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Please assist. Done perfectly.
Portland uses sodium hydroxide (NaOH) to increase the pH of its drinking water to 8.0 as a high
pH values, lead wil form lead hydroxides (Pb(OH)2) What concentration of Pb2* is expected to
be found in the drinking water supply if lead pipes/fixtures are present (assume euilibrium
conditions)? Is this concentration below the EPA action level threshold of 15 ppb? HINTS:
Pb(OH)2(s) ?? Pb2+ + 2OH' Ksp : 1.2*10-15 Recall, when using the Ksp equation, the
concentrations are all in M (moles/L).
Solution
Pb(OH) 2 -----> Pb +2
+ 2OH -
K sp = [Pb +2
] [OH -
] 2
= 1.2 x 10 -15
pOH = -log[OH -
] = 6 (pOH = 14-pH = 14-8 =6)
[OH -
] = 10 -6
= 0.000001
K sp = [Pb +2
] [OH -
] 2
= 1.2 x 10 -15
[Pb +2
] (10 -6
) 2
= 1.2 x 10 -15
[Pb +2
] = 1.2 x 10 -15
/10 -12
= 1.2 x 10 -3
M
[Pb +2
] = 0.0012 moles/lt = 0.0012x mol wt = 12 x 207.2x 10 -4
= 2486.4 × 10 -4
g/lt = 24864
ppb
No, the concentration of lead is more than thresold 15ppb
Please assist- Done perfectly-  Portland uses sodium hydroxide (NaOH).docx

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Please assist- Done perfectly- Portland uses sodium hydroxide (NaOH).docx

  • 1. Please assist. Done perfectly. Portland uses sodium hydroxide (NaOH) to increase the pH of its drinking water to 8.0 as a high pH values, lead wil form lead hydroxides (Pb(OH)2) What concentration of Pb2* is expected to be found in the drinking water supply if lead pipes/fixtures are present (assume euilibrium conditions)? Is this concentration below the EPA action level threshold of 15 ppb? HINTS: Pb(OH)2(s) ?? Pb2+ + 2OH' Ksp : 1.2*10-15 Recall, when using the Ksp equation, the concentrations are all in M (moles/L). Solution Pb(OH) 2 -----> Pb +2 + 2OH - K sp = [Pb +2 ] [OH - ] 2 = 1.2 x 10 -15 pOH = -log[OH - ] = 6 (pOH = 14-pH = 14-8 =6) [OH - ] = 10 -6 = 0.000001 K sp = [Pb +2 ] [OH - ] 2 = 1.2 x 10 -15 [Pb +2 ] (10 -6 ) 2 = 1.2 x 10 -15 [Pb +2 ] = 1.2 x 10 -15 /10 -12 = 1.2 x 10 -3 M [Pb +2 ] = 0.0012 moles/lt = 0.0012x mol wt = 12 x 207.2x 10 -4 = 2486.4 × 10 -4 g/lt = 24864 ppb No, the concentration of lead is more than thresold 15ppb