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11/11/2016 seminar_ppt I ND I rev00 Sangli
A Presentation on
“A REVIEW ON
POLYMER HEAT EXCHANGERS
FOR THERMAL SYTEMS”
Presented by : Mr. Nandkishor R. Darade
nandkishor.darade@gmail.com
 Introduction
• Challenges
• Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 2
• In thermal systems, heat exchangers are very
important to the overall efficiency, cost, and size
of the system. Currently, these applications rely
heavily on heat exchanger designs, often
constructed using copper, aluminum, or steel.
• Metal HX issues are expensive to manufacture,
limited by operating conditions, materials and
manufacturing techniques.
• So the alternative designs are created using
Polymers.
 Introduction
• Challenges
• Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 3
Characteristics of materials used in HX
• Introduction
 Challenges
• Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 4
• Thermal conductivity
• Strength of polymers
• Operating Temperature, Pressure
Material Thermal Conductivity
W/(K m)
PE 0.33 ‐ 0.57
PEEK 0.25
Cu (pure) 401
Cu
(commercial) 240 ‐ 380
Al 99,5% 236
Steel 48 ‐ 58
Steel (SS) 15
Material Tensile strength
MPa
PE 30
PEEK 97
Cu 200
Al 99,5% 75 ‐ 110
Steel 310 ‐ 630
Steel (SS) 700 ‐ 1300
11/11/2016 seminar_ppt I ND I rev00 5
Material Min.
Application
Temperature
°C
Max.
Application
Temperature
°C
Max.
Temperature
for Short
Term °C
PE ‐80 90 100
PEEK ‐65 240 300
• Introduction
 Challenges
• Properties
• Applications
• Conclusions
• References
The utilization of polymer materials in high
performance HX applications requires
totally new design approaches with very
thin materials, reduced mechanical forces on
the material and alternative solutions to
achieve turbulent flow regimes.
• Introduction
• Challenges
 Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 6
• Material properties of Polymers & PMCs
• The most important properties include
• Thermal conductivity
• Specific heat capacity
• Max. operating Temprature
• Coefficient of thermal expansion
• Tensile strength, modulus
• Density
• Introduction
• Challenges
 Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 7
• Zaheed and Jachuck (2004) compared a Ni–Cr–Mo (8 W/m-K)
alloy tubular heat exchanger to a PVDF version of the same unit,
and when considering the difference in density and in material
cost, it was found that, despite being 6 times larger, the PVDF
heat exchanger will cost 2.5 times less than the metal version.
• Ma et al. (2002) Condensation experiments on a single tube
coated with a PTFE film showed an increase of the heat transfer
rate ranging from 0.3 to 4.6 times compared to a regular brass
tube. Drop-wise condensation was found to occur for more than
22,000 h.
• Brouwers and Van Der Geld (1996) found drop-wise
condensation occurred within a pure PVDF plate heat exchanger.
This indicates that polymer films could be used to increase the
heat transfer rate in condensing applications sustaining drop-wise
condensation over an extended period of time.
• Introduction
• Challenges
 Properties
• Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 8
Reinforcement Matrix Formulation Thermal
conductivity
Continuous
carbon fibers Polymer
-
330
Natural graphite Epoxy
-
370
1DP-120 Polyester
45 wt 245.0
1DVGCF Epoxy
38 Vf 695
2DVGCF Epoxy 56 Vf 292
The material properties of polymers and different composites shows
these materials can be used in heat exchange applications.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 9
• Liquid-to-liquid heat exchangers
• Morcos and Shafey (1995) presented a PVC shell and
tube heat exchanger for varying tube and shell side
Reynolds numbers.
• The wall thickness was found to limit the overall heat
transfer coefficient to a maximum of 90 W/ m2-K.
• To enhance the heat transfer rate, double conical PVC
turbulators were introduced in the tubes.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 10
• In a review of the use of polymers in liquid- to- liquid
heat transfer, Davidson et al. (1998) assessed polymers
according to strength, stiffness, cost, and thermal
conductivity.
• For the tubes, high temperature nylon (HTN), cross-
linked polyethylene (PEX) were chosen.
• For the headers, glass fiber reinforced polymers were
preferred, with HTN, PP, and PPS being the
recommended types.
