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Presented by
Dr. Neelam
Department of chemistry
Polymers - II
Classification based on Mechanism of polymerisation:
(i) Chain growth polymerisation : Additional polymers are chain
growth polymers. Chain growth polymerisation takes place by-
(a) Free radical mechanism :
(b) Cationic mechanism :
Alkenes having electron releasing group are polymerised by cationic
mechanism.
Examples : CH2=CH–O–CH3
(c) Anionic mechanism :
Alkenes having electron withdrawing group are polymerised by cationic
mechanism.
Examples : CH2=CH–CN
(ii) Step growth polymerisation :
Condensation polymers are step growth polymer. This polymerisation
progresses through step by step.
Examples : Nylon, bakelite, dacron, etc.
Some common addition polymers/chain growth polymers
Some condensation polymers/step growth polymers
Thank you

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Polymer 2

  • 1. Presented by Dr. Neelam Department of chemistry Polymers - II
  • 2. Classification based on Mechanism of polymerisation: (i) Chain growth polymerisation : Additional polymers are chain growth polymers. Chain growth polymerisation takes place by- (a) Free radical mechanism :
  • 3. (b) Cationic mechanism : Alkenes having electron releasing group are polymerised by cationic mechanism. Examples : CH2=CH–O–CH3 (c) Anionic mechanism : Alkenes having electron withdrawing group are polymerised by cationic mechanism. Examples : CH2=CH–CN (ii) Step growth polymerisation : Condensation polymers are step growth polymer. This polymerisation progresses through step by step. Examples : Nylon, bakelite, dacron, etc.
  • 4. Some common addition polymers/chain growth polymers
  • 5.