Project Goal: Assess the long-term, undisturbed
performance of the SBE63 optical oxygen sensor in a
high fouling coastal environment over a two-year
period. Results indicate stability within +/- 2% in the
field.
• Instrument left on the mooring for 2 years without removal, cleaning,
or servicing
• Test site was a shallow nearshore estuarine environment at Shilshole
Marina, north of Seattle, WA USA
• Test site visited periodically with water samples and CTD profiles
collected for field validation of mooring
Presentation given at the 2nd SILTFLUX workshop on 19/05/2015 at UCD. Authors: Elizabeth Conroy, Jonathan Turner, Michael Bruen, John O'Sullivan, Anna Rymszewicz, Mary Kelly-Quinn
Presentation given at the 2nd SILTFLUX workshop on 19/05/2015 at UCD. Authors: Michael Bruen, Mary Kelly-Quinn, John O'Sullivan, Jonathan Turner, Elizabeth Conroy, Anna Rymszewicz, Damian Lawler, John Wallace
Presentation given at the 2nd SILTFLUX workshop on 19/05/2015 at UCD. Authors: Elizabeth Conroy, Jonathan Turner, Michael Bruen, John O'Sullivan, Anna Rymszewicz, Mary Kelly-Quinn
Presentation given at the 2nd SILTFLUX workshop on 19/05/2015 at UCD. Authors: Michael Bruen, Mary Kelly-Quinn, John O'Sullivan, Jonathan Turner, Elizabeth Conroy, Anna Rymszewicz, Damian Lawler, John Wallace
Polishing Multiple California Service Station Sites to Achieve Low Threat Cl...Antea Group
Antea Group Consultant Jack Sheldon presented at the AEHS 2016 conference on "Polishing Multiple California Sites to Achieve Low Threat Closure" including case studies from several active CA service stations.
A study was carried out to determine the distribution and behaviour of nitrogen (N) compounds (nitrite, nitrate, ammonia,
dissolved and particulate organic nitrogen) in Sungai Terengganu estuary (TRE). Surface water samples were collected
during ebb neap and spring tides for the longitudinal survey along the salinity gradient. The results indicated that all N
compounds behave non-conservatively with addition during both tidal cycles, except for nitrate which exhibited removal
behaviour during spring tide. In general, higher concentration of N compounds was observed during spring tide compared
to neap tide. It is suggested that during spring tide, stronger water turbulence resulted in resuspension of nutrients in
bottom sediment and lead to the increase in N compounds concentrations in the surface water. The diurnal survey for the
freshwater station showed that the concentrations of N compounds follow the ebb and flood variations, whereas for the
coastal station the reverse trend was observed. Comparisons with a previous study under similar tidal conditions show
there was an increase in nitrite and ammonia concentrations in TRE, which was probably due to increase in discharge
from the rapid development activities around this area. In addition, the presence of a breakwater at the lower part of
the estuary may also contribute to the high nutrient content in the estuary due to restricted outflow of nutrients to the
coastal area. Overall, the results from this study highlighted the importance of monitoring the N compounds for future
protection of the estuary.
Kevin Kraus, Saint Francis University Environmental Engineering Department, “...Michael Hewitt, GISP
Ancient technology that found its roots in the Catalan Forge in Spain, has seen a revival in recent years to treat acid mine drainage. This technology harnesses the power of hydraulics and hydrology by passively compressing air via the use of falling water, using no moving parts. A group of recently-graduated students from Saint Francis University have done extensive research in attempt to procure sizing guidance and parameters for the installation of this passive technology.
1Department of Biotechnology, Techno India University, Salt Lake Campus Kolkata, India
2Department of Microbiology, Techno India University, Salt Lake Campus, Kolkata, India
3Department of Marine Science, University of Calcutta, 35 B.C. Road, Kolkata, India
*Address for Correspondence: Atanu Roy, Research Scholar, Department of Biotechnology, Techno India University,
Salt lake Campus, Kolkata, India
ABSTRACT- Three decades data (1984 – 2015) was used to study the effect of surface water temperature, pH, dissolved
oxygen, nitrate, phosphate and silicate on chlorophyll a concentration in three water bodies meant for fish culture (locally
known as Bheries) in East Kolkata Wetlands. The data revealed significant spatio-temporal variations (p < 0.01). The
increasing trend of temperature, nitrate and phosphate reflects the effect of intense urbanization at local level. The
pronounced variation of dissolved oxygen and chlorophyll a (decreasing trend) may be attributed to increased load of
sewage in the selected water bodies, which has posed an adverse impact on the phytoplankton standing stock as revealed
through decreasing chlorophyll a trend.
