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Organic
Herbicides:
Efficacy and
Safety
Dr. Scott Nissen
Weed Scientist
Colorado State University
Rank the Following for Toxicity
•
•
•
•
•
•
•
•
•

Caffeine
2,4-D (common lawn herbicide)
Aspirin
Roundup (most common herbicide used
in the world)
Nicotine
Malathion (insecticide)
Tordon (common non-crop herbicide)
Gasoline
Salt
Toxicity Based on LD50 Values
•
•
•
•
•
•
•
•
•

Nicotine
Gasoline
Caffeine
2,4-D
Aspirin
Malathion
Salt
Roundup
Tordon

LD50 50-60
LD50 50-100
LD50 192
LD50 699
LD50 750
LD50 1000-2800
LD50 3320-4180
LD50 4300
LD50 8200
General Weed Management Factors
• Exclusion
• Elimination
• Prevent
Establishment
• Removal
• Amelioration
Weed Management for Organics
-Exclusion• Field selection
– a good choice
– knowledge needed of sites
– usefulness depends on available
certified land

• Prevent weed additions
– critical for Organics
– “bring-ins” may contain weeds
• Organic mulches
• Raw manures
Weed Management for Organics
- Elimination • Prevent weed build-up
– timely cultivation, tillage
– purposeful plantings – don’t let weeds
take over

• Weed population reduction
– perennial management through
grazing
– fallow / tillage cycles
– solarization
– fumigants???
Weed Management for Organics
- Prevent Establishment • Preemergence “herbicides”
– corn gluten meal, mustard meal

• Timely cultivation
• Stale seedbeds
• Cover crop management
– Species important: e.g. rye
– Crop sequence

• Grazing
• Mulches
– organic and synthetic
Weed Management for Organics
- Weed Removal –
“Stop ‘em in their tracks”

• Mechanical – cultivation
–keep it shallow
–minimize injury to the crop
–Improve the root zone

• Manual
– choose easy-to-use tools
Weed Management for Organics
- Weed Removal (cont.)–
“Stop ‘em in their tracks”

• Chemical: vinegar, pelargonate, etc.
– currently just contact activity
– good foliage cover needed

• Physical: energy consumers!
– flame
• special equipment, directed flame
• best for small, annual weeds

– steam
Weed Management for Organics
- Amelioration • Crop Selection
– use crops that tolerate weeds
• rapid growth, dense canopy

– crops that allow weed control
• sweet corn – easily cultivated

• Give crop an edge
– plant date
– transplants
USDA National Organic Program Standards
• Consistent national standards
• Any farm, wild crop harvesting, or
handling operation that wants to sell
an agricultural product as
organically produced must adhere to
the NOP standards
• Requirements apply to the way the
product is created, not to
measurable properties of the
product itself
USDA NOP Standards
• Crop pests, weeds, and diseases will
be controlled primarily through
management practices including
physical, mechanical, and biological
controls
– When these practices are not
sufficient, a biological, botanical,
or synthetic substance approved
for use on the National List may be
used
OMRI Listed® Products
• Organic Materials Review Institute is
a non-profit organization
• The OMRI Products List is a
directory of all products OMRI has
determined are allowed for use in
organic production, processing, and
handling.
• OMRI Review Program is voluntary
Organic Herbicides
• Advantages:
– Breakdown rapidly in the
environment after application
– Generally have no residual activity
– Many have a low toxicity to people
& animals
Organic Pesticides
• Disadvantages:
– Expensive
– Differences in quality from batch
to batch
– Gross misconception that these
products are not dangerous
Signal Words Required
• Caution: LD50 500-5,000 mg/kg
– Simple precautions-wash hands,
ware gloves

• Warning: Health concerns, eye,
skin or lung irritation (temp)
• Danger: Permanent eye, skin or
lung damage
• Danger/Poison: Permanent eye,
skin or lung damage possibly
fatal
Organic Applicators
• Anyone applying organic
pesticides for hire needs an
applicators license
• Must adhere to EPA Worker
Protection Standards
Organic Herbicides
• Corn Gluten
Meal
Corn Gluten Meal
• Status as a pesticide
– Classified by EPA as a "minimum
risk pesticide"
– Exempt from EPA registration
requirements
• Section 25b

– Must be registered with CDA
Corn Gluten Meal
• By-product of processing corn to
make corn starch and corn syrup
• Generally sold as a golden yellow
meal or as light brown granules
• Uses
– Herbicide
– Food for cows, cats, dogs, fish, and
poultry
– Fertilizer – about 10% nitrogen
Corn Gluten Meal
• Herbicide
– Prevents sprouting seeds from
developing normal roots
– Does not directly kill the seedlings
• Makes them susceptible to
dehydration if the soil gets dry

– Established plants are not affected
Potential Health Problems
• Corn and corn by-products are
known to cause allergies for
some people
• A few people have serious
reactions
– Respiratory problems
– Hypersensitivity

• People with known corn
allergies should avoid exposure
to corn gluten meal
Active Ingredients
• Most product active ingredients are
vinegar (acetic acid), clove oil
(eugenol), or soap (fatty acids)
• Products must be allowed by your
certifier
–On USDA National Organic
Program Approved Materials List
–Evaluated by Organic Materials
Review Institute (OMRI)
<http://www.omri.org>
Common Active Ingredients
Active ingredient

Products ai.Conc.

