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Load Apportionment
Which loads are dominant
Build Partnership
Create an ICM
Vision
Characterise the
Catchment
Undertake further
characterisation
Identify &
Evaluate Possible
Management
Strategies
Design an
Implementation
Programme
Implement the
River Basin
Management Plan
Measure Progress
and Make
Adjustments
Further Characterisation
• Loads are used for quantifying
pressures within a catchment
• Loads also assist in the further
characterisation of critical
source areas for these
pressures
Load vs Concentration
• Load is derived from Concentration x flow and is expressed as mass
per time
• The nutrient loading delivered to a water body drives its
productivity and can therefore be a more meaningful indicator
compared to concentration
• Concentration also has value in determining, for instance, eco-
toxicological effect, or whether levels can be considered normal or
are elevated
How do you measure Load & apportion
Load to Pressures?
• Investigative Monitoring
• OSPAR nutrient quantification tools (HARP-NUT)
• Use of models
WFD monitoring programme
Surveillance
• long term trends
• all quality elements
Operational
• record improvements due to
measures
• targeted quality elements
Investigative
• unpredicted water quality problems
or pollution events
• targeted quality elements
Rivers Surveillance Sites
Measuring pollutant concentrations
Measuring flow
Relating flow to water level
Stage(h)
Flow (cumecs)
Graph showing the connection between the water level elevation
(stage) at a cross-section and the corresponding flow.
Typical Catchment
Annual Total Phosphorus Loading
0
20
40
60
80
100
120
01-Jan-
01-Feb-
01-Mar-
01-Apr-
01-May
01-Jun-
01-Jul-0
01-Aug-
01-Sep-
01-Oct-
01-Nov-
01-Dec-
kgTPperday
0
1
2
3
4
5
6
7
8
9
10
Flow(m
3/
s)
TP load
Flow
Deenagh
0
1
2
3
4
5
6
7
Monthly Fortnightly Weekly Actual
TPload(tonnesyear-1
)
Maximum estimate Minimum estimate Actual load
0
2
4
6
8
10
12
Monthly Fortnightly Weekly Actual
TPload(tonnesyear-1
)
Maximum estimate Minimum estimate Actual load
0
100
200
300
400
Monthly Fortnightly Weekly Actual
TONload(tonnesyear-1
)
Maximum estimate Minimum estimate Actual load
0
100
200
300
400
Monthly Fortnightly Weekly Actual
TONload(tonnesyear-1
)
Maximum estimate Minimum estimate Actual load
Daily auto-sampler data - sub-sample data at weekly, fortnightly monthly intervals
TP
TON
How often do you need to sample?
Courtesy Eleanor Jennings, TCD
Types of Error
Type I error: over-estimate load
…. could lead to substantial costs being unnecessarily imposed on
water users.
Type II error: under-estimate load
…. fail to identify risks of significant damage that could be averted.
Sampling
Cost
Sampling
Accuracy
Typical Catchment d/s of a large lake
Retention in the system is important!
0
200
400
600
800
1000
1200
01-Jan-
01-Feb-
01-Mar-
01-Apr-
01-May
01-Jun-
01-Jul-0
01-Aug-
01-Sep-
01-Oct-
01-Nov-
01-Dec-
kgTPperday
0
20
40
60
80
100
120
140
160
Flow(m3
/s)
TP
Flow
Flesk
Export Coefficients
• Export Coefficient = Load / contributing
catchment area
• Export coefficients can be calculated for each Lough
Leane Subcatchment:
– Clydagh Valley (dominated by forestry);
– Upper Lough Guitane catchment (sheep farming);
– Upper Deenagh catchment (dairy/dry stock).
Sub catchment loading
Source Apportionment – Lough Leane
Background
23%
Urban & Industry
15%
Agriculture
47%
Septic Tanks
12%
Forestry
3%
Background
Urban & Industry
Agriculture
Septic Tanks
Forestry
Where do you start if you have very little
monitoring data?