Key-words- East Kolkata Wetlands (EKW), Phytoplankton, Chlorophyll a, Nutrients, ANOVA
The quality of any body of surface or ground water
is a function of either both natural influences and human
influences. Without human influences water quality would be
determined by the weathering of bedrock minerals, by the
atmospheric processes of evaporation, transpiration and the
deposition of dust and salt by wind, by the natural leaching of
organic matter and nutrients from soil, by hydrological factors
that lead to runoff, and by biological processes within the aquatic
environment that can alter the physical and chemical
composition of water. Declining water quality has become a
global issue of concern as human populations griesrow, industrial
and agricultural activities expand, and climate change threatens
to cause major alterations to the hydrological cycle.
Proposal written by a team of chemical engineers at UC Berkeley in order to suggest alternative solutions for effectively irrigating and restoring the Dow Wetlands site in Antioch, CA.
Multidisciplinary Research Week 2013 at the University of Southampton. #MDRWeek. World Water Day and International Year of Water Cooperation 2013.
Water quality: addressing global problems at source’, Presentation by Dr Jim Wright, Geography and Environment, University of Southampton.
See the latest videos, interviews, pictures, tweets and views from the floor at: www.southampton.ac.uk/multidisciplinary
Water is an important natural resource, which forms the cause of all life. Water is
one of the most requisite materials in our day to day life. It is a key resource in all
economic activities ranging from agriculture to industries. Only a minimal fraction of
the planet’s plentiful water is available to the living beings as fresh water. About 97%
is found in the oceans and is very salty for drinking, irrigation, or industry. The
remaining 3% is fresh water. About 2.997% of it is arrested in ice caps or glaciers or
is concealed so deep that it costs too much time & money to extract. Only about
0.0035 of Earth’s total volume of water is easily available to us as soil moisture,
exploitable ground water, water vapor, rivers, lakes and streams. In this present study
by a systematic sampling has been carried out to find the water quality parameters of
the Lake, by collecting samples from Six different positions, which covering entire
area of the lake, and the stations were distributed covering the periphery of the entire
tank, and also considering the inflow and the discharges and to suggest required
management techniques to make water free from the pollution
Mems based optical sensorMEMS BASED OPTICAL SENSOR FOR SALINITY MEASUREMENTprj_publication
In this paper, we purpose a two dimensional photonic crystal based optical sensor for
salinity measurement. The salinity percentage of is sea water changes as we go down the sea
water surface. This gives change to the index of refraction of the sea water at the different
levels. Thus the salinity percentage of sea water can be detected by measuring this change in the
effective refractive index of sea water. In this paper, the effective refractive index method has
been used for the detection of the salinity concentration from (0-40%). The slab waveguide is
designed and the effective refractive changed is captured. Even as the refractive index change
for the change in salinity of the sea water, is very small, the effective index change is visible,
making the sensor very sensitive.
Week 2 Environmental Monitoring_Sampling & Data Quality Objectives.pptxSansenHandagJr
The basic principles of monitoring and characterization are described
for different environments, considering their most relevant processes. Initially, sampling protocols are described,
followed by documentation of quality control issues and
statistical methods for data analysis. Methods for making
field measurements in soil, vadose zone, water, and atmospheric environments are described. This includes
real-time monitoring, temporal and spatial issues, and
the issues of scale of measurement.
Polishing Multiple California Service Station Sites to Achieve Low Threat Cl...Antea Group
Antea Group Consultant Jack Sheldon presented at the AEHS 2016 conference on "Polishing Multiple California Sites to Achieve Low Threat Closure" including case studies from several active CA service stations.
A study was carried out to determine the distribution and behaviour of nitrogen (N) compounds (nitrite, nitrate, ammonia,
dissolved and particulate organic nitrogen) in Sungai Terengganu estuary (TRE). Surface water samples were collected
during ebb neap and spring tides for the longitudinal survey along the salinity gradient. The results indicated that all N
compounds behave non-conservatively with addition during both tidal cycles, except for nitrate which exhibited removal
behaviour during spring tide. In general, higher concentration of N compounds was observed during spring tide compared
to neap tide. It is suggested that during spring tide, stronger water turbulence resulted in resuspension of nutrients in
bottom sediment and lead to the increase in N compounds concentrations in the surface water. The diurnal survey for the
freshwater station showed that the concentrations of N compounds follow the ebb and flood variations, whereas for the
coastal station the reverse trend was observed. Comparisons with a previous study under similar tidal conditions show
there was an increase in nitrite and ammonia concentrations in TRE, which was probably due to increase in discharge
from the rapid development activities around this area. In addition, the presence of a breakwater at the lower part of
the estuary may also contribute to the high nutrient content in the estuary due to restricted outflow of nutrients to the
coastal area. Overall, the results from this study highlighted the importance of monitoring the N compounds for future
protection of the estuary.
