This document provides a 3-page summary of a licentiate thesis that examines the impact of moisture on the long-term performance of insulating products made from stone wool. The thesis includes 4 papers that study moisture issues with stone wool insulation in practice and laboratory experiments to analyze stone wool properties under varying moisture and temperature conditions. The summary outlines the background, aim, and structure of the thesis. It provides a brief introduction to insulation needs, standards in Europe, the manufacturing of mineral wool, and moisture transport in porous materials.
Mineral wool is a man-made inorganic fiber made from melting and spinning various raw materials like stone, glass, volcanic rock, and blast furnace slag at high temperatures. Glass wool, also called fiberglass, is made from melted natural and recycled glass. Rockwool or stone wool comes from melted volcanic rock or blast furnace slag. These fibers are bound together and used for insulation, creating pockets of trapped air that serve as barriers to heat transfer.
This study investigated whether melted extruded polystyrene foam could be used as a sealant. Small pieces of styrofoam were melted in gasoline and then applied to holes in metal sheets. The melted styrofoam successfully sealed the holes and hardened into a plastic-like material over several days. The study concluded that melted extruded polystyrene foam is an effective sealant that could potentially be used as an alternative to commercial sealants while also recycling styrofoam waste.
Mineral wool is a common acoustic panel material made from molten glass or stone that is spun into flexible fibers and processed into boards. It has high porosity and sound absorption properties dependent on its composition, thickness, and mounting. Mineral wool boards can be used in acoustic ceilings and are highly fire resistant due to preventing convection and providing a physical barrier to heat transfer. As a porous material, mineral wool controls noise by allowing sound waves to enter its fabric where friction dissipates the sound energy as heat.
Plastics have become widely used in construction due to their low cost, versatility, and resistance to water. While early plastics were derived from natural sources, completely synthetic plastics later emerged. There are two main types of plastics - thermoplastics that can be reshaped with heat and thermosets that set permanently. Plastics are used in buildings for pipes, cables, flooring, windows, doors, tanks and more. They provide benefits like durability, light weight and resistance to weather, but also have limitations like degradation from sunlight and flammability without treatment.
This document discusses plastics used in construction. It describes the main types of plastics commonly used, including acrylics, composites, expanded polystyrene, ETFE, polycarbonate, polyethylene, polypropylene, and polyvinyl chloride. It provides details on the properties and applications of each plastic type. The document also discusses plastic manufacturing processes, mechanical and physical properties of plastics, advantages and disadvantages of plastics in construction, and required tests for plastics.
1. Thin films are layers of material ranging from fractions of a nanometer to several micrometers thick.
2. Common methods for applying thin films include physical vapor deposition, chemical vapor deposition, electrodeposition, and sol-gel.
3. Physical vapor deposition works by controllably transferring atoms from a source to a substrate, with important methods being evaporation and sputtering.
more chemistry contents are available
1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
2. YouTube: https://www.youtube.com/channel/UCKxWnNdskGHnZFS0h1QRTEA
3. Facebook: https://web.facebook.com/Chemist.Rabia.Aziz/
4. Blogger: https://chemistry-academy.blogspot.com/
Ceramics manufacture process, properties, uses and classification
Mineral wool is a man-made inorganic fiber made from melting and spinning various raw materials like stone, glass, volcanic rock, and blast furnace slag at high temperatures. Glass wool, also called fiberglass, is made from melted natural and recycled glass. Rockwool or stone wool comes from melted volcanic rock or blast furnace slag. These fibers are bound together and used for insulation, creating pockets of trapped air that serve as barriers to heat transfer.
This study investigated whether melted extruded polystyrene foam could be used as a sealant. Small pieces of styrofoam were melted in gasoline and then applied to holes in metal sheets. The melted styrofoam successfully sealed the holes and hardened into a plastic-like material over several days. The study concluded that melted extruded polystyrene foam is an effective sealant that could potentially be used as an alternative to commercial sealants while also recycling styrofoam waste.
Mineral wool is a common acoustic panel material made from molten glass or stone that is spun into flexible fibers and processed into boards. It has high porosity and sound absorption properties dependent on its composition, thickness, and mounting. Mineral wool boards can be used in acoustic ceilings and are highly fire resistant due to preventing convection and providing a physical barrier to heat transfer. As a porous material, mineral wool controls noise by allowing sound waves to enter its fabric where friction dissipates the sound energy as heat.
Plastics have become widely used in construction due to their low cost, versatility, and resistance to water. While early plastics were derived from natural sources, completely synthetic plastics later emerged. There are two main types of plastics - thermoplastics that can be reshaped with heat and thermosets that set permanently. Plastics are used in buildings for pipes, cables, flooring, windows, doors, tanks and more. They provide benefits like durability, light weight and resistance to weather, but also have limitations like degradation from sunlight and flammability without treatment.
This document discusses plastics used in construction. It describes the main types of plastics commonly used, including acrylics, composites, expanded polystyrene, ETFE, polycarbonate, polyethylene, polypropylene, and polyvinyl chloride. It provides details on the properties and applications of each plastic type. The document also discusses plastic manufacturing processes, mechanical and physical properties of plastics, advantages and disadvantages of plastics in construction, and required tests for plastics.
1. Thin films are layers of material ranging from fractions of a nanometer to several micrometers thick.
2. Common methods for applying thin films include physical vapor deposition, chemical vapor deposition, electrodeposition, and sol-gel.
3. Physical vapor deposition works by controllably transferring atoms from a source to a substrate, with important methods being evaporation and sputtering.
more chemistry contents are available
1. pdf file on Termmate: https://www.termmate.com/rabia.aziz
2. YouTube: https://www.youtube.com/channel/UCKxWnNdskGHnZFS0h1QRTEA
3. Facebook: https://web.facebook.com/Chemist.Rabia.Aziz/
4. Blogger: https://chemistry-academy.blogspot.com/
Ceramics manufacture process, properties, uses and classification
The document provides information on the ceramic industry in Egypt. Some key points:
- Ceramics make up 7% of Egyptian industrial production and include items made of clay and silicates.
- Raw materials for ceramics include sand, feldspar, clay, and other minerals. Testing of raw materials includes chemical analysis by XRF and thermal analysis by dilatometry and TG-DTA.
- The production process for ceramic tiles includes batching, grinding, spraying, pressing, drying, firing, and sorting. Finished tiles undergo tests for properties like dimensions, strength, and abrasion resistance.
- Emissions from the ceramic industry can impact the environment through air pollution, effluents,
Microscopic inspection of pure metals and solid solutions. Saif al-din ali
1. Name of Experiment:
Microscopic inspection of pure metals and solid solutions.
2. The Objective of the Experiment:
To study the different shapes and sizes of grains and the flaws found in casts
The document provides information about plastics used as building materials. It discusses the introduction to plastics, their chemical composition and properties. It describes various plastic forming processes like extrusion, injection moulding, blow moulding and compression moulding. It also talks about the classification of plastics into thermoplastics, thermosets and elastomers. Thermoplastics can be reshaped upon heating while thermosets and elastomers cannot. The document provides details on the typical manufacturing process of plastics from raw materials to the final products.
Causes of deterioration of concrete structuresKarthi Kavya
The document discusses types of deterioration that can occur in concrete structures. It identifies three main types: distress in concrete, permeability of concrete, and aggressive deterioration agents. Distress can be physical, chemical, or mechanical due to issues like high water-cement ratio, inadequate curing, poor aggregates, overloading, or design deficiencies. Permeability is increased by porosity, microcracks, and dampness/seepage, allowing chemicals to enter. Major agents are chlorides, sulfates, and alkali-silica reaction, which can cause corrosion, cracking, or expansion through carbonation, sulfate attack, or silica gel formation.
Ceramic materials have been produced by humans for at least 24,000 years and are inorganic, nonmetallic solids formed through heating. Ceramics have a variety of properties including hardness, attractiveness, chemical inertness, and heat insulation. They are used widely in construction materials, decorative items, kitchenware, medical devices, and more. The production of ceramic tiles involves batching raw materials like clay and feldspar, grinding them, spray drying, pressing, drying, and high-temperature firing to form durable tiles.
This document discusses different approaches for nanofabrication including top-down and bottom-up. It describes various synthesis methods for nanoparticles including solid, liquid, and gas phase techniques. Specific solid phase methods like agitated ball milling and specific liquid phase techniques like sol-gel synthesis and solvothermal synthesis are explained. Gas phase methods like chemical vapor deposition, laser ablation, and references for further reading are also summarized.
Material technology Newly develpoed engineering materialsMihir Taylor
This document discusses several newly developed engineering materials including lead zirconate titanate (PZT), zirconium dioxide (ZrO2), amorphous silicon, and magneto rheological fluid. PZT is a piezoelectric ceramic used in sensors and actuators due to its ability to generate voltage or change shape with electric fields or temperature changes. ZrO2 is a ceramic material that can be stabilized in different crystal phases for uses like thermal barriers or insulators. Amorphous silicon lacks a crystalline structure but can be used in devices like thin-film transistors and solar cells when hydrogenated. Magneto rheological fluid increases viscosity when exposed to magnetic fields, allowing controllable damp
Ceramics can be crystalline, amorphous, or bonded materials beyond traditional clay pottery. Ceramics have a wide range of applications including glass, abrasives, construction materials, electrical insulators, cements, refractory furnace linings, and refractory metal coatings. Ceramics are strong in compression but weak in tension, shear, and brittle. They maintain strength at high temperatures and include microcracks that can lead to weaknesses. Most ceramics are very hard, making them suitable for cutting tools and abrasives, and they can withstand high heat conditions due to their refractoriness.