• Liu (2000) studied the feasibility of both a shell-and-
tube heat exchanger and an immersed unit
numerically.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 11
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 12
Heat transfer capacity PEX Nylon Copper
3000 W 1.78 m2 0.50 m2 0.50 m2
6000 W 7.78 m2 2.16 m2 2.19 m2
Heat transfer capacity PEX Nylon Copper
3000 W 4.21 m2 1.89 m2 1.10 m2
6000 W 11.4 m2 8.42 m2 2.03 m2
Total exterior heat transfer surface areas for shell and tube HX
at 5.7L/min
Total exterior heat transfer surface areas for Immersed HX at
5.7L/min
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 13
• Zakardas et al. (2005) presented a novel design of
polymer heat exchanger for liquid-to-liquid or
condensing-fluid-to-liquid heat transfer: hollow fiber
heat exchangers.
• These units showed a very high compactness
achieving 1500 m2 of exterior surface in an 11.8 cm
long shell with a diameter of 2.3 cm. OHTC upto1360
W/m2-K were reported.
• The unit ‘41939’ was found to be able to transfer up to
5.3 kW with a volume which is over 250 times smaller
than a conventional design.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 14
• Patel and Brisson (2000) studied a polymer kapton
heat exchanger for cryogenic applications.
• A novel design for a plastic thin-film heat exchanger
was developed and tested by Lowenstein and Sibilia
(1993, 1999). This investigation proved the feasibility
of designing and producing evaporators and absorbers
from thin plastic films.
• Based on tests of the long-term creep characteristics of
a HDPE film, the projected life of this heat exchanger
made from HDPE and operating at 172 kPa/38 C
would be 20 years.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 15
• Spiral HX using polymer films
HX diameter 0.1 – 0.4 m
HX height 0.3 – 0. 8 m
HX –weight 1 - 10 kg
Heat transfer 0.5 – 3 kW/K
Typical pressure drop 150 – 400 mbar
Typical liq. volume flow 0.2 – 1.5 m³/h
Maximum system pressure (20 °C) 9 bar
Maximum system pressure (90 °C) 5 bar
Maximum system temperature 120 °C
Maximum pressure difference between
Channels 3 bar
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 16
• Gas-to-gas heat exchangers
• Rousse et al. (2000) presented an experimental study
of a PE shell-and-tube heat recovery unit for
greenhouses.
• The designed unit met the requirements and
satisfactory performance under frosting conditions. In
operation, efficiencies up to 84% were measured.
• Introduction
• Challenges
• Properties
 Applications
• Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 17
• Saman and Alizadeh (2001, 2002) presented a
numerical and experimental study of a polymer plate
heat exchanger aimed at dehumidification and cooling
• Thin PE sheets (0.2 mm) separate both streams.
• The numerical results were compared with measured
data and good agreement was found.
• Introduction
• Challenges
• Properties
• Applications
 Conclusions
• References
11/11/2016 seminar_ppt I ND I rev00 18
• By using very thin polymer structures, both plate and
tubular heat exchangers can be successfully designed,
constructed, and tested with their performance being
comparable to conventional units at lower cost and
reduced weight.
• If one considers the advances made in composite
materials, as well as the new emerging technologies
such as nano scale composites, it is clear that, through
careful material selection and design modification, the
incorporation of polymer materials into HVAC&R
applications holds tremendous promise for future heat
exchanger designs.
• Introduction
• Challenges
• Properties
• Applications
• Conclusions
 References
11/11/2016 seminar_ppt I ND I rev00 19
• [1] C. T’Joen, Y. Park, Q. Wang, A. Sommers, X. Han, A. Jacobi.
A review on polymer heat exchangers for HVAC&R applications.
• [2] T. Malik and C. W. Bullard. Suitability of Polymer Heat
Exchangers for Air Conditioning Applications.
• [3] Ullrich Hesse, Thomas Weimer. Polymer Material Heat
Exchangers Application in Refrigerant Cycles.
• [4] A. Sommers, Q. Wang, X. Han, C. T'Joen, Y. Park, A. Jacobi.
Ceramics and ceramic matrix composites for heat exchangers in
advanced thermal systems-A review.
