Natural rubber is a polyisoprene polymer that is commercially produced from the latex of the Hevea Brasiliensis tree. It consists of cis-1,4-polyisoprene along with other components that make up around 6-8% of the product. Virtually all natural rubber comes from rubber trees cultivated in Southeast Asia. The latex is extracted from the tree through incisions and is coagulated and dried into sheets. Natural rubber can be vulcanized with sulfur and other agents. Its properties include stress crystallization and good abrasion resistance, making it suitable for applications like tires, hoses and other rubber goods.
The objective of this presentation is to give an overview of rubber compounding. We will briefly focus on:
Elastomer System
Filler System
Protection system
Process Aids
Cure System
Natural Rubber - Sources, Coagulation & Processing of Coagulate, Structure & ...Geevarghese George
Sources, Plantation Economy
Coagulation & Processing of Coagulate
Structure & Composition
Properties of raw NR
Compounding, Processing of NR
Properties of NR vulcanizates
Uses of NR
Competitive products of NR
The objective of this presentation is to give an overview of rubber compounding. We will briefly focus on:
Elastomer System
Filler System
Protection system
Process Aids
Cure System
Natural Rubber - Sources, Coagulation & Processing of Coagulate, Structure & ...Geevarghese George
Sources, Plantation Economy
Coagulation & Processing of Coagulate
Structure & Composition
Properties of raw NR
Compounding, Processing of NR
Properties of NR vulcanizates
Uses of NR
Competitive products of NR
polymers which possess the property of elasticity is called rubber. Temporary deformation in structure on applying some stress is more than 600 e.u. When stress is applied polymer chain gets partially aligned with respect to another there by causing crystallisation, which makes the polymer stiff.
About different types of pultrusion resinsSugamPolytech
Also, a typical type of polyester resin is quite resistant to water. As a result, it is assumed to be one of the most beneficial for manufacturing products, usually done in small sarcastic configurations.
Recycling and Reuse of Rubber Goods.pptxLuis Tormento
Why Recycle or reuse rubber goods?
Rubber Recovery can be a difficult process. There are many reasons, however why rubber should be reclaimed or recovered?
Recovered rubber can cost half that of natural or synthetic rubber.
Recovered rubber has some properties that are better than those of virgin rubber.
Producing rubber from reclaim requires less energy in the total production process than does virgin material.
It is an excellent way to dispose of unwanted rubber products, which is often difficult.
It conserves non-renewable petroleum products, which are used to produce synthetic rubbers.
Recycling activities can generate work in developing countries.
Many useful products are derived from reused tires and other rubber products.
If tires are incinerated to reclaim embodied energy then they can yield substantial quantities of useful power. For example, some cement factories use waste tires as a fuel source.
polymers which possess the property of elasticity is called rubber. Temporary deformation in structure on applying some stress is more than 600 e.u. When stress is applied polymer chain gets partially aligned with respect to another there by causing crystallisation, which makes the polymer stiff.
About different types of pultrusion resinsSugamPolytech
Also, a typical type of polyester resin is quite resistant to water. As a result, it is assumed to be one of the most beneficial for manufacturing products, usually done in small sarcastic configurations.
Recycling and Reuse of Rubber Goods.pptxLuis Tormento
Why Recycle or reuse rubber goods?
Rubber Recovery can be a difficult process. There are many reasons, however why rubber should be reclaimed or recovered?
Recovered rubber can cost half that of natural or synthetic rubber.
Recovered rubber has some properties that are better than those of virgin rubber.
Producing rubber from reclaim requires less energy in the total production process than does virgin material.
It is an excellent way to dispose of unwanted rubber products, which is often difficult.
It conserves non-renewable petroleum products, which are used to produce synthetic rubbers.
Recycling activities can generate work in developing countries.
Many useful products are derived from reused tires and other rubber products.
If tires are incinerated to reclaim embodied energy then they can yield substantial quantities of useful power. For example, some cement factories use waste tires as a fuel source.
The objective of this presentation is to give a briefly description of:
The legislation about the use of rubber in contact with food.
Both in US / Europe.
Implications.
Challenges for the future.
While each component is designed to meet a set of operational requirements, there are a number of common principles that will reduce the time and cost to obtain an economical component. Many of these are evident, but some need a perfect understanding of the differences between molding thermoset rubbers and molding plastics.