This document discusses plastics, including what they are, their history, common types and uses. It also discusses how plastics can be prevented from polluting the environment through reduction, control and proper disposal methods. Reduction involves redesigning plastic products to use less material and reusing items more. Control involves ensuring plastics from industrial and household waste are properly contained and disposed of in landfills or recycling. Legislation also prohibits dumping plastics at sea. With improved management practices, the amount of plastic marine debris can be reduced.
Plastics are synthetic organic materials that can be molded under heat and pressure into shapes that are retained when the heat and pressure are removed. There are two main types of plastics: thermoplastics, which can be softened and reshaped by reheating, and thermosetting plastics, which undergo a chemical change when heated and hardened that prevents them from being re-softened. Plastic forming involves shaping plastics using molds or frames, with common processes including injection molding, extrusion molding, blow molding, vacuum forming, compression molding, and rotational molding.
Ceramics can be divided into three main categories based on their processing: traditional ceramics made from clay and other silicates, new ceramics made from synthetic materials like oxides and carbides, and glasses which have a non-crystalline structure. The processing of ceramics typically involves crushing and grinding raw materials, shaping, drying, and high-temperature firing. Shaping methods include casting, plastic forming techniques like extrusion and injection molding, and pressing operations. Drying removes moisture without causing cracking, while firing sinters the particles to develop strength and hardness through bonding. The properties of ceramics make them useful for a wide range of applications.
This document provides an overview of various casting processes including expendable mold casting (sand, plastic, shell, plaster, and investment casting), plaster casting, sand casting, shell molding, investment casting, non-expendable mold casting (permanent, die, centrifugal, and continuous casting), and discusses factors such as cooling rate, shrinkage, and patternmaker's shrink. Key points covered include definitions of casting, molding, and solidification processes; materials and applications of different casting techniques; and how cooling rate and shrinkage are addressed in casting design.
This document discusses the past, present, and future of plastics. It outlines the history of plastics from the first plastic invented in 1862 to modern polymers and applications. Currently, plastics are widely used in products like cars, medical devices, electronics, and more. The future of plastics may include 3D printing of body parts, bacteria-resistant varieties, and use in OLED displays. Plastics have become an important part of modern life due to their versatility, durability and low cost.
This document provides an overview of several modern engineering materials, including aerogel, carbon nanotubes, biomaterials, metallic glasses, programmable matter, and metamaterials. It discusses the properties and applications of each material. For example, it states that aerogel is 98.2% air and an excellent thermal insulator. Carbon nanotubes are stronger and stiffer than other materials. Biomaterials are engineered to interact with biological systems for medical purposes. Metallic glasses have high strength without grain boundaries. Programmable matter and metamaterials can change their physical properties in response to external stimuli.
Nanomaterials are engineered materials that are 100 nm or less in at least one dimension. They can be classified as zero-dimensional, one-dimensional, two-dimensional, or three-dimensional structures. There are two main methods for synthesizing nanomaterials - the top-down approach breaks down bulk materials into nano-sized pieces, while the bottom-up approach assembles atoms and molecules into nanostructures. Common bottom-up synthesis techniques include sol-gel processing, where a sol transitions into a gel network, and gas-phase methods like chemical vapor deposition, which use gas-phase precursors and reactions to form nanoparticles. Nanomaterials have a variety of applications in electronics, energy, medicine and other fields due to their unique
Biological, physical and chemical properties of dental materials.Bhavika Nagpal
This document discusses the biological properties of dental materials. It begins by defining biomaterials and biocompatibility. Biocompatibility involves biosafety and biofunctionality. The ideal biological properties of dental materials are outlined. Materials are classified based on where they contact tissues in the oral cavity. Common adverse reactions from dental materials like inflammation, allergy and toxicity are discussed. The document examines various dental materials and their effects on pulp and hard tissues. Occupational hazards for dental personnel are also reviewed.
This document summarizes Wolfram Schott's research into heat treating bamboo for rod making. It provides background on the history of bamboo heat treating in rod making literature. It also discusses the chemical composition of bamboo and how heat can affect its properties. The document aims to share Schott's personal observations and heat treating procedures based on his testing over 20 years, with the goal of clarifying best practices and debunking myths around this process.
Glass is an amorphous solid made by cooling molten ingredients without crystallization. It is typically made from mixtures of silicates, borates, and aluminates. Glass can be transparent, translucent, or opaque depending on its composition. Common types of glass include soda-lime glass for windows, borosilicate glass for laboratory equipment, and lead glass for radiation shielding. Glass has many uses including windows, tableware, light bulbs, and optical lenses due to its optical properties and resistance to corrosion.
Polymeric materials are formed by joining many small monomer units together through chemical reactions. They have properties like low density, good corrosion resistance, and mouldability. There are three main types of polymerization reactions: addition, copolymerization, and condensation. Polymeric materials can be formed into fibers, coatings, foams, and used as adhesives through various production techniques. Common polymers include polyethene, polyvinyl chloride, polystyrene, nylon 6,6, and teflon.
This document discusses various techniques for synthesizing nanoparticles, including sol-gel synthesis, colloidal precipitation, co-precipitation, combustion technique, hydrothermal technique, high energy ball milling, and sonochemistry. It provides details on specific methods like the Frens method for synthesizing gold nanoparticles, co-precipitation reaction for iron oxide nanoparticles using FeCl3 and benzene tetracarboxylic acid, combustion synthesis using lithium nitrate and bismuth nitrate with urea and glycerol, and hydrothermal treatment for titanium dioxide nanoparticles. The advantages of these techniques in producing nanoparticles at low temperatures and with good control of properties are highlighted.
El documento resume las cuatro principales regiones naturales del Perú: la región del Mar Peruano, la región de la Costa, la región de la Sierra y la región de la Selva. La región del Mar Peruano se extiende a lo largo de la costa peruana y es rica en vida marina. La región de la Costa está bordeada por el océano y contiene desiertos, valles y ciudades atravesados por ríos. La región de la Sierra comprende la cordillera de los Andes con valles, nevados y punas de cl
The document provides information on the ceramic industry in Egypt. Some key points:
- Ceramics make up 7% of Egyptian industrial production and include items made of clay and silicates.
- Raw materials for ceramics include sand, feldspar, clay, and other minerals. Testing of raw materials includes chemical analysis by XRF and thermal analysis by dilatometry and TG-DTA.
- The production process for ceramic tiles includes batching, grinding, spraying, pressing, drying, firing, and sorting. Finished tiles undergo tests for properties like dimensions, strength, and abrasion resistance.
- Emissions from the ceramic industry can impact the environment through air pollution, effluents,
Microscopic inspection of pure metals and solid solutions. Saif al-din ali
1. Name of Experiment:
Microscopic inspection of pure metals and solid solutions.
2. The Objective of the Experiment:
To study the different shapes and sizes of grains and the flaws found in casts
The document provides information about plastics used as building materials. It discusses the introduction to plastics, their chemical composition and properties. It describes various plastic forming processes like extrusion, injection moulding, blow moulding and compression moulding. It also talks about the classification of plastics into thermoplastics, thermosets and elastomers. Thermoplastics can be reshaped upon heating while thermosets and elastomers cannot. The document provides details on the typical manufacturing process of plastics from raw materials to the final products.
Causes of deterioration of concrete structuresKarthi Kavya
The document discusses types of deterioration that can occur in concrete structures. It identifies three main types: distress in concrete, permeability of concrete, and aggressive deterioration agents. Distress can be physical, chemical, or mechanical due to issues like high water-cement ratio, inadequate curing, poor aggregates, overloading, or design deficiencies. Permeability is increased by porosity, microcracks, and dampness/seepage, allowing chemicals to enter. Major agents are chlorides, sulfates, and alkali-silica reaction, which can cause corrosion, cracking, or expansion through carbonation, sulfate attack, or silica gel formation.
Ceramic materials have been produced by humans for at least 24,000 years and are inorganic, nonmetallic solids formed through heating. Ceramics have a variety of properties including hardness, attractiveness, chemical inertness, and heat insulation. They are used widely in construction materials, decorative items, kitchenware, medical devices, and more. The production of ceramic tiles involves batching raw materials like clay and feldspar, grinding them, spray drying, pressing, drying, and high-temperature firing to form durable tiles.
This document discusses different approaches for nanofabrication including top-down and bottom-up. It describes various synthesis methods for nanoparticles including solid, liquid, and gas phase techniques. Specific solid phase methods like agitated ball milling and specific liquid phase techniques like sol-gel synthesis and solvothermal synthesis are explained. Gas phase methods like chemical vapor deposition, laser ablation, and references for further reading are also summarized.
Material technology Newly develpoed engineering materialsMihir Taylor
This document discusses several newly developed engineering materials including lead zirconate titanate (PZT), zirconium dioxide (ZrO2), amorphous silicon, and magneto rheological fluid. PZT is a piezoelectric ceramic used in sensors and actuators due to its ability to generate voltage or change shape with electric fields or temperature changes. ZrO2 is a ceramic material that can be stabilized in different crystal phases for uses like thermal barriers or insulators. Amorphous silicon lacks a crystalline structure but can be used in devices like thin-film transistors and solar cells when hydrogenated. Magneto rheological fluid increases viscosity when exposed to magnetic fields, allowing controllable damp
Ceramics can be crystalline, amorphous, or bonded materials beyond traditional clay pottery. Ceramics have a wide range of applications including glass, abrasives, construction materials, electrical insulators, cements, refractory furnace linings, and refractory metal coatings. Ceramics are strong in compression but weak in tension, shear, and brittle. They maintain strength at high temperatures and include microcracks that can lead to weaknesses. Most ceramics are very hard, making them suitable for cutting tools and abrasives, and they can withstand high heat conditions due to their refractoriness.
