substrates. TiO2 thin films then were annealed at 400-600 °C in air for a period of 2 hours. Effect of annealing on the structural and morphological were studied. Many growth parameters have been considered to specify the optimum conditions, namely substrate temperature (300 °C), oxygen pressure (10-2 Torr), laser fluence energy density (0.4 J/cm2), using double frequency Q-switching Nd:YAG laser beam (wavelength 532nm), repetition rate (1-6 Hz) and the pulse duration of 10 ns. The results of the X-ray test show that all nanostructures tetragonal are polycrystalline. These results show that grain size increase from 19.5 nm to 29.5 with the increase of annealing temperature. The XRD results also reveal that the deposited thin film, annealed at 400 °C of TiO2 have anatase phase. Thin films annealed at 500 °C and 600 °C have mixed anatase and rutile phases. Full Width at Half Maximum (FWHM) values of the (101) peaks of these films decrease from 0.450° to 0.301° with the increase of annealing temperature. Surface morphology of the thin films have been studied by using atomic force microscopes (AFM). AFM measurements confirmed that the films have good crystalline and homogeneous surface. The Root Mean Square (RMS) value of thin films surface roughness are increased with the increase of annealing temperature.
الخلاصة
على (PLD) النانویة بوساطة تقنیة ترسیب اللیزر النبضي (TiO في ھذا البحث، تم انماء أغشیة اوكسید التیتانیوم ( 2
الرقیقة من 400 الى 600 درجة مئویة في الھواء مدة ساعتین . ودرس تأثیر TiO قواعد زجاجیة. ومن ثم لدنت أغشیة 2
التلدین في الخصائص التركیبیة والطبوغرافیة. عوامل عدیدة لأنماء الأغشیة اخذت بنظر الاعتبار لتحدید الحالة المثلى مثل
0.4 ) باستخدام J/cm 10-2 ) ،كثافة طاقة الفیض اللیزري( 2 Torr) 300 ) ،ضغط الأوكسجین ºC) درجة حرارة القاعدة
532 بمعدل تكراریة - 1 nm التردد المضاعف للیزر النیدیمیوم- یاك الذي یعمل بتقنیة عامل النوعیة عند الطول الموجي
6 ھرتز) وامد نبضة 10 نانوثانیة. تظُھر نتائج فحوصات الأشعة السینیة أن جمیع التراكیب النانویة رباعیة متعددة )
التبلور. وان ھذه النتائج تظھر زیادة في حجم الحبیبات من 19.5 نانومتر الى 29.5 نانومترمع زیادة درجة حرارة التلدین.
نتائج الأشعة السینیة اظھرت ایضا ان الغشاء المرسب والملدن في 400 درجة مئویة لثنائي اوكسید
This document provides an overview of a lecture series on nanomaterials science and technology. It contains 5 lectures that cover topics such as an introduction to nanoscience and nanotechnology, fabrication of nanomaterials, physical and chemical properties of nanomaterials, carbon nanotubes and their applications, and applications of nanomaterials in areas like materials technology, electronics, energy, and biomedicine. The document includes presentation slides with content on definitions, production methods, quantum confinement effects, carbon nanotube structure, and examples of uses for nanomaterials.
Studying photnic crystals in linear and nonlinear mediaIslam Kotb Ismail
This document outlines a presentation on photonic crystals and nonlinear optics. It discusses:
- What photonic crystals are and how they inhibit light propagation through periodic refractive index patterns. Maxwell's equations are used to model light propagation in these structures.
- Common photonic crystal topologies in 1D, 2D and 3D, including photonic bandgap properties. Applications like mirrors and waveguides are mentioned.
- How nonlinear optical effects like the Pockels and Kerr effects modify a material's refractive index with an electric field. Nonlinear photonic crystals combine these effects.
- The document concludes by proposing nonlinear photonic crystals can act as optical limiters that regulate light transmission intensity.
This document discusses various nanofabrication techniques and photoresist materials. It begins by explaining the benefits of nanotechnology including higher reactivity, better mechanical strength, and designed physical properties. It then describes methods of nano-manipulation and micro/nanofabrication including photolithography, soft lithography, deposition, etching, and bonding. Photolithography and electron beam lithography processes are explained in detail. Finally, it discusses various types of nanolithography such as optical, X-ray, electron beam, nanoimprint, scanning probe, and charged particle lithography.
Sonia Katdare Research Presentation 2008soniakatdare
Sonia Katdare conducted research on the synthesis and characterization of gold nanoparticles. She used a bottom-up foam-based chemical synthesis method to produce gold nanoparticles by reducing gold ions trapped at the interface between gas bubbles and liquid in an aqueous foam. Characterization using UV-vis spectroscopy, XRD, and TEM showed that mono-dispersed spherical gold nanoparticles around 19nm in size were produced using this method. The foam-based synthesis provides control over nanoparticle size and morphology based on reaction conditions like gas pressure and drainage rate.
X-ray crystallography uses X-rays to determine the atomic structure of crystals. When X-rays hit a crystal, they cause the electrons in the crystal to diffract the X-rays into specific directions. By measuring the angles and intensities of these diffracted X-rays, a three-dimensional picture of electron density within the crystal can be produced to determine the positions of atoms and their bonds. Bragg's law describes X-ray diffraction from crystals and states that diffraction occurs when the path length difference between X-rays reflected from successive crystal planes is an integer multiple of the wavelength. X-ray crystallography has numerous applications including determining crystal structures, identifying impurities, and analyzing chemical composition.
Characterization of nanoparticles & its regulatory aspectsvivek vyas
This document summarizes techniques for characterizing nanoparticles, including particle size, shape, surface charge, crystal structure, yield, drug entrapment efficiency, and in vitro drug release. Key characterization techniques mentioned are microscopy (SEM, TEM), laser light scattering, zeta potential measurement, XRD, FTIR, and dialysis-based in vitro release testing. Regulatory considerations for nanoparticles are also briefly discussed.
This document discusses various spectroscopy techniques including UV-visible spectroscopy, flame photometry, atomic absorption spectroscopy, circular dichroism, optical rotatory dispersion, electron spin resonance (ESR), and nuclear magnetic resonance (NMR) spectroscopy. It provides details on the principles, instrumentation, applications, and limitations of these techniques. The key applications mentioned are detection of impurities, structure elucidation, quantitative and qualitative analysis, and studying chemical kinetics, drugs, and metals in samples.
Nanotechnology involves working with materials at the nanoscale, between 1 to 100 nanometers. There are top-down and bottom-up approaches to creating nanoparticles. Top-down involves breaking bulk materials into nanoparticles while bottom-up involves building nanoparticles from individual atoms or molecules. Nanoparticles can be created through various methods including attrition, pyrolysis, and liquid phase techniques like sol-gel and microemulsions. Nanoparticles find applications in areas like batteries and 3D printing.
