SlideShare a Scribd company logo
1
Compact wastewater treatment
with MBBR
DSD International Conference
Hong Kong, 12.‐14.11.2014
Hallvard Ødegaard
Prof. em. Norwegian University of Science and Technology (NTNU)
CEO Scandinavian Environmental Technology (SET) AS
hallvard.odegaard@ntnu.no
SET AS
2
Aerobic reactor
The principle of the moving bed biofilm reactor
(MBBR) technology
Anoxic reactor
SET AS
3
The Moving Bed Biofilm Reactor (MBBR) in practice
SET AS
4
THE MAJOR COMPONENTS
a) Tank
b) Media
c) Aeration System
d) Sieve Assemblies
e) Blowers
f) Mixers
The components of the MBBR treatment system
SET AS
Carrier filling fraction (%)
(bulk volume occupied by media
in empty reactor):
Possible filling fraction: 0 – 70 %
Normal filling fraction: 50 – 65 %
5
The MBBR reactor
SET AS
Rectangular covered concrete reactors
Rectangular/Circular open concrete reactors
Circular fiber glass reactors
Circular Steel Reactors (Bolted or Welded)
6
The (MBBR) carriers
Courtesy Aqwise
•650 m2/m3 bulk
•13 x 13 mm
diameter/depth
Courtesy Biowater Technology
•650 m2/m3 bulk
•18.5 x 14.5 x 7.3 mm
length/width/depth
ABC BWT S
K1 K3 K5 BiofilmChip M
• 1200 m2/m3 bulk
• 48 x 2.2 mm
diameter/depth
• 500 m2/m3 bulk
• 25 x 10 mm
diameter/depth
• 500 m2/m3 bulk
• 9.1 x 7.2 mm
diameter/depth
• 800 m2/m3 bulk
• 25 x 3.5 mm
diameter/depth
Courtesy AnoxKaldnes
Z‐MBBR
SET AS
Courtesy Qingdao Spring
7
Carriers from the MBBR-based
SANI pilot at Shatin
8
Aeration /oxygen transfer
• Oxygen transfer is enhanced by the
presence of carriers
• The higher the filling fraction, the better
SOTR
• Influence dependent on carrier design.
Suppliers should provide SOTR data
0,00
2,00
4,00
6,00
8,00
10,00
12,00
14,00
16,00
Renvatten, grov K3, 30% grov K3, 50% grov
gO
2
/Nm
3
m
Clean
water
K3
30 %
K3
50 %
K3
30 %
g
O
2
/Nm
3
.
m
16
14
12
10
8
6
4
2
0
Christensson, 2013
9
SET AS
SET AS
The sieve assembly
The mixers in anoxic reactors
10
The principal moving bed reactor processes
The basic MBBR
processes
The high‐rate MBBR
processes
The IFAS
processes
SET AS
11
Flow diagrams for moving bed biofilm reactor
(MBBR) processes for various applications
BOD- and N/P-removal
BOD- and NH
4-N-removal
BOD- and P-removal
BOD-removal
Pure MBBR-processes
a)
b) d)
Coag.
Coag.
c)
Pure MBBR-processes
e)
f)
g)
Pure MBBR-processes
(Coag.).
Coag. Coag
.
h)
i)
j)
COD
COD
Pure MBBR- processes
l)
k)
IFAS-processes
n)
m)
IFAS-processes
SET AS
12
Aerobic COD‐removal rates (Ødegaard et al, 2004)
0
5
10
15
20
25
30
35
40
45
50
0 20 40 60 80 100
Filtered COD loading rate [g SCOD/m2
*d]
Filtered
COD
removal
rate
[g
SCOD/m
2
*d]
K1 K2 100%
Soluble COD removal rate vs soluble COD
loading rate
0
20
40
60
80
100
120
140
0 50 100 150 200
Total COD loading rate [g COD/m2
*d]
Obtainable
removal
rate
(COD
in
-SCOD
out
)
[g/m
2
*d]
K1 K2 100%
Obtainable COD removal rate vs total COD
loading rate
SET AS
”Obtainable" COD removal rate : (CODinfluent‐SCODeffluent)*Q/A
Demonstrates removal rate of tot. COD if all particles > 1 µm were removed
13
High rate MBBR systems
SET AS
Air
Coagulant
Fe+polymer
Secondary treatment
+ 90 % P-removal
could be met at a:
total HRT ~ 1 hr
The high‐rate MBBR‐coagulation process
The high‐rate MBBR ‐ AS process
MBBR
Frequently used in
industrial plants
e.g. pulp and paper
14
1. The load of organic matter
2. The oxygen concentration
3. The ammonium concentration
Factors determining the nitrification rate in
MBBR’s (Hem, Rusten and Ødegaard, 1994)
Temperature dependency:
kT2 = kT1∙θ(T2‐T1) , θ = 1,06‐1,08
SET AS
0.0
0.3
0.6
0.9
1.2
1.5
1.8
2.1
2.4
2.7
0 2 4 6 8 10
Oxygen concentration, mg O2/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 ºC
Organic load = 0.0 g BOD 5
/m
2 /d
1.0
2.0
3.0
4.0
5.0
6.0
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Ammonium concentration, mg NH4-N/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 oC
0.4 g BOD5/m
2
/d
DO = 2 mg/L
DO = 6 mg/L
DO = 4 mg/L
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Ammonium concentration, mg NH4-N/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 oC
0.4 g BOD5/m
2
/d
DO = 2 mg/L
DO = 6 mg/L
DO = 4 mg/L
0.0
0.3
0.6
0.9
1.2
1.5
1.8
2.1
2.4
2.7
0 2 4 6 8 10
Oxygen concentration, mg O2/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 ºC
Organic load = 0.0 g BOD 5
/m
2 /d
1.0
2.0
3.0
4.0
5.0
6.0
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Ammonium concentration, mg NH4-N/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 oC
0.4 g BOD5/m
2
/d
DO = 2 mg/L
DO = 6 mg/L
DO = 4 mg/L
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Ammonium concentration, mg NH4-N/L
Nitrification