This document discusses plastics, including what they are, their history, common types and uses. It also discusses how plastics can be prevented from polluting the environment through reduction, control and proper disposal methods. Reduction involves redesigning plastic products to use less material and reusing items more. Control involves ensuring plastics from industrial and household waste are properly contained and disposed of in landfills or recycling. Legislation also prohibits dumping plastics at sea. With improved management practices, the amount of plastic marine debris can be reduced.
Plastics are synthetic organic materials that can be molded under heat and pressure into shapes that are retained when the heat and pressure are removed. There are two main types of plastics: thermoplastics, which can be softened and reshaped by reheating, and thermosetting plastics, which undergo a chemical change when heated and hardened that prevents them from being re-softened. Plastic forming involves shaping plastics using molds or frames, with common processes including injection molding, extrusion molding, blow molding, vacuum forming, compression molding, and rotational molding.
Ceramics can be divided into three main categories based on their processing: traditional ceramics made from clay and other silicates, new ceramics made from synthetic materials like oxides and carbides, and glasses which have a non-crystalline structure. The processing of ceramics typically involves crushing and grinding raw materials, shaping, drying, and high-temperature firing. Shaping methods include casting, plastic forming techniques like extrusion and injection molding, and pressing operations. Drying removes moisture without causing cracking, while firing sinters the particles to develop strength and hardness through bonding. The properties of ceramics make them useful for a wide range of applications.
This document provides an overview of various casting processes including expendable mold casting (sand, plastic, shell, plaster, and investment casting), plaster casting, sand casting, shell molding, investment casting, non-expendable mold casting (permanent, die, centrifugal, and continuous casting), and discusses factors such as cooling rate, shrinkage, and patternmaker's shrink. Key points covered include definitions of casting, molding, and solidification processes; materials and applications of different casting techniques; and how cooling rate and shrinkage are addressed in casting design.
This document discusses the past, present, and future of plastics. It outlines the history of plastics from the first plastic invented in 1862 to modern polymers and applications. Currently, plastics are widely used in products like cars, medical devices, electronics, and more. The future of plastics may include 3D printing of body parts, bacteria-resistant varieties, and use in OLED displays. Plastics have become an important part of modern life due to their versatility, durability and low cost.
This document provides an overview of several modern engineering materials, including aerogel, carbon nanotubes, biomaterials, metallic glasses, programmable matter, and metamaterials. It discusses the properties and applications of each material. For example, it states that aerogel is 98.2% air and an excellent thermal insulator. Carbon nanotubes are stronger and stiffer than other materials. Biomaterials are engineered to interact with biological systems for medical purposes. Metallic glasses have high strength without grain boundaries. Programmable matter and metamaterials can change their physical properties in response to external stimuli.
Nanomaterials are engineered materials that are 100 nm or less in at least one dimension. They can be classified as zero-dimensional, one-dimensional, two-dimensional, or three-dimensional structures. There are two main methods for synthesizing nanomaterials - the top-down approach breaks down bulk materials into nano-sized pieces, while the bottom-up approach assembles atoms and molecules into nanostructures. Common bottom-up synthesis techniques include sol-gel processing, where a sol transitions into a gel network, and gas-phase methods like chemical vapor deposition, which use gas-phase precursors and reactions to form nanoparticles. Nanomaterials have a variety of applications in electronics, energy, medicine and other fields due to their unique
Biological, physical and chemical properties of dental materials.Bhavika Nagpal
This document discusses the biological properties of dental materials. It begins by defining biomaterials and biocompatibility. Biocompatibility involves biosafety and biofunctionality. The ideal biological properties of dental materials are outlined. Materials are classified based on where they contact tissues in the oral cavity. Common adverse reactions from dental materials like inflammation, allergy and toxicity are discussed. The document examines various dental materials and their effects on pulp and hard tissues. Occupational hazards for dental personnel are also reviewed.
This document summarizes Wolfram Schott's research into heat treating bamboo for rod making. It provides background on the history of bamboo heat treating in rod making literature. It also discusses the chemical composition of bamboo and how heat can affect its properties. The document aims to share Schott's personal observations and heat treating procedures based on his testing over 20 years, with the goal of clarifying best practices and debunking myths around this process.
Glass is an amorphous solid made by cooling molten ingredients without crystallization. It is typically made from mixtures of silicates, borates, and aluminates. Glass can be transparent, translucent, or opaque depending on its composition. Common types of glass include soda-lime glass for windows, borosilicate glass for laboratory equipment, and lead glass for radiation shielding. Glass has many uses including windows, tableware, light bulbs, and optical lenses due to its optical properties and resistance to corrosion.
Polymeric materials are formed by joining many small monomer units together through chemical reactions. They have properties like low density, good corrosion resistance, and mouldability. There are three main types of polymerization reactions: addition, copolymerization, and condensation. Polymeric materials can be formed into fibers, coatings, foams, and used as adhesives through various production techniques. Common polymers include polyethene, polyvinyl chloride, polystyrene, nylon 6,6, and teflon.
This document discusses various techniques for synthesizing nanoparticles, including sol-gel synthesis, colloidal precipitation, co-precipitation, combustion technique, hydrothermal technique, high energy ball milling, and sonochemistry. It provides details on specific methods like the Frens method for synthesizing gold nanoparticles, co-precipitation reaction for iron oxide nanoparticles using FeCl3 and benzene tetracarboxylic acid, combustion synthesis using lithium nitrate and bismuth nitrate with urea and glycerol, and hydrothermal treatment for titanium dioxide nanoparticles. The advantages of these techniques in producing nanoparticles at low temperatures and with good control of properties are highlighted.
El documento resume las cuatro principales regiones naturales del Perú: la región del Mar Peruano, la región de la Costa, la región de la Sierra y la región de la Selva. La región del Mar Peruano se extiende a lo largo de la costa peruana y es rica en vida marina. La región de la Costa está bordeada por el océano y contiene desiertos, valles y ciudades atravesados por ríos. La región de la Sierra comprende la cordillera de los Andes con valles, nevados y punas de cl
Ubicado al norte de Loja, el Parque Recreacional Jipiro constituye una de las principales atracciones de la ciudad. Cuenta con más de 10 hectáreas, conocido también como el parque de la Universalidad Cultural, aquí se encuentran las réplicas arquitectónicas representativas de las facetas etno - culturales de la humanidad, por lo que se le determinado como un pequeño lugar en el que la diversidad cultural se mezcla con la biodiversidad de la región.
Este documento describe las instalaciones eléctricas propuestas para una vivienda unifamiliar de lujo de 230 metros cuadrados en Maturín, Venezuela. Incluye cálculos de carga eléctrica, especificaciones de circuitos ramales, tableros eléctricos y acometida. Se propone un tablero principal de 120/208V con 21 circuitos para satisfacer la demanda estimada de 31,475W en fases y 20,418W en neutro.
Sasikala provides a summary of her professional experience as a test engineer, including 5 years working for Infosys on various projects testing software for clients like RBS, Microsoft, and Citi. Her responsibilities included requirements analysis, designing and executing test cases, preparing test data, and reporting bugs. She has experience with tools like Quality Center, TOAD, and manual testing processes like data warehouse testing.
This document provides a bio-data and work experience summary of M.Sudhindra Kumar. It details his contact information, date of birth, languages, 39 years of work experience, and B.E. in Electrical Engineering. It describes his experience as a consultant to BESCOM on reducing transformer failures and developing cost models. It also outlines his current role since 2008 working with Aparna Engineers on renewable energy projects and obtaining carbon credits, which involves writing project documents, obtaining approvals, and coordinating with validators.
1) The author experienced brain damage as an infant due to a high fever and childhood vaccines, leaving them with developmental disabilities. Doctors said they would never walk or talk, but their family provided intensive therapy and support.
2) The author struggled in mainstream school due to their disabilities and lacked social inclusion. They felt out of place in special education classes with more severe disabilities.
3) After leaving high school's transition program at age 19, the author enrolled in community college and has thrived, achieving a 3.5 GPA. The support from faculty and programs has helped empower them to challenge themselves academically and pursue their goals.
The document provides an overview of different building materials, their properties, and classifications. It discusses natural materials like stone, wood, and clay as well as synthetic materials like steel, concrete, glass, and plastics. The properties of building materials that are described include density, porosity, strength, durability, and resistance to factors like fire, moisture, and frost.
expanded polystyrene technology in constructionvutkuri Keerthi
This document provides a technical seminar report on the use of expanded polystyrene technology in construction. It begins with an abstract that discusses how construction techniques have improved over time to use lighter materials and faster construction methods. One such technique is the use of expanded polystyrene (EPS) in construction, which provides benefits like less weight, cost effectiveness, faster construction, insulation, and more sustainable use of resources. The document then provides a table of contents and list of figures before diving into chapters that discuss EPS properties, applications, installation methodology, case studies, and conclusions.
This document provides information on block work systems (IBS) used in construction, including:
1. It describes the manufacturing process of block work systems which involves mixing, molding, curing, and cubing of concrete blocks.
2. The advantages of block work systems are that they are durable, can be constructed entirely on-site, have professionals that are easy to find locally, and have a high thermal mass for insulation.
3. The disadvantages include limited insulation capability compared to other materials, slower construction speeds, risk of settlement cracks, inability to construct during severe weather, and potential for dampness if cavities are not sealed properly.
4. A case study of a secondary school in
This document provides information on block work systems (IBS) used in construction, including:
1. It describes the manufacturing process of block work systems which involves mixing, molding, curing, and cubing of concrete blocks.
2. The advantages of block work systems are that they are durable, can be constructed entirely on-site, have professionals that are easy to find locally, and have good thermal insulation.
3. The disadvantages include limited insulation thickness, slower construction compared to other materials, risk of settlement cracks, inability to work in severe weather, and potential for dampness infiltration.