Kevin Kraus, Saint Francis University Environmental Engineering Department, “...Michael Hewitt, GISP
Ancient technology that found its roots in the Catalan Forge in Spain, has seen a revival in recent years to treat acid mine drainage. This technology harnesses the power of hydraulics and hydrology by passively compressing air via the use of falling water, using no moving parts. A group of recently-graduated students from Saint Francis University have done extensive research in attempt to procure sizing guidance and parameters for the installation of this passive technology.
1Department of Biotechnology, Techno India University, Salt Lake Campus Kolkata, India
2Department of Microbiology, Techno India University, Salt Lake Campus, Kolkata, India
3Department of Marine Science, University of Calcutta, 35 B.C. Road, Kolkata, India
*Address for Correspondence: Atanu Roy, Research Scholar, Department of Biotechnology, Techno India University,
Salt lake Campus, Kolkata, India
ABSTRACT- Three decades data (1984 – 2015) was used to study the effect of surface water temperature, pH, dissolved
oxygen, nitrate, phosphate and silicate on chlorophyll a concentration in three water bodies meant for fish culture (locally
known as Bheries) in East Kolkata Wetlands. The data revealed significant spatio-temporal variations (p < 0.01). The
increasing trend of temperature, nitrate and phosphate reflects the effect of intense urbanization at local level. The
pronounced variation of dissolved oxygen and chlorophyll a (decreasing trend) may be attributed to increased load of
sewage in the selected water bodies, which has posed an adverse impact on the phytoplankton standing stock as revealed
through decreasing chlorophyll a trend.
Key-words- East Kolkata Wetlands (EKW), Phytoplankton, Chlorophyll a, Nutrients, ANOVA
The quality of any body of surface or ground water
is a function of either both natural influences and human
influences. Without human influences water quality would be
determined by the weathering of bedrock minerals, by the
atmospheric processes of evaporation, transpiration and the
deposition of dust and salt by wind, by the natural leaching of
organic matter and nutrients from soil, by hydrological factors
that lead to runoff, and by biological processes within the aquatic
environment that can alter the physical and chemical
composition of water. Declining water quality has become a
global issue of concern as human populations griesrow, industrial
and agricultural activities expand, and climate change threatens
to cause major alterations to the hydrological cycle.
Proposal written by a team of chemical engineers at UC Berkeley in order to suggest alternative solutions for effectively irrigating and restoring the Dow Wetlands site in Antioch, CA.
Multidisciplinary Research Week 2013 at the University of Southampton. #MDRWeek. World Water Day and International Year of Water Cooperation 2013.
Water quality: addressing global problems at source’, Presentation by Dr Jim Wright, Geography and Environment, University of Southampton.
See the latest videos, interviews, pictures, tweets and views from the floor at: www.southampton.ac.uk/multidisciplinary
Water is an important natural resource, which forms the cause of all life. Water is
one of the most requisite materials in our day to day life. It is a key resource in all
economic activities ranging from agriculture to industries. Only a minimal fraction of
the planet’s plentiful water is available to the living beings as fresh water. About 97%
is found in the oceans and is very salty for drinking, irrigation, or industry. The
remaining 3% is fresh water. About 2.997% of it is arrested in ice caps or glaciers or
is concealed so deep that it costs too much time & money to extract. Only about
0.0035 of Earth’s total volume of water is easily available to us as soil moisture,
exploitable ground water, water vapor, rivers, lakes and streams. In this present study
by a systematic sampling has been carried out to find the water quality parameters of
the Lake, by collecting samples from Six different positions, which covering entire
area of the lake, and the stations were distributed covering the periphery of the entire
tank, and also considering the inflow and the discharges and to suggest required
management techniques to make water free from the pollution
Mems based optical sensorMEMS BASED OPTICAL SENSOR FOR SALINITY MEASUREMENTprj_publication
In this paper, we purpose a two dimensional photonic crystal based optical sensor for
salinity measurement. The salinity percentage of is sea water changes as we go down the sea
water surface. This gives change to the index of refraction of the sea water at the different
levels. Thus the salinity percentage of sea water can be detected by measuring this change in the
effective refractive index of sea water. In this paper, the effective refractive index method has
been used for the detection of the salinity concentration from (0-40%). The slab waveguide is
designed and the effective refractive changed is captured. Even as the refractive index change
for the change in salinity of the sea water, is very small, the effective index change is visible,
making the sensor very sensitive.