• [5] Bidisha Ghosh, Wadeema Yousef, Mariam Al Jaberi, Nuha Al
Hajeri, Asrar Al Braiki,Valerie Eveloy, and Peter Rodgers. Design
and Investigation into the Thermal andMechanical Performance
of a Polymer Composite Prototype Gas-Liquid Heat Exchanger.
• [6] Alberto Fina, Guido Saracco, Samuele Porro, Fabrizio Pirri,
Franco Anzioso,Carloandera Malvicino. Potential of thermally
conductive polymers based on carbon allotropes in the
development of new heat management components on board a
car.
• [7] Dr. Catherine Thibaud-Erkey. High thermal conductivity
polymer composites for low cost heat exchangers.
11/11/2016 seminar_ppt I ND I rev00 20
• Introduction
• Challenges
• Properties
• Applications
• Conclusions
• References
 Thank You
“Quality is a Journey,
not a Destination”

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Polymer Heat Exchangers Review

  • 1. 11/11/2016 seminar_ppt I ND I rev00 Sangli A Presentation on “A REVIEW ON POLYMER HEAT EXCHANGERS FOR THERMAL SYTEMS” Presented by : Mr. Nandkishor R. Darade nandkishor.darade@gmail.com
  • 2.  Introduction • Challenges • Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 2 • In thermal systems, heat exchangers are very important to the overall efficiency, cost, and size of the system. Currently, these applications rely heavily on heat exchanger designs, often constructed using copper, aluminum, or steel. • Metal HX issues are expensive to manufacture, limited by operating conditions, materials and manufacturing techniques. • So the alternative designs are created using Polymers.
  • 3.  Introduction • Challenges • Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 3 Characteristics of materials used in HX
  • 4. • Introduction  Challenges • Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 4 • Thermal conductivity • Strength of polymers • Operating Temperature, Pressure Material Thermal Conductivity W/(K m) PE 0.33 ‐ 0.57 PEEK 0.25 Cu (pure) 401 Cu (commercial) 240 ‐ 380 Al 99,5% 236 Steel 48 ‐ 58 Steel (SS) 15 Material Tensile strength MPa PE 30 PEEK 97 Cu 200 Al 99,5% 75 ‐ 110 Steel 310 ‐ 630 Steel (SS) 700 ‐ 1300
  • 5. 11/11/2016 seminar_ppt I ND I rev00 5 Material Min. Application Temperature °C Max. Application Temperature °C Max. Temperature for Short Term °C PE ‐80 90 100 PEEK ‐65 240 300 • Introduction  Challenges • Properties • Applications • Conclusions • References The utilization of polymer materials in high performance HX applications requires totally new design approaches with very thin materials, reduced mechanical forces on the material and alternative solutions to achieve turbulent flow regimes.
  • 6. • Introduction • Challenges  Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 6 • Material properties of Polymers & PMCs • The most important properties include • Thermal conductivity • Specific heat capacity • Max. operating Temprature • Coefficient of thermal expansion • Tensile strength, modulus • Density
  • 7. • Introduction • Challenges  Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 7 • Zaheed and Jachuck (2004) compared a Ni–Cr–Mo (8 W/m-K) alloy tubular heat exchanger to a PVDF version of the same unit, and when considering the difference in density and in material cost, it was found that, despite being 6 times larger, the PVDF heat exchanger will cost 2.5 times less than the metal version. • Ma et al. (2002) Condensation experiments on a single tube coated with a PTFE film showed an increase of the heat transfer rate ranging from 0.3 to 4.6 times compared to a regular brass tube. Drop-wise condensation was found to occur for more than 22,000 h. • Brouwers and Van Der Geld (1996) found drop-wise condensation occurred within a pure PVDF plate heat exchanger. This indicates that polymer films could be used to increase the heat transfer rate in condensing applications sustaining drop-wise condensation over an extended period of time.
  • 8. • Introduction • Challenges  Properties • Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 8 Reinforcement Matrix Formulation Thermal conductivity Continuous carbon fibers Polymer - 330 Natural graphite Epoxy - 370 1DP-120 Polyester 45 wt 245.0 1DVGCF Epoxy 38 Vf 695 2DVGCF Epoxy 56 Vf 292 The material properties of polymers and different composites shows these materials can be used in heat exchange applications.