rate,
g
NH
4
-N/m
2
/d
15 oC
0.4 g BOD5/m
2
/d
DO = 2 mg/L
DO = 6 mg/L
DO = 4 mg/L
15
Influence of oxygen on nitrification rate ‐
practical experiences
SET AS
16
Nitrification process design
Organic matter removal prior to nitrification:
rBOD = 3,9 g BOD5/m2d (10 oC) (kT = 1.06(T-10))
Nitrification rate (when NH4-N is the limiting substrate)
rN = k . (Sn)n
rN = nitrification rate (g NH4-N/m2.d)
SN = NH4-N concentration in the reactor
n = reaction rate order - n is normally set at 0,7
k = reactor rate constant – 0,4 – 0,6 (varies with the organic load, i.e pre-treatment)
NH4-N is only rate limiting at low NH4-concentrations (ca 1-2 mg NH4-N/l).
At higher concentrations, SN will be determined by the bulk liquid DO concentration and
Sn should be replaced by Sn,transition
Sn,transition = (DO-0,5) / 3,2
SET AS
17
Nitrification rates in full‐scale plants
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
1.8
2.0
0.0 0.4 0.8 1.2 1.6 2.0 2.4 2.8 3.2
Ammonium load, g NH4-N/m
2
/d
Removal
rate,
g
NH
4
-N/m
2
/d
R4
R4 + R5
Temp. 11 º C
Lillehammer WWTP
Intensive study at Lillehammer WWTP
• Very high max rates (1,4 g NH4/m2.d)
• Complete nitrification at < 1,2 g NH4/m2.d
(Rusten and Ødegaard, 2007)
10oC
1.17 g NH4-N/m2d
10oC
1.17 g NH4-N/m2d
Nitrification performance at Givaudan WWTP
Switzerland (Tschui, personal comm.)
Challenge: Alkalinity limitation. Recommendation > 1,5 meq./l residual alkalinity
SET AS
18
N‐removal
1. If carbon source is abundant and
treatment efficiency needed is < 75 %,
pre‐DN is preferable
2. If carbon source is limited and
treatment efficiency required is
> 75 %, combined‐DN is preferable
3. If, in addition to 2., space is very
limited, post‐DN may be preferable
Choice of process is primarily dependent on availability of internal
carbon source for denitrification and treatment efficiency requirement:
C
Post-denitrification
Pre-denitrification
C
Combined denitrification
C
C
Post-denitrification
Pre-denitrification
C
Combined denitrification
Post-denitrification
Pre-denitrification
C
C
Combined denitrification
SET AS
19
Denitrification
R= r/(r+1)
C/N
(g BSCOD/g N)
R= r/(r+1)
C/N
(g BSCOD/g N)
There is a limit to treatment efficiency in
conventional pre‐DN caused by the
oxygen recycle
Rusten, Hem and Ødegaard, 1995
Pre‐denitrification
rDN = k * [SCOD/(SCOD+KS,COD)]* [SNO3/(SNO3+KS,NO3)]
SET
No carbon limitation as long as:
• g CODadded/ g NO3‐Nequiv. is > 3,5
• NO3‐N may be the limiting factor at low NO3‐N
Rusten, Hem and Ødegaard, 1995
Post‐denitrification
20
The combined pre‐ and post‐DN MBBR process
Recirculation of NO3‐N
DN‐rate controlled
by carbon addition
• Aerated when larger nitrification volume
is needed (winter).
• Not aerated in summer – more pre‐DN
volume – higher recycle in summer
Nitrification rate
controlled through O2
Low recirculation of oxygen
Not aerated nitrification
O2 consumption only ‐
in order to reduce the
amount of recycled O2
SET AS
Carbon
21
DN‐rates with external carbon sources
(practical results from combined‐DN plant)
0
1
2
3
4
5
3 5 7 9 11 13 15 17
Temperature, °C
Denitrification
rate,
g
NO
3
-N/m
2
/d
Ethanol
Methanol
Monopropylene glycol
Rusten et al, 1996
SET AS
22
Four Norwegian combined DN‐plants
Flocc.
Secondary sed.
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AN/
AE
AE AE AN AN AE
a)
Flocc.
DAF
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AN/
AE
AE AE AN AE
b)
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AE AE AN AE
c) Secondarysed.
AN
Flocc.
Secondary sed.
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AN/
AE
AE AE AN AN AE
a)
Flocc.
DAF
Primarysed.
Chem.
Carbon
NO3 recycle
AE
Flocc.
Secondary sed.
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AN/
AE
AE AE AN AN AE
a)
Flocc.
DAF
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AN/
AE
AE AE AN AE
b)
Primarysed.
Chem.
Carbon
NO3 recycle
AE
AN AE AE AN AE
c) Secondarysed.
AN
Lillehammer WWTP
Nordre Follo and Gardermoen WWTP
RA2 WWTP
SET AS
23
MBBR design/operating values and performances
Parameter Lille-
hammer
Nordre
Follo
Garder-
moen
NRA
Average flow (m3/h)
Max flow (m3/h)
Temperature (oC)
1200
1900
3-14
750
1125
6-14
920
1300
4-14
2300
7200
7-14
MBBR
Total volume (m3)
Carrier fill fraction (%)
Average(max) HRT (hrs)
3840
65,0
3,2 (2,0)
3710
66,2
4,9 (3,3)
5790
58.5
6,3 (4,5)
19370
42,7
8,4 (2,7)
Carbon source
g CODadded/g TNequiv
Ethanol
3.3
Methanol
(now glycol)
2.2
Glycol
2.4
Methanol
(now glycol)
-
Efficiency, 2005
Average out conc.
and treatment efficiency
BOD5
COD
Tot N
Tot P
Out Rem
mg/l %
2,2 99
35 93
2,9 92
0.12 98
Out Rem
mg/l %
2,8 98
39 91