Greener cum chemical synthesis and characterization of Mg doped ZnS nanoparti...IJERA Editor
In the present investigations, high-quality Mg doped ZnS nanoparticles were synthesized by Greener cum
chemical process with the assistance of polyvinyl pyrrolidone (PVP) with two different Mg concentrations.
Doping of Mg metal in nanoparticles were found to be a good technique for tuning the band gap of ZnS
nanoparticles. Simultaneously, Mg doping also inhibited the growth of particle size and it decreased from 33.2
nm to 18.3 nm with the increase in doping concentration from 0% to 5%. Band gap was found to rise from 3.12
eV to 3.38 eV and photoluminescence studies exposed that visible Photoluminescence (PL) emission was
improved with doping concentration. The nanoparticles have been characterized by Field Emission Scanning
Electron Microscopy (FESEM), X-Ray Diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy,
Ultra Violet visible (UV–vis) spectroscopy, and Energy Dispersive X-ray Analysis (EDAX).
Study of magnetic and structural and optical properties of Zn doped Fe3O4 nan...Nanomedicine Journal (NMJ)
Objective(s):
This paper describes synthesizing of magnetic nanocomposite with co-precipitation
method.
Materials and Methods:
Magnetic ZnxFe3-xO4 nanoparticles with 0-14% zinc doping (x=0, 0.025, 0.05, 0.075, 0.1 and 0.125) were successfully synthesized by co-precipitation method. The prepared zinc-doped Fe3O4 nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM) and UV-Vis spectroscopy.
Results:
results obtained from X-ray diffraction pattern have revealed the formation of single phase nanoparticles with cubic inverse spinal structures which size varies from 11.13 to 12.81 nm. The prepared nanoparticles have also possessed superparamagnetic properties at room temperature and high level of saturation magnetization with the maximum level of 74.60 emu/g for x=0.075. Ms changing in pure magnetite nanoparticles after impurities addition were explained based on two factors of “particles size” and “exchange interactions”. Optical studies results revealed that band gaps in all Zn-doped NPs are higher than pure Fe3O4. As doping percent increases, band gap value decreases from 1.26 eV to 0.43 eV.
Conclusion:
These magnetic nanocomposite structures since having superparamagnetic property
offer a high potential for biosensing and biomedical application.
Optical and Dielectric Studies on Semiorganic Nonlinear Optical Crystal by So...ijrap
The field of nonlinear optics became practically a reality after the invention of laser. High performance electro-optic switching elements for telecommunication and optical information processing are based on materials with high nonlinear optical (NLO) properties. Single crystals of nonlinear optical material Llysine sulphate (LLS) are grown by slow evaporation technique. The crystal structure and lattice parameters are determined for the grown crystal by single X-ray diffraction studies. The wide transparency range of the crystals in the visible region of the electromagnetic spectrum is identified by the UV-Vis-NIR technique. The mechanical property of the grown crystal is determined by Vicker’s microhardness test. It is observed from the microhardness studies of the grown crystals that the hardness increases with increase in load. Meyer’s index n is calculated which proves that the material belongs to soft material category. The dielectric constant and dielectric loss are calculated by varying the frequencies at room temperature. The emission of green light on passing the Nd: YAG laser confirms the second harmonic generation (SHG) property of the crystals .The SHG efficiency of the crystals are found to be better than that of Potassium Di hydrogen Phosphate (KDP)
X- Rays were discovered by Wilhelm Roentgen, so x-rays are also called Roentgen rays.
X-ray diffraction in crystals was discovered by Max von Laue. The wavelength range is 10-7 to about 10-15 m.
The penetrating power of x-rays depends on energy-
Hard x-rays: High frequency & More energy
Soft x-rays: Less penetrating & Low energy
X-rays are short-wavelength electromagnetic radiations produced by the deceleration of high energy electrons or by electronic transitions of electrons in the inner orbital of atoms.
X-ray region- 0.1-100 A˚
Analytical purpose- 0.7-2 A˚
Properties: Highly penetrating invisible rays
Liberate minute amounts of heat on passing through matter
Not deflected by electric and magnetic fields
Poly energetic, having widespread energies and wavelengths
Cause ionization (adding or removing electrons in atoms and molecules)
Transmitted by (pass-through) healthy body tissue
Principle: X-ray diffraction is based on constructive interference of monochromatic x-rays and a crystalline sample.
The interaction of incident rays with the sample produces constructive interference when conditions satisfy Bragg’s law.
Production of x rays: X- Rays are generated when the high velocity of electrons impinge on a metal target.
1% of total energy of the electron beam is converted into X –radiation.
Biomedical Application of Magnetic NanomaterialsMahmudun Nabi
This document discusses a project to characterize magnetic nanoparticles for use in biomedical applications. The objectives are to:
1. Characterize the magnetic nanoparticles and study their AC susceptibility, size distribution, magnetic properties, and relaxation to determine parameters like magnetic moment and blocking temperature.
2. Develop a system to detect biological targets using magnetic nanoparticles and improve the system's sensitivity.
3. Validate the magnetic immunoassay technique by comparing results to conventional methods and analyzing outcomes for biological targets.
Nanoparticle Size and Shape Separation using Size Exclusion ChromatographyShakil Ahmed
This document discusses using size exclusion chromatography (SEC) to separate nanoparticles by size and potentially shape. Spherical silver nanoparticles of different sizes were synthesized and characterized with dynamic light scattering. SEC experiments with just spheres showed inconclusive separation that was likely only due to particle size. Cubic silver nanoparticles were also synthesized and characterized. Initial SEC experiments mixing spheres and cubes showed little contribution from the cubes. Future work involves taking SEM images before and after SEC, improving particle monodispersity and purity, and finding alternative ways to prevent nanoparticle adsorption to the SEC column. SEC shows promise for low-resolution nanoparticle separation but requires more experimentation to confirm separation by shape as well as size.
Controlling sound transmission with density-near-zero acoustic membrane networkellunatico69
This document describes a design for a density-near-zero (DNZ) acoustic membrane network that can control sound transmission. The network is made of circular membranes arranged in a square lattice inside a waveguide. The unit cell is modeled as an equivalent lumped-circuit of inductors and capacitors. Simulations show the effective mass density approaches zero near 987 Hz, the resonance frequency predicted by the circuit model, demonstrating DNZ behavior. Further simulations then examine how the DNZ membrane network can achieve applications like cloaking, high transmission through sharp corners, and wave splitting.