Week 2 Environmental Monitoring_Sampling & Data Quality Objectives.pptxSansenHandagJr
The basic principles of monitoring and characterization are described
for different environments, considering their most relevant processes. Initially, sampling protocols are described,
followed by documentation of quality control issues and
statistical methods for data analysis. Methods for making
field measurements in soil, vadose zone, water, and atmospheric environments are described. This includes
real-time monitoring, temporal and spatial issues, and
the issues of scale of measurement.
Lutes, C., B. Cosky, B. Schumacher, J. Zimmerman, R. Truesdale and R., Norberg “Four Winters of Continuous Vapor Intrusion Monitoring In Indianapolis –Temporal Variability in Indoor Air” Oral presentation at EPA Vapor Intrusion Workshop at the AEHS 23rd International Conference on Soil, Water, Energy and Air, March 2013, San Diego
A Statistical Approach to Optimize Parameters for Electrodeposition of Indium...Arkansas State University
A Statistical Approach to Optimize Parameters for Electrodeposition of Indium (III) Sulfide Films, Potential Low-Hazard Buffer Layers for Photovoltaic Applications
Unit Hydrograph (UH) is the most famous and generally utilized technique for analysing and deriving flood hydrograph resulting from a known storm in a basin area. For ungauged catchments, unit hydrograph are derived using either regional unit hydrograph approach. Central Water Commission (CWC) derived the regional unit hydrograph relationships for different sub-zones of India relating to the various unit hydrograph parameters with some prominent physiographic characteristics. The Study Area is located between Latitude 15º57′58′′ N to 16º11′25.6′′ N and 77º18′1′′ E to77º32′5.3′′ E Longitude and covers area of 360.97 km2, having maximum length of 26.17 km. The maximum and minimum elevation of the basin is 533 m and 323 m above MSL, respectively. The Peak discharge of unit hydrograph obtained is 311.469 m3/s. The final cumulative discharge is 1458.55 m3/s.
Considerations on the collection of data from bio-argo floats across sampling...SeaBirdScientific
Ian D. Walsh, Ph. D, Joel Reiter, Dan Quittman, David J. Murphy, Thomas O. Mitchell, Ph.D. Sea-Bird Scientific. GAIC 2015 Meeting, Galway, Ireland, 14 – 18 Sept. 2015.
ABSTRACT
The flexibility of the current generation of float sensor packages peovides an opportunity to craft mission specific sampling schemes that balance the collection of data for specific sampling goals with the practicalities of float operation. Autonomous floats operate within constraints of battery life and data transfer rates.
For simplicity of data transfer and handling, most float data sets are transmitted after binning on pressure. Within a given pressure bin different instruments will be sampling within a particular defined sequence. A sampling sequence should be balanced towards minimizing energy consumption while maximizing data accuracy of each instrument. As the number of sensors increases and the breadth of mission parameters expands it becomes more difficult to optimize data sequencing and reporting.
We consider methods to reduce the size of the problem by setting rules for sequence development and test those rules relative to field data. We examine a set of data from a float that was equipped with internal memory that captured the full set of sample data taken during the profiling mission.
Comparing the ‘raw’ data and the transmitted data we examine the variance around the transmitted data and discuss the impact of data sequencing on the data.
Advances in bio-optical sensing on robotic platforms to elucidate ecosystem p...SeaBirdScientific
ABSTRACT
The global view of ocean productivity has been defined for the past three decades by satellite-derived images of optical properties of the ocean’s surface layer. Yet in most of the ocean, zones of enhanced phytoplankton production and nutrient recycling are located at depths below the view of optical satellites. In the subtropical gyres, the almost ubiquitous deep chlorophyll maximum is often located at depths exceeding 100m, along density interfaces at a boundary between the down welling light flux and upward transport of nutrients. Below the chlorophyll maximum heterotrophic production is the dominant process resulting in strong oxygen consumption and dissolved nutrient regeneration. Observing the physical forcing and biogeochemical dynamics that drive this system at the relevant time scales ranging from the diel to the seasonal has been a long-standing challenge in oceanography. In particular, measuring the processes occurring through perturbations to relaxation has often been more happenstance than design. In this presentation we describe advances in sensor systems deployed on autonomous robotic profilers to quantify carbon, oxygen and nutrient cycling within the interior ocean and present examples from the subtropical Indian Ocean and western Mediterranean.