4. A case study of a secondary school construction project in Malaysia is presented that utilized loadbearing block
This document summarizes research on the thermal performance of light steel-framed walls. Thermal bridges were reduced through double framing, exterior insulation, and perforated steel profiles. Laboratory tests and simulations showed that perforated profiles can reduce heat conduction by 70-80% compared to solid steel. Field measurements of steel houses in Finland found no condensation issues. Thermal transmittance values from simulations matched well with standardized laboratory measurements.
Application of nano-technology in constructionAmeer Muhammed
This document discusses the application of nanotechnology in construction. It begins by defining nanotechnology as the study and manipulation of matter at the nanoscale. It then outlines several nanomaterials that are being used in construction, such as carbon nanotubes, titanium dioxide, zinc oxide, and tungsten oxide. These nanomaterials can improve properties like strength, conductivity, and self-cleaning abilities when added to materials like concrete, steel, wood, glass, and coatings. The document also discusses potential barriers to nanotechnology like health effects, environmental impacts, and cost, but concludes that with further research, nanotechnology could allow for more durable and economical infrastructure.
The document discusses various applications of nanotechnology in engineering and construction materials, including using nanoparticles to improve the strength and properties of concrete, steel, wood, and glass. Nanoparticles can enhance qualities like compressive strength, corrosion resistance, self-healing abilities, and sustainability. The document evaluates how nanotechnology may lead to improved construction systems and materials in the future.
Terra Mar Architectural - These 8 Innovative Materials Will Revolutionize the...terramararchitectural
These materials include translucent wood, cement that generates light, floating piers, Martian concrete, lightweight seismic reinforcement, self-cooling walls, biodegradable furniture, pollution-absorbing bricks, and self-healing concrete. Scientists and engineers have developed these innovative materials to revolutionize the construction industry by enabling new architectural designs, improving sustainability, and reducing maintenance needs.
Nanotechnology offers possibilities to improve materials used in civil engineering. At the nanoscale, materials demonstrate new properties. Concrete can be made stronger and more durable using nano-silica and carbon nanotubes. Steel can incorporate nanoparticles to increase strength and resistance to fatigue and corrosion. Titanium dioxide and carbon nanotubes make glass self-cleaning. Nanoparticles in coatings provide insulation and hydrophobicity. While costs are currently high, nanotechnology research aims to advance sustainability in the construction industry by developing higher performance, longer lasting materials.
Nanotechnology can improve many building materials. Concrete can be made stronger and more durable using nano-silica particles that improve packing and reduce water penetration. Glass can be made self-cleaning using titanium dioxide nanoparticles. Carbon nanotubes give steel 5 times the strength but only 1/6 the density when added to concrete. Nanoparticles in paints can make them more insulating and corrosion-resistant. While nanotechnology offers improvements, the main limitations are currently the high costs and potential environmental effects.
Fire Resistant Concrete using Sustainable Fibersijtsrd
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Impact of moisture on long term performance of insulating products based on stone wool
1. Impact of moisture on long term
performance of insulating products
based on stone wool
Tomáš Vrána
Licentiate Thesis
Stockholm
September 2007
KTH – The Royal Institute of Technology
School of Architecture and the Built Environment
Div. Of Building Technology
3. “All you have to decide is what to do with the time that is given to you”
Tolkien John Ronald Reuel (1892-1973)
“One that would have the fruit must climb the tree”
Fuller Thomas (1608-1661)
4.
5. Preface
This licentiate thesis is the result of the author’s research during the past
three years at the Department of Physics at the Czech Technical
University in Prague, Czech Republic and at the Division of Building
Technology at the Royal Institute of technology in Stockholm, Sweden.
After finishing my undergraduate studies in Prague I got an opportunity
to continue as a doctoral student and participate in a research taking aim
at flat-roof constructions using stone-wool insulant, which were
damaged by extremely high level of inbuilt moisture.
To spend some time abroad is an educational duty at CTU in Prague.
Through the professor Gudni Jóhannesson I got a chance to continue
with my studies and research in Stockholm.
The first paper describes a real case from practice, where flat roofs of
an administrative building in Prague were exposed to rain precipitation,
snow and other climate effects for several months in winter 2002/2003
without having completed a layer of water membrane on the top.
The second project was elaborated for Strängbetong. A point of this
paper is to estimate a time period, in which wet spots around windows
and inbuilt moisture in the facade will dry up.
The third paper is a first step in the research project intent on finding
damages of mineral insulation based on stone wool caused by frosting
condensate and inbuilt moisture in time. It aims at designing a testing
set-up, that provides a very well contolled moisture load, to detect real
material properties, which might be slightly distinct from tabulated
values.
The fourth paper reports on a laboratory experiment of frost formation
and moisture condensation in stone-wool insulants with varying density.
An understanding about appearance of frost formation is good for
knowledge of processes when high thicknesses of thermal insulation are
used in cold climates and moisture might become trapped in the
building envelope.
I am indebted to Docent Folke Björk and Professor Gudni
Jóhannesson at the Royal Institute of Technology in Stockholm for
their fruitful discussions and inspiring comments. They helped me to
bring my research project into life.
i
6. Finally, I would like to thank to my girlfriend, my family and my friends,
who always supported me in my studies abroad and were ready to help
anytime I needed.
Stockholm, September 2007
Tomáš Vrána
ii
7. Abstract
Demands for energy have been increasing in the whole world.
According to higher consumption, the price of energy rises yearly too.
This evokes usage of insulating products in a wider range. By adding
insulation, we lower the amount of energy needed to heat our homes,
resulting in fewer associated greenhouse gas emissions and a lower
monthly heating bill. Savings depend on insulation thicknesses and on
conditions, in which the insulant is kept. Mineral insulation based on
stone wool is also a member of building insulants that defends buildings
and constructions against temperature changes of the ambient.
However, even when we use modern technologies and building
techniques to reduce high energy losses, we can never provide
unimpeachable protection of stone wool from damage. During a
construction process on a building site or at fast climate changes, it
often happens that stone wool is exposed to rain precipitaions or other
climate effets. This brings water to the insulating structure. Besides the
loss of insulating qualities, the stone wool is left permanently wet. Even
the fibres of stone wool are inorganic, they still can be attacked by
degradation processes due to organic agents fixing fibres together.
Analysis of damaged flat-roof constructions using stone wool and
verification of material properties is a starting point of this licentiate
thesis.
The attached paper section can be divided into two parts:
In-situ practice that notes troubles with insulating materials based on
stone wool with inbuilt moisture on a building site
Laboratory measurement that observe material properties of stone wool
under varying conditions
Keywords
Mineral insulation, Stone wool, Material properties, Moisture transport,
Heat transport, Test equipment, Moisture properties, Frost formation
iii
8. List of Papers
This Licentiate thesis is based on the following research and conference
papers:
I. Vrána T., 2005. Impact of moisture on long term performance of
insulating products. Proceedings of the Nordic Symposium on Building
Physics, Reykjavik, Vol. 1, pp.71-77
II. Vrána T., Jóhannesson G., 2006. Examination of wall
constructions - Inbuilt moisture in wall constructions of a newly
built apartment house. Internal report.
III. Vrána T., Björk F., 2007. A laboratory equipment for the study of
moisture processes in thermal insulation materials when placed in
a temperature field. Submitted to Construction and building materials
Journal.
IV. Vrána T., Björk F., 2007. Frost formation and condensation in
stone-wool insulants. Submitted to Construction and building materials
Journal.
iv
9. Table of Contents
Preface........................................................................................... i
Abstract ....................................................................................... iii
Keywords..................................................................................... iii
List of Papers................................................................................iv
Table of Contents..........................................................................v
Nomenclature............................................................................. vii
1. Introduction...............................................................................1
1.1. Background.............................................................................................1
1.2. Aim and Limitations..............................................................................2
1.3. Outline of the Thesis.............................................................................3
2. Need For Insulation ..................................................................4
2.1. Insulation Standards and Energetic Perspectives in Europe...........4
2.2. Types of Thermal Insulations..............................................................7
3. Mineral Wool .............................................................................8
3.1. Manufacturing Process..........................................................................8
3.2. Physical Properties of Mineral Wool ................................................12
4. Application of Mineral Wool in Practice.................................16
4.1. General Characteristics of Used Stone-Wool Specimens..............18
5. Moisture...................................................................................19
5.1. Moisture Transport in Porous Material............................................20
6. Methodology of Research........................................................22
6.1. In-situ Measurement Campaign.........................................................22
6.1.1. Case Study No.1........................................................................22
6.1.2. Case Study No.2........................................................................27
6.2. Laboratory Measurement....................................................................32
6.2.1. Designing the Test Set-Up......................................................32
6.2.2. Measurement above 0°C - Processing...................................36
6.2.3. Measurement below 0°C - Processing...................................41
v
10. 7. Results of the Test Set-Up and Discussion.............................43
7.1. Measurement above 0°C.....................................................................43
7.2. Measurement below 0°C.....................................................................45
7.3. Discussion.............................................................................................55
8. Conclusions and Future Research ..........................................57
8.1. Concluding Remarks...........................................................................57
8.2. Future Research ...................................................................................58
9. References ...............................................................................59
10. Bibliography...........................................................................60
vi
11. Nomenclature
Majority of symbols used in this thesis is listed below. Others are
defined as they first appear.