• The OSPAR Convention has developed guidelines
towards harmonised procedures for the quantification
of nutrient losses to the North-East Atlantic (HARP-NUT)
• There are 9 guidelines for producing annual catchment-
based figures for total discharges / losses / inputs of N
and P from point and diffuse sources
• Ensures harmonised & transparent approach to nutrient
reporting across OSPAR member countries
HARP-NUT Guidelines
• A selection of quantification methodologies is provided for each pressure;
from simple theoretical quantification to more sophisticated methods
based on monitoring information.
• Application of the HARP-NUT guidelines in Ireland:
– 1999 Screening Procedure for Irish Coastal Waters with regards to Eutrophication Status
(EPA, 1999);
– 1999 trial in the Lough Derg and Ree catchment (Murdoch, 1999);
– 2004 WFD Article V Characterisation Report (2005);
– 2008 OSPAR PARCOM Recommendation 88/2 Report;
– 2010 WFD Water Management Unit Action Plans;
– 2012 OSPAR PARCOM Recommendation 88/2 Report.
HARP-NUT Guidelines
• The sectors for which N and P loads are estimated in Ireland include:
– Waste Water Treatment Plants (WWTPs)
– Unsewered industries (industries licenced to discharge to surface water i.e. IPPCs
and LA Section 4s)
– Agriculture
– Foresty
– Urban areas
– Unsewered rural populations
• Background losses are also estimated
• Retention factors are applied
• The quantification of N and P losses at source are reconciled with N & P measurements
WWTPs - Guideline No. 4
Load = Population Equivalent x nutrient loading x
treatment reduction factor
Nutrient production figures
Total N = 9.0g person-1 day-1
Total P = 2.7g person-1 day-1
Level of Treatment N Reduction Factor P Reduction Factor
Raw 1.000 1.000
Preliminary treatment 0.900 0.900
Primary treatment 0.727 0.667
Secondary treatment 0.545 0.467
Additional nutrient removal 0.300 0.100
Unsewered Industry - Guideline No. 3
Load = 25% of max allowable discharge
i.e.
Load = 0.25 x (max flow x max nutrient concentration)
Agriculture - Guideline No. 6
Load = (Number of Livestock Units x Nutrient Production +
chemical fertiliser usage ) x nutrient loss factor
Livestock Type N production per LU P production per LU
Bulls 85 13
Dairy cows 85 13
Suckler cows 65 10
Cattle (0-1) 24 3
Cattle (1-2) 57 5
Cattle (>2) 65 10
Sheep 13 10
Nutrient Loss Factors
N loss factor = 0.20
P loss factor = 0.04
Livestock Units (LU)
1 grazing dairy cow = 1 LU
1 grazing lowland sheep = 0.2 LU
Forestry - Guideline No. 6
Load = area of forestry plantation x standard coefficient
N loss coefficient
(kg ha-1 annum-1)
P loss coefficient
(kg ha-1 annum-1)
Forestry 5.42 0.33
Woodland scrub 3.71 0.565
Urban Areas - Guideline No. 6
Load = area under urban cover x standard coefficient
N loss coefficient
(kg ha-1 annum-1)
P loss coefficient
(kg ha-1 annum-1)
Continuous urban fabric 5 1.4
Discontinuous urban fabric 5 0.86
Industrial areas 5 1.88
Construction sites 5 2.15
OSWWTS - Guideline No. 5
Load = non-sewered population x nutrient emission value
N emission value
kg person-1 year-1
P emission value
kg person-1 year-1
Septic tank 2.4 0.25
Septic tank remote 0.7 0.25
Background - Guideline No. 6
Load = Area x standard coefficient
N background runoff = 0.75 kg ha-1 annum-1
P background runoff = 0.05 kg ha-1 annum-1
Retention - Guideline No. 9
Factors applied to catchments upstream of lakes.