Periodic structures can effectively suppress vibrations through the use of stop bands. Stop bands are frequency ranges where vibrations are unable to propagate through a periodic structure. Two types of periodic structures are phononic crystals and locally resonant structures. Phononic crystals use a repeating pattern of multiple materials to generate stop bands. Mathematical models and simulations show that a phononic crystal structure is able to attenuate vibrations within stop band frequencies, while a uniform structure does not. Locally resonant structures contain internal resonators that interact with a base structure to also produce stop bands. Both types of periodic structures have potential to isolate delicate spacecraft components from vibrations.
This document summarizes a seminar presentation about irradiation effects in high melting oxides and the synthesis of new luminescent composite materials. The presentation covered self-introduction of the speaker, introduction to the topic, purpose of the study which was to investigate irradiation effects in oxides like MgAl2O4 and α-Al2O3 as well as synthesize luminescent composites. Experimental methods used included irradiation of samples using neutrons and electrons followed by measurement techniques like photoluminescence spectroscopy. Results showed irradiation induced defects in oxides and conversion of Sm3+ to Sm2+ in Na2SO4 under irradiation. In conclusion, irradiation was found to modify optical and structural properties of materials.
Bismuth ferrite is a multiferroic material with rhombohedral crystal structure and Curie and Neel temperatures of 825°C and 360°C respectively. It exhibits ferroelectricity and ferromagnetism simultaneously. Bismuth ferrite nanoparticles were synthesized using a sol-gel method, which is a bottom-up approach involving hydrolysis and condensation of bismuth nitrate, iron nitrate, and citric acid precursors. The nanoparticles were characterized using X-ray diffraction, which confirmed the hexagonal crystal structure and an average crystalline size of 33.87 nm. Nanoparticle-based technologies are important for developing advanced applications in areas such as memory devices, telecommunications, and
Synthesis Of Nanostructured TiO2 Thin Films By Pulsed Laser Deposition (PLD) ...sarmad
Sarmad Sabih Al-Obaidi
Ali Ahmed Yousif
Abstract
In this work, nanostructured TiO2 thin films were grown by pulsed laser deposition (PLD) technique on glass substrates. TiO2 thin films then were annealed at 400-600 °C in air for a period of 2 hours. Effect of annealing on the structural and morphological were studied. Many growth parameters have been considered to specify the optimum conditions, namely substrate temperature (300 °C), oxygen pressure (10-2 Torr), laser fluence energy density (0.4 J/cm2), using double frequency Q-switching Nd:YAG laser beam (wavelength 532nm), repetition rate (1-6 Hz) and the pulse duration of 10 ns. The results of the X-ray test show that all nanostructures tetragonal are polycrystalline. These results show that grain size increase from 19.5 nm to 29.5 with the increase of annealing temperature. The XRD results also reveal that the deposited thin film, annealed at 400 °C of TiO2 have anatase phase. Thin films annealed at 500 °C and 600 °C have mixed anatase and rutile phases. Full Width at Half Maximum (FWHM) values of the (101) peaks of these films decrease from 0.450° to 0.301° with the increase of annealing temperature. Surface morphology of the thin films have been studied by using atomic force microscopes (AFM). AFM measurements confirmed that the films have good crystalline and homogeneous surface. The Root Mean Square (RMS) value of thin films surface roughness are increased with the increase of annealing temperature.
الخلاصة
على (PLD) النانویة بوساطة تقنیة ترسیب اللیزر النبضي (TiO في ھذا البحث، تم انماء أغشیة اوكسید التیتانیوم ( 2
الرقیقة من 400 الى 600 درجة مئویة في الھواء مدة ساعتین . ودرس تأثیر TiO قواعد زجاجیة. ومن ثم لدنت أغشیة 2
التلدین في الخصائص التركیبیة والطبوغرافیة. عوامل عدیدة لأنماء الأغشیة اخذت بنظر الاعتبار لتحدید الحالة المثلى مثل
0.4 ) باستخدام J/cm 10-2 ) ،كثافة طاقة الفیض اللیزري( 2 Torr) 300 ) ،ضغط الأوكسجین ºC) درجة حرارة القاعدة
532 بمعدل تكراریة - 1 nm التردد المضاعف للیزر النیدیمیوم- یاك الذي یعمل بتقنیة عامل النوعیة عند الطول الموجي
6 ھرتز) وامد نبضة 10 نانوثانیة. تظُھر نتائج فحوصات الأشعة السینیة أن جمیع التراكیب النانویة رباعیة متعددة )
التبلور. وان ھذه النتائج تظھر زیادة في حجم الحبیبات من 19.5 نانومتر الى 29.5 نانومترمع زیادة درجة حرارة التلدین.
نتائج الأشعة السینیة اظھرت ایضا ان الغشاء المرسب والملدن في 400 درجة مئویة لثنائي اوكسید
This document provides an overview of a lecture series on nanomaterials science and technology. It contains 5 lectures that cover topics such as an introduction to nanoscience and nanotechnology, fabrication of nanomaterials, physical and chemical properties of nanomaterials, carbon nanotubes and their applications, and applications of nanomaterials in areas like materials technology, electronics, energy, and biomedicine. The document includes presentation slides with content on definitions, production methods, quantum confinement effects, carbon nanotube structure, and examples of uses for nanomaterials.
Studying photnic crystals in linear and nonlinear mediaIslam Kotb Ismail
This document outlines a presentation on photonic crystals and nonlinear optics. It discusses:
- What photonic crystals are and how they inhibit light propagation through periodic refractive index patterns. Maxwell's equations are used to model light propagation in these structures.
- Common photonic crystal topologies in 1D, 2D and 3D, including photonic bandgap properties. Applications like mirrors and waveguides are mentioned.
- How nonlinear optical effects like the Pockels and Kerr effects modify a material's refractive index with an electric field. Nonlinear photonic crystals combine these effects.
- The document concludes by proposing nonlinear photonic crystals can act as optical limiters that regulate light transmission intensity.
This document discusses various nanofabrication techniques and photoresist materials. It begins by explaining the benefits of nanotechnology including higher reactivity, better mechanical strength, and designed physical properties. It then describes methods of nano-manipulation and micro/nanofabrication including photolithography, soft lithography, deposition, etching, and bonding. Photolithography and electron beam lithography processes are explained in detail. Finally, it discusses various types of nanolithography such as optical, X-ray, electron beam, nanoimprint, scanning probe, and charged particle lithography.
Sonia Katdare Research Presentation 2008soniakatdare
Sonia Katdare conducted research on the synthesis and characterization of gold nanoparticles. She used a bottom-up foam-based chemical synthesis method to produce gold nanoparticles by reducing gold ions trapped at the interface between gas bubbles and liquid in an aqueous foam. Characterization using UV-vis spectroscopy, XRD, and TEM showed that mono-dispersed spherical gold nanoparticles around 19nm in size were produced using this method. The foam-based synthesis provides control over nanoparticle size and morphology based on reaction conditions like gas pressure and drainage rate.