9,7 73
0.20 96
Out Rem
mg/l %
3,2 98
25 96
7,0 87
0.18 98
Out Rem
mg/l %
4,0 95
27 93
5,0 83
0.05 99
SET AS
24
MBBR biomass separation alternatives
MBBR – Coag./settling
(also Actiflo)
MBBR - settling
MBBR - flotation
MBBR – media filtration
MBBR – microscreening
(i.e. Disc filtration)
MBBR – Membrane filtration
SET AS
25
Anaerobic ammonium oxidation (Anammox):
NH4
+ + NO2
- -> N2 + 2H20
Advantages
• No carbon source needed
• Less air needed (than in N/DN):
~1,8 g O2/g N (60 % less)
• Very low sludge production
~ 0,11 g SS/g NH4-N
• Less CO2 - production/
less alkalinity consumption
Disadvantages
• Some nitrate is formed:
i.e max N-removal ca 80 %
• Nitrite has to be generated
• Slow growth rate - long start-up
• Necessary to have a long SRT
(Biofilm or granules favorable)
SET AS
Primarily used for N‐removal in sludge water treatment
26
Anammox with MBBR (Christensson et al, 2013)
Biofilm
Media
Liquid
Nitritation
NH4
+
NO2
‐
AOB
Anammox
N2
O2
Aerobic
Anoxic
Biofilm
Media
Liquid
Nitritation
NH4
+
NO2
‐
AOB
Nitritation
NH4
+
NO2
‐
AOB
Anammox
N2
Anammox
N2
O2
O2
Aerobic
Anoxic
MBBR
= 0.5-1.5
mg/L
AOB in biofilm = NO2
- limitation
IFAS
SET AS
Biofilm
Media
Liquid
Nitritation
NH4
+
NO2
‐
AOB
Anammox
N2
O2
Anoxic
Media
Liquid
Nitritation
NH4
+
NO2
‐
AOB
Anammox
N2
O2
Anoxic
< 0.5
mg/L
Flocs (1-3 g/L)
AOB in flocs = less NO2
- limitation
27
 BioFarm concept = Providing seeded carriers for
rapid start‐up of future full‐scale ANITATM Mox units
Seeded carriers
ANITA™ Mox – Sjölunda WWTP, Malmö (Sweden)
• 4 x 50m3 MBBR
• Capacity = 200 kgN/d
• 800‐1200 mgN‐NH4/L
• 1st ANITA™ Mox reference
• Flexibility for fullscale testing
SET AS
28
Full‐scale test results
ANITA™Mox ,
Sjölunda WWTP
(Christensson et al, 2013)
SET AS
• High removal rates and good
N‐removal with MBBR
• Very high removal rate with
IFAS ‐ up to 3 kg NH4‐N/m3.d
(7.5 g NH4‐N/m2.d)
• Energy consumption :
1.2 kWh/kg NH4‐N removed
0
0,5
1
1,5
2
2,5
3
3,5
NH4
load
&
removal
(kgN/m
3
.d)
NH4‐load
NH4‐removal
0
10
20
30
40
50
60
70
80
90
930 950 970 990 1010 1030 1050 1070 1090 1110 1130 1150
%NH4
and
%TN
removal
Days
%TN‐removal
%NH4‐removal
%NO3‐prod : NH4‐rem
MBBR Tran-
sition
IFAS
• K5 – filling fraction 50 %
• DOMBBR = 1.0 ‐ 1.3 mg/l
• DOIFAS = 0.2 ‐ 1.0 mg/l
• MLSSMBBR = 20–400 mg/l
• MLSSIFAS = 1800 – 4600 mg/l
29
Removal of pharmaceuticals
(Falås, 2013)
Comparison between activated sludge and
carrier‐based processes
30
Removal og pharmaceuticals in the biomass
from an IFAS plant (Bad Ragaz WWTP, CH)
0
0.2
0.4
0.6
0.8
1
1.2
0 5 10 15 20 25
C/Cinitial
Time (h)
Atenolol
0
0.2
0.4
0.6
0.8
1
1.2
0 5 10 15 20 25
C/Cinitial
Time (h)
Carbamazepine
Anoxic sludge
Oxic sludge
Carriers
0
0.2
0.4
0.6
0.8
1
1.2
0 5 10 15 20 25
C/Cinitial
Time (h)
Mefenamic acid
0
0.2
0.4
0.6
0.8
1
1.2
0 5 10 15 20 25
C/Cinitial
Time (h)
Diclofenac
(Falås et al, 2014)
Where does the removal take place?
31
Conclusions
1. The MBBR is a well‐proven, robust and very compact technology
(Now altogether > 800 plants in > 50 countries – 50/50 industrial/municipal).
2. The MBBR is used in pure biofilm processes as well as in hybrid processes (IFAS)
3. The combined pre‐ and post denitrification MBBR process is especially suitable
for low C/N waters and offers great flexibility in operation
4. The MBBR is very efficient in the upgrading of activated sludge plants:
a. as ”roughing” reactor before AS in order to reduce organic matter loading
b. in an IFAS‐process in order to achieve: nitrification, N‐removal and or P‐removal
5. The MBBR‐based processes are especially suitable for developing special
cultures – for instance for:
a. N‐removal by anammox processes
b. Organic micropollutants removal
SET AS
32
Thanks
a lot
for listening
The Pulpit, Lysefjord, Norway
33
Upgrading AS‐plants by the use of MBBR
Three options for nitrification
Pure MBBR BAS HYBAS
SET AS
IFAS
MBBR MBBR Activated sludge Activated sludge + MBBR
34
SRT Vs Temperature
0
1
2
3
4
5
6
7
8
9
10
11
12
13
14
5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25
Temperature, C
SRT,
d
ATV Design Curve
Nitrifier Growth Rate
Broomfield
(4.7 days at 13C)
Cheyenne (4.5 days at 9C)
Yucaipa (2.3 days at 18C)
Taos (5.2 days at 8C)
Oxford
(3.9 days at 11C) Fields Point & Flagstaff (3.3 days at 14C)
James River
(2.7 days at 14C)
Greensboro (5.25 days at 14C)
Springettsbury
(2.4 days at 10C)
Lubbock (3.8 days at 15C)
Fairplay (2.5 days at 5C)
New Castle (4.1 days at 10C)
Crestted Butte (3.2 days at 7.5C)
Mamaroneck
(1.8 days at 13C)
Georgetown (5.0 days at 9C)
SET AS
Design SRT vs temp for full scale IFAS
systems (installed by ANOXKALDNES)