  • 9. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 9 • Liquid-to-liquid heat exchangers • Morcos and Shafey (1995) presented a PVC shell and tube heat exchanger for varying tube and shell side Reynolds numbers. • The wall thickness was found to limit the overall heat transfer coefficient to a maximum of 90 W/ m2-K. • To enhance the heat transfer rate, double conical PVC turbulators were introduced in the tubes.
  • 10. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 10 • In a review of the use of polymers in liquid- to- liquid heat transfer, Davidson et al. (1998) assessed polymers according to strength, stiffness, cost, and thermal conductivity. • For the tubes, high temperature nylon (HTN), cross- linked polyethylene (PEX) were chosen. • For the headers, glass fiber reinforced polymers were preferred, with HTN, PP, and PPS being the recommended types. • Liu (2000) studied the feasibility of both a shell-and- tube heat exchanger and an immersed unit numerically.
  • 11. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 11
  • 12. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 12 Heat transfer capacity PEX Nylon Copper 3000 W 1.78 m2 0.50 m2 0.50 m2 6000 W 7.78 m2 2.16 m2 2.19 m2 Heat transfer capacity PEX Nylon Copper 3000 W 4.21 m2 1.89 m2 1.10 m2 6000 W 11.4 m2 8.42 m2 2.03 m2 Total exterior heat transfer surface areas for shell and tube HX at 5.7L/min Total exterior heat transfer surface areas for Immersed HX at 5.7L/min
  • 13. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 13 • Zakardas et al. (2005) presented a novel design of polymer heat exchanger for liquid-to-liquid or condensing-fluid-to-liquid heat transfer: hollow fiber heat exchangers. • These units showed a very high compactness achieving 1500 m2 of exterior surface in an 11.8 cm long shell with a diameter of 2.3 cm. OHTC upto1360 W/m2-K were reported. • The unit ‘41939’ was found to be able to transfer up to 5.3 kW with a volume which is over 250 times smaller than a conventional design.
  • 14. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 14 • Patel and Brisson (2000) studied a polymer kapton heat exchanger for cryogenic applications. • A novel design for a plastic thin-film heat exchanger was developed and tested by Lowenstein and Sibilia (1993, 1999). This investigation proved the feasibility of designing and producing evaporators and absorbers from thin plastic films. • Based on tests of the long-term creep characteristics of a HDPE film, the projected life of this heat exchanger made from HDPE and operating at 172 kPa/38 C would be 20 years.
  • 15. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 15 • Spiral HX using polymer films HX diameter 0.1 – 0.4 m HX height 0.3 – 0. 8 m HX –weight 1 - 10 kg Heat transfer 0.5 – 3 kW/K Typical pressure drop 150 – 400 mbar Typical liq. volume flow 0.2 – 1.5 m³/h Maximum system pressure (20 °C) 9 bar Maximum system pressure (90 °C) 5 bar Maximum system temperature 120 °C Maximum pressure difference between Channels 3 bar
  • 16. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 16 • Gas-to-gas heat exchangers • Rousse et al. (2000) presented an experimental study of a PE shell-and-tube heat recovery unit for greenhouses. • The designed unit met the requirements and satisfactory performance under frosting conditions. In operation, efficiencies up to 84% were measured.
  • 17. • Introduction • Challenges • Properties  Applications • Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 17 • Saman and Alizadeh (2001, 2002) presented a numerical and experimental study of a polymer plate heat exchanger aimed at dehumidification and cooling • Thin PE sheets (0.2 mm) separate both streams. • The numerical results were compared with measured data and good agreement was found.
  • 18. • Introduction • Challenges • Properties • Applications  Conclusions • References 11/11/2016 seminar_ppt I ND I rev00 18 • By using very thin polymer structures, both plate and tubular heat exchangers can be successfully designed, constructed, and tested with their performance being comparable to conventional units at lower cost and reduced weight. • If one considers the advances made in composite materials, as well as the new emerging technologies such as nano scale composites, it is clear that, through careful material selection and design modification, the incorporation of polymer materials into HVAC&R applications holds tremendous promise for future heat exchanger designs.