Acknowledgements: Funding for CSIRO provided through the Australia-India Strategic Research Fund, OCE Postdoctoral fellowship scheme and Antarctic Climate and Ecosystems Cooperative Research Centre.
Oil in water fluorescence and backscattering relationshipsSeaBirdScientific
Ian Walsh
Sea-Bird Scientific Ocean Research
Brian Robinson
Fisheries and Oceans Canada, Bedford Institute of Oceanography
John Koegler
Sea-Bird Scientific Ocean Research
Robyn Conmy
3USEPA/NRMRL/LRPCD
February, 2016
In-situ tracking of oil from the Deepwater Horizon oil spill using spectral f...SeaBirdScientific
Corey Koch, Paula Coble,2Leslie Slasor,3Joseph Needoba,3Andrew Barnard,1Scott Pegau4
1-WET Labs Inc. Philomath OR. 2-University of South Florida, St. Petersburg FL. 3-Oregon Health and Sciences University, Portland, OR. 4-Oil Spill Recovery Institute, Cordova, AK.
Multi-source connectivity as the driver of solar wind variability in the heli...Sérgio Sacani
The ambient solar wind that flls the heliosphere originates from multiple
sources in the solar corona and is highly structured. It is often described
as high-speed, relatively homogeneous, plasma streams from coronal
holes and slow-speed, highly variable, streams whose source regions are
under debate. A key goal of ESA/NASA’s Solar Orbiter mission is to identify
solar wind sources and understand what drives the complexity seen in the
heliosphere. By combining magnetic feld modelling and spectroscopic
techniques with high-resolution observations and measurements, we show
that the solar wind variability detected in situ by Solar Orbiter in March
2022 is driven by spatio-temporal changes in the magnetic connectivity to
multiple sources in the solar atmosphere. The magnetic feld footpoints
connected to the spacecraft moved from the boundaries of a coronal hole
to one active region (12961) and then across to another region (12957). This
is refected in the in situ measurements, which show the transition from fast
to highly Alfvénic then to slow solar wind that is disrupted by the arrival of
a coronal mass ejection. Our results describe solar wind variability at 0.5 au
but are applicable to near-Earth observatories.
THE IMPORTANCE OF MARTIAN ATMOSPHERE SAMPLE RETURN.Sérgio Sacani
The return of a sample of near-surface atmosphere from Mars would facilitate answers to several first-order science questions surrounding the formation and evolution of the planet. One of the important aspects of terrestrial planet formation in general is the role that primary atmospheres played in influencing the chemistry and structure of the planets and their antecedents. Studies of the martian atmosphere can be used to investigate the role of a primary atmosphere in its history. Atmosphere samples would also inform our understanding of the near-surface chemistry of the planet, and ultimately the prospects for life. High-precision isotopic analyses of constituent gases are needed to address these questions, requiring that the analyses are made on returned samples rather than in situ.
Richard's aventures in two entangled wonderlandsRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
This pdf is about the Schizophrenia.
For more details visit on YouTube; @SELF-EXPLANATORY;
https://www.youtube.com/channel/UCAiarMZDNhe1A3Rnpr_WkzA/videos
Thanks...!
What is greenhouse gasses and how many gasses are there to affect the Earth.moosaasad1975
What are greenhouse gasses how they affect the earth and its environment what is the future of the environment and earth how the weather and the climate effects.
Richard's entangled aventures in wonderlandRichard Gill
Since the loophole-free Bell experiments of 2020 and the Nobel prizes in physics of 2022, critics of Bell's work have retreated to the fortress of super-determinism. Now, super-determinism is a derogatory word - it just means "determinism". Palmer, Hance and Hossenfelder argue that quantum mechanics and determinism are not incompatible, using a sophisticated mathematical construction based on a subtle thinning of allowed states and measurements in quantum mechanics, such that what is left appears to make Bell's argument fail, without altering the empirical predictions of quantum mechanics. I think however that it is a smoke screen, and the slogan "lost in math" comes to my mind. I will discuss some other recent disproofs of Bell's theorem using the language of causality based on causal graphs. Causal thinking is also central to law and justice. I will mention surprising connections to my work on serial killer nurse cases, in particular the Dutch case of Lucia de Berk and the current UK case of Lucy Letby.