______________________________
Vinegar
Nature’s Touch Ecosharp 6.25%
Weed/Grass Killer Weed Pharm 20%
-------------------------------------------------------Eugenol
Products containing up to 22%
clove oil
AgraLawn CrabGrass Killer
• Also EPA minimum risk
• NOT registered with
CDA
• Active Ingredient:
Cinnamon Bark - 0.95%
Weed Pharm
•
•
•
•

20% Acetic Acid
Non-selective contact herbicide
Signal word – Danger
Not registered in CO
Weed Pharm Label
Weed Pharm -- MSDS
• EMERGENCY OVERVIEW
• Vapors irritating to the eyes and
respiratory tract. Avoid inhalation.
Liquid may cause eye burns and
permanent damage to cornea, possibly
leading to blindness. Causes skin
irritation.
Weed ZAP
• JH Biotech Inc.
• Active ingredient: 30% Cinnamon Oil
• Inert ingredients: lactose, vinegar, water –
Vinegar likely contributes to herbicidal
activity herbicidal activity
• Contact herbicide (no selectivity)
Will cause crop injury
Small annual weeds
• Use 3% solution and spray weeds to point
of run off
• Peaceful Valley $79.99/gallon
Matratec AG
• ClawE! Specialty Products
• Active ingredient: 50% clove oil • Inert
ingredients: Wintergreen, Butyl
lactateLecithin lactate, Lecithin
• Contact herbicide with no selectivity
–Will injure crops
–Complete weed coverage important
• Use on annual weeds less than 4” in
height
• Use rate 5 to 8%
• $98.20/gallon
EcoExempt HC
• Active Ingredients:
Clove Oil-21.4%
2-phenethyl propionate-21.4%
EcoSMART Technologies; Franklin
Tennesee
Burnout II
• Active ingredients:
12% clove oil & 8% sodium lauryl
sulfate
• Inert ingredients: acetic acid & citric
acid
• Dilute 3:1 for small weeds or 2:1
larger weeds
• St. Gabriel Laboratories $37.20/gallon
Conclusions
• Organic herbicides are generally
non-selective
• Contact activity only
• High concentration of vinegar/acetic
acid can cause significant eye
damage
• No control of perennial weeds
• Pick fields with low weed pressure is
the best way to start

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Organic Herbicides: Efficacy and Safety ~ Colorado

  • 1. Organic Herbicides: Efficacy and Safety Dr. Scott Nissen Weed Scientist Colorado State University
  • 2. Rank the Following for Toxicity • • • • • • • • • Caffeine 2,4-D (common lawn herbicide) Aspirin Roundup (most common herbicide used in the world) Nicotine Malathion (insecticide) Tordon (common non-crop herbicide) Gasoline Salt
  • 3. Toxicity Based on LD50 Values • • • • • • • • • Nicotine Gasoline Caffeine 2,4-D Aspirin Malathion Salt Roundup Tordon LD50 50-60 LD50 50-100 LD50 192 LD50 699 LD50 750 LD50 1000-2800 LD50 3320-4180 LD50 4300 LD50 8200
  • 4. General Weed Management Factors • Exclusion • Elimination • Prevent Establishment • Removal • Amelioration
  • 5. Weed Management for Organics -Exclusion• Field selection – a good choice – knowledge needed of sites – usefulness depends on available certified land • Prevent weed additions – critical for Organics – “bring-ins” may contain weeds • Organic mulches • Raw manures
  • 6. Weed Management for Organics - Elimination • Prevent weed build-up – timely cultivation, tillage – purposeful plantings – don’t let weeds take over • Weed population reduction – perennial management through grazing – fallow / tillage cycles – solarization – fumigants???
  • 7. Weed Management for Organics - Prevent Establishment • Preemergence “herbicides” – corn gluten meal, mustard meal • Timely cultivation • Stale seedbeds • Cover crop management – Species important: e.g. rye – Crop sequence • Grazing • Mulches – organic and synthetic
  • 8. Weed Management for Organics - Weed Removal – “Stop ‘em in their tracks” • Mechanical – cultivation –keep it shallow –minimize injury to the crop –Improve the root zone • Manual – choose easy-to-use tools
  • 9. Weed Management for Organics - Weed Removal (cont.)– “Stop ‘em in their tracks” • Chemical: vinegar, pelargonate, etc. – currently just contact activity – good foliage cover needed • Physical: energy consumers! – flame • special equipment, directed flame • best for small, annual weeds – steam
  • 10. Weed Management for Organics - Amelioration • Crop Selection – use crops that tolerate weeds • rapid growth, dense canopy – crops that allow weed control • sweet corn – easily cultivated • Give crop an edge – plant date – transplants
  • 11. USDA National Organic Program Standards • Consistent national standards • Any farm, wild crop harvesting, or handling operation that wants to sell an agricultural product as organically produced must adhere to the NOP standards • Requirements apply to the way the product is created, not to measurable properties of the product itself
  • 12. USDA NOP Standards • Crop pests, weeds, and diseases will be controlled primarily through management practices including physical, mechanical, and biological controls – When these practices are not sufficient, a biological, botanical, or synthetic substance approved for use on the National List may be used
  • 13. OMRI Listed® Products • Organic Materials Review Institute is a non-profit organization • The OMRI Products List is a directory of all products OMRI has determined are allowed for use in organic production, processing, and handling. • OMRI Review Program is voluntary
  • 14. Organic Herbicides • Advantages: – Breakdown rapidly in the environment after application – Generally have no residual activity – Many have a low toxicity to people & animals
  • 15. Organic Pesticides • Disadvantages: – Expensive – Differences in quality from batch to batch – Gross misconception that these products are not dangerous
  • 16. Signal Words Required • Caution: LD50 500-5,000 mg/kg – Simple precautions-wash hands, ware gloves • Warning: Health concerns, eye, skin or lung irritation (temp) • Danger: Permanent eye, skin or lung damage • Danger/Poison: Permanent eye, skin or lung damage possibly fatal
  • 17. Organic Applicators • Anyone applying organic pesticides for hire needs an applicators license • Must adhere to EPA Worker Protection Standards
  • 19. Corn Gluten Meal • Status as a pesticide – Classified by EPA as a "minimum risk pesticide" – Exempt from EPA registration requirements • Section 25b – Must be registered with CDA
  • 20. Corn Gluten Meal • By-product of processing corn to make corn starch and corn syrup • Generally sold as a golden yellow meal or as light brown granules • Uses – Herbicide – Food for cows, cats, dogs, fish, and poultry – Fertilizer – about 10% nitrogen
  • 21. Corn Gluten Meal • Herbicide – Prevents sprouting seeds from developing normal roots – Does not directly kill the seedlings • Makes them susceptible to dehydration if the soil gets dry – Established plants are not affected
  • 22. Potential Health Problems • Corn and corn by-products are known to cause allergies for some people • A few people have serious reactions – Respiratory problems – Hypersensitivity • People with known corn allergies should avoid exposure to corn gluten meal
  • 23. Active Ingredients • Most product active ingredients are vinegar (acetic acid), clove oil (eugenol), or soap (fatty acids) • Products must be allowed by your certifier –On USDA National Organic Program Approved Materials List –Evaluated by Organic Materials Review Institute (OMRI) <http://www.omri.org>
  • 24. Common Active Ingredients Active ingredient Products ai.Conc. ______________________________ Vinegar Nature’s Touch Ecosharp 6.25% Weed/Grass Killer Weed Pharm 20% -------------------------------------------------------Eugenol Products containing up to 22% clove oil
  • 25. AgraLawn CrabGrass Killer • Also EPA minimum risk • NOT registered with CDA • Active Ingredient: Cinnamon Bark - 0.95%
  • 26. Weed Pharm • • • • 20% Acetic Acid Non-selective contact herbicide Signal word – Danger Not registered in CO
  • 28. Weed Pharm -- MSDS • EMERGENCY OVERVIEW • Vapors irritating to the eyes and respiratory tract. Avoid inhalation. Liquid may cause eye burns and permanent damage to cornea, possibly leading to blindness. Causes skin irritation.
  • 29. Weed ZAP • JH Biotech Inc. • Active ingredient: 30% Cinnamon Oil • Inert ingredients: lactose, vinegar, water – Vinegar likely contributes to herbicidal activity herbicidal activity • Contact herbicide (no selectivity) Will cause crop injury Small annual weeds • Use 3% solution and spray weeds to point of run off • Peaceful Valley $79.99/gallon
  • 30. Matratec AG • ClawE! Specialty Products • Active ingredient: 50% clove oil • Inert ingredients: Wintergreen, Butyl lactateLecithin lactate, Lecithin • Contact herbicide with no selectivity –Will injure crops –Complete weed coverage important • Use on annual weeds less than 4” in height • Use rate 5 to 8% • $98.20/gallon
  • 31. EcoExempt HC • Active Ingredients: Clove Oil-21.4% 2-phenethyl propionate-21.4% EcoSMART Technologies; Franklin Tennesee
  • 32. Burnout II • Active ingredients: 12% clove oil & 8% sodium lauryl sulfate • Inert ingredients: acetic acid & citric acid • Dilute 3:1 for small weeds or 2:1 larger weeds • St. Gabriel Laboratories $37.20/gallon
  • 33. Conclusions • Organic herbicides are generally non-selective • Contact activity only • High concentration of vinegar/acetic acid can cause significant eye damage • No control of perennial weeds • Pick fields with low weed pressure is the best way to start