  • 19. • Introduction • Challenges • Properties • Applications • Conclusions  References 11/11/2016 seminar_ppt I ND I rev00 19 • [1] C. T’Joen, Y. Park, Q. Wang, A. Sommers, X. Han, A. Jacobi. A review on polymer heat exchangers for HVAC&R applications. • [2] T. Malik and C. W. Bullard. Suitability of Polymer Heat Exchangers for Air Conditioning Applications. • [3] Ullrich Hesse, Thomas Weimer. Polymer Material Heat Exchangers Application in Refrigerant Cycles. • [4] A. Sommers, Q. Wang, X. Han, C. T'Joen, Y. Park, A. Jacobi. Ceramics and ceramic matrix composites for heat exchangers in advanced thermal systems-A review. • [5] Bidisha Ghosh, Wadeema Yousef, Mariam Al Jaberi, Nuha Al Hajeri, Asrar Al Braiki,Valerie Eveloy, and Peter Rodgers. Design and Investigation into the Thermal andMechanical Performance of a Polymer Composite Prototype Gas-Liquid Heat Exchanger. • [6] Alberto Fina, Guido Saracco, Samuele Porro, Fabrizio Pirri, Franco Anzioso,Carloandera Malvicino. Potential of thermally conductive polymers based on carbon allotropes in the development of new heat management components on board a car. • [7] Dr. Catherine Thibaud-Erkey. High thermal conductivity polymer composites for low cost heat exchangers.
  • 20. 11/11/2016 seminar_ppt I ND I rev00 20 • Introduction • Challenges • Properties • Applications • Conclusions • References  Thank You “Quality is a Journey, not a Destination”

Editor's Notes

  1. Why this topic? Polymer material have become common in daily life & gaining imp as technical design component.
  2. Rising prices & depleting sources of conventional materials, operating conditions limi. includes: corrosive, food industry, acidic medium applications
  3. Manu. Tech like 3D printing,additive manu provide flexibility in design,no geometric limit, pinpoint accuracy. High compact HX can be manufactured.
  4. Significant difference in th cond.k, use of min thickness leads to strength issues. But these challenges are overcomed by diff composite polymers.
  5. T,P range sufficient for many appli in HVAC&R. new design approaches means setting of diff stds like ASTM,ASHRAE for minimal(mech, etc.) requirements.
  6. Selection depends on process data, medium, service temp,pr. (FEA result for expt suggest that 1% inc in k+.005% more H.T. but 1% inc. in S.Area =.8%more H.T.) ,op temp are limited by m.p. and glass transi. Temp,density of copper ~8g/cc, polymers~ 1to2g/cc
  7. If low cost is only criterion for selection.
  8. These diff PMCs also have comparable mechanical prop.
  9. 1.3 m long circular tubes , Five baffles , reducing the thickness would result in a higher maximum value, HT enhancement 3.5 were recorded without pressure drop penalty
  10. The arrangement and the number of tubes, shell dimensions, flow rate of the liquids, and the required heat transfer rate in an external tube-in-shell heat exchanger were fixed and the required length of the tube was calculated,
  11. the copper immersed heat exchanger was modeled as a single 15.88 mm outside diameter tube
  12. thin-walled nylon heat exchanger has a very similar thermal performance as the copper heat exchanger,
  13. thin hollow fibers connected between two headers ,pp(425/575 mm ID/OD) &PEEK fibers (150/360 mm ID/OD) were used. excellent replacement for the conventional metal designs
  14. advantages for very low temperature applications
  15. two tubes for liquid in- and output, red lines represent glues , evaporators, condensers and solution heat exchanger in cooling and refrigeration cycles
  16. 5 corrugated PE tubes, single shell, low cost (3-year pay back period); ease of assembly, repair, maintenance, and operation; corrosion resistance, efficiency:temperature difference between inlet and outlet of the inlet air to the maximum temperature difference
  17. the injection angle, air mass flow rate, temperature and humidity, achieve desired summer comfort level conditions
  18. CNT:k=2000~6000,diamond:2000,graphene:800-5000 W/mK
  19. Elsevier,ASHRAE,International Refrigeration and Air Conditioning Conference etc. papers were used.