Professional air quality monitoring systems provide immediate, on-site data for analysis, compliance, and decision-making.
Monitor common gases, weather parameters, particulates.
Long-term stability of a moored optical oxygen sensor in an estuary
1. LONG-TERM STABILITY OF A MOORED OPTICAL OXYGEN SENSOR IN AN ESTUARY
Stephanie Jaeger*1, Simone Simbeck1, Carol Janzen2, Samuel Bennett1, & David Murphy1
1Sea-Bird Scientific, Bellevue, Washington 98005 USA · 2Alaska Ocean Observing System, Anchorage, Alaska 99501 USA
*Corresponding author: sjaeger@seabird.com
Introduction
Project Goal: Assess the long-term, undisturbed
performance of the SBE63 optical oxygen sensor in a
high fouling coastal environment over a two-year
period. Results indicate stability within +/- 2% in the
field.
• Instrument left on the mooring for 2 years without removal, cleaning,
or servicing
• Test site was a shallow nearshore estuarine environment at Shilshole
Marina, north of Seattle, WA USA
• Test site visited periodically with water samples and CTD profiles
collected for field validation of mooring
Acknowledgements:
Many thanks to Rory Holt for analyzing Winkler water samples, and all of the
Sea-Bird team members who helped with fieldwork. Thanks to Lydia
Kapsenberg, recipient of the 2013 Sea-Bird Graduate Student Equipment
Loan Program Award, for sharing data and feedback.
References:
• Bittig, H. and A. Körtzinger, 2015. Tackling Oxygen Optode Drift: Near-Surface and In-
Air Oxygen Optode Measurements on a Float Provide an Accurate in Situ Reference. J.
Atmos. Oceanic Technol. 32: 1536–1543.
• Garcia, H. and L. Gordon, 1992. Oxygen solubility in seawater: better fitting equations.
Limnol. Oceanogr. 37: 1307–1312.
• Kapsenberg, L. and G. Hofmann, 2016. Ocean pH time-series and drivers of variability
along the northern Channel Islands, California, USA. Limnol. Oceanogr., early release:
DOI: 10.1002/lno.10264.
• Knap, A., A. Michaels, A. Close, H. Ducklow and A. Dickson (eds.), 1996. Chapter 6:
Determination of Dissolved Oxygen by the Winkler Procedure; Protocols for Joint
Global Ocean Flux Study (JGOFS) Core Measurements. JGOFS Report 19: 29 – 36.
• Sea-Bird Electronics, 2015. User Manual for SBE37-SMP-ODO MicroCAT
C-T-ODO(P) Recorder. Sea-Bird Scientific: 97 pp.
Why is this important?
Dissolved oxygen (DO) is a key parameter for understanding biological
production, deep water mass transport, biogeochemical cycling, and other
oceanographic processes. Improvements and assessments of the long-
term stability of oxygen sensors contribute to a better understanding of
oxygen data quality. An understanding of potential impacts from
biofouling can lead to fewer field servicing visits needed at moored sites,
and leave more time for data analysis.
Results
Time series of mooring data shows seasonal and diurnal oxygen variability over the deployment period, and field validation data also mapped the same
features. In particular, oxygen super-saturation events from phytoplankton blooms are captured, with DO reaching as high as 185% oxygen saturation (up to
12.2 mL/L), shown in Fig. 1.
Near the end of the deployment, salinity showed less tidal fluctuation, while DO dropped to 0, presumably due to clogging of the sensor/plumbing. Then,
mooring was pulled and recovered in June 2015, after 21 months at the estuarine site. The extent of biofouling on recovery is shown in Fig. 2 and 4. Note the
clear path around the anti-foulant cartridges at the intake/exhaust that remains, confirming the efficacy of the anti-foulant in high growth environments.
After recovery, housing exterior was cleaned, and sensors lightly flushed with DI water only. Calibration was completed at Sea-Bird to assess drift, shown in
Fig. 3. The post calibration of the ODO sensor shows a slope drift of -1.2%, where the sensor was deployed for 21 months of the two year period. This result
falls within the initial accuracy specification of the ODO sensor (+/- 2%), showing negligible impacts from biofouling at this site.
Methods:
A SBE37SMP CTD (37) with a SBE63 optical dissolved oxygen sensor
(ODO) was deployed on a floating dock in central Puget Sound at 3 m
depth, and 4 m above the bottom. Sole biofouling protection was Sea-
Bird’s standard anti-foulant cartridges installed on the plumbing
intake/exhaust (Sea-Bird Electronics, 2015). Instrument sampled every 15
minutes and output in real-time via cellular telemetry.