More Related Content

Similar to Presentation_(B4-1).pdf

IRJET- Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...
IRJET-  	  Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...IRJET-  	  Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...
IRJET- Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...IRJET Journal
 
Benfield system
Benfield systemBenfield system
Benfield systemPrem Baboo
 
Bivo4/g-c3n4 hybrid nanomaterial
Bivo4/g-c3n4 hybrid nanomaterialBivo4/g-c3n4 hybrid nanomaterial
Bivo4/g-c3n4 hybrid nanomaterialsubash133305
 
Moving bed biofilm reactor for denitrification corey
Moving bed biofilm reactor for denitrification coreyMoving bed biofilm reactor for denitrification corey
Moving bed biofilm reactor for denitrification coreymayurshinde1987
 
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...Donald Carpenter
 
Low temperature nitrification_ningan_20MLD
Low temperature nitrification_ningan_20MLDLow temperature nitrification_ningan_20MLD
Low temperature nitrification_ningan_20MLDAmit Christian
 
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...Engineers Australia
 
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...CRL Asia
 
Dr Wang Rui - Status of Sinopec CCUS technology
Dr Wang Rui - Status of Sinopec CCUS technologyDr Wang Rui - Status of Sinopec CCUS technology
Dr Wang Rui - Status of Sinopec CCUS technologyGlobal CCS Institute
 
Sweetening and sulfur recovery of sour associated gas in the middle east
Sweetening and sulfur recovery of sour associated gas in the middle eastSweetening and sulfur recovery of sour associated gas in the middle east
Sweetening and sulfur recovery of sour associated gas in the middle eastFrames
 
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERS
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERSDISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERS
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERSiQHub
 
2022 KNAW webinar Olivijn Pol Knops V2.pdf
2022 KNAW webinar Olivijn Pol Knops V2.pdf2022 KNAW webinar Olivijn Pol Knops V2.pdf
2022 KNAW webinar Olivijn Pol Knops V2.pdfGreen Minerals B.V.
 
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...Nancy BOVY
 
ArthurRempelPresentation150808
ArthurRempelPresentation150808ArthurRempelPresentation150808
ArthurRempelPresentation150808Arthur Rempel
 
engr103_grp94014_finPres
engr103_grp94014_finPresengr103_grp94014_finPres
engr103_grp94014_finPresMarina D'souza
 

Similar to Presentation_(B4-1).pdf (20)

NextGen Altenrhein, Switzerland
NextGen Altenrhein, SwitzerlandNextGen Altenrhein, Switzerland
NextGen Altenrhein, Switzerland
 
IRJET- Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...
IRJET-  	  Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...IRJET-  	  Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...
IRJET- Capturing carbon dioxide from air by using Sodium hydroxide (CO2 T...
 
Benfield system
Benfield systemBenfield system
Benfield system
 
Bivo4/g-c3n4 hybrid nanomaterial
Bivo4/g-c3n4 hybrid nanomaterialBivo4/g-c3n4 hybrid nanomaterial
Bivo4/g-c3n4 hybrid nanomaterial
 
Moving bed biofilm reactor for denitrification corey
Moving bed biofilm reactor for denitrification coreyMoving bed biofilm reactor for denitrification corey
Moving bed biofilm reactor for denitrification corey
 
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...
Optimized Geochemical Modeling of Produced Fluids Provides Important Insight ...
 
Low temperature nitrification_ningan_20MLD
Low temperature nitrification_ningan_20MLDLow temperature nitrification_ningan_20MLD
Low temperature nitrification_ningan_20MLD
 
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...
ICWES15 -Comparative Absorption of Copper from Synthetic and Real Wastewater ...
 
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...
Application on Semi-aerobic Landfill. Technology in in Tropical Climate: Lysi...
 
Dr Wang Rui - Status of Sinopec CCUS technology
Dr Wang Rui - Status of Sinopec CCUS technologyDr Wang Rui - Status of Sinopec CCUS technology
Dr Wang Rui - Status of Sinopec CCUS technology
 
Effective Adsorbents for Establishing Solids Looping as a Next Generation NG ...
Effective Adsorbents for Establishing Solids Looping as a Next Generation NG ...Effective Adsorbents for Establishing Solids Looping as a Next Generation NG ...
Effective Adsorbents for Establishing Solids Looping as a Next Generation NG ...
 
Alternative Point-Source CO2 Mitigation: Spontaneous Conversion of CO2 to Oce...
Alternative Point-Source CO2 Mitigation: Spontaneous Conversion of CO2 to Oce...Alternative Point-Source CO2 Mitigation: Spontaneous Conversion of CO2 to Oce...
Alternative Point-Source CO2 Mitigation: Spontaneous Conversion of CO2 to Oce...
 
Sweetening and sulfur recovery of sour associated gas in the middle east
Sweetening and sulfur recovery of sour associated gas in the middle eastSweetening and sulfur recovery of sour associated gas in the middle east
Sweetening and sulfur recovery of sour associated gas in the middle east
 
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERS
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERSDISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERS
DISCUSSION ON UTILIZING AMMONIA FOR CAPTURING CO₂ AND PRODUCING FERTILIZERS
 
2022 KNAW webinar Olivijn Pol Knops V2.pdf
2022 KNAW webinar Olivijn Pol Knops V2.pdf2022 KNAW webinar Olivijn Pol Knops V2.pdf
2022 KNAW webinar Olivijn Pol Knops V2.pdf
 
CO2 Separation - A Proposal
CO2 Separation - A Proposal CO2 Separation - A Proposal
CO2 Separation - A Proposal
 
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...
Plein gaz : enjeux et perspectives sur la valorisation du CO2 | LIEGE CREATIV...
 
ArthurRempelPresentation150808
ArthurRempelPresentation150808ArthurRempelPresentation150808
ArthurRempelPresentation150808
 
CO2 capture from NGCC Flue Gas and Ambient Air Using PEI-Silica Adsorbent - D...
CO2 capture from NGCC Flue Gas and Ambient Air Using PEI-Silica Adsorbent - D...CO2 capture from NGCC Flue Gas and Ambient Air Using PEI-Silica Adsorbent - D...
CO2 capture from NGCC Flue Gas and Ambient Air Using PEI-Silica Adsorbent - D...
 
engr103_grp94014_finPres
engr103_grp94014_finPresengr103_grp94014_finPres
engr103_grp94014_finPres
 

Recently uploaded

Natural farming @ Dr. Siddhartha S. Jena.pptx
Natural farming @ Dr. Siddhartha S. Jena.pptxNatural farming @ Dr. Siddhartha S. Jena.pptx
Natural farming @ Dr. Siddhartha S. Jena.pptxsidjena70
 
Environmental Science Book By Dr. Y.K. Singh
Environmental Science Book By Dr. Y.K. SinghEnvironmental Science Book By Dr. Y.K. Singh
Environmental Science Book By Dr. Y.K. SinghAhmadKhan917612
 