X-ray crystallography uses X-rays to determine the atomic structure of crystals. When X-rays hit a crystal, they cause the electrons in the crystal to diffract the X-rays into specific directions. By measuring the angles and intensities of these diffracted X-rays, a three-dimensional picture of electron density within the crystal can be produced to determine the positions of atoms and their bonds. Bragg's law describes X-ray diffraction from crystals and states that diffraction occurs when the path length difference between X-rays reflected from successive crystal planes is an integer multiple of the wavelength. X-ray crystallography has numerous applications including determining crystal structures, identifying impurities, and analyzing chemical composition.
Characterization of nanoparticles & its regulatory aspectsvivek vyas
This document summarizes techniques for characterizing nanoparticles, including particle size, shape, surface charge, crystal structure, yield, drug entrapment efficiency, and in vitro drug release. Key characterization techniques mentioned are microscopy (SEM, TEM), laser light scattering, zeta potential measurement, XRD, FTIR, and dialysis-based in vitro release testing. Regulatory considerations for nanoparticles are also briefly discussed.
This document discusses various spectroscopy techniques including UV-visible spectroscopy, flame photometry, atomic absorption spectroscopy, circular dichroism, optical rotatory dispersion, electron spin resonance (ESR), and nuclear magnetic resonance (NMR) spectroscopy. It provides details on the principles, instrumentation, applications, and limitations of these techniques. The key applications mentioned are detection of impurities, structure elucidation, quantitative and qualitative analysis, and studying chemical kinetics, drugs, and metals in samples.
Nanotechnology involves working with materials at the nanoscale, between 1 to 100 nanometers. There are top-down and bottom-up approaches to creating nanoparticles. Top-down involves breaking bulk materials into nanoparticles while bottom-up involves building nanoparticles from individual atoms or molecules. Nanoparticles can be created through various methods including attrition, pyrolysis, and liquid phase techniques like sol-gel and microemulsions. Nanoparticles find applications in areas like batteries and 3D printing.
Greener cum chemical synthesis and characterization of Mg doped ZnS nanoparti...IJERA Editor
In the present investigations, high-quality Mg doped ZnS nanoparticles were synthesized by Greener cum
chemical process with the assistance of polyvinyl pyrrolidone (PVP) with two different Mg concentrations.
Doping of Mg metal in nanoparticles were found to be a good technique for tuning the band gap of ZnS
nanoparticles. Simultaneously, Mg doping also inhibited the growth of particle size and it decreased from 33.2
nm to 18.3 nm with the increase in doping concentration from 0% to 5%. Band gap was found to rise from 3.12
eV to 3.38 eV and photoluminescence studies exposed that visible Photoluminescence (PL) emission was
improved with doping concentration. The nanoparticles have been characterized by Field Emission Scanning
Electron Microscopy (FESEM), X-Ray Diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy,
Ultra Violet visible (UV–vis) spectroscopy, and Energy Dispersive X-ray Analysis (EDAX).
Study of magnetic and structural and optical properties of Zn doped Fe3O4 nan...Nanomedicine Journal (NMJ)
Objective(s):
This paper describes synthesizing of magnetic nanocomposite with co-precipitation
method.
Materials and Methods:
Magnetic ZnxFe3-xO4 nanoparticles with 0-14% zinc doping (x=0, 0.025, 0.05, 0.075, 0.1 and 0.125) were successfully synthesized by co-precipitation method. The prepared zinc-doped Fe3O4 nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometer (VSM) and UV-Vis spectroscopy.
Results:
results obtained from X-ray diffraction pattern have revealed the formation of single phase nanoparticles with cubic inverse spinal structures which size varies from 11.13 to 12.81 nm. The prepared nanoparticles have also possessed superparamagnetic properties at room temperature and high level of saturation magnetization with the maximum level of 74.60 emu/g for x=0.075. Ms changing in pure magnetite nanoparticles after impurities addition were explained based on two factors of “particles size” and “exchange interactions”. Optical studies results revealed that band gaps in all Zn-doped NPs are higher than pure Fe3O4. As doping percent increases, band gap value decreases from 1.26 eV to 0.43 eV.
Conclusion:
These magnetic nanocomposite structures since having superparamagnetic property
offer a high potential for biosensing and biomedical application.
Optical and Dielectric Studies on Semiorganic Nonlinear Optical Crystal by So...ijrap
The field of nonlinear optics became practically a reality after the invention of laser. High performance electro-optic switching elements for telecommunication and optical information processing are based on materials with high nonlinear optical (NLO) properties. Single crystals of nonlinear optical material Llysine sulphate (LLS) are grown by slow evaporation technique. The crystal structure and lattice parameters are determined for the grown crystal by single X-ray diffraction studies. The wide transparency range of the crystals in the visible region of the electromagnetic spectrum is identified by the UV-Vis-NIR technique. The mechanical property of the grown crystal is determined by Vicker’s microhardness test. It is observed from the microhardness studies of the grown crystals that the hardness increases with increase in load. Meyer’s index n is calculated which proves that the material belongs to soft material category. The dielectric constant and dielectric loss are calculated by varying the frequencies at room temperature. The emission of green light on passing the Nd: YAG laser confirms the second harmonic generation (SHG) property of the crystals .The SHG efficiency of the crystals are found to be better than that of Potassium Di hydrogen Phosphate (KDP)
X- Rays were discovered by Wilhelm Roentgen, so x-rays are also called Roentgen rays.
X-ray diffraction in crystals was discovered by Max von Laue. The wavelength range is 10-7 to about 10-15 m.
The penetrating power of x-rays depends on energy-
Hard x-rays: High frequency & More energy
Soft x-rays: Less penetrating & Low energy
X-rays are short-wavelength electromagnetic radiations produced by the deceleration of high energy electrons or by electronic transitions of electrons in the inner orbital of atoms.
X-ray region- 0.1-100 A˚
Analytical purpose- 0.7-2 A˚
Properties: Highly penetrating invisible rays
Liberate minute amounts of heat on passing through matter
Not deflected by electric and magnetic fields
Poly energetic, having widespread energies and wavelengths
Cause ionization (adding or removing electrons in atoms and molecules)
Transmitted by (pass-through) healthy body tissue
Principle: X-ray diffraction is based on constructive interference of monochromatic x-rays and a crystalline sample.
The interaction of incident rays with the sample produces constructive interference when conditions satisfy Bragg’s law.
Production of x rays: X- Rays are generated when the high velocity of electrons impinge on a metal target.
1% of total energy of the electron beam is converted into X –radiation.
Biomedical Application of Magnetic NanomaterialsMahmudun Nabi
This document discusses a project to characterize magnetic nanoparticles for use in biomedical applications. The objectives are to:
1. Characterize the magnetic nanoparticles and study their AC susceptibility, size distribution, magnetic properties, and relaxation to determine parameters like magnetic moment and blocking temperature.