The parts will be obtained at a minimal cost when there are no surprises in the design, delivery or use. Good communication and prior contact with suppliers will particularly assist in the development of the new part
What is and what is the function of a rubber seal
The Increasing of the speed of mechanical systems, driven by the desire for greater productivity, leads to higher operating temperatures and reduced fluid viscosities. This, coupled with higher pressures, causes an increasing tendency for fluid to leak. This leak in fuel systems that handle highly flammable solvents cannot be overlooked as there is a high probability of a fire hazard.
For this reason it has become common practice to include a safe leak path in the system design, to an escape or collection point, in order to minimize risk.
Seals prevent fluid from escaping from a hollow cylinder when a shaft penetrates the cylinder wall. Most commonly, the axis will have a rotary or linear motion. If a seal is not made for functional requirements, or installed and maintained properly, it can fail, causing fluid loss. The two main functions of a seal are to keep the fluid in while keeping dirt and debris out.
Rubber injection molding is not a new idea. The process has been successfully developed in the United States since the 1940s, albeit on a very limited scale. Today, however, injection molding has become an increasingly important manufacturing process for molded rubber parts, since it is an essentially high-speed operation, which conducts itself through a semi-automatic or fully automatic system.
Although injection molding‚ is used for a relatively small proportion of molded artifacts today, by the mid-1970s it will be the method of choice for approximately 25% of all technical molded parts.
A hose is a flexible tube designed to transport fluids from one location to another. The shape of a hose is generally cylindrical. Having a circular cross section. Hose design is based on a combination of application and performance. Common factors are size, working pressure, weight, length, shape (straight or molded) and chemical compatibility.
Transformation and vulcanization of rubberLuis Tormento
In the manufacture of molded rubber artifacts, the raw compound is introduced into the cavity of a heated metallic mold, with the shape of the artifact to be manufactured, and, under molding pressure, the plastic compound flows and acquires the shape of the cavity; the heat transmitted from the press to the mold vulcanizes the compound, which permanently acquires the configuration adopted in the mold
Reinforced rubber products combine a rubber matrix and a reinforcement material so that high rates of strength and flexibility can be achieved. The reinforcing material, usually a type of fiber, provides strength and rigidity. The rubber matrix, with low strength and rigidity, provides air-fluid tightness and supports the reinforcement materials to maintain their relative positions. These positions are of great importance as they influence the resulting mechanical properties.
Rubber and textiles have been used together, each working in combination to deliver performance in a wide range of applications, since the early days of the rubber industry in the most developed areas of the world.
For many years, sizable rubber companies, using textile reinforcement, employed their own textile technologist working alongside rubber technologists. But in the last third of the 20th century, faced with global competition and the need to control and reduce total costs, this luxury has practically disappeared, as well as large companies (especially tire companies). Most organizations now rely on their textile suppliers to provide technical knowledge and experience. As a result, the textile component for many applications is now considered in the same way as other raw materials, that is, as an existing product, which only requires introduction into the manufacturing process, without any special knowledge or understanding, and is supplied with an agreed specification, which was probably drawn up by the textile manufacturer.
Zinc oxide (ZnO) is added to rubber compounds to activate sulfur vulcanization and thereby reduce the vulcanization time. ... The release of zinc into the environment from rubber occurs during the production, disposal, and recycling of rubber products (e.g., through leaching in landfill sites).
Its most common application is as a vulcanization activator in conjunction with stearic acid. Its addition is recommended at the beginning of the mixture, after the addition of stearic acid - its addition before stearic acid causes difficulty in incorporation and problems with dispersion.
Nanotechnology applied in rubber compounds current market and new developmentsLuis Tormento
Nanotechnology is fast becoming a key technology of the 21st century.
Nanotechnology can be defined as the engineering of matter at scales smaller than 100 nanometers (nm), to achieve properties and functions depending on size.
Nanotechnology is seen as one of the key technologies of the future. Nanotechnology refers to a wide range of scientific and technological phenomena which focuses on nanoscale (0.1 to 100 nm). It is the science of developing materials through individual control of atoms and molecules to create products that are thousands of times smaller than current technology allows for. The basis of this technology is to modify the inherent material properties such as color, abrasion resistance, conductivity, etc. the reduction of its size without modifying its chemical composition. nano-particles artificially produced have new properties which are important for the development of new products and applications.