N retention = 0.1 of the predicted inflow loading
P retention = 0.24 of the predicted inflow loading
Load Reconciliation
• It is important to verify that the estimated N and P loadings at
source (source orientated approach) are realistic
• A verification exercise is therefore required by comparing the
estimated results with monitoring results (load orientated
approach) i.e. loads measured in the Riverine Inputs and Direct
Discharges (RID) Programme
Discussion on HARP-NUT Guidelines
• Does not take account of all sources of nutrients e.g. atmospheric deposition in
marine area, dumping at sea, unregulated industry, slurry spreading
• Some sectors are more poorly accounted for than others
• Background losses and retention are poorly accounted for
• Does not consider changes in loads during transport e.g. sedimentation,
mineralisation
• Does not reflect management practices
• As datasets improve, it will be possible to move toward using monitoring data to
quantify loads which is the preferred approach outlined in the HARP-NUT guidelines
Use of Models
Complexity of River Quality issues
• Rivers usually receive loads from numerous sources
• The decisions made at one location in the catchment to address point or diffuse
pressures can depend on the choices to be made at those upstream or downstream
• Water quality calculations can be complex and time consuming
• An attractive option is to provide an automatic method of doing all the water quality
calculations for an entire catchment in one go:
– Saves time;
– Allows for catchment-wide water quality management;
– Provides useful planning / decision making tool;
– Prioritisation of water quality issues.
SIMCAT model
Mixing of a discharge with a river is described by the
Mass Balance Equation
SIMCAT looks at the distribution of the flows and concentrations when
determining the mass balance equation
SIMCAT model
Agricultural Models at Catchment Level
There are a number of Nutrient Loss Models available to estimate the nutrient losses
from diffuse agricultural sources in use by EU Member States. The following where
evaluated by the EuroHARP Project
NL-CAT N,P
REALTA P
SWAT N,P
EvenFlow N
NLES-CAT N
TRK N,P
NOPOLU N,P
Moneris N,P
The models generally require detailed datasets to be effective
Agricultural Bye-Laws introduced under the
Water Pollution Act within High Risk Areas
by
Cavan Co Co
Westmeath Co Co
Offaly Co Co
North Tipperary Co Co
Source apportionment
In Action

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10. Load Apportionment

  • 2. Build Partnership Create an ICM Vision Characterise the Catchment Undertake further characterisation Identify & Evaluate Possible Management Strategies Design an Implementation Programme Implement the River Basin Management Plan Measure Progress and Make Adjustments Further Characterisation • Loads are used for quantifying pressures within a catchment • Loads also assist in the further characterisation of critical source areas for these pressures
  • 3. Load vs Concentration • Load is derived from Concentration x flow and is expressed as mass per time • The nutrient loading delivered to a water body drives its productivity and can therefore be a more meaningful indicator compared to concentration • Concentration also has value in determining, for instance, eco- toxicological effect, or whether levels can be considered normal or are elevated
  • 4. How do you measure Load & apportion Load to Pressures? • Investigative Monitoring • OSPAR nutrient quantification tools (HARP-NUT) • Use of models
  • 5. WFD monitoring programme Surveillance • long term trends • all quality elements Operational • record improvements due to measures • targeted quality elements Investigative • unpredicted water quality problems or pollution events • targeted quality elements Rivers Surveillance Sites
  • 8. Relating flow to water level Stage(h) Flow (cumecs) Graph showing the connection between the water level elevation (stage) at a cross-section and the corresponding flow.