37-ODO was not disturbed or recovered for 21 months. Periodic field site
visits were completed every 1 – 3 months to help validate mooring data,
and three major steps were completed with each visit:
1) Water samples were manually collected using a Niskin bottle, matching
the 37-ODO depth and sample period. Triplicates collected for
dissolved oxygen analysis by Winkler titration method (Knap et. al,
1996).
2) Side-by-side comparisons were made using profiling CTD (SBE19Plus
with SBE43 Clark electrode-type oxygen sensor) for reference, hung
in-situ adjacent to the 37-ODO.
3) A vertical profile was completed using same profiling CTD. Water
column structure and stratification were assessed to provide context of
the mooring relative to gradients. Spatial variability and position
relative to surface mixed layer are considered when comparing the
mooring to water samples.
Fig. 1 Time series of shallow SBE37-ODO deployed in central Puget Sound from Sept. 2013 – May 2015, undisturbed for duration. Temperature
(°C, shown in red) and salinity (PSU, shown in blue) on top. On bottom, DO shown in green with oxygen solubility (OxSol; Garcia & Gordon,
1992) shown in purple, plotted with discrete measurements taken from a clean reference SBE43 sensor and bottle samples.
Fig. 2B After 21-month
deployment: Same close-up of
SBE37-ODO. Note the clear
area around the white anti-
foulant cartridges on the
intake/exhaust.
Results and Precautions from Field Validations
Field validation results using both discrete water samples and a clean reference SBE43 sensor are shown below. During well-mixed conditions
(Table 2), the samples and moored sensor data agree better than during gradient conditions when sensor and samples were in the oxycline
(Table 1). This stresses the importance of understanding vertical and horizontal water column structure when making sensor and water sample
comparisons.
Conclusions
• ODO sensor showed stability within the initial accuracy
specification (+/- 2%) and negligible effects from biofouling,
until clogging of flow path after 21 months.
• Helps to provide a baseline when deciding how often to service
and maintain a mooring in similar environments, which can lead
to fewer field visits than typically expected.
Intake Exhaust
Thermistor
Intake Exhaust
Thermistor
Fig. 2A Prior to deployment:
Close-up of SBE37-ODO
intake/exhaust. Temperature,
conductivity, and oxygen
sensors are all contained
within the pumped flow path.
Fig. 3 Pre-
and post-
calibration
data from the
same SBE63
ODO sensor
as plotted in
Fig.1.
Residuals
show a slope
drift of -1.2%
after the two
year period.
Fig. 4 Photos of the entire SBE37-ODO instrument, both before
and after the 21-month deployment with biofouling.
Time
DO,
SBE37ODO
DO, ref.
SBE43
Date (PST) (mL/L) Rep. 1 Rep 2. Rep 3. AVG STD (mL/L)
03/12/14 13:00 6.75 7.14 7.32 7.54 7.33 0.20 6.65 -8.0 1.4
04/30/14 11:15 7.55 7.66 7.76 7.86 7.76 0.10 7.58 -2.7 -0.4
05/07/14 13:30 9.93 10.27 10.21 10.10 10.19 0.08 10.13 -2.6 -2.0
11/05/14 12:15 4.25 4.50 4.82 4.96 4.76 0.24 4.44 -10.6 -4.1
03/05/15 12:00 6.47 6.42 6.42 6.42 6.42 0.002 6.50 0.7 -0.5
DO, Winkler water samples (mL/L)
%Diff. of
ODO from
Avg. Winkler
%Diff. of
ODO from
SBE43
Time
DO,
SBE37ODO
DO, ref.
SBE43
Date (PST) (mL/L) Rep. 1 Rep 2. Rep 3. AVG STD (mL/L)
11/14/13 12:30 4.33 4.75* 4.91* 4.92* 4.86* 0.10* 4.26 ND 1.4
12/18/13 11:45 4.69 4.77 4.78 4.80 4.78 0.02 4.60 -1.9 1.9
01/29/14 11:15 5.35 5.39 5.44 5.52 5.45 0.07 5.33 -2.0 0.4
05/22/14 10:46 6.34 6.40 6.40 6.38 6.39 0.01 6.39 -0.8 -0.7
07/02/14 12:17 6.36 6.51 6.50 6.46 6.49 0.02 6.56 -2.0 -3.1
07/17/14 11:16 5.75 5.87 5.86 5.86 5.87 0.01 ND -1.9
07/17/14 11:30 5.69 5.76 -1.2
* = Not used as poor water sample collected for Winkler analysis
DO, Winkler water samples (mL/L)
%Diff. of
ODO from
Avg. Winkler
%Diff. of
ODO from
SBE43
Table 2. Station sampled while mooring (SBE37ODO; at 3 m depth) lies
in a well-mixed water mass. Mooring DO data is ≤ 2% different than
bottle samples.