2. Develop a system to detect biological targets using magnetic nanoparticles and improve the system's sensitivity.
3. Validate the magnetic immunoassay technique by comparing results to conventional methods and analyzing outcomes for biological targets.
Nanoparticle Size and Shape Separation using Size Exclusion ChromatographyShakil Ahmed
This document discusses using size exclusion chromatography (SEC) to separate nanoparticles by size and potentially shape. Spherical silver nanoparticles of different sizes were synthesized and characterized with dynamic light scattering. SEC experiments with just spheres showed inconclusive separation that was likely only due to particle size. Cubic silver nanoparticles were also synthesized and characterized. Initial SEC experiments mixing spheres and cubes showed little contribution from the cubes. Future work involves taking SEM images before and after SEC, improving particle monodispersity and purity, and finding alternative ways to prevent nanoparticle adsorption to the SEC column. SEC shows promise for low-resolution nanoparticle separation but requires more experimentation to confirm separation by shape as well as size.
Controlling sound transmission with density-near-zero acoustic membrane networkellunatico69
This document describes a design for a density-near-zero (DNZ) acoustic membrane network that can control sound transmission. The network is made of circular membranes arranged in a square lattice inside a waveguide. The unit cell is modeled as an equivalent lumped-circuit of inductors and capacitors. Simulations show the effective mass density approaches zero near 987 Hz, the resonance frequency predicted by the circuit model, demonstrating DNZ behavior. Further simulations then examine how the DNZ membrane network can achieve applications like cloaking, high transmission through sharp corners, and wave splitting.
Periodic structures can effectively suppress vibrations through the use of stop bands. Stop bands are frequency ranges where vibrations are unable to propagate through a periodic structure. Two types of periodic structures are phononic crystals and locally resonant structures. Phononic crystals use a repeating pattern of multiple materials to generate stop bands. Mathematical models and simulations show that a phononic crystal structure is able to attenuate vibrations within stop band frequencies, while a uniform structure does not. Locally resonant structures contain internal resonators that interact with a base structure to also produce stop bands. Both types of periodic structures have potential to isolate delicate spacecraft components from vibrations.
This document summarizes research on hypersonic phononic crystals conducted by Edwin L. Thomas at MIT. Key points:
1) Phononic crystals have periodic variations in density and elastic constants that create band gaps for sound/mechanical waves, allowing uses like sound isolation. The research focuses on hypersonic crystals with 100nm features for enhancing acousto-optical interactions.
2) Hypersonic phononic crystals with band gaps in the GHz frequency range were fabricated using interference lithography and their phonon dispersion was measured using Brillouin light scattering, demonstrating the first experimentally observed band gap at hypersonic frequencies.
3) The grant supported graduate students working on fabricating the crystals using
This document discusses phononic crystals and acoustic metamaterials. Phononic crystals are periodically arranged materials that can strongly confine, diffract, and disperse elastic waves. They can create band gaps where waves become evanescent, and exhibit phenomena like negative refraction. Experiments have demonstrated band gaps, tunneling, confinement in defects, and locally resonant acoustic shields. Future work includes developing three-dimensional phononic crystals and incorporating phononic structures into surface acoustic wave and Lamb wave devices to control elastic waves at higher frequencies.
1. The document summarizes work using computational modeling and experiments to characterize the elastic properties of freestanding silicon nanomembranes under different loading conditions.
2. Finite element analysis is used to model the deflection, strain, and vibrational modes of nanomembranes subjected to concentrated point loads and uniform pressure.
3. The results of modeling are compared to analytical calculations and experimental measurements to validate the models and determine effective elastic constants at the nanoscale.
This document aims at presenting Nanophononics to attract all the relevant stakeholders and help them to synergize into a vast but sound and well defined field. This call is made in direction of academic members, industries, SMEs and governmental organizations to join the European nanophononics community (www.euphonon.eu)
Synthesis, Growth and Characterization of Nonlinear Optical Semi Organic Pota...IRJET Journal
The document summarizes the synthesis, growth, and characterization of Potassium Sulphate Formate (PSF) single crystals grown by slow evaporation method. PSF crystals were grown by dissolving equimolar ratios of Potassium Sulphate and Formic acid in water. Single crystal XRD analysis confirmed the crystals belong to the orthorhombic system with space group Pna21. Powder XRD and FTIR analysis verified the crystallinity and functional groups. UV-Vis spectroscopy determined the optical transmission range and bandgap. Thermal analysis and SHG measurements showed the crystals have good thermal stability and higher SHG efficiency than KDP.
Optical Properties of Mesoscopic Systems of Coupled MicrospheresShashaanka Ashili
Two mechanisms of optical coupling between spherical cavities, tight-binding between their whispering gallery modes and focusing produced by periodically coupled microlenses, are directly observed using spatially resolved scattering spectroscopy and imaging. The results can be used for developing device concepts of lasers, optical filters, microspectrometers and sensors based on mesoscopic systems of coupled microspheres.
X-ray crystallography uses X-rays to determine the atomic structure of crystals. Crystals are bombarded with X-rays, which diffract upon contact with the atoms in the crystal. The angles and intensities of the diffracted X-rays are measured to deduce the positions of atoms in the crystal. This technique is useful for visualizing protein structures and identifying unknown crystal structures. It involves growing a crystal, exposing it to X-rays, and computationally analyzing the diffraction pattern to produce an atomic model of the crystal structure. X-ray crystallography has applications in characterizing polymers, assessing metal fatigue, and soil classification.
Synthesis and characterization of structural and Magnetic Properties of ZnO d...IRJET Journal
This document summarizes research on synthesizing and characterizing ZnO-doped SnO2 nano composites. It discusses:
1. Using a microwave-assisted co-precipitation method to synthesize SnO2-ZnO nano composite samples with varying calcination temperatures from 200-600°C.
2. Characterizing the samples using XRD, FTIR, UV-Vis, and VSM. XRD and FTIR confirmed the formation of nano composites.
3. Magnetic characterization using VSM showed the samples exhibited soft ferromagnetic behavior, with coercivity and retentivity decreasing slightly as calcination temperature increased.
EFFECT OF ULTRAVIOLET RADIATION ON STRUCTURAL PROPERTIES OF NANOWIRESijoejournal
Copper nanowires were prepared through electrochemical template synthesis using Nucleopore polycarbonate membranes having nominal pore sizes of 800nm and 15nm diameter. The 800nm and 15nm nanowires thus grown were viewed under SEM and TEM respectively, while their FCC crystallographic structure was confirmed through X-ray and electron diffraction patterns. The X-ray diffraction peaks indicated strong texturing for (200). The texturing was found to reduce significantly upon exposure to ultraviolet radiation.