A Area [m2
]
cp Specific heat capacity [J/kgK]
D Coefficient of diffusion water vapour in air [m2
/s]
d Width of a layer [m]
Fp Point load [N]
G Moisture flow rate [kg/s]
g Steady state diffusive flux [kg/m2
s]
L Thermal conductance [W/m2
K]
Ma Accumulated moisture [kg/m2]
m Weight of wet sample [g]
m0 Weight of dried sample [g]
R Thermal resistance [m2
K/W]
RHi Interior relative humidity [%]
RHe Exterior relative humidity [%]
sd Equivalent diffusive thickness [m]
T Temperature [°C]
Te Exterior temperature [°C]
Ti Interior temperature [°C]
tt Construction-load by self-weight [°C]
u Moisture content mass by mass [%]
U
Transmission heat loss coefficient (or total heat
thermal transmittance or U-value)
[W/m2
K]
V Volume [m3
]
v
Humidity by volume (or water vapour content of
air)
[kg/m3
]
vs Humidity by volume at saturation [kg/m3
]
w Moisture content mass by volume [kg/m3
]
Wlp Long-term absorbability [kg/m2]
Wp Short-term absorbability [kg/m2]
Z Water vapour resistance [s/m]
vii
12. Greek
symbols
δv Vapour permeability [m2
/s]
θ Temperature [°C]
θim Design indoor temperature [°C]
μ
Moisture resistance factor (or water vapour
diffusion resistance factor)
[ - ]
λ Thermal conductivity [W/mK]
Φ Relative humidity [%]
ρd Dry density [kg/m3
]
σ Compressive stress [kPa]
σmt Tensile strength perpendicular to board [kPa]
φi Indoor relative humidity [%]
viii
13. 1. Introduction
1.1. Background
Basically, all building materials have a thermal insulating function.
Effective insulating materials, which are used together with common
building materials to increase thermal resistance of a construction, are
those with λ<0,175 W/m*K. As we know, thermal conductivity is rising
with higher humidity. Therefore, it is necessary to keep the insulating
layer as dry as possible. In natural conditions no building material can
be absolutely dry. There is always, so-called, practical (final) moisture,
which slightly debases insulating properties of a building material.
Moisture problems in building envelopes have been long considered as
a source of a reduced quality of living and as a reason of a permanent
damage of building structures. Next to the impact on dwellers, the
moisture problems reflect also on qualities of used building materials.
Due to their structure and a thickness of the insulating layer in building
constructions, especially fibrous insulating materials are in danger of the
moisture attack. Usually, inbuilt moisture is a product of the following
processes:
• bad design of a building construction
• unsuitable storing of building materials on a building site
• mistreatment with building materials, negligence, inappropriate
installation on a building site
• condensation process
• other factors ( unpredictable phenomena - e.g. sudden climate
changes during a construction process)
Some of these factors can be reduced by better planning and thorough
monitoring, nevertheless, some factors we can not completely avoid.
Water stored in mineral wool, as inbuilt moisture or as a product of
condensation, starts slow degradation and significantly decrease
insulating properties of a building material. More detailed studies of
water transport and travel of condensate throughout the insulation layer
can help to answer what kind of damage mineral wool undergoes and
how to avoid or diminish this adverse effect.
1
14. Studies of moisture transport and absorbent properties of mineral-wool
insulants are not as frequent as scientific papers concerning thermal
properties. Available data are restricted to basic properties of an
insulating material that can be found in catalogue lists of producers.
They usually inform about resistance factor μ, which is very similar for
all mineral-wool products. However, to acquire more information is not
easy and this field looks unexplored. Observing real cases of inbuilt
moisture in mineral wool on building sites seemed to be a good starting
place for planning and aiming the scope of this thesis. The presented
work was concentrated on analyzing practical problems of using mineral
wool, and consequently, on finding and designing a suitable laboratory
set-up, put it into use to gather experimental data and then analyze this
data, attempting to settle the unclarities, as it is described above.
1.2. Aim and Limitations
The primary aim of this study was to describe case studies and indicate
problems with inbuilt moisture that was stored in stone wool during its
installation on a building site. The secondary aim was to analyze
material properties of chosen stone-wool specimens loaded by moisture
flux and frost formation in varying outdoor conditions using a
laboratory set-up. This experimental set-up was designed with reference
to moisture transport properties of thermal insulation materials exposed
to both a temperature gradient and transport of moisture. Knowledge
of real material properties is desired for further studies of freezing
condensate and its trace throughout a stone-wool insulant.
Material specimens analyzed in this thesis are fibrous insulants based on
stone-wool structure with different densities and specific sphere of use.
This choice was primarily based on a varying content of binding agents
that are prone to moisture attack and also for widespread of a material
on the European (or world) market. The introduced materials are used
especially for flat-roof constructions, pitched roofs and walls. All these
constructions are at high risk of condensation, if not designed and
treated properly. All the experiments in the laboratory were performed
under similar climatic conditions; the same indoor temperature and
moisture gradient were applied, outdoor temperature was varying for
given tests.
2
15. 1.3. Outline of the Thesis
This licentiate thesis consists of a resumptive text and four appended
papers. The summarizing text divides into three main parts. The first
part contains a brief introduction (chapter 1) and a general overview of
insulating standards in EU, description of stone wool and relationship
between stone wool and moisture transport in porous materials
(chapters 2, 3, 4 and 5). The following part (chapters 6, 7) describes
problem cases of stone wool from practice and then designing a specific
laboratory set-up for testing material properties of stone-wool
specimens under defined outdoor and indoor conditions. Chapter 8
concludes the studies and proposes future research.
3
16. 2. Need For Insulation
Almost all energy, that mankind need for desirable living comfort,
comes from coal-, lignite coke-, gas- and furnace oil combustion.
However, consumption of fossil fuel is associated with extensive air
pollution, which is endangering human health and, in some regions,
destroying the green life at all. Trying to find a way from this vicious
circle simultaneously results in rising prices of fuels and energetic
industry as a whole. Of course, there is a possibility how to save a part
of the spent energy, as well as, prevent our nature from exhaust
emission and, last but not least, to save our health and finances. One of
the most effective economy measures is an improved thermal-technical
characteristic of building constructions. Energy delivered for heating
runs out to the surrounding environment with a lower air temperature
and must be continually supplied. This heat leakage can be effectively
slowed down by additional thermal insulation of all building envelopes.
In this way, we can markedly decrease our heat consumption and costs.
Computer calculations can clearly show how much we save with each
added centimeter of the insulating layer.
(Source: Rockwool CZ a.s.)
2.1. Insulation Standards and Energetic Perspectives in Europe
Claims on thermal-technical properties of building constructions vary all
over Europe. It is caused by different climate conditions of particular
regions and required heating period in winter time, which is
characterized by number of heating days per year. Countries in
Southern Europe, as well as, Western Europe have seaside weather,
while the rest of Europe has continental climate with higher fluctuation
of temperatures. The following pictures show differences in applied
4
17. insulation thickness for wall and roof constructions in most of
European countries.
a)
b)
FIGURE 1: Applied insulation thickness of a) wall and b) roof
constructions for new built residental buildings in EU.
(Source: http://www.eurima.org/facts_figures/insulation_thickness.html
August 2007)
5
18. a)
b)
FIGURE 2: New built residental buildings a) wall and b) roof
constructions applied thermal resistance in insulation 2004.
(Source: http://www.eurima.org/facts_figures/insulation_thickness.html
August 2007)
6
19. 2.2. Types of Thermal Insulations
There are different criteria how to sort thermal insulations [1]:
a) type of the ground substance
- inorganic,
- organic,
b) structure
- fibrous,
- porous (foam),
- granulated,
c) binder content
- containing binder,
- binder-free,
d) shape of product
- loose (back fill, wool)
- flat (board, mat, felt)
e) reaction to fire (Euroclass)
- non-combustible (class A1)
- limited combustibility (class A2, B)
- combustible (class C, D, E, F)
According to nature of the material thermal-insulating products can be
divided to [2]:
a) light silicate substances – light aggregate, light concrete,
b) foam inorganic substances – foam glass,
c) foam organic substances – foam plastics,
d) fibrous substances – glass wool and mineral (stone) wool
e) organic substances – cork, timber wool, paper.
Every single type of the listed thermal insulations has its advantages and
disadvantages – e.g. insulating qualities, durability, material and
dimensional stability, resistance to fire, impact on the environment and
human health. Choice of the right insulating material should always
take into account sort of the building construction and conditions in
which it will serve. Due to its wide-spread and complex features, our
research is focused just on mineral wool manufactured out of molten
rocks. The following chapter throws light upon closer description and
definition of manufacturing process and material properties of stone-
wool insulants.
7
20. 3. Mineral Wool
In the building industry we use the term ‘mineral wool’ for inorganic
fibres produced especially for thermal insulating purpose and keeping a
stable temperature and acoustic properties of building constructions
during the year. It is made from molten glass, stone or slag that is spun
into a fiber-like structure.
We recognize two basic types of fibrous mineral insulation, which are
widely used in building sector [3]:
Stone wool is made from volcanic rock, typically basalt or
dolomite; the remaining proportion is recycled material in the form of
briquettes.
Glass wool is made from sand or recycled glass, limestone and
soda ash; the same ingredients as for familiar glass objects such as
window panes or glass bottles. In addition, glass fiber has boron added
to improve its moisture tolerance.
To facilitate the understanding of mineral insulation based on stone
wool, a brief introduction to manufacturing process and description of
basic physical properties is enclosed. Further information can be
attained from several sources, among them Eurima (European
Insulation Manufacturers Association) or domestic producers.
3.1. Manufacturing process
“Mineral wool insulation prevents heat loss through roofs, walls, floors,
pipes and boilers, reduces noise pollution and protects homes and
industrial facilities from the risk of fire.” [3]
Mineral wool is utilized to:
• Save energy
• Be environmental friendly
• Absorb sound energy and eliminate noise
• Contribute to fire insulation
• Keep dimensional stability in time
• Be permeable for water vapour
8
21. While this licentiate thesis is focused just on mineral wool based on
stone wool, a closer description of manufacturing glass wool is not
included. First production of stone wool is dated to the beginning of
20th
century [3]. It is a highly sophisticated process inspired by nature.