  • 9. Typical Catchment Annual Total Phosphorus Loading 0 20 40 60 80 100 120 01-Jan- 01-Feb- 01-Mar- 01-Apr- 01-May 01-Jun- 01-Jul-0 01-Aug- 01-Sep- 01-Oct- 01-Nov- 01-Dec- kgTPperday 0 1 2 3 4 5 6 7 8 9 10 Flow(m 3/ s) TP load Flow Deenagh
  • 10. 0 1 2 3 4 5 6 7 Monthly Fortnightly Weekly Actual TPload(tonnesyear-1 ) Maximum estimate Minimum estimate Actual load 0 2 4 6 8 10 12 Monthly Fortnightly Weekly Actual TPload(tonnesyear-1 ) Maximum estimate Minimum estimate Actual load 0 100 200 300 400 Monthly Fortnightly Weekly Actual TONload(tonnesyear-1 ) Maximum estimate Minimum estimate Actual load 0 100 200 300 400 Monthly Fortnightly Weekly Actual TONload(tonnesyear-1 ) Maximum estimate Minimum estimate Actual load Daily auto-sampler data - sub-sample data at weekly, fortnightly monthly intervals TP TON How often do you need to sample? Courtesy Eleanor Jennings, TCD
  • 11. Types of Error Type I error: over-estimate load …. could lead to substantial costs being unnecessarily imposed on water users. Type II error: under-estimate load …. fail to identify risks of significant damage that could be averted. Sampling Cost Sampling Accuracy
  • 12. Typical Catchment d/s of a large lake Retention in the system is important! 0 200 400 600 800 1000 1200 01-Jan- 01-Feb- 01-Mar- 01-Apr- 01-May 01-Jun- 01-Jul-0 01-Aug- 01-Sep- 01-Oct- 01-Nov- 01-Dec- kgTPperday 0 20 40 60 80 100 120 140 160 Flow(m3 /s) TP Flow Flesk
  • 13. Export Coefficients • Export Coefficient = Load / contributing catchment area • Export coefficients can be calculated for each Lough Leane Subcatchment: – Clydagh Valley (dominated by forestry); – Upper Lough Guitane catchment (sheep farming); – Upper Deenagh catchment (dairy/dry stock).
  • 15. Source Apportionment – Lough Leane Background 23% Urban & Industry 15% Agriculture 47% Septic Tanks 12% Forestry 3% Background Urban & Industry Agriculture Septic Tanks Forestry
  • 16. Where do you start if you have very little monitoring data? • The OSPAR Convention has developed guidelines towards harmonised procedures for the quantification of nutrient losses to the North-East Atlantic (HARP-NUT) • There are 9 guidelines for producing annual catchment- based figures for total discharges / losses / inputs of N and P from point and diffuse sources • Ensures harmonised & transparent approach to nutrient reporting across OSPAR member countries
  • 17. HARP-NUT Guidelines • A selection of quantification methodologies is provided for each pressure; from simple theoretical quantification to more sophisticated methods based on monitoring information. • Application of the HARP-NUT guidelines in Ireland: – 1999 Screening Procedure for Irish Coastal Waters with regards to Eutrophication Status (EPA, 1999); – 1999 trial in the Lough Derg and Ree catchment (Murdoch, 1999); – 2004 WFD Article V Characterisation Report (2005); – 2008 OSPAR PARCOM Recommendation 88/2 Report; – 2010 WFD Water Management Unit Action Plans; – 2012 OSPAR PARCOM Recommendation 88/2 Report.
