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MATERIAL SCIENCE - POLYMERS
Web: www.amiestudycircle.com     Ph/WA: +91 9412903929       1/2 
AMIE(I) STUDY CIRCLE(REGD.)
STUDY MATERIAL FOR AMIE EXAMS
Example (AMIE Winter 2019, 5 marks)
Calculate the weight of sulphur required to fully cross-link 68 kg of polyisoprene starting from natural
rubber. Which product will form due to full cross-linking?
Solution
Given
The molecular weight of isoprene monomer = 68 g.
Figure
After vulcanization with sulphur, it is observed from following figure that the two molecules of isoprene
monomer require two molecules of sulphur.
MATERIAL SCIENCE - POLYMERS
Web: www.amiestudycircle.com     Ph/WA: +91 9412903929       2/2 
AMIE(I) STUDY CIRCLE(REGD.)
STUDY MATERIAL FOR AMIE EXAMS
Analysis
Hence, for full cross-linking, (68 x 2) g of isoprene requires (32 x 2) g of sulphur.
Therefore, 68 kg of isoprene requires
32 2
68 32
68 2
x
x
x
 kg of sulphur

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Material Science - Polymers - Numerical - AMIE (Winter 2019)

  • 1. MATERIAL SCIENCE - POLYMERS Web: www.amiestudycircle.com     Ph/WA: +91 9412903929       1/2  AMIE(I) STUDY CIRCLE(REGD.) STUDY MATERIAL FOR AMIE EXAMS Example (AMIE Winter 2019, 5 marks) Calculate the weight of sulphur required to fully cross-link 68 kg of polyisoprene starting from natural rubber. Which product will form due to full cross-linking? Solution Given The molecular weight of isoprene monomer = 68 g. Figure After vulcanization with sulphur, it is observed from following figure that the two molecules of isoprene monomer require two molecules of sulphur.
  • 2. MATERIAL SCIENCE - POLYMERS Web: www.amiestudycircle.com     Ph/WA: +91 9412903929       2/2  AMIE(I) STUDY CIRCLE(REGD.) STUDY MATERIAL FOR AMIE EXAMS Analysis Hence, for full cross-linking, (68 x 2) g of isoprene requires (32 x 2) g of sulphur. Therefore, 68 kg of isoprene requires 32 2 68 32 68 2 x x x  kg of sulphur