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...ipcc-media
 
Prevention and Control of Water Pollution
Prevention and Control of Water PollutionPrevention and Control of Water Pollution
Prevention and Control of Water Pollutionlinciy03
 
@@how to Join @occult for money ritual..☎️+2349022657119.
@@how to Join @occult for money ritual..☎️+2349022657119.@@how to Join @occult for money ritual..☎️+2349022657119.
@@how to Join @occult for money ritual..☎️+2349022657119.RoyaleEaglepriest
 
Green house gases GlobalWarmingPotential.pptx
Green house gases GlobalWarmingPotential.pptxGreen house gases GlobalWarmingPotential.pptx
Green house gases GlobalWarmingPotential.pptxViniHema
 
Paper: Man and Environmental relationship
Paper: Man and Environmental relationshipPaper: Man and Environmental relationship
Paper: Man and Environmental relationshipSANTU GUCHHAIT
 
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business Ventures
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business VenturesWillie Nelson Net Worth: A Journey Through Music, Movies, and Business Ventures
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business Venturesgreendigital
 
International+e-Commerce+Platform-www.cfye-commerce.shop
International+e-Commerce+Platform-www.cfye-commerce.shopInternational+e-Commerce+Platform-www.cfye-commerce.shop
International+e-Commerce+Platform-www.cfye-commerce.shoplaozhuseo02
 
Prevalence, biochemical and hematological study of diabetic patients
Prevalence, biochemical and hematological study of diabetic patientsPrevalence, biochemical and hematological study of diabetic patients
Prevalence, biochemical and hematological study of diabetic patientsOpen Access Research Paper
 
ppt on beauty of the nature by Palak.pptx
ppt on  beauty of the nature by Palak.pptxppt on  beauty of the nature by Palak.pptx
ppt on beauty of the nature by Palak.pptxRaniJaiswal16
 
Artificial Reefs by Kuddle Life Foundation - May 2024
Artificial Reefs by Kuddle Life Foundation - May 2024Artificial Reefs by Kuddle Life Foundation - May 2024
Artificial Reefs by Kuddle Life Foundation - May 2024punit537210
 
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...Open Access Research Paper
 
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...Open Access Research Paper
 
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单一比一原版(Monash毕业证)莫纳什大学毕业证成绩单
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单pcoow
 
DRAFT NRW Recreation Strategy - People and Nature thriving together
DRAFT NRW Recreation Strategy - People and Nature thriving togetherDRAFT NRW Recreation Strategy - People and Nature thriving together
DRAFT NRW Recreation Strategy - People and Nature thriving togetherRobin Grant
 
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单tyvaq
 
NRW Board Paper - DRAFT NRW Recreation Strategy
NRW Board Paper - DRAFT NRW Recreation StrategyNRW Board Paper - DRAFT NRW Recreation Strategy
NRW Board Paper - DRAFT NRW Recreation StrategyRobin Grant
 

Recently uploaded (20)

Natural farming @ Dr. Siddhartha S. Jena.pptx
Natural farming @ Dr. Siddhartha S. Jena.pptxNatural farming @ Dr. Siddhartha S. Jena.pptx
Natural farming @ Dr. Siddhartha S. Jena.pptx
 
Environmental Science Book By Dr. Y.K. Singh
Environmental Science Book By Dr. Y.K. SinghEnvironmental Science Book By Dr. Y.K. Singh
Environmental Science Book By Dr. Y.K. Singh
 
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...
IPCC Vice Chair Ladislaus Change Central Asia Climate Change Conference 27 Ma...
 
Prevention and Control of Water Pollution
Prevention and Control of Water PollutionPrevention and Control of Water Pollution
Prevention and Control of Water Pollution
 
@@how to Join @occult for money ritual..☎️+2349022657119.
@@how to Join @occult for money ritual..☎️+2349022657119.@@how to Join @occult for money ritual..☎️+2349022657119.
@@how to Join @occult for money ritual..☎️+2349022657119.
 
Green house gases GlobalWarmingPotential.pptx
Green house gases GlobalWarmingPotential.pptxGreen house gases GlobalWarmingPotential.pptx
Green house gases GlobalWarmingPotential.pptx
 
Paper: Man and Environmental relationship
Paper: Man and Environmental relationshipPaper: Man and Environmental relationship
Paper: Man and Environmental relationship
 
Major-Environmental-Problems and Proven Solutions.pdf
Major-Environmental-Problems and Proven Solutions.pdfMajor-Environmental-Problems and Proven Solutions.pdf
Major-Environmental-Problems and Proven Solutions.pdf
 
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business Ventures
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business VenturesWillie Nelson Net Worth: A Journey Through Music, Movies, and Business Ventures
Willie Nelson Net Worth: A Journey Through Music, Movies, and Business Ventures
 
International+e-Commerce+Platform-www.cfye-commerce.shop
International+e-Commerce+Platform-www.cfye-commerce.shopInternational+e-Commerce+Platform-www.cfye-commerce.shop
International+e-Commerce+Platform-www.cfye-commerce.shop
 
Prevalence, biochemical and hematological study of diabetic patients
Prevalence, biochemical and hematological study of diabetic patientsPrevalence, biochemical and hematological study of diabetic patients
Prevalence, biochemical and hematological study of diabetic patients
 
ppt on beauty of the nature by Palak.pptx
ppt on  beauty of the nature by Palak.pptxppt on  beauty of the nature by Palak.pptx
ppt on beauty of the nature by Palak.pptx
 
Artificial Reefs by Kuddle Life Foundation - May 2024
Artificial Reefs by Kuddle Life Foundation - May 2024Artificial Reefs by Kuddle Life Foundation - May 2024
Artificial Reefs by Kuddle Life Foundation - May 2024
 
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...
Micro RNA genes and their likely influence in rice (Oryza sativa L.) dynamic ...
 
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...
Use of Raffias’ species (Raphia spp.) and its impact on socioeconomic charact...
 