X-ray crystallography is a technique used to determine the three-dimensional atomic structure of crystals. X-rays are diffracted by the crystal and the diffraction pattern is collected on a detector. By analyzing the diffraction pattern using Bragg's law and Fourier transforms, scientists can construct electron density maps and refine protein structures at high resolution. Key aspects of X-ray crystallography include generating X-rays, collecting diffraction data, solving protein structures, and refining models using computational methods. This technique has provided atomic level insights into protein structure and been instrumental in numerous scientific discoveries through applications like determining unknown material structures.
Calculation of Optical Properties of Nano ParticlePHYSICS 5535- .docxRAHUL126667
Calculation of Optical Properties of Nano Particle
PHYSICS 5535- Optical Properties Matter-Spring 2017
Raznah Yami
Outline
1. Introduction: this part gives a precise overview of the whole paper. It begins by illustrating a brief introduction and importance of Nano Particles and the theoretical approaches used for their calculation.
2. Main idea: this section provides a step-by-step in-depth analysis of recently developed theories the calculation of optical properties of nanoparticles. It also provides calculation and equations employed these approaches.
2.1 Optical Properties of Nanoparticles: this section talks about the basics principles and governing the optical behavior of Nano particles and provides in-depth knowledge of different phenomena observed while dealing with optical properties of Nano particles.
2.2 Mie-Theory: the research provides exhaustive information the study optical properties of nanoparticles using Mie theory. This research focuses on Mie theory for the calculation of optical properties of Nano particle according to which we can calculate the place of surface Plasmon resonance in optical spectra of metallic spherical nanoparticle.
2.3 Discrete Dipole Approximation method: this section enumerates sufficient information about the calculation of absorption and scattering efficiencies and optical resonance wavelengths for three commonly used classes of nanoparticles: gold Nano spheres, silica-gold Nano shells, and gold Nano rods and we examine the magneto-optical scattering from nanometer-scale structures using a discrete dipole approximation.
3. Conclusion: This section provides a summary of the most important points, which presents an overview of the practical application and calculation methods of optical properties of Nano particles talking about core principles, which therefore explain the behavior exhibited by nanoparticles.
List of figures:
Figure 1: Localized surface Plasmon resonance ,resulting from the collective oscillations of delocalized electrons in response to an external electric field
Figure 2: Absorption spectra of semiconductor nanoparticles of different diameter. Right-nanoparticles suspended in solution.
Figure 3: Comparison of absorbance along increasing wavelength between Nano GaAs (7-15 nm) and Bulk GaAs showing an apparent blue shift
Figure 4: Showing the effect of blue shift because of quantum confinement as the wavelength shifts from 1100 nm to 2000 nm when we move from particle size of 9nm to parcile size of 3 nm.
Figure 5: Emission spectra of several sizes of (Cdse) Zns core-shell quantum dots.
Figure 6: The optical spectra and transmission electron micrographs for the particles in vials 1–5 are also shown. Scale bars in micrographs are all 100 nm
Figure7: Shows the effect of varying relative core and shell thickness of gold Nano Shells, there is an apparent blue shift as the frequency increases
References:
1. . P. S. Per ...
Study of highly broadening Photonic band gaps extension in one-dimensional Me...IOSR Journals
This document discusses the theoretical study of enhancing the reflectance spectra of one-dimensional metallo-organic multilayer photonic structures. It examines structures composed of alternating thin layers of silver and the organic material N,N'-bis-(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine. The transfer matrix method is used to calculate the reflectance spectra for different configurations of layer thicknesses and incident angles of light. Tuning of the photonic band gap is observed by varying the thickness of either the metal or organic layers. Broadening and shifting of the band edges from ultraviolet to visible and infrared regions occurs due to the optical absorption properties of both the
This thesis investigates the direct laser writing of fluorescent microstructures containing silver nanoclusters in polyvinyl alcohol films. Polymer thin films were prepared by spin-coating PVA solutions containing silver nitrate. A continuous-wave laser at 405 nm was used to perform single-photon direct laser writing on the films by tightly focusing the beam and scanning the sample. Photoluminescence of the structures was studied using fluorescence microscopy and spectroscopy. Atomic force microscopy was used to characterize the film thickness and written structures. The results showed broadband visible fluorescence from the silver nanoclusters. Fluorescence intensity depended on silver concentration and writing laser power. The silver nanoclusters exhibited photostable fluorescence and were similar to nanoclusters stabilized in organic solutions
International Journal of Computational Engineering Research (IJCER) is dedicated to protecting personal information and will make every reasonable effort to handle collected information appropriately. All information collected, as well as related requests, will be handled as carefully and efficiently as possible in accordance with IJCER standards for integrity and objectivity.
2005 when x rays modify-protein_structure_radiationd_amage at workOsama Abdulkareem
This document discusses radiation damage that can occur during X-ray crystallography experiments used to determine protein structures. When X-rays interact with protein crystals, they can damage the crystals through ionization and the generation of free radicals. This radiation damage can modify the protein structure being analyzed from its native state. A new technique called "multi-crystal data collection" is described that allows determining the structures of different redox states of proteins by collecting data from multiple crystals exposed to different radiation doses. This helps characterize protein structures before they are altered by radiation damage during data collection.
This document summarizes research on using metallic nanostructures to enhance fluorescence. Specifically, it proposes using "stair-gratings" - nanostructures with corrugations that have an excavated rectangular section to create a stair-like profile. Experiments show that stair-gratings provide higher fluorescence enhancement and narrower emission directionality compared to conventional gratings, covering both the excitation and emission bands of fluorophores. Finite-difference time-domain simulations agree with experimental results, demonstrating the potential of stair-gratings for applications requiring enhanced and directional single-molecule fluorescence.
This study used variable angle ellipsometry to characterize the optical properties of RF sputtered permalloy oxide (PyO) thin films in the infrared range. Analysis of the ellipsometry data revealed a Lorentzian dispersion peak at 381.5 cm-1, which is attributed to the transverse optical phonon of PyO and confirms the rocksalt crystal structure of the films. The phonon peak position was consistent across samples deposited at the same temperature, though properties like width and height varied, with their product remaining nearly constant. This study provides insight into the infrared optical behavior and crystal structure of sputtered PyO thin films.
This document is the dissertation of Zhang Yan for the degree of Ph.D. It summarizes his research on sputtering niobium films into RF cavities and sputtering of superconducting V3Si films. The dissertation contains 6 chapters that discuss sputtering techniques for niobium cavities, sputtering niobium films on an RFQ model, co-sputtering and reactive sputtering of V3Si films, and thermal diffusion of V3Si films. The research aimed to develop sputtering methods for producing superconducting coatings on RF cavities and investigate the properties of V3Si films for potential use in superconducting radio frequency applications.