Some volcanos eruct lava of a special constitution and viscosity, so wind
can scatter cooling magma to thin fibres and so a natural insulant can be
created. This process has been known for instance already to American
Indians, but its massive use was spread later. Thanks to modern
technique and technologies this procedure was upgraded.
The most typical molten rock is basalt or dolomite. The remaining
component is represented by recycled material in the form of briquettes
(see FIGURE 3.). Slag wool is made from blast furnace slag (waste).
FIGURE 3: Samples of source stones for production of stone wool:
Dolomite, Basalt and Briquette.
The manufacturing process can be divided into eight main stages, which
can slightly differ in details for different producers of stone wool [3].
9
22. • Inputs
The required amounts of raw material are measured and sent to a
melting furnace. For stone wool this is the volcanic rock or recycled
material plus energy. Manufacturers try to increase the recycled content
of mineral wool whilst maintaining the high quality of their product.
Structure of inputs (proportion between basalt and slag) affects final
acidity factor, which is usually 1,4 for fibres type A in common use, or
1,6 for fibres type B used in demanding moisture and thermal
conditions [4].
Acidity factor =
MgOCaO
OAlSiO
+
+ 322
(eqn 1)
• Furnace
The raw materials are melted in a furnace at very high temperatures,
typically 1300°C to 1500°C. To keep the production environmental
friendly, the smoke that is created during this process is filtered and flue
gases cleaned to minimise any impact to nature.
• Spinning
After the furnace droplets of the vitreous melt are spun into fibres,
droplets fall onto rapidly rotating flywheels or the mixture is drawn
through tiny holes in rapidly rotating spinners. This shapes it into fibres
of a diameter between 3 - 20 μm.
• Binding
Small quantities of binding agents, usually organic phenolformaldehyde
resins, are added to the fibres. The structure and density of the product
can be adapted to its precise final usage due to different quantity of the
binding agent. Final density can be varied between 15-250 kg/m3
.
• Curing
The binding agent is cured at around 200°C, so after installation on the
building site does not happen a larger compression of the insulating
board. Proper curing is also important to prevent later releasing of
formaldehyde into air.
• Cutting
The mineral wool is sawn to the required size and shape, for example
into rolls, batts, boards or it is customised for addition to other
10
23. products. Off-cuts and other mineral wool scraps are recycled back into
the production process.
• Packaging
Due to its impressive elasticity, mineral wool with lower content of the
binder (lower density) can be compressed to reduce its volume during
packaging, making it cheaper and easier to transport and handle.
• Gases and waste
Waste such as off-cuts are recycled into the production process
reducing inputs and energy requirements and make the production even
more effective. Gases from the production processes are cleaned in
filters and after-burners to minimise impact on the environment.
FIGURE 4: A production process of stone-wool insulant.
(Source: http://www.eurima.org/mineral_wool/production_process.html
August 2007)
11
24. 3.2. Physical Properties of Mineral Wool
Mineral wool combines several interesting attributes in one material.
They derive from the structure and wooly consistency. The European
Standard EN 13162 specifies the requirements for factory made mineral
wool products with or without facings, which are used for the thermal
insulation of buildings. The products are manufactured in the form of
rolls, batts boards and slabs [1].
• batt is a portion of mat in the form of a rectangular piece,
generally between 1m and 3m in length, an usually supplied flat;
typical Dry Density ρd varies between 100 – 120 kg/m3
and
Thermal Conductivity λ is circa 0,04 W/m*K
• roll is a product supplied in the form of a spirally wound
cylinder with ρd =70 kg/m3
and λ= 0,04 W/m*K
• boards, that are rigid or semi-rigid (insulation) product of
rectangular shape and cross section in which the thickness is
uniform and substantially smaller than other dimensions; typical
ρd varies between 35 – 220 kg/m3
and λ between 0,033 – 0,045
W/m*K. Stiffness of insulating boards can be improved by
´lamelling´ - boards are cut into stripes 100 mm wide (lamella)
turned 90° and fixed to a pad
Thermal properties
Thermal-insulating properties interest us at most. Reach for the lowest
values of thermal conductance is not possible without a significant
representation of gas phase in the structure of the insulant. However,
the gas phase must stay in calm and, therefore, can not create large
cavities in the insulating material that could influence heat gradient and
cause convective heat transfer. So, these small inter-fiber air gaps are the
source of thermal-insulating effect and the basalt fibres mainly provide
discerptibility of air into such small gaps, in which convective heat
transfer is not realized.
To keep thermal-insulating qualities, we must provide maintenance of
dry air in inter-fiber space. Wet mineral wool means degradation of
thermal properties and permanent destruction of the insulant. The
following table shows thermal conductivity of mineral wool in compare
with other building materials. Arising therefrom, mere 1cm of mineral
wool insulate with the same efficiency as 20 cm of full brick.
12
25. Comparison of thermal conductivities of selected building materials
λ [W/mK]
Material thicknesses with same thermal
resistances R as 1cm of mineral wool
Reinforced concrete 1,4 35 cm
Full brick 0,8 20 cm
Air brick 0,35 8,75 cm
Wood 0,15 3,75 cm
Mineral wool 0,04 1 cm
TABLE 1: Thermal conductivities of selected dry building materials
and necessary material thicknesses to reach same thermal resistances R
[5].
Acoustic properties
Mineral wool absorbs sound energy and reduces noise pollution. Special
acoustic measurements specify best acoustic properties for mineral wool
with density between 50-70 kg/m3
.
Water vapour permeability
Mineral wool assures high permeability for water vapour due to high
quantity of air gaps in the material. It is expressed by Moisture Resistance
Factor μ (also known as Water Vapour Diffusion Resistance Factor). This
value, together with material thickness, determines Equivalent Diffusive
Thickness sd – resistance of a material against diffusion of water vapour as
against diffusion through a layer of dry air 1m thick.
sd = μ*d [m] (eqn 2)
Material (100 mm) μ [-] sd [m]
Mineral wool 1-3 0,1-0,3
Masonry from full bricks 8,5-9 0,85-0,9
Polystyrene 40-100 4-10
Polyurethane 180-200 18-20
TABLE 2: Comparison of sd for selected building materials [5].
13
26. Hydrophobic properties
Mineral wool is moisture sensitive. Even it is impregnated by dispersed
silicon oil with addition of silane in the binding agent [4], still we must
keep an eye out for possible moisture problems and protect it from
water. There is varying content of binders in different types of mineral
wool. It ranges between 3%-8% of the product weight and depends on
demanded stiffness. Binders are added within few minutes in the
toughening chamber at 180-220°C and a polycondensation rate of the
resin have to reach at least 95%. Insulants for flat roofs usually have
higher density than wall boards and the risk for elution of bonding
agents is therefore higher. Figure No.5 zoom into the fiber-structure of
three different types of mineral wool with varying density (these
materials were used in the laboratory measument).
1) 2)
3)
1) magnification
80x
2) magnification
80x
3) magnification
40x
FIGURE 5: Microscopic structure of stone wool showing rising
content of the binding agent for specific products.
1) Insulation used pitched roofs, sandwich walls (ρd= 44 kg/m3
)
2) Flat-roof insulation (ρd= 112 kg/m3
)
3) Flat-roof insulation with double-layer characteristics (ρd= 145 kg/m3
)
14
27. Fire protection
In fighting fires time is essential, particularly in the first few minutes of
a fire. In a room fire the temperature reaches 700°C in the first fifteen
minutes and then can rise up to 1100°C. Fire-resistant materials such as
mineral wool provide those extra vital minutes to delay the fire
spreading and help save lives, money, property and pollution.
The EU adopted the new rules or "Euro classes" for the fire properties
of building materials in 1999. The system classifies products, according
to their fire resistance using the designations: A1, A2, B, C, D, E and F.
The most fireproof products (including mineral wool) have been placed
in classes A1 and A2, with the fire risk increasing down through the
table.
Some common building materials and likely European Classification
Example materials Euroclass Flashover Potential
Concrete, WoolGlass, Wool A1 NO
Plasterboard, Rock Wool-faced A2 NO
Painted gypsum board B NO
Plywood, Phenolic foam C YES
Expanded polystyrene type A D YES
Polyurethane foam E YES
Expanded polystyrene type N F YES
TABLE 3: Comparison of sd for selected building materials. The lower
sd , the better breathing of a material and the lower risk of condensation
[5].
Stability of size and lifetime
Mineral wool is based on rocks, which are resistant to climate impact.
They keep declared properties, shape and volume in the long term and
serve for more than 50 years, as we know from practice. The stability of
size is one of the basic advantages of fibrous insulants in compare with
other materials.
15
28. Thanks to listed number of impressive material properties, mineral wool
is used in a wide range of applications. All we always have to keep in
mind is to protect it from moisture.
4. Application of Mineral Wool in Practice
Insulation wools have been widely used for more than 60 years, in
thermal and acoustic insulation and fire protection. Their most
important applications are as insulation for buildings and industrial
constructions.
Applications for buildings [3]:
• loft insulation and pitched-roof constructions
• ventilated and contact facades
• wall constructions
• inner wall insulation
• flat roof insulation
• the insulation of heating systems
• hot and cold water services
Industrial applications include:
• large diameter pipe insulation
• insulation of tanks and vessels
• insulation for boilers and turbines
16
29. FIGURE 6: Sudden climate changes can cause unexpected troubles on
the building site. Pictures show finishing of a flat roof in Russia. Falling
snow will stay as inbuilt moisture in mineral wool and start its
degradation in time.
(Source: M. Matějček and his personal archive, November 2006)
17
30. 4.1. General Characteristics of Used Stone-Wool Specimens
Material specimens analyzed in this work are fibrous insulants based on
stone-wool. The material specimens are commercial products taken
from the portfolio of a major producer of thermal insulation materials.