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单一比一原版(Monash毕业证)莫纳什大学毕业证成绩单
一比一原版(Monash毕业证)莫纳什大学毕业证成绩单
 
DRAFT NRW Recreation Strategy - People and Nature thriving together
DRAFT NRW Recreation Strategy - People and Nature thriving togetherDRAFT NRW Recreation Strategy - People and Nature thriving together
DRAFT NRW Recreation Strategy - People and Nature thriving together
 
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单
一比一原版(Lincoln毕业证)新西兰林肯大学毕业证成绩单
 
A systematic review of the implementation of Industry 4.0 in human resources
A systematic review of the implementation of Industry 4.0 in human resourcesA systematic review of the implementation of Industry 4.0 in human resources
A systematic review of the implementation of Industry 4.0 in human resources
 
NRW Board Paper - DRAFT NRW Recreation Strategy
NRW Board Paper - DRAFT NRW Recreation StrategyNRW Board Paper - DRAFT NRW Recreation Strategy
NRW Board Paper - DRAFT NRW Recreation Strategy
 

Presentation_(B4-1).pdf

  • 1. 1 Compact wastewater treatment with MBBR DSD International Conference Hong Kong, 12.‐14.11.2014 Hallvard Ødegaard Prof. em. Norwegian University of Science and Technology (NTNU) CEO Scandinavian Environmental Technology (SET) AS hallvard.odegaard@ntnu.no SET AS
  • 2. 2 Aerobic reactor The principle of the moving bed biofilm reactor (MBBR) technology Anoxic reactor SET AS
  • 3. 3 The Moving Bed Biofilm Reactor (MBBR) in practice SET AS
  • 4. 4 THE MAJOR COMPONENTS a) Tank b) Media c) Aeration System d) Sieve Assemblies e) Blowers f) Mixers The components of the MBBR treatment system SET AS Carrier filling fraction (%) (bulk volume occupied by media in empty reactor): Possible filling fraction: 0 – 70 % Normal filling fraction: 50 – 65 %
  • 5. 5 The MBBR reactor SET AS Rectangular covered concrete reactors Rectangular/Circular open concrete reactors Circular fiber glass reactors Circular Steel Reactors (Bolted or Welded)
  • 6. 6 The (MBBR) carriers Courtesy Aqwise •650 m2/m3 bulk •13 x 13 mm diameter/depth Courtesy Biowater Technology •650 m2/m3 bulk •18.5 x 14.5 x 7.3 mm length/width/depth ABC BWT S K1 K3 K5 BiofilmChip M • 1200 m2/m3 bulk • 48 x 2.2 mm diameter/depth • 500 m2/m3 bulk • 25 x 10 mm diameter/depth • 500 m2/m3 bulk • 9.1 x 7.2 mm diameter/depth • 800 m2/m3 bulk • 25 x 3.5 mm diameter/depth Courtesy AnoxKaldnes Z‐MBBR SET AS Courtesy Qingdao Spring
  • 7. 7 Carriers from the MBBR-based SANI pilot at Shatin
  • 8. 8 Aeration /oxygen transfer • Oxygen transfer is enhanced by the presence of carriers • The higher the filling fraction, the better SOTR • Influence dependent on carrier design. Suppliers should provide SOTR data 0,00 2,00 4,00 6,00 8,00 10,00 12,00 14,00 16,00 Renvatten, grov K3, 30% grov K3, 50% grov gO 2 /Nm 3 m Clean water K3 30 % K3 50 % K3 30 % g O 2 /Nm 3 . m 16 14 12 10 8 6 4 2 0 Christensson, 2013
  • 9. 9 SET AS SET AS The sieve assembly The mixers in anoxic reactors
  • 10. 10 The principal moving bed reactor processes The basic MBBR processes The high‐rate MBBR processes The IFAS processes SET AS
  • 11. 11 Flow diagrams for moving bed biofilm reactor (MBBR) processes for various applications BOD- and N/P-removal BOD- and NH 4-N-removal BOD- and P-removal BOD-removal Pure MBBR-processes a) b) d) Coag. Coag. c) Pure MBBR-processes e) f) g) Pure MBBR-processes (Coag.). Coag. Coag . h) i) j) COD COD Pure MBBR- processes l) k) IFAS-processes n) m) IFAS-processes SET AS
  • 12. 12 Aerobic COD‐removal rates (Ødegaard et al, 2004) 0 5 10 15 20 25 30 35 40 45 50 0 20 40 60 80 100 Filtered COD loading rate [g SCOD/m2 *d] Filtered COD removal rate [g SCOD/m 2 *d] K1 K2 100% Soluble COD removal rate vs soluble COD loading rate 0 20 40 60 80 100 120 140 0 50 100 150 200 Total COD loading rate [g COD/m2 *d] Obtainable removal rate (COD in -SCOD out ) [g/m 2 *d] K1 K2 100% Obtainable COD removal rate vs total COD loading rate SET AS ”Obtainable" COD removal rate : (CODinfluent‐SCODeffluent)*Q/A Demonstrates removal rate of tot. COD if all particles > 1 µm were removed
  • 13. 13 High rate MBBR systems SET AS Air Coagulant Fe+polymer Secondary treatment + 90 % P-removal could be met at a: total HRT ~ 1 hr The high‐rate MBBR‐coagulation process The high‐rate MBBR ‐ AS process MBBR Frequently used in industrial plants e.g. pulp and paper
