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David Barton Baldwin High School Pittsburgh, PA Science and Engineering Apprenticeship Program Naval Research Laboratory Washington, DC Mentor: Dr. David A. Kidwell 10 August 2007 Effects of Counterions on Reverse Micelles www.bioeng.cstm.kyushu-u.ac.jp

Background ,[object Object],[object Object],Jeff Owrutsky, 2007 The water structure of RMs are still widely unknown. Determining the properties of the water core will help us understand what applications they can be used for…

Infrared Spectroscopy Fourier Transform Infrared (FTIR) Spectroscopy

Reverse Micelle Probes ,[object Object],[object Object],[object Object],[object Object],[object Object],w 0 Sando et al. Azide

Ion-Pairing in Bulk DMSO M(OCN) FTIR Spectra Li(OCN) Na(OCN) K(OCN) OCN- ,[object Object]

Ion-Pair Equilibrium Constants M + + OCN - M(OCN) ,[object Object],[object Object],[object Object],K Na Li 2145 2157 2169 Frequency 16.4 46.5 110.1 JR and MC K eq 9.0 31.0 78.8 Average K eq K + Na + Li + M +

Reverse Micelles ,[object Object],[object Object],OCN-

Surfactant (AOT) ,[object Object],AOT -Performed by a liquid-liquid extraction.

Initial Water Concentration ,[object Object]

Conclusions ,[object Object],[object Object],Levinger, Science 2002

Acknowledgements ,[object Object],[object Object],[object Object],[object Object]

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