  • 18. HARP-NUT Guidelines • The sectors for which N and P loads are estimated in Ireland include: – Waste Water Treatment Plants (WWTPs) – Unsewered industries (industries licenced to discharge to surface water i.e. IPPCs and LA Section 4s) – Agriculture – Foresty – Urban areas – Unsewered rural populations • Background losses are also estimated • Retention factors are applied • The quantification of N and P losses at source are reconciled with N & P measurements
  • 19. WWTPs - Guideline No. 4 Load = Population Equivalent x nutrient loading x treatment reduction factor Nutrient production figures Total N = 9.0g person-1 day-1 Total P = 2.7g person-1 day-1 Level of Treatment N Reduction Factor P Reduction Factor Raw 1.000 1.000 Preliminary treatment 0.900 0.900 Primary treatment 0.727 0.667 Secondary treatment 0.545 0.467 Additional nutrient removal 0.300 0.100
  • 20. Unsewered Industry - Guideline No. 3 Load = 25% of max allowable discharge i.e. Load = 0.25 x (max flow x max nutrient concentration)
  • 21. Agriculture - Guideline No. 6 Load = (Number of Livestock Units x Nutrient Production + chemical fertiliser usage ) x nutrient loss factor Livestock Type N production per LU P production per LU Bulls 85 13 Dairy cows 85 13 Suckler cows 65 10 Cattle (0-1) 24 3 Cattle (1-2) 57 5 Cattle (>2) 65 10 Sheep 13 10 Nutrient Loss Factors N loss factor = 0.20 P loss factor = 0.04 Livestock Units (LU) 1 grazing dairy cow = 1 LU 1 grazing lowland sheep = 0.2 LU
  • 22. Forestry - Guideline No. 6 Load = area of forestry plantation x standard coefficient N loss coefficient (kg ha-1 annum-1) P loss coefficient (kg ha-1 annum-1) Forestry 5.42 0.33 Woodland scrub 3.71 0.565
  • 23. Urban Areas - Guideline No. 6 Load = area under urban cover x standard coefficient N loss coefficient (kg ha-1 annum-1) P loss coefficient (kg ha-1 annum-1) Continuous urban fabric 5 1.4 Discontinuous urban fabric 5 0.86 Industrial areas 5 1.88 Construction sites 5 2.15
  • 24. OSWWTS - Guideline No. 5 Load = non-sewered population x nutrient emission value N emission value kg person-1 year-1 P emission value kg person-1 year-1 Septic tank 2.4 0.25 Septic tank remote 0.7 0.25
  • 25. Background - Guideline No. 6 Load = Area x standard coefficient N background runoff = 0.75 kg ha-1 annum-1 P background runoff = 0.05 kg ha-1 annum-1
  • 26. Retention - Guideline No. 9 Factors applied to catchments upstream of lakes. N retention = 0.1 of the predicted inflow loading P retention = 0.24 of the predicted inflow loading
  • 27. Load Reconciliation • It is important to verify that the estimated N and P loadings at source (source orientated approach) are realistic • A verification exercise is therefore required by comparing the estimated results with monitoring results (load orientated approach) i.e. loads measured in the Riverine Inputs and Direct Discharges (RID) Programme
  • 28. Discussion on HARP-NUT Guidelines • Does not take account of all sources of nutrients e.g. atmospheric deposition in marine area, dumping at sea, unregulated industry, slurry spreading • Some sectors are more poorly accounted for than others • Background losses and retention are poorly accounted for • Does not consider changes in loads during transport e.g. sedimentation, mineralisation • Does not reflect management practices • As datasets improve, it will be possible to move toward using monitoring data to quantify loads which is the preferred approach outlined in the HARP-NUT guidelines
  • 29. Use of Models Complexity of River Quality issues • Rivers usually receive loads from numerous sources • The decisions made at one location in the catchment to address point or diffuse pressures can depend on the choices to be made at those upstream or downstream • Water quality calculations can be complex and time consuming • An attractive option is to provide an automatic method of doing all the water quality calculations for an entire catchment in one go: – Saves time; – Allows for catchment-wide water quality management; – Provides useful planning / decision making tool; – Prioritisation of water quality issues.
  • 30. SIMCAT model Mixing of a discharge with a river is described by the Mass Balance Equation
  • 31. SIMCAT looks at the distribution of the flows and concentrations when determining the mass balance equation SIMCAT model
  • 32. Agricultural Models at Catchment Level There are a number of Nutrient Loss Models available to estimate the nutrient losses from diffuse agricultural sources in use by EU Member States. The following where evaluated by the EuroHARP Project NL-CAT N,P REALTA P SWAT N,P EvenFlow N NLES-CAT N TRK N,P NOPOLU N,P Moneris N,P The models generally require detailed datasets to be effective
  • 33. Agricultural Bye-Laws introduced under the Water Pollution Act within High Risk Areas by Cavan Co Co Westmeath Co Co Offaly Co Co North Tipperary Co Co Source apportionment In Action