Materials with different densities and specific sphere of use were
chosen. Specimens were cut to blocks with following dimensions -
300mm (length) x 300mm (width) x 100mm (thickness). Samples were
dried and weighed prior to measurements and their dry densities ρd were
calculated.
FIGURE 7: Cross section of a stone-wool roof board with integrated
double-layer characteristics [5].
The heaviest material sample – SPECIMEN A is primarily used
for flat-roof constructions. It is a stiff heavy board of stone wool with
integrated double-layer characteristics, which is bonded by organic resin
and fully hydrofobised throughout its capacity. The upper highly stiff
layer is up to 20 mm thick and provides sturdiness against mechanical
stress; ρd = 145 kg/m3
(material with the highest content of binders used
in the measurement).
The second fibrous material – SPECIMEN B is a rigid stone-wool
board, fully hydrofobised, especially used for flat roofs; ρd = 112 kg/m3
.
The lightest insulant in the laboratory measurement – SPECIMEN C is
a semisoft batt, fully hydrofobised, used for insulating pitched roofs,
ventilated facades and sandwich walls; ρd = 44 kg/m3
(material with the
lowest content of binders used in the measurement).
Detailed description of our in-situ measurement, as well as, designing
the laboratory test set-up can be found in subsequent chapters.
18
31. Basic technical parameters of used material samples are summarized in
the Table No.4 below.
Specimen Declared thermal
conductivity
λD [Wm-1
K-1
]
Moisture
resistance
factor
μ [-]
Dry density
ρd [kgm-3
]
A 0,040 2,95 145
B 0,039 2,15 112
C 0,035 3,55 44
TABLE 4: Basic technical parameters of the used material specimens
based on stone-wool structure.
5. Moisture
Water can exist in three stages: solid (ice), liquid (water) and gas
(vapour). In the environmental conditions that building constructions
are of service, all these three stages of moisture can occur. All these
three stages can be dangerous for building materials, if building
techniques are not adhered thoroughly and water has chance to enter
into building constructions [6].
Moisture in buildings has its origin in the following sources:
• Indoor and outdoor humidity
• Precipitation
• Ground dampness
• Construction damp
• Water leakage
Indoor humidity is generated by everyday activities like cooking,
bathing, washing and drying clothes, as well as, breathing [6].
Precipitation is represented by rain-, snow- and hail showers. They
differ. In combination with wind, rain showers can get horizontal
direction and hit vertical surface. We know it as driven rain.
Water can also be found in the ground in both vapour and liquid phase.
19
32. Construction damp often depends on storing conditions and actual
weather situation on a building site.
Water leakages can come from different sources and result in severe
moisture problems; they are dealt with in later chapters.
5.1. Moisture Transport in Porous Material [6]
Moisture transport in porous materials can be realized by:
• Diffusion
• Capillary suction
• Combined diffusion and capillary suction
Our test set-up calculates with diffusion transport in the sample of
stone wool.
Diffusion
Figure 8. shows a layer of a
porous material (e.g. stone
wool). The width of the
material is d (m). The
humidity by volume v is
kept at v1 at one side of the
layer and at v2 on the other
side. The steady-state
diffusive flux g becomes:
FIGURE 8: Diffusion of water vapour flux through a porous material.
d
vv
g v
21
*
−
= δ [kg/(m2
s)] (eqn 3)
Here δv is the vapour permeability of the material.
Diffusive flux multiplied by area creates moisture flow rate G:
G = A*g [kg/s] (eqn 4)
The rate of diffusion can be compared with the one obtained in
stagnant air. Introducing the ratio between D and δv gives:
20
33. v
D
δ
μ = [-] (eqn 5)
Empirically, D varies with temperature as [7]:
D=(22,2+0,14*θ)*10-6
[m2
/s] (eqn 6)
Here θ is a temperature in degrees centigrade.
Vapour resistance, Z, is declared for faced or non-homogenous
products [1]. For the water vapour resistance of a layer we have:
v
d
Z
δ
= [s/m] (eqn 7)
Moisture in air
Air consists of many gases, each contributing with its partial pressure to
the total air pressure. For water vapour we denote the partial pressure
by pv (Pa).The General Gas Law gives the relation between the vapour
content and the partial pressure:
pv=461,4*(T+273,15)*v [Pa] (eqn 8)
Here, the temperature, T, is given in degrees Celsius. The water content
of air, or the humidity by volume, is denoted by v. Due to liquid-gas
equlibrium for water, there is a maximum possible water vapour content
in the air. It will be denoted by vs. This humidity by volume at saturation
is a function of temperature [6]:
)15,273(*4,461
)
100
(*
+
+
=
T
T
ba
v
n
s [kg/m3
] (eqn 9)
0 ≤ T ≤ 30 a = 288,68 Pa b = 1,098 n = 8,02
-20 ≤ T ≤ 0 a = 4,689 Pa b = 1,486 n = 12,3
A relative humidity Φ is defined as:
Φ
sv
v
= [-] or [%] (eqn 10)
21
34. 6. Methodology of Research
There will be moisture in building constructions from time to time,
although we try to avoid it. What kind of damage will occur and what is
a time scale for critical expansion of damages? This is the starting point
of our research – to make data available and to find the right way of
solving problems with in-built moisture in the most economical way.
6.1. In-situ Measurement Campaign
Practically all defects of roof or wall constructions can occur as a result
of one dominant reason or concurrence of several factors.
Determination of the primary cause is often very difficult. Typical water
in-leak into a roof construction is a damage of the roofing membrane
and its untightness in joints and details. Wall constructions offen
struggle with thermal bridges. From the view of building physics,
defects have their origin in the period of design or pursuance of a
construction. In the lifetime of a building structure, these defects stem
from dramatic outdoor climate changes or inner conditions. The
following case studies demonstrate how one reconstructed and one
newly built construction were at risk from moisture attack.
6.1.1. Case Study No.1
Administrative building of Česká Pojišťovna Co., Prague, Czech Republic
Flat roofs of a reconstructed administrative building in Prague
were exposed to rain precipitation, snow and other climate effects for
several months from November 2002 to April 2003 without having
completed a layer of water proofing membrane on the top due to a
delay in the building process. During that winter, the top layer on the
exterior side was 5 cm thick cement screed. The complete (planned)
roof structure is described in Figure 9. The membrane Sarnafil S 327-15
and the underlining textile Arabeva were still not installed. This meant
that the roof had no water protection. Water passed through the layer
of cement screed and fall concrete and was stored in the layer of
mineral wool. Additional passage of water was stopped by the vapour
barrier. The aim of this case study was to investigate water content in
the roof construction and to calculate a time period needed to let the
roof construction dry up, as well as, to propose possible renovation
processes.
22
35. a) b)
FIGURE 9: a) Section view and description of a roof construction that
was planned for the administrative building in Prague
b) One of probes made to the roof construction; samples
of wet mineral wool, cement screed and fall concrete were taken
• Processing of the set problem
In April 2003 five openings were made to the wet flat-roof
construction and samples of the cement screed, fall concrete and
mineral wool were taken. Weighing bottles including wet samples were
weighed on a laboratory precision balance and then placed in a dryer.
Samples were dried for five days at 110°C. After the drying process, in-
built moisture in all samples were calculated from the Gravimetric Weight
Method, which is worldwide accepted as a standard method for setting
moisture ratios in specimens [8]. Its principle is based on comparing
weights of wet and dry samples, see eqn 11.
%100*
o
o
m
mm
u
−
= , where (eqn 11)
m – is weight of the wet sample; mo - weight of the dried sample
u – moisture content mass by mass
23
36. Thermal insulation u = 38,11 %
Fall concrete + cement screed u = 5,16 %
TABLE 5: Measured moisture content mass by mass “u” in the
material sample with the highest content of inbuilt moisture.
The numbers of the mass moisture ratio are extremely high, especially,
in the layer of the mineral wool. The requirement in the Czech
Technical Standards says that the level of built-in moisture ought to be
u ≤ 8%; u coefficients were recalculated (concerning thickness of the
relevant material layer) to dampness of the material in kg/m2
and then
used as a data input in a thermal-technical calculation.
The Computing software used for calculation of condensation was
Teplo 2004. It was developed by Dr. Ing. Zbyněk Svoboda at the
Faculty of Civil Engineering of the Czech Technical University in
Prague. This program calculates U values and balances of condensed
and evaporated water in multi-layer building constructions in time. The
calculation is based on the Czech localization of the EU standards EN
ISO 13788, EN ISO 6946. Software is applicable for wall-, roof-
constructions and cellars. The software also allows setting up
redistribution of inbuilt moisture in a construction.
Contractors decided to finish planned roof construction without solving
the problem of inbuilt moisture. The layers of cement screed and fall
concrete were dried a bit by the spring sun, but the layer of mineral
wool was soaked in water and there were visible drops of water on the
vapour membrane below mineral wool. Completing water membrane
on the top closes the roof structure and rapidly slows down the drying
process. The computer simulation follows contractors´ decision and
calculates with the finished roof construction. Accumulated moisture
was implemented in the calculation and its redistribution was set in the
input data.
Particular results of the simulation can be seen in Figure No.10 below.
The computer calculation confirmed that this solution means slowed
drying process and permanent presence of moisture in the roof
construction during its lifetime - accumulated moisture stays in the
construction for more than 100 years. Unfortunatelly, contractors did
not change their decision. Beside the loss of thermal-technical
properties, investors never get the roof construction they payed. On the
24
37. other hand, this imperfect roof construction would be worth to monitor
in time. A follow up of this roof after 10 years would be of high
interrest.
FIGURE 10: Change of accumulated moisture Ma [kg/m2
] in the layer
of mineral wool within 10 years of using the construction with finished
water membrane on the top.