X-ray crystallography is a technique used to determine the atomic and molecular structure of crystals. An X-ray beam is directed at a crystal and causes the beam to diffract into specific directions. The angles and intensities of the diffracted beams are used to produce a 3D image of electron density within the crystal. This allows determining the positions of atoms and chemical bonds within the crystal. There are several methods of X-ray crystallography including single crystal diffraction, powder diffraction, and rotating crystal techniques. Each method uses X-ray diffraction patterns to analyze crystal structure.
1. The document discusses various methods used to investigate the structure of fibers, including nuclear magnetic resonance, infrared spectroscopy, optical and x-ray diffraction, thermal analysis, optical microscopy, electron microscopy, and density measurement.
2. It provides details on specific techniques like nuclear magnetic resonance spectroscopy, optical diffraction, x-ray diffraction, and electron microscopy and electron diffraction. These techniques help determine properties of fibers like composition, molecular structure, crystallinity, and orientation.
3. The structure investigation of fibers is important to understand fiber properties in order to improve their use in textiles. Different methods are used to study characteristics like chemical bonding, molecular spacing, and cross-sectional structure.
1. The document discusses X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) techniques. It provides details on how XRD works using Bragg's law and can be used to determine crystal structure.
2. The morphology and composition of polypyrrole films decorated with copper nanoparticles were analyzed using scanning electron microscopy (SEM) and EDX. SEM images show the copper nanoparticles have different morphologies as deposition time increases.
3. EDX results show that the atomic percentage of copper in the films increases with more cycles of copper oxide deposition. The films were tested for their electrocatalytic activity towards glucose, and the polypyrrole/copper nanoparticle films
Analysis Of Carbon Nanotubes And Quantum Dots In A Photovoltaic DeviceM. Faisal Halim
Analysis of Carbon Nanotubes and Quantum Dots in a Photovoltaic Device
A poster prepared by Francis and me; presented by Francis. I modified on of the photographs used, in this copy.
The document describes a proposed design for trapping and imaging rubidium-85 ions using near-field scanning optical microscopy techniques. The design involves using three orthogonal laser beams to form an optical molasses trap for cooling rubidium ions. This trap will be assisted by an anti-Helmholtz coil pair to create a magneto-optical trap. Tapered optical fibers etched with hydrofluoric acid will be used as probes in near-field scanning optical microscopy to detect and image the trapped ions with high resolution. Fluorescence detection of the trapped ions will aim to optimize the signal-to-noise ratio using lock-in amplification.
Dario Scotto - Detecting and Imaging Magneto-Optically Trapped Rubidium-85 Io...
research report
1. 1
Phononic Crystals
Propagation and Visualization of waves
Zhe Yi Soo, Dr. Ankit Srivastava
Illinois Institute of Technology
Phononic crystal has gained a lot of interested recently due to its ability to control, direct, and manipulate sound
waves. However, it requires a carefully design and manufacture process. Hence, a better underastanding on phononic
crystal is needed. In this paper, we are going to use stress analysis technique, Photoelastic method to observe propagation
of stress waves in phononic crystal. Experiments set up for photoelastic method and the theory behind it will be explained
in this paper.
A solid-fluid phononic crystal will be simulated through Fenics in this paper and a solid-solid phononic crystal will be
done in future experiments. The result will be compared to simulation results using Fenics. Negative refraction and
focusing will be the main topic that we will be experimenting in phononic crystal.
I. INTRODUCTION
The field of phononic crystals emerged over the past
two decades. The reason for the emerging interest towards
phononic crystals is due to phononic crystals are novel
material that provides exceptional control over phonons,
sounds, and mechanical waves [1].
Negative refraction and focusing are some of those
interesting topics in phononic crystals. These special
properties of elastic waves can only be achieved by phononic
crystals and could lead to a lot of great applications in
industry or even daily life. Sound proofing, sound cancelling,
and focusing sound are some of those important applications
for industry. Mechanical waves are waves that propagate as
an oscillation of matter and transfer energy while travelling
through a medium. Since we are able to control the
properties of mechanical waves using phononic crystals,
which means transfers of energy in mechanical waves are
being controlled. Hence, this research topic can be related to
Engineerng themes – Energy area.
However, it requires a precise and careful design in
order to control propagation of waves. This requires a great
understanding of how waves propagate in phononic crystals.
A lot of work has been done describing propagation of waves
in phononic crystals using calculation or Finite Element
Method (FEM) but we are focusing on visualization of waves
in phononic crystals using stress analysis method.
Photoelastic visualization technique has been chosen in
this experiment in imaging propagation of waves in
Phononic crystals. By using this technique, it provides us a
clear and detail image of the elastic waves. Hence, a better
understanding of the fundamental nature of wave
propagation in Phononic crystals can be achieved. This could
be very useful in future study of phononic crystal as we are
no longer restricted to computer simulation and analyzation
for observation of wave propagation in phononic crystals.
Besides, it can shorten the experiment time in observation of
wave propagation on phononic crystals. These can lead to an
easier designing and understanding of phononic crystals in
the future.
Photoelastic method has been used in many areas in
order to visualize stress waves. A quantitative evaluation of
ultrasonic waves in glass using photoelastic method has been
done. Principle of photoelastic and experiment set up details
is explained in this paper. This paper presented both 2D and
3D of sound pressure as a result of photoelastic method [2].
Photoelastic method is used to investigate sound field and
pressure that is generated using phased array transducer.
Phased array transducer provides an easier angle control,
more precise focal point control, and easier imaging
inspection result. Quarts glass is being chosen as the medium
in this experiment. Directivity measurement is done using
photoelastic method and is compared with the result using
Finite Element Method [3]. Image processing technique for
photoelastic method has been explained in this paper.
Residual stress is being eliminated using the image
processing technique and hence showing a clearer and better
result of propagation of ultrasonic waves [4].
Since photoelastic method requires a solid medium, a
solid-solid phononic crystal is needed in order to conduct the
experiment. A two dimensional solid-solid phononic crystal
2. 2
has been created by using epoxy and steel rods in this paper.
The phononic crystals is made of triangular arrangement f
steel rods embedded in an epoxy matrix. Epoxy is chosen
due to its viscosity and waves speed which made negative
fraction and focusing possible. The structure in this paper has
been chosen for our research project and we will use
photoelastic method to analyze the propagation of waves in
this phononic crystal.
II. METHODS
A simulation was done using Cygwin code. By setting
the domain and the orientation of the phononic crystal based
on the information below, simulation can be done using
Finite Element Method. The code is written based on the
calculation of how waves will propagate in solid-solid case
phononic crystal. Paraview is a data analysis and
visualization software that is used to visualize the result.