The composition of an organic coating (paint) may be may be a formulation simple or complex, with a variety of materials, each having a specific function. The formulations generally have three components designed to be permanent and serve specific functions in the dry film. These components are the pigment, carrier and additives. Pigments provide color and other functions. The vehicles commonly called ligands act as an adhesive to adhere the pigment particles to the substrate or to each other. Finally, the additives are chemicals which modify the coating properties in fluid or solid state.
Hierarchical Digital Twin of a Naval Power SystemKerry Sado
A hierarchical digital twin of a Naval DC power system has been developed and experimentally verified. Similar to other state-of-the-art digital twins, this technology creates a digital replica of the physical system executed in real-time or faster, which can modify hardware controls. However, its advantage stems from distributing computational efforts by utilizing a hierarchical structure composed of lower-level digital twin blocks and a higher-level system digital twin. Each digital twin block is associated with a physical subsystem of the hardware and communicates with a singular system digital twin, which creates a system-level response. By extracting information from each level of the hierarchy, power system controls of the hardware were reconfigured autonomously. This hierarchical digital twin development offers several advantages over other digital twins, particularly in the field of naval power systems. The hierarchical structure allows for greater computational efficiency and scalability while the ability to autonomously reconfigure hardware controls offers increased flexibility and responsiveness. The hierarchical decomposition and models utilized were well aligned with the physical twin, as indicated by the maximum deviations between the developed digital twin hierarchy and the hardware.
Explore the innovative world of trenchless pipe repair with our comprehensive guide, "The Benefits and Techniques of Trenchless Pipe Repair." This document delves into the modern methods of repairing underground pipes without the need for extensive excavation, highlighting the numerous advantages and the latest techniques used in the industry.
Learn about the cost savings, reduced environmental impact, and minimal disruption associated with trenchless technology. Discover detailed explanations of popular techniques such as pipe bursting, cured-in-place pipe (CIPP) lining, and directional drilling. Understand how these methods can be applied to various types of infrastructure, from residential plumbing to large-scale municipal systems.
Ideal for homeowners, contractors, engineers, and anyone interested in modern plumbing solutions, this guide provides valuable insights into why trenchless pipe repair is becoming the preferred choice for pipe rehabilitation. Stay informed about the latest advancements and best practices in the field.
Saudi Arabia stands as a titan in the global energy landscape, renowned for its abundant oil and gas resources. It's the largest exporter of petroleum and holds some of the world's most significant reserves. Let's delve into the top 10 oil and gas projects shaping Saudi Arabia's energy future in 2024.
Student information management system project report ii.pdfKamal Acharya
Our project explains about the student management. This project mainly explains the various actions related to student details. This project shows some ease in adding, editing and deleting the student details. It also provides a less time consuming process for viewing, adding, editing and deleting the marks of the students.
Water scarcity is the lack of fresh water resources to meet the standard water demand. There are two type of water scarcity. One is physical. The other is economic water scarcity.
Sachpazis:Terzaghi Bearing Capacity Estimation in simple terms with Calculati...Dr.Costas Sachpazis
Terzaghi's soil bearing capacity theory, developed by Karl Terzaghi, is a fundamental principle in geotechnical engineering used to determine the bearing capacity of shallow foundations. This theory provides a method to calculate the ultimate bearing capacity of soil, which is the maximum load per unit area that the soil can support without undergoing shear failure. The Calculation HTML Code included.
Final project report on grocery store management system..pdfKamal Acharya
In today’s fast-changing business environment, it’s extremely important to be able to respond to client needs in the most effective and timely manner. If your customers wish to see your business online and have instant access to your products or services.
Online Grocery Store is an e-commerce website, which retails various grocery products. This project allows viewing various products available enables registered users to purchase desired products instantly using Paytm, UPI payment processor (Instant Pay) and also can place order by using Cash on Delivery (Pay Later) option. This project provides an easy access to Administrators and Managers to view orders placed using Pay Later and Instant Pay options.
