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 Topic : Production of Blue Hydrogen
from Biomethane and its Applications.
Contents:-
1. Demand of Hydrogen
2. What is Blue Hydrogen ?
3. Methods to produce Blue Hydrogen(SMR, ATR)
4. Steam methane reforming (SMR)
5. Flow diagram with CCS
6. CCS Methods (MDEA , VPSA)
7. Economics Feasibilty / Challenges
8. Transportation
o Applications
CCS Utilization ,
Extent of CCS
 Demand of Hydrogen:-
 India’s hydrogen demand in 2020 is
roughly estimated to 6 MMT per
annum.
https://wri-india.org/blog/hydrogen-application-indian-fertilizer-industry-
introduction
 Expected demand increase is about 4-5
times.
 https://auto.economictimes.indiatimes.com/news/industry/commodit
y-price-hike-may-slowdown-indias-hydrogen-consumption-goals-
report/91344206
What is Blue Hydrogen ?
Green
Hydrogen:-
• Produced using Electrolysis.
• Reaction :
• 2H₂O(l) + 2e⁻ → 2H₂(g) +
O₂(g)
• No CO2 emitted
 Blue
Hydrogen :-
• Produced using Natural
gas.
• Reaction:
• CH₄(g) + H₂O(g) → 3H₂(g)
+ CO₂(g)
• CO2 is captured using CCS
tech.
 Grey
Hydrogen:-
• Produced using Natural
gas.
• Reaction:
• CH₄(g) + H₂O(g) →
3H₂(g) + CO₂(g)
• CO2 is emitted. No CCS is
used.
Methods
to
produce
Blue
Hydrogen.
Steam Methane
Reforming (SMR) with
CCS
Autothermal Reforming
(ATR) with CCS
A. Steam Methane Reforming (SMR) with
CCS :-
 Reaction
CH4 + H2O 3H2 + CO (H)298 = 206 kJ/mol
CO + H2O CO2 + H2 (H)298 = - 41.1 kJ/mol {WGS}
 Parameters
Temp. = 700°C – 900°C
Press. = 20 – 40 Bar
 Steam-to-Carbon Ratio (S/C) { 2:3 }
 Catalysts (Ni, Co, Ru) based catalysts
 Flow Diagram for SMR using CCS :-
 Carbon Capture and Storage (CCS) Methods :-
Why important ?
 M.D.E.A.
 Methyl Di-ethanol Amine.
 Advantages :
• Selectivity
• Versatility
• Regenerability
• Low Energy Requirements
 V.P.S.A.
 Vacuum Pressure Swing Adsorption.
 Advantages :
• Low Operating Costs
• Continuous Operation
• Adaptability
M.D.E.A.
V.P.S.A.
 Economic
Feasibility:
 Carbon capture, specifically in the
context of blue hydrogen
production, can increase the cost
of hydrogen compared to grey
hydrogen due to several factors:
Challenges :-
Carbon Capture
and Storage (CCS)
Energy
Requirements
Maintenance Costs CO2 Storage Costs
Risk and
Uncertainty
Initial Capital
Investment
 Transportation:-
The storage options that are under consideration includes :-
Liquid organic
hydrogen
Pressurized
gaseous
hydrogen,
Cryogenic
liquefied
hydrogen,
Carbonaceous
materials
hydrogen,
Metal alloy
hydrogen,
Complex
hydride
hydrogen,
Glass
microspheres
hydrogen,
 Applications :-
 Blue Hydrogen’s application holds
vast potential across diverse
sectors, including energy,
industry, and transportation, as a
crucial step toward a sustainable,
low-carbon future.
Applications:
A.) CCS Utilisation :-
 CCS utilisation has the potential to turn CO2
emissions into valuable resources:
Extent of CCS
utilisation :-

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Production of Blue Hydrogen from Biomethane and its Applications.pptx

  • 1.  Topic : Production of Blue Hydrogen from Biomethane and its Applications.
  • 2. Contents:- 1. Demand of Hydrogen 2. What is Blue Hydrogen ? 3. Methods to produce Blue Hydrogen(SMR, ATR) 4. Steam methane reforming (SMR) 5. Flow diagram with CCS 6. CCS Methods (MDEA , VPSA) 7. Economics Feasibilty / Challenges 8. Transportation o Applications CCS Utilization , Extent of CCS
  • 3.  Demand of Hydrogen:-  India’s hydrogen demand in 2020 is roughly estimated to 6 MMT per annum. https://wri-india.org/blog/hydrogen-application-indian-fertilizer-industry- introduction  Expected demand increase is about 4-5 times.  https://auto.economictimes.indiatimes.com/news/industry/commodit y-price-hike-may-slowdown-indias-hydrogen-consumption-goals- report/91344206
  • 4. What is Blue Hydrogen ? Green Hydrogen:- • Produced using Electrolysis. • Reaction : • 2H₂O(l) + 2e⁻ → 2H₂(g) + O₂(g) • No CO2 emitted  Blue Hydrogen :- • Produced using Natural gas. • Reaction: • CH₄(g) + H₂O(g) → 3H₂(g) + CO₂(g) • CO2 is captured using CCS tech.  Grey Hydrogen:- • Produced using Natural gas. • Reaction: • CH₄(g) + H₂O(g) → 3H₂(g) + CO₂(g) • CO2 is emitted. No CCS is used.
  • 5. Methods to produce Blue Hydrogen. Steam Methane Reforming (SMR) with CCS Autothermal Reforming (ATR) with CCS
  • 6. A. Steam Methane Reforming (SMR) with CCS :-  Reaction CH4 + H2O 3H2 + CO (H)298 = 206 kJ/mol CO + H2O CO2 + H2 (H)298 = - 41.1 kJ/mol {WGS}  Parameters Temp. = 700°C – 900°C Press. = 20 – 40 Bar  Steam-to-Carbon Ratio (S/C) { 2:3 }  Catalysts (Ni, Co, Ru) based catalysts
  • 7.  Flow Diagram for SMR using CCS :-
  • 8.  Carbon Capture and Storage (CCS) Methods :- Why important ?  M.D.E.A.  Methyl Di-ethanol Amine.  Advantages : • Selectivity • Versatility • Regenerability • Low Energy Requirements  V.P.S.A.  Vacuum Pressure Swing Adsorption.  Advantages : • Low Operating Costs • Continuous Operation • Adaptability
  • 10.  Economic Feasibility:  Carbon capture, specifically in the context of blue hydrogen production, can increase the cost of hydrogen compared to grey hydrogen due to several factors:
  • 11. Challenges :- Carbon Capture and Storage (CCS) Energy Requirements Maintenance Costs CO2 Storage Costs Risk and Uncertainty Initial Capital Investment
  • 12.  Transportation:- The storage options that are under consideration includes :- Liquid organic hydrogen Pressurized gaseous hydrogen, Cryogenic liquefied hydrogen, Carbonaceous materials hydrogen, Metal alloy hydrogen, Complex hydride hydrogen, Glass microspheres hydrogen,
  • 13.  Applications :-  Blue Hydrogen’s application holds vast potential across diverse sectors, including energy, industry, and transportation, as a crucial step toward a sustainable, low-carbon future.
  • 14. Applications: A.) CCS Utilisation :-  CCS utilisation has the potential to turn CO2 emissions into valuable resources: