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21st Irish Environmental Researchers’ Colloquium
                                        6-8 April, 2011



Nutrient Retention in an Integrated Constructed
 Wetland used to Treat Domestic Wastewater

            Mawuli Dzakpasu1 , Oliver Hofmann2, Miklas Scholz3,
            Rory Harrington4, Siobhán Jordan1, Valerie McCarthy1




    1  Centre for Freshwater Studies, Dundalk Institute of Technology, Dundalk, Co. Louth, Ireland.
       2 School of the Built Environment, Edinburgh Napier University, Edinburgh EH10 5DT, UK
3 Civil Engineering Research Group, the University of Salford, Newton Building, Salford M5 4WT, UK.
    4 Water and Environment section, Waterford County Council, Kilmeadan, Co. Waterford, Ireland.
Presentation outline
• Introduction
    o Background
    o Objectives
•   Case study description
•   Materials and methods
•   Results
•   Conclusions
•   Acknowledgements
                              1
Background
• Constructed wetlands are used to treat several
  categories of wastewater worldwide.
• Nutrient removal efficiencies are generally
  lower and more variable.
• Irish integrated constructed wetlands (ICW)
  concept has developed over last decade.



                                                   2
Background
Integrated Constructed Wetlands are:
• Free water surface flow wetlands.
• Predominantly shallow densely
  emergent vegetated.




• Multi-celled with sequential through-flow.
                                               3
Background


                Water treatment

                    ICW
Landscape fit      concept        Biodiversity enhancement




         ICW conceptual framework                            4
Background
                    O2 UPTAKE AND TRANSFER
                         TO ROOT ZONE




INFLUENT                                  CHEMICAL
                               PHYSICAL
                                                     TREATED
                  BIOLOGICAL                          WATER




           Contaminant removal processes                   5
Objectives
• To evaluate nutrient removal in ICW over a 3-year
  full-scale operation by:
  o establishing a water balance of the system, using
    hydrological variables of inflow, outflow,
    precipitation, evapotranspiration, runoff, storage,
    and assess its effects on nutrient treatment.
  o comparing annual and seasonal nutrient removal
    rates of the ICW.
  o modelling kinetics of nutrient removal in the
    ICW and the influence of water temperature.
                                                     6
Study site description
           •   Total area = 6.74 ha
           •   Pond water surface = 3.25 ha
           •   Commissioned Oct. 2007
           •   1 pump station
           •   2 sludge ponds
           •   5 vegetated cells
           •   Natural local soil liner
           •   Current load = 800 pe.
           •   Mixed black and grey water

      ICW layout                       8
Study site description




 Process overview of ICW   9
Materials and methods
Wetland water sampling regime
• Automated composite
  samplers at each pond inlet.

• 24-hour flow-weighted
  composite water samples
  taken to determine mean
  daily chemical quality.
                                 10
Materials and methods
Water quality analysis
• Water samples analysed for NH3-N,
NO3-N and PO4-P using HACH
spectrophotometer DR/2010 49300-22.
• N-allylthiourea BOD5 determined with
WTW GmbH OxiTop system.
• Dissolved oxygen, temperature, pH, redox
potential measured with WTW GmbH
portable multiparameter meter.               11
Materials and methods




• Onsite weather station measures
  elements of weather.
• Electromagnetic flow meters and allied
  data loggers installed at each cell inlet.   12
Data analysis and modelling


Ci and Ce= influent and effluent nutrient concentrations (mg/L),
Qi and Qe = influent and effluent volumetric flow rate of water (m3/d).




q = hydraulic loading rate (m/yr); Q = volumetric flow rate in
wetland (m3/d); A = wetland area (m2); P = precipitation rate (m/d);
ET = evapotranspiration rate (m/d); I = infiltration rate (m/d).
                                                                       13
Data analysis and modelling


C* = background concentrations (mg/L);
K = areal first-order removal rate constant (m/yr).




                                                      14
Results
               39 ± 27.9 m3 day-1   139 ± 65.7 m3 day-1
                    14.8%              52.9%


124 ± 77.8 m3 day-1
   47.1%
                                                     149 ± 174.7 m3 day-1
                      64 ± 371.3 m3 day-1              56.7%




                                    4.2%
                                 11 ± 9.4 m3 day-1


                      ICW water budget                              15
Concentration (mg/l)                                                 Concentration (mg/l)




                                                                                                          10




                                                                                0
                                                                                                1
                                                                                                                                                         10
                                                                                                                                                                    1000




                                                                                                                                                     1
                                                                                                                                                              100
                                                                       Feb-08
                                                                                                                                            Feb-08
                                                                       May-08
                                                                                                                                            May-08
                                                                       Aug-08
                                                                                                                                            Aug-08
                                                                       Nov-08
                                                                                                                                            Nov-08
                                                                       Feb-09
                                                                                                                                                                           Results




                                                    Nitrate influent
                                                                                                                         BOD influent
                                                                                                                                            Feb-09
                                                                       May-09
                                                                                                                                            May-09
                                                                       Aug-09                                                               Aug-09
                                                                       Nov-09                                                               Nov-09
                                                                       Feb-10                                                               Feb-10
                                                                       May-10                                                               May-10
                                                                                                                         BOD effluent


                                                                       Aug-10                                                               Aug-10




                                                    Nitrate effluent
                                                                       Nov-10                                                               Nov-10
                                                                       Feb-11                                                               Feb-11
                                                                       Concentration (mg/l)                                                 Concentration (mg/l)
                                                                                                                                                              10



                                                                                                                                                     0
                                                                                                                                                         1
                                                                                                                                                                    100
                                                                                                                                                                           Results




                                                                                0.001
                                                                                        0.010
                                                                                                0.100
                                                                                                        1.000
                                                                                                                10.000




                                                                                                                                            Feb-08
                                                                       Feb-08                                                               May-08
                                                                       May-08                                                               Aug-08
                                                                       Aug-08                                                               Nov-08
                                                                       Nov-08                                                               Feb-09
                                                    MRP influent
                                                                                                                         Ammonia influent




                                                                       Feb-09
                                                                                                                                            May-09
                                                                       May-09
                                                                                                                                            Aug-09
                                                                       Aug-09
                                                                                                                                            Nov-09
                                                                       Nov-09
                                                                                                                                            Feb-10
                                                                       Feb-10
                                                                       May-10                                                               May-10
                                                                                                                                            Aug-10
                                                    MRP effluent




                                                                       Aug-10
16




                                                                       Nov-10                                                               Nov-10
                                                                                                                         Ammonia effluent




ICW influent and effluent nutrient concentrations




                                                                       Feb-11                                                               Feb-11
Results
Nutrient mass loading and removal rates
           Loadings (kg/yr)    Mass retained
Variable
           Influent Effluent   (%)    (kg/yr)
 BOD5      8275.8     123.3    98.5    8152.4
NH3-N      1025.5     42.2     92.4     983.4
NO3-N       116.8      9.7     88.4     107.1
 PO4-P      110.3      6.5     94.3     103.9
                                                17
Results
   Areal first-order kinetic coefficients
      for nutrient removal in ICW
               K (m/yr)         K20 (m/yr)
Parameter                                      θ
            Mean SD n Mean SD       n
 BOD5       10.5 6.69 194 9.3 5.96 194 0.982
 NH3-N      10.0 7.34 204 13.2      9.11 204 1.025
 NO3-N       6.0   4.47 195   5.3   3.97 195 0.979
 PO4-P       9.5   8.53 197 12.7 11.04 197 1.026
                                               18
Results
                   100                                                                                                               15
Removal Rate (%)


                    80




                                                                                                                                          HLR (mm/d)
 Removal rate



                                                                                                                                     10
                    60
                    40
                                                                                                                                     5
                    20
                     0                                                                                                               0
                                           Autumn




                                                                               Autumn




                                                                                                                   Autumn
                                                                                                          Summer
                                  Summer




                                                                      Summer
                         Spring




                                                             Spring




                                                                                                 Spring
                                                    Winter




                                                                                        Winter




                                                                                                                            Winter
                                    2008                                2009                                2010
                          BOD5
                          BOD                  NH3-N
                                               NH3-N                  NO3-N
                                                                      NO3-N                      PO4-P
                                                                                                 PO4-P                 HLR

                    Seasonal variation of nutrient removal
                       rate and hydraulic loading rate                                                                                     19
Conclusions
• Removal rates consistently > 90 %.

• Removal rates slightly influenced by seasonality.

• Removal rates influenced by hydrological regime.

• Slightly minimal temperature coefficients indicate
  slight temperature dependence.


                                                      20
Acknowledgements
• Monaghan County Council, Ireland for funding
  the research.

• Dan Doody, Mark Johnston and Eugene Farmer
  at Monaghan County Council and Susan Cook at
  Waterford County Council for technical support.




                                               21
Thank you for your attention!
    We welcome your questions,
      suggestions, comments!



              Contact:
       mawuli.dzakpasu@dkit.ie   26

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Nutrient Retention in an Integrated Constructed Wetland used to Treat Domestic Wastewater

  • 1. 21st Irish Environmental Researchers’ Colloquium 6-8 April, 2011 Nutrient Retention in an Integrated Constructed Wetland used to Treat Domestic Wastewater Mawuli Dzakpasu1 , Oliver Hofmann2, Miklas Scholz3, Rory Harrington4, Siobhán Jordan1, Valerie McCarthy1 1 Centre for Freshwater Studies, Dundalk Institute of Technology, Dundalk, Co. Louth, Ireland. 2 School of the Built Environment, Edinburgh Napier University, Edinburgh EH10 5DT, UK 3 Civil Engineering Research Group, the University of Salford, Newton Building, Salford M5 4WT, UK. 4 Water and Environment section, Waterford County Council, Kilmeadan, Co. Waterford, Ireland.
  • 2. Presentation outline • Introduction o Background o Objectives • Case study description • Materials and methods • Results • Conclusions • Acknowledgements 1
  • 3. Background • Constructed wetlands are used to treat several categories of wastewater worldwide. • Nutrient removal efficiencies are generally lower and more variable. • Irish integrated constructed wetlands (ICW) concept has developed over last decade. 2
  • 4. Background Integrated Constructed Wetlands are: • Free water surface flow wetlands. • Predominantly shallow densely emergent vegetated. • Multi-celled with sequential through-flow. 3
  • 5. Background Water treatment ICW Landscape fit concept Biodiversity enhancement ICW conceptual framework 4
  • 6. Background O2 UPTAKE AND TRANSFER TO ROOT ZONE INFLUENT CHEMICAL PHYSICAL TREATED BIOLOGICAL WATER Contaminant removal processes 5
  • 7. Objectives • To evaluate nutrient removal in ICW over a 3-year full-scale operation by: o establishing a water balance of the system, using hydrological variables of inflow, outflow, precipitation, evapotranspiration, runoff, storage, and assess its effects on nutrient treatment. o comparing annual and seasonal nutrient removal rates of the ICW. o modelling kinetics of nutrient removal in the ICW and the influence of water temperature. 6
  • 8. Study site description • Total area = 6.74 ha • Pond water surface = 3.25 ha • Commissioned Oct. 2007 • 1 pump station • 2 sludge ponds • 5 vegetated cells • Natural local soil liner • Current load = 800 pe. • Mixed black and grey water ICW layout 8
  • 9. Study site description Process overview of ICW 9
  • 10. Materials and methods Wetland water sampling regime • Automated composite samplers at each pond inlet. • 24-hour flow-weighted composite water samples taken to determine mean daily chemical quality. 10
  • 11. Materials and methods Water quality analysis • Water samples analysed for NH3-N, NO3-N and PO4-P using HACH spectrophotometer DR/2010 49300-22. • N-allylthiourea BOD5 determined with WTW GmbH OxiTop system. • Dissolved oxygen, temperature, pH, redox potential measured with WTW GmbH portable multiparameter meter. 11
  • 12. Materials and methods • Onsite weather station measures elements of weather. • Electromagnetic flow meters and allied data loggers installed at each cell inlet. 12
  • 13. Data analysis and modelling Ci and Ce= influent and effluent nutrient concentrations (mg/L), Qi and Qe = influent and effluent volumetric flow rate of water (m3/d). q = hydraulic loading rate (m/yr); Q = volumetric flow rate in wetland (m3/d); A = wetland area (m2); P = precipitation rate (m/d); ET = evapotranspiration rate (m/d); I = infiltration rate (m/d). 13
  • 14. Data analysis and modelling C* = background concentrations (mg/L); K = areal first-order removal rate constant (m/yr). 14
  • 15. Results 39 ± 27.9 m3 day-1 139 ± 65.7 m3 day-1 14.8% 52.9% 124 ± 77.8 m3 day-1 47.1% 149 ± 174.7 m3 day-1 64 ± 371.3 m3 day-1 56.7% 4.2% 11 ± 9.4 m3 day-1 ICW water budget 15
  • 16. Concentration (mg/l) Concentration (mg/l) 10 0 1 10 1000 1 100 Feb-08 Feb-08 May-08 May-08 Aug-08 Aug-08 Nov-08 Nov-08 Feb-09 Results Nitrate influent BOD influent Feb-09 May-09 May-09 Aug-09 Aug-09 Nov-09 Nov-09 Feb-10 Feb-10 May-10 May-10 BOD effluent Aug-10 Aug-10 Nitrate effluent Nov-10 Nov-10 Feb-11 Feb-11 Concentration (mg/l) Concentration (mg/l) 10 0 1 100 Results 0.001 0.010 0.100 1.000 10.000 Feb-08 Feb-08 May-08 May-08 Aug-08 Aug-08 Nov-08 Nov-08 Feb-09 MRP influent Ammonia influent Feb-09 May-09 May-09 Aug-09 Aug-09 Nov-09 Nov-09 Feb-10 Feb-10 May-10 May-10 Aug-10 MRP effluent Aug-10 16 Nov-10 Nov-10 Ammonia effluent ICW influent and effluent nutrient concentrations Feb-11 Feb-11
  • 17. Results Nutrient mass loading and removal rates Loadings (kg/yr) Mass retained Variable Influent Effluent (%) (kg/yr) BOD5 8275.8 123.3 98.5 8152.4 NH3-N 1025.5 42.2 92.4 983.4 NO3-N 116.8 9.7 88.4 107.1 PO4-P 110.3 6.5 94.3 103.9 17
  • 18. Results Areal first-order kinetic coefficients for nutrient removal in ICW K (m/yr) K20 (m/yr) Parameter θ Mean SD n Mean SD n BOD5 10.5 6.69 194 9.3 5.96 194 0.982 NH3-N 10.0 7.34 204 13.2 9.11 204 1.025 NO3-N 6.0 4.47 195 5.3 3.97 195 0.979 PO4-P 9.5 8.53 197 12.7 11.04 197 1.026 18
  • 19. Results 100 15 Removal Rate (%) 80 HLR (mm/d) Removal rate 10 60 40 5 20 0 0 Autumn Autumn Autumn Summer Summer Summer Spring Spring Spring Winter Winter Winter 2008 2009 2010 BOD5 BOD NH3-N NH3-N NO3-N NO3-N PO4-P PO4-P HLR Seasonal variation of nutrient removal rate and hydraulic loading rate 19
  • 20. Conclusions • Removal rates consistently > 90 %. • Removal rates slightly influenced by seasonality. • Removal rates influenced by hydrological regime. • Slightly minimal temperature coefficients indicate slight temperature dependence. 20
  • 21. Acknowledgements • Monaghan County Council, Ireland for funding the research. • Dan Doody, Mark Johnston and Eugene Farmer at Monaghan County Council and Susan Cook at Waterford County Council for technical support. 21
  • 22. Thank you for your attention! We welcome your questions, suggestions, comments! Contact: mawuli.dzakpasu@dkit.ie 26