25
38. The drying process of accumulated moisture within
100 years
0
2
4
6
8
10
12
0 10 20 30 40 50 60 70 75 80 90 100
Years
Accumulatedmoisture
Ma[kg/m2]
Fall concrete Mineral wool Cement screed
FIGURE 11: Simulation of the drying process in time in the layers of
mineral wool, cement screed and fall concrete.
From measurements and calculations can be deduced these conclusions:
A possible solution to save the roof can be removal of the cement
screed and the fall concrete and in desiccation of mineral wool in order
to reuse it in the future. This solution needs good natural drying
conditions and a temporary roof protection against rain precipitation.
Another solution could be to blow a stream of hot air into unfinished
wet roof construction to dry up accumulated moisture from the affected
layers. This would mean making several openings to the roof structure
and measure moisture content in outlet air.
To respect contractors´ decision about finishing the layer water
membrane, additional erection of an extract system would be necessary.
Taking into account the amount of accumulated moisture, the extract
system would have to consist of many ventilating chimneys, which
would mean high costs and complicated building details.
Finishing the roof construction and leaving the problem with inbuilt
moisture unsolved means risk for future damage and costs of the
discussed flat roof. Mineral wool is left permanent wet. That opens
question what happens with implemented organic binders and material
qualities of mineral wool as a whole.
26
39. 6.1.2. Case Study No.2
Apartment house BRF MAJGLÄNTAN, Solna, Sweden
The envelope of a new apartment house in Solna was finished in the
middle of September 2005. The building was heated by 20°C from the
second half of October 2005. In the following period two wet places
appeared inside on window lintels. Both these wet places were situated
in the northern facade of the building and were visible just inside. Joints
around window at one wet place were not finished yet. The second wet
place was covered from outside by an advertising poster.
A point of this review was to estimate a time period, in which these wet
spots dry up and will not cause any additional inconvenience.
Walls are constructed from prefabricated sandwich elements. They
consist of two reinforced-concrete panels (thicknesses 150mm and
75mm) and a board of mineral wool (thickness 150mm) between them.
Density of reinforced concrete used for the calculation equals to 2300
Kg/m3
and thermal conductivity equals to 1,43 W/m*K. Density of
mineral wool panel Roxull Hardock is 65 Kg/m3
and thermal
conductivity equals to 0,035 W/m*K.
FIGURE 12: A wall sandwich element compact of concrete and
mineral wool panel. (Source: Strängbetong)
27
40. • Processing of the set problem
Material samples were taken from several places in the facade. Openings
were made both in parts known to be wet, and in parts that should be
dry. This could give us a better view to moisture problem. Precise
position of openings is evident from Figure 13.
FIGURE 13: Position of openings on
the facade in side-view and in section-
view.
The samples were weighed on a precision laboratory balance.
Consequently, samples were dried in a dryer for five days at 110°C.
Finally, the specimens were weighed again. We used Gravimetric Weight
Method (see Case Study No.1.) to calculate moisture content in each
sample. Due to the drilling process, concrete specimens were dried a bit
and some moisture evaporated. That is why all values of moisture
weight ratios were rounded up to be more relevant.
28
41. Calculation was carried out using software Teplo 2004, the same as in
the first case study.
u1,1 concrete = 5,10 % u5,1 concrete = 4,65 %
u1,2 mineral wool = 5,49 % u5,2 mineral wool = 4,28 %
u2,1 concrete = 5,53 % u6,1 concrete = 5,06 %
u2,2 mineral wool = 6,05 % u6,2 mineral wool = 4,53 %
u3,1 concrete = 5,51 % u7,1concrete = 5,18 %
u3,2 mineral wool = 5,59 % u7,2 mineral wool = 4,74 %
u4,1 concrete exterior = 4,86 % u8,1concrete = 5,20 %
u4,2 mineral wool = 4,78 % u8,2 mineral wool = 2,71 %
´Wet´placeonthefacade
u4,3 concrete interior = 4,73 %
´Dry´placeonthefacade
TABLE 6: Moisture weight ratio of each material sample [8]. The table
also compares ´wet place´ with chosen ´dry place´ on the facade, where
we expected lower u coefficients. Index numbers placed behind
moisture content coefficients, u, correspond to numbers of openings
and sample materials.
After setting all climate data and material properties the following facts
were deduced: three zones of inbuilt moisture were detected in the wall
construction - a) condensing zone in the inner concrete panel
- b) condensing zone in the layer of mineral wool
- c) condensing zone in the outdoor concrete panel
It is easier for wall constructions with inbuilt moisture to dry up than
for roof constructions for instance. Walls are not closed with a diffusion
tight membrane, evaporation of water is then easier on the exterior side.
And more, the interior surface is heated. The calculation show how
moisture thus evaporate during spring and summer months. In the
following year cycles, there will be repetitional condensation in the wall
constructions during late autumn, winter and early spring period. That is
typical. Anyway, the level of condensation will be lower than the in the
first year, when inbuilt moisture was implied. Wall construction will dry
up repeatedly during spring and summer period (see FIGURE 14).
29
42. A)
B)
FIGURE 14: A) Accumulated amount of condensed moisture (up) and
B) actual rate of condensation and evaporation of water vapour in the
condensing zone month by month in the second year cycle.
30
43. To sum up the most important facts about this report:
As the results of the simulator calculation show, the wall
construction with inbuilt moisture should dry up in the following year
cycle. There was not found an extreme amount of inbuilt moisture in
the specimens, which were taken from the openings made on the ´wet´
place on the facade. Their moisture weight ratios are comparable with
those, taken from the ´dry´ place on the facade. Wettest samples in the
applied openings were found in the opening situated 100 mm above the
horizontal joint between facade sandwich panels.
It seems there are some local problems with moisture on the facade and
not a general one. This could be caused by several reasons. For instance
- joints between sandwich panels were not closed properly. Also joints
around some windows were not finished at the time of taking
specimens on the building site; they were unprotected for days. This
also allowed driven rain to get deeper to the wall construction. Another
reason for the higher level of inbuilt moisture in some sandwich panels
could be their inadequate storing. And more, even though the building
was heated from October, condensation could occur.
31
44. 6.2. Laboratory Measurement
The two practical cases from the previous pages described problems of
mineral wool used in a flat-roof construction and in a wall construction.
All requirements and standards lose their sense, when an insulating
material is attacked by moisture in time. To provide detailed study of a
building material and its use, it is important to know real material
qualities, which might be slightly distinct from tabulated values.
Other issues of importance is how these materials respond to
circumstances where condensation or frost formation may occur, and
how this kind of processes might influence the service life of the
materials. Therefore, we focused on designing a laboratory set-up that
could be used for registering moisture transport properties of thermal
insulation materials exposed to temperature gradient and transport of
moisture.
6.2.1. Designing the Test Set-Up
To investigate behaviour of water or condensate in mineral insulant, it is
necessary to simulate a building construction with an installed layer of
thermal insulation. In this case a layer of stone wool. The test set-up is
an insulated box, whose ´roof´ part is substituted by a specimen of
thermal insulation. This box is ment to simulate a room with apparent
inner source of moisture flux. It is represented by a water reservoir,
which is placed on a precision laboratory balance for registration of
evaporation of moisture (Kern&Sohn, Kern EW 1500 2M).
FIGURE 15: Precision laboratory balance Kern EW 1500 2M.
32
45. FIGURE 17:
Wettex – a piece of
non-woven material
based on cellulose
with high water
retention and water
sorption.
FIGURE 16: Graphic model of the testing box placed in the climate
chamber with constant conditions RHe [%], Te[°C]. Temperature in the
testing box is 20°C and relative humidity is varying due the water
reservoir in the testing box.
1. material sample (Rockwool Dachrock Max d= 100 mm), 2. XPS
insulation of the box-walls with thickness of 40 mm, 3. aluminium-foil
coating, 4. plastic wall of the box, 5. light bulp providing heating of the
box, 6. cover of the light bulp to avoid radiation effect on the material
sample,
7. ventilation fan providing circulation of air in the testing box, 8.
calibrated humidity sensor,
9. temperature sensor, 10. Wettex textile installed to bring water closer
to the material sample,
11. water reservoir with circa 400 ml of water, 12. precision laboratory
balance registering evaporation of water from the tank, 13. precision
laboratory balance registering a change of weight of the entire system
33
46. For some of the tests a dry sponge cloth (Freudenberg household
products) was used. It is a piece of non-woven material based on cellulose
with high water retention and water sorption (FIGURE 17). It provided
faster transport of moisture to the air in the box. The box is injection
moulded of polyethylene, 500 mm high and 300x300 mm in cross
section and originaly intended for household applications. Inner volume
of the testing box was about 30 litres. The walls were insulated with
blocks of extruded polysterene (XPS), 40 mm thick, and wrapped by an
aluminium foil to prevent weight increase because of moisture in the
ambient. The box is heated by a light bulb (100W), which heating power
is regulated with an adjustable transformer.
Temperature is measured with ´thermistors´ and the level of moisture is
measured by the use of a RH-sensor (Mitec HMP50U-1).
FIGURE 18: Humidity sensor Mitec HMP50U-1, which was settled in
the testing set-up, as well as, in the climate chamber. Data from the
sensors were collected in time together with outdoor and indoor
temperature by datalogger Mitec AT40 (to the right).
An axial flow fan (of the size used in a PC) is installed in the box to
make air circulating inside the box.
Cables to the sensors in the box passes through a hole that is scaled by a
rubber plug. The entire box is placed on a precision balance
(Kern&Sohn, model Kern EW 6000-1M) in order to record mass
changes of the entire system.
34
47. FIGURE 19: Pictures of the real testing set-up showing inner
accessories (upper picture