Photochemical smog is formed when sunlight reacts with nitrogen oxides and volatile organic compounds in the atmosphere. Nitrogen oxides primarily come from vehicle and truck exhaust, while volatile organic compounds are emitted from numerous sources like paints, pesticides, and building materials. When these pollutants react in the presence of sunlight, they form secondary pollutants like peroxyacetyl nitrate which can cause respiratory issues in humans. Exposure to smog has been linked to diseases like lung cancer and can negatively impact vegetation and animals as well. Reducing emissions from vehicles, industry, and consumer products can help lower photochemical smog levels.