  • 14. 14 1. The load of organic matter 2. The oxygen concentration 3. The ammonium concentration Factors determining the nitrification rate in MBBR’s (Hem, Rusten and Ødegaard, 1994) Temperature dependency: kT2 = kT1∙θ(T2‐T1) , θ = 1,06‐1,08 SET AS 0.0 0.3 0.6 0.9 1.2 1.5 1.8 2.1 2.4 2.7 0 2 4 6 8 10 Oxygen concentration, mg O2/L Nitrification rate, g NH 4 -N/m 2 /d 15 ºC Organic load = 0.0 g BOD 5 /m 2 /d 1.0 2.0 3.0 4.0 5.0 6.0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Ammonium concentration, mg NH4-N/L Nitrification rate, g NH 4 -N/m 2 /d 15 oC 0.4 g BOD5/m 2 /d DO = 2 mg/L DO = 6 mg/L DO = 4 mg/L 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Ammonium concentration, mg NH4-N/L Nitrification rate, g NH 4 -N/m 2 /d 15 oC 0.4 g BOD5/m 2 /d DO = 2 mg/L DO = 6 mg/L DO = 4 mg/L 0.0 0.3 0.6 0.9 1.2 1.5 1.8 2.1 2.4 2.7 0 2 4 6 8 10 Oxygen concentration, mg O2/L Nitrification rate, g NH 4 -N/m 2 /d 15 ºC Organic load = 0.0 g BOD 5 /m 2 /d 1.0 2.0 3.0 4.0 5.0 6.0 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Ammonium concentration, mg NH4-N/L Nitrification rate, g NH 4 -N/m 2 /d 15 oC 0.4 g BOD5/m 2 /d DO = 2 mg/L DO = 6 mg/L DO = 4 mg/L 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 0.0 0.5 1.0 1.5 2.0 2.5 3.0 Ammonium concentration, mg NH4-N/L Nitrification rate, g NH 4 -N/m 2 /d 15 oC 0.4 g BOD5/m 2 /d DO = 2 mg/L DO = 6 mg/L DO = 4 mg/L
  • 15. 15 Influence of oxygen on nitrification rate ‐ practical experiences SET AS
  • 16. 16 Nitrification process design Organic matter removal prior to nitrification: rBOD = 3,9 g BOD5/m2d (10 oC) (kT = 1.06(T-10)) Nitrification rate (when NH4-N is the limiting substrate) rN = k . (Sn)n rN = nitrification rate (g NH4-N/m2.d) SN = NH4-N concentration in the reactor n = reaction rate order - n is normally set at 0,7 k = reactor rate constant – 0,4 – 0,6 (varies with the organic load, i.e pre-treatment) NH4-N is only rate limiting at low NH4-concentrations (ca 1-2 mg NH4-N/l). At higher concentrations, SN will be determined by the bulk liquid DO concentration and Sn should be replaced by Sn,transition Sn,transition = (DO-0,5) / 3,2 SET AS
  • 17. 17 Nitrification rates in full‐scale plants 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 0.0 0.4 0.8 1.2 1.6 2.0 2.4 2.8 3.2 Ammonium load, g NH4-N/m 2 /d Removal rate, g NH 4 -N/m 2 /d R4 R4 + R5 Temp. 11 º C Lillehammer WWTP Intensive study at Lillehammer WWTP • Very high max rates (1,4 g NH4/m2.d) • Complete nitrification at < 1,2 g NH4/m2.d (Rusten and Ødegaard, 2007) 10oC 1.17 g NH4-N/m2d 10oC 1.17 g NH4-N/m2d Nitrification performance at Givaudan WWTP Switzerland (Tschui, personal comm.) Challenge: Alkalinity limitation. Recommendation > 1,5 meq./l residual alkalinity SET AS
  • 18. 18 N‐removal 1. If carbon source is abundant and treatment efficiency needed is < 75 %, pre‐DN is preferable 2. If carbon source is limited and treatment efficiency required is > 75 %, combined‐DN is preferable 3. If, in addition to 2., space is very limited, post‐DN may be preferable Choice of process is primarily dependent on availability of internal carbon source for denitrification and treatment efficiency requirement: C Post-denitrification Pre-denitrification C Combined denitrification C C Post-denitrification Pre-denitrification C Combined denitrification Post-denitrification Pre-denitrification C C Combined denitrification SET AS
  • 19. 19 Denitrification R= r/(r+1) C/N (g BSCOD/g N) R= r/(r+1) C/N (g BSCOD/g N) There is a limit to treatment efficiency in conventional pre‐DN caused by the oxygen recycle Rusten, Hem and Ødegaard, 1995 Pre‐denitrification rDN = k * [SCOD/(SCOD+KS,COD)]* [SNO3/(SNO3+KS,NO3)] SET No carbon limitation as long as: • g CODadded/ g NO3‐Nequiv. is > 3,5 • NO3‐N may be the limiting factor at low NO3‐N Rusten, Hem and Ødegaard, 1995 Post‐denitrification
  • 20. 20 The combined pre‐ and post‐DN MBBR process Recirculation of NO3‐N DN‐rate controlled by carbon addition • Aerated when larger nitrification volume is needed (winter). • Not aerated in summer – more pre‐DN volume – higher recycle in summer Nitrification rate controlled through O2 Low recirculation of oxygen Not aerated nitrification O2 consumption only ‐ in order to reduce the amount of recycled O2 SET AS Carbon
  • 21. 21 DN‐rates with external carbon sources (practical results from combined‐DN plant) 0 1 2 3 4 5 3 5 7 9 11 13 15 17 Temperature, °C Denitrification rate, g NO 3 -N/m 2 /d Ethanol Methanol Monopropylene glycol Rusten et al, 1996 SET AS
  • 22. 22 Four Norwegian combined DN‐plants Flocc. Secondary sed. Primarysed. Chem. Carbon NO3 recycle AE AN AN/ AE AE AE AN AN AE a) Flocc. DAF Primarysed. Chem. Carbon NO3 recycle AE AN AN/ AE AE AE AN AE b) Primarysed. Chem. Carbon NO3 recycle AE AN AE AE AN AE c) Secondarysed. AN Flocc. Secondary sed. Primarysed. Chem. Carbon NO3 recycle AE AN AN/ AE AE AE AN AN AE a) Flocc. DAF Primarysed. Chem. Carbon NO3 recycle AE Flocc. Secondary sed. Primarysed. Chem. Carbon NO3 recycle AE AN AN/ AE AE AE AN AN AE a) Flocc. DAF Primarysed. Chem. Carbon NO3 recycle AE AN AN/ AE AE AE AN AE b) Primarysed. Chem. Carbon NO3 recycle AE AN AE AE AN AE c) Secondarysed. AN Lillehammer WWTP Nordre Follo and Gardermoen WWTP RA2 WWTP SET AS