In order to develop an e-commerce website, a number of Technologies must be studied and understood. These include multi-tiered architecture, server and client-side scripting techniques, implementation technologies, programming language (such as PHP, HTML, CSS, JavaScript) and MySQL relational databases. This is a project with the objective to develop a basic website where a consumer is provided with a shopping cart website and also to know about the technologies used to develop such a website.
This document will discuss each of the underlying technologies to create and implement an e- commerce website.
2. Natural rubber
• Introduction
• Basically, natural rubber consists of cis-1,4-
polyisoprene. The commercial product has,
along with polyisoprene, other components
(proteins, phosphatides, mineral salts, etc.)
that represent 6-8% of the product. Some of
these impurities have a beneficial effect; can,
for example, act as natural antioxidants.
4. Polyisoprene
• There are many plant species that produce rubber,
but virtually all natural rubber used industrially
comes from the Hevea Brasiliensis tree, originally
from the Amazon rainforest and later cultivated on
plantations in Southeast Asia and equatorial Africa.
Propagation is carried out using the technique of
grafting or cloning, ensuring that the entire
plantation or a good part of it derives from a single
plant.
5. Obtaining methods and commercial
types R
• Rubber is found in the Hevea tree in the form of a
colloidal suspension with a milky appearance, called
latex, which has 30% rubber. The latex circulates
through a network of lactiferous channels from which
it is extracted through an incision (bleeding) in the bark
that surrounds these channels, which causes the
secretion of latex for a few hours, until, due to
spontaneous coagulation, the incision is closed; the
incision must be redone in order for the process to be
repeated, but this operation must be done on alternate
days.
6. Obtaining methods and commercial
types R
• The latex that flows from the incision is collected in
properly disposed containers, the bleeding is done
in the early hours of the morning and, at the end of
the day, the latex accumulated in the container is
collected. Before making a new incision, the
existing clot is collected in the vessels, formed by
the evaporation of the residual latex from the
previous operation (known as the bottom of the
vessel - in English cum lump) and the clot strip
formed on the previous incision (called tree-lace or
sernamby).
7. Obtaining methods and commercial
types R
• The collected latex is taken to a unit where it
is homogenized in large storage tanks, and
then, by adding diluted acetic or formic acid,
the latex is coagulated into 4-5 cm thick
plates.
8. Traditional business types
• The plates are successively washed and laminated
between cylinders; gradually, these cylinders
reduce the thickness of the plate and eliminate
residual water; the last pair of cylinders are
grooved, so that the rubber has a rough surface,
facilitating the subsequent drying of the board.
Drying is done by various processes, with
moderately hot air and heltered from light (Air
Dried Sheet or ADS ) or, more often, by smoke from
combustion wood (Smoked Sheet or RSS, Ribbed
Smoked Sheet), which is darker in color than ADS
9. Traditional business types
• Another alternative is the manufacture of white or
pale crepe (Pale Crepe). In this process, partial
coagulation is carried out under controlled
conditions, so that only the so-called yellow
fraction, consisting mainly of lutoids responsible for
the color of the latex, is separated from the rest of
the latex, which will then be coagulated with the
addition of more acid. The clot is dried at room
temperature and protected from light.
10. Traditional business types
• A similar treatment to the one used to obtain the
pale crepe is also applied to the clots collected as a
by-product (bottom of a vessel, tree-laces, etc) and
we obtain the brown crepes (Brown Crepes)
• The classification of these types of natural rubber is
made by comparison in terms of color, presence
and frequency of impurities, mold, etc. with the
standards described in the International Quality
and Packaging Standards for types of Natural
Rubber, better known as the Green Book.
11. Technically Specified Rubber
• Although many use the Green Book as a standard,
other standards were developed to control the
quality of natural rubber: in 1965 the System was
introduced in the market Standard Malaysian
Rubber or SMR (Standard Malaysian Rubber), a
procedure that was followed by other producing
countries, until the International Organization for
Standardization, ISO, issued the ISO 2000 standard
for the so-called TSR (Technically Specified Rubber)
rubbers .
12. Technically Specified Rubber
• The characteristics controlled by TSR rubbers are:
• the content of impurities, in the sense of foreign
bodies, such as grains of sand, usks, etc
• ash and nitrogen content;
• volatile matter content;
• plasticity retention index or PRI (Plasticity
Retention Index); in some
• types, the coloring
13. Formulations
• Due to the activating effect of the methyl
group on the reactivity of the double bond of
the polyisoprene chain, natural rubber can be
vulcanized with virtually all known vulcanizing
agents.