Table 1. Station sampled during vertical DO gradient through-out water
column (~ 7 m total depth). Note discrepancy between mooring and
bottle samples; likely due to sampling in different water masses.
ODO
Sensor Time
DO,
SBE37OD
S/N: Date (UTC) Status (mL/L)
0265 06/25/14 21:15 Start interval 5.97 6.01 -0.61
0265 07/09/14 16:45 Mid-interval 4.94 4.97 -0.63
0265 07/09/14 20:45 Mid-interval 5.74 5.76 -0.29
0265 09/20/14 19:15 End of interval 5.32 5.32 0.08
0356 06/25/14 16:45 End of interval 5.43 5.56 -2.37
%Diff. of ODO
from Bottle
sample
DO, Bottle
water sample
(mL/L)
Discussion:
What is the mechanism and type of sensor drift?
• Drift characteristic of the SBE63 ODO observed by SBE across numerous
factory calibrations indicates sensor drifts linearly low of correct.
• Exact mechanism for drift in optical oxygen sensors is not well
understood, and may be due to a combination of factors.
• Bittig and Körtzinger (2015) suggest that reduction of oxygen sensitivity
over time could be attributed to a physical change of the sensing
membrane such as decreased oxygen accessibility of the luminophore or
decreased oxygen diffusivity inside the membrane.
• As with the SBE43, the instrument configuration with plumbing and anti-
foulants clearly helps to protect the sensor from external biofouling
growth.
How does this compare to drift while in storage?
Drift tests for optical oxygen sensors stored dry at room temperature,
completed at Sea-Bird over a three year period, indicate that shelf drift can
be on the order of -1.0 to -1.5% per year.
0
5
10
15
20
25
30
35
5
7
9
11
13
15
17
19
Salinity,PSU
Temperature,degC
Temp.
Salinity
0
100
200
300
400
500
600
0
2
4
6
8
10
12
14
DO,umol/kg
DissolvedOxygen,mL/L
DO, SBE37-ODO
OxSol
DO, SBE43 on SBE19Plus
DO, Winkler water sample
usingmeansigma-t
-0.2
-0.1
0
0.1
0.2
0 1 2 3 4 5 6 7 8 9 10
SBE 63 0497 - Oxygen (2 of 9) - 26-Jul-13
Residual(ml/l)
Oxygen (ml/l)
26-Jul-13 1.0000 18-Aug-15 1.0115
Table 3. Comparison between discrete water samples collected at
deployment depth and SBE37-ODO’s at Anacapa Island show good
agreement (< 2.4% difference). (Data from Kapsenberg and Hofmann, 2016).
Fig. 5 Pre and post calibrations completed at SBE from ODO sensors
deployed in the Channel Islands. Post calibrations show -0.7% drift
from ID 0265 and -1.8% drift from ID 0356 over the 1.5 year time
period.
Example of mooring in Channel Islands, CA
Another example of ODO performance at a nearshore site, in this case with
periodic cleaning, from Kapsenberg and Hofmann (2016). Deployment in a
kelp forest in northern Channel Islands at Anacapa Island pier from May
2013 – Sept. 2014. Instruments rotated between sites, and cleaned every 2
– 3 months. Results indicate negligible drift in ODO sensors.
-0.2
-0.1
0
0.1
0.2
0 1 2 3 4 5 6 7 8 9 10
SBE 63 0265 - Oxygen (2 of 10) - 09-Jan-13
Residual(ml/l)
Oxygen (ml/l)
09-Jan-13 1.0000
29-Oct-14 1.0072
-0.2
-0.1
0
0.1
0.2
0 1 2 3 4 5 6 7 8 9 10
SBE 63 0356 - Oxygen (2 of 5) - 09-Jan-13
Residual(ml/l)
Oxygen (ml/l)
09-Jan-13 1.0000
25-Jul-14 1.0176 ODO ID 0356 ODO ID 0265
Status indicates stage of a given deployment interval (each 2-3 months long).