The phononic crystal is made of a triangular
arrangement of steel rods embedded in an epoxy matrix. The
diameter of the steel rods are 2mm and the lattice parameter
is 2.84mm. Thus the filling factor of the epoxy matrix is
equal to 0.45. There are a total of 420 rods which 40 rods on
base and a height of 20 rods. The density of the steel is 7800
kg/m^3, the longitudinal wave velocities are 6180 m/s and
the transverse wave velocities are 3245 m/s. The density of
the epoxy is 1150 kg/m^3, the longitudinal wave velocities
are 2440 m/s and the transverse wave velocities are 1130 m/s
[5].
The source of 780 kHz which is around 8 times larger
than the longitudinal wavelength in the epoxy is being used.
This design of phononic crystal is used for observation of
negative refraction.
The focus on this paper is observation of properties of
waves using photoelastic method. The result of the
photoelastic method will be compared with the simulation
result.
Photoelastic method is a non-destructive, whole field,
graphic stress analysis technique. The advantages of
photoelastic are as below.
1. Provides reliable full-field values of the
difference between the principal normal
stresses in the plane of the model.
2. Provides uniquely the value of the non-
vanishing principal normal stress along the
perimeter of the model, where stresses are
generally the largest.
3. Furnishes full-field values of the principal-
stress direction. (Sometimes called stress
trajectories.)
4. Is adaptable to both static and dynamic
investigations.
5. Requires only a modest investment in
equipment and materials or ordinary work.
6. It is fairly simple to use [6].
Figure 1 Experiment set up for photoelastic method.
The experiment set up for photoelastic method is shown
in figure 1. The photoelasticity method is based on the
properties of light. Stroboscope will be sending out pulsed
light with a fixed frequency that we require. A polarizer will
be converting randomly polarized light to plane polarized
light which in simple means filtering light and letting light
waves with specific direction to pass through. From figure 2,
the incoming light is resolved into two vector axis and one of
them passes through while the others are rejected [6].
Photoelastic materials which in here is the phononic
crystals are birefringent. This means that they are able to
refract light differently for different light-amplitude
orientation depending upon the state of stress in the material
[6]. As ultrasonic waves are mechanical waves, the state of
stress in the phononic crystal is changing according to the
waves emitted by probe.
In conclusion, the birefringent materials resolve
incoming light into two components which is parallel to the
principal stress axis. It retards the out coming light by an
amount that is proportional to the difference of principal
stresses [6].
Figure 2 Polarizer
3. 3
The analyzer works the same way as polarizer just in a
different orientation. Light coming out from the analyzer will
be focused by the lens and captured by the CCD camera.
Light captured will go through image processor and analyzed
using computer to show the propagation of waves in
phononic crystal.
The models of phononic crystals are made out by first
setting up the steel rods in triangular periodic arrangement in
order to obtain prism-shaped phononic crystals. Then, the
steel rods are embedded in liquid epoxy resin and a partial
vacuum is used during the hardening of resin in order to
avoid residual air bubbles in the phononic crystal [5].
III. RESULTS
Simulation of negative refraction and focusing has been
done using Fenics code.
Figure 3 Fenics simulation of negative refraction
As shown in the figure 3, it illustrates waves passing
through a 2D triangular arrangement or steel circular rods
embedded in water. A fluid solid case has been used in this
simulation. It shows a clear and detail negative refraction
phenomenon when the waves is coming out from the
triangular arrangement of steel rods. The wave is refracting
in a negative direction which is impossible for normal
refraction and hence called as negative refraction.
Figure 4 Fenics simulation of focusing
Simulation of focusing has been done using FENICS
code too. From figure 4, rectangular arrangements of steel
circular rods are embedded in water which acts like a lens.
The waves passing through the steel rods and focus in a short
distance from the end of the steel rods.
Solid-solid case which uses steel rods in epoxy matrix
requires more complex coding and still under
experimentation.
IV. DISCUSSION
The experiments has ensured that the simulation is
working correctly and will be used to simulate the solid-solid
case of phononic crystal. However, it requires more tuning
on the coding as it is more complex to simulate a solid-solid
case phononic crystal.
Figure 5 Positive refraction and negative refraction
According to Snell’s Law, waves will refract when
passing through a different median. As shown in figure 5,
when the waves are refracting to the other side of normal line,
it is positive refraction. However, it is negative refraction
when the waves refract on the same side of the normal line.
Figure 6 Explanation on Fenics simulation
From the simulation result, it is shown that the waves are
refracting at the same side of refraction and hence negative
refraction is achieved.
Using the properties of negative refraction, a better
focusing can be achieved which is shown in figure 7.
4. 4
Figure 7 Focusing using negative refraction property.
It is not possible for a conventional lens to produce an
image containing details that are finer than half of the
wavelength of the waves (diffraction limit). This loss in
detail is due to the non-propagating nature of evanescent
waves.
However, in lens made out of negative index material,
evanescent waves can propagate over small distances leading
to the preservation of detail. Negative refractive lens doesn’t
require a curved shape to focus the waves and, therefore,
leads to easier production.
V. CONCLUSION
Our research has done simulation on simpler case for
determining properties of phononic crystals such as negative
refraction and focusing. This established a good background
for us in future experiments on harder simulation which is on
solid-solid phononic crystal.
After simulation is done, we will be implementing the
model to hands on experiments which require techniques of
photoelastic method.
VI. ACKNOWLEDGEMENTS
This research is made possible through the help and
support from ACE Undergraduate Research Program. I
would also like to thank Yan Lu for providing technical
support in Fenics coding and simulation progress.
VII. REFERNCES
1. T. Gorishnyy, M. Maldovan, C. Ullal, E. Thomas,
(Dec 2005) Sound ideas. physics world: 1-7
2. K.Date,Y.Tabata*,H.Shjmada , A Quantitative
Evaluation Of Ultrasonic Wave in Solid By the
Photoelastic Visualization Method. Miyagi National
College of Technology, Medeshima Natori,
00900-560718710000- 1093, 1987 IEEE
3. Sho Washimori, Tsuyoshi Mihara and Hatsuzo
Tashiro (2012) Investigation of the Sound Field of
Phased Array Using the Photoelastic Visualization
Technique and the Accurate FEM. Materials
Transactions 53(4):631 to 635.
4. Kazuhiro Date, Yoshio Udagawa, Visualisation of
Ultrasonic waves in a solid by stroboscopic
Photoelasticity and Image Processing Techniques :
1755-1762
5. James W. Phillips, TAM 32, Experimental Stress
Analysis. University of Illinois at Urbana-
Champaign, 6.2-6.62.
6. A. Tinel, B. Dubus, J. Vasseur, and A.-C. Hladky-
Hennion (Feb 2011), Negative refraction of
longitudinal waves in a two-dimensional solid-solid
phononic crystal. Phys. Rev. B 83, 054301.