  • 23. 23 MBBR design/operating values and performances Parameter Lille- hammer Nordre Follo Garder- moen NRA Average flow (m3/h) Max flow (m3/h) Temperature (oC) 1200 1900 3-14 750 1125 6-14 920 1300 4-14 2300 7200 7-14 MBBR Total volume (m3) Carrier fill fraction (%) Average(max) HRT (hrs) 3840 65,0 3,2 (2,0) 3710 66,2 4,9 (3,3) 5790 58.5 6,3 (4,5) 19370 42,7 8,4 (2,7) Carbon source g CODadded/g TNequiv Ethanol 3.3 Methanol (now glycol) 2.2 Glycol 2.4 Methanol (now glycol) - Efficiency, 2005 Average out conc. and treatment efficiency BOD5 COD Tot N Tot P Out Rem mg/l % 2,2 99 35 93 2,9 92 0.12 98 Out Rem mg/l % 2,8 98 39 91 9,7 73 0.20 96 Out Rem mg/l % 3,2 98 25 96 7,0 87 0.18 98 Out Rem mg/l % 4,0 95 27 93 5,0 83 0.05 99 SET AS
  • 24. 24 MBBR biomass separation alternatives MBBR – Coag./settling (also Actiflo) MBBR - settling MBBR - flotation MBBR – media filtration MBBR – microscreening (i.e. Disc filtration) MBBR – Membrane filtration SET AS
  • 25. 25 Anaerobic ammonium oxidation (Anammox): NH4 + + NO2 - -> N2 + 2H20 Advantages • No carbon source needed • Less air needed (than in N/DN): ~1,8 g O2/g N (60 % less) • Very low sludge production ~ 0,11 g SS/g NH4-N • Less CO2 - production/ less alkalinity consumption Disadvantages • Some nitrate is formed: i.e max N-removal ca 80 % • Nitrite has to be generated • Slow growth rate - long start-up • Necessary to have a long SRT (Biofilm or granules favorable) SET AS Primarily used for N‐removal in sludge water treatment
  • 26. 26 Anammox with MBBR (Christensson et al, 2013) Biofilm Media Liquid Nitritation NH4 + NO2 ‐ AOB Anammox N2 O2 Aerobic Anoxic Biofilm Media Liquid Nitritation NH4 + NO2 ‐ AOB Nitritation NH4 + NO2 ‐ AOB Anammox N2 Anammox N2 O2 O2 Aerobic Anoxic MBBR = 0.5-1.5 mg/L AOB in biofilm = NO2 - limitation IFAS SET AS Biofilm Media Liquid Nitritation NH4 + NO2 ‐ AOB Anammox N2 O2 Anoxic Media Liquid Nitritation NH4 + NO2 ‐ AOB Anammox N2 O2 Anoxic < 0.5 mg/L Flocs (1-3 g/L) AOB in flocs = less NO2 - limitation
  • 27. 27  BioFarm concept = Providing seeded carriers for rapid start‐up of future full‐scale ANITATM Mox units Seeded carriers ANITA™ Mox – Sjölunda WWTP, Malmö (Sweden) • 4 x 50m3 MBBR • Capacity = 200 kgN/d • 800‐1200 mgN‐NH4/L • 1st ANITA™ Mox reference • Flexibility for fullscale testing SET AS
  • 28. 28 Full‐scale test results ANITA™Mox , Sjölunda WWTP (Christensson et al, 2013) SET AS • High removal rates and good N‐removal with MBBR • Very high removal rate with IFAS ‐ up to 3 kg NH4‐N/m3.d (7.5 g NH4‐N/m2.d) • Energy consumption : 1.2 kWh/kg NH4‐N removed 0 0,5 1 1,5 2 2,5 3 3,5 NH4 load & removal (kgN/m 3 .d) NH4‐load NH4‐removal 0 10 20 30 40 50 60 70 80 90 930 950 970 990 1010 1030 1050 1070 1090 1110 1130 1150 %NH4 and %TN removal Days %TN‐removal %NH4‐removal %NO3‐prod : NH4‐rem MBBR Tran- sition IFAS • K5 – filling fraction 50 % • DOMBBR = 1.0 ‐ 1.3 mg/l • DOIFAS = 0.2 ‐ 1.0 mg/l • MLSSMBBR = 20–400 mg/l • MLSSIFAS = 1800 – 4600 mg/l
  • 29. 29 Removal of pharmaceuticals (Falås, 2013) Comparison between activated sludge and carrier‐based processes
  • 30. 30 Removal og pharmaceuticals in the biomass from an IFAS plant (Bad Ragaz WWTP, CH) 0 0.2 0.4 0.6 0.8 1 1.2 0 5 10 15 20 25 C/Cinitial Time (h) Atenolol 0 0.2 0.4 0.6 0.8 1 1.2 0 5 10 15 20 25 C/Cinitial Time (h) Carbamazepine Anoxic sludge Oxic sludge Carriers 0 0.2 0.4 0.6 0.8 1 1.2 0 5 10 15 20 25 C/Cinitial Time (h) Mefenamic acid 0 0.2 0.4 0.6 0.8 1 1.2 0 5 10 15 20 25 C/Cinitial Time (h) Diclofenac (Falås et al, 2014) Where does the removal take place?
  • 31. 31 Conclusions 1. The MBBR is a well‐proven, robust and very compact technology (Now altogether > 800 plants in > 50 countries – 50/50 industrial/municipal). 2. The MBBR is used in pure biofilm processes as well as in hybrid processes (IFAS) 3. The combined pre‐ and post denitrification MBBR process is especially suitable for low C/N waters and offers great flexibility in operation 4. The MBBR is very efficient in the upgrading of activated sludge plants: a. as ”roughing” reactor before AS in order to reduce organic matter loading b. in an IFAS‐process in order to achieve: nitrification, N‐removal and or P‐removal 5. The MBBR‐based processes are especially suitable for developing special cultures – for instance for: a. N‐removal by anammox processes b. Organic micropollutants removal SET AS
  • 32. 32 Thanks a lot for listening The Pulpit, Lysefjord, Norway
  • 33. 33 Upgrading AS‐plants by the use of MBBR Three options for nitrification Pure MBBR BAS HYBAS SET AS IFAS MBBR MBBR Activated sludge Activated sludge + MBBR
  • 34. 34 SRT Vs Temperature 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Temperature, C SRT, d ATV Design Curve Nitrifier Growth Rate Broomfield (4.7 days at 13C) Cheyenne (4.5 days at 9C) Yucaipa (2.3 days at 18C) Taos (5.2 days at 8C) Oxford (3.9 days at 11C) Fields Point & Flagstaff (3.3 days at 14C) James River (2.7 days at 14C) Greensboro (5.25 days at 14C) Springettsbury (2.4 days at 10C) Lubbock (3.8 days at 15C) Fairplay (2.5 days at 5C) New Castle (4.1 days at 10C) Crestted Butte (3.2 days at 7.5C) Mamaroneck (1.8 days at 13C) Georgetown (5.0 days at 9C) SET AS Design SRT vs temp for full scale IFAS systems (installed by ANOXKALDNES)