14. Formulations
• In the case of sulfur vulcanization, the most common, it presents a relatively
high vulcanization speed. Doses of vulcanizing ingredients depend on their
nature and processing conditions:
• 2-3 parts sulfur, 0.4-1 part accelerators, 4-5 parts zinc oxide and 2-3 parts
stearic acid are common. The only inconvenience is the strong tendency to
reversal, which is verified by a decrease in hardness and mechanical
resistance, when surpassing the vulcanization plateau; this trend can be the
cause of problems in the injection or continuous vulcanization of extruded
profiles, or when the greater thickness of the part requires the use of long
vulcanization times. In this case, we resort to the so-called EV (Efficient
Vulcanization) vulcanizing systems , characterized by low doses of sulfur, 2.0-
5.0 parts, complemented by a sulfur donor and a high dose of accelerators, 3-
5 parts. With these systems, the
15. Formulations
• Crossing bridges are basically monosulfidic or
disulfidic, thermally more stable than
polysulfidic ones. Thus, the vulcanizates are
better able to resist an eventual excess of
vulcanization, as well as having better
resistance to thermal aging. Another solution
is the use of a semi-EV system, with medium
doses of sulfur and accelerators.
16. Formulations
• Natural rubber, like other rubbers that
crystallize under stress, has good mechanical
resistance and does not require fillers; for this
reason, they are used to make the formulation
cheaper and to improve resistance to abrasion
and tearing. Both reinforcing fillers and fillers
in moderate proportions contribute to
facilitate the processing of compounds, mainly
in extrusion and calendering
17. Formulations
• Natural rubber is miscible with other general
purpose rubbers (IR, SBR, BR) and with special
rubbers (NBR, CR, XIIR, EPDM, etc.), which allows
us to combine properties between different
polymers; only saturated (EPM) or slightly
unsaturated (IIR) rubbers have compatibility issues.
• The viscosity of natural rubber is reduced by
chewing; thus, plasticizers are not as necessary as
in synthetic rubbers, but they are often used to
facilitate and improve the dispersion of fillers
18. Processing
• The first operation in the preparation of any NR
compound is to carry out the mastication process, to
reduce its initial high viscosity, enabling the incorporation
of the other ingredients.
• Since 1939, it has been experimentally known that
chewing carried out at temperatures of 100-115°C offers
the best solution to the viscosity problem; it is believed
that there is an oxidation process involved, as chewing
experiments carried out in an inert atmosphere had no
effect.
19. Processing
• In practice, mastication is carried out in
internal mixers at elevated temperatures and
often in the presence of a peptizer, which
basically catalyzes the oxidation process.
• If the process is carried out in a cylinder mixer,
the temperature must remain at 70°C. The use
of TSR-type rubbers reduces or even
eliminates this step.
20. Processing
• Once the viscosity is reduced, the preparation of
the compound does not present any problems,
since the high nerve of the natural rubber ensures
the existence of the necessary shear forces for the
adequate dispersion of the loads.
• In the press molding stages, the only problem is the
tendency of reversal due to excessive vulcanization;
the selection of an adequate vulcanizing system
and vulcanization conditions solve this
inconvenience, but in special cases we must resort
to high frequency preheating, mainly in thick
artifacts
21. Processing
• pecial cases we must resort to high frequency
preheating, mainly in thick artifacts
• In extrusion and calendering operations in
compounds with moderate loads, it does not
present processing problems
22. Properties and Applications
• One of the main characteristics that gives natural
rubber its properties, and is a consequence of its
structural regularity, is its tendency to
crystallization. Crystallization occurs when the NR
undergoes some type of deformation or
temperature reduction, making the product more
rigid and harder. Its maximum and spontaneous
crystallization occurs at -26ºC and is a totally
reversible process, requiring only a slight heating
• This phenomenon is less accentuated in
vulcanizates
23. Properties and Applications
• Abrasion resistance depends a lot on the type
of service: for example, in tires, due to the
type of service, abrasion is lower than SBR;
however, in mining hoses its behavior is
superior.
• Its main use is in large tires, such as tractor
and truck tires, aircraft and racing car tires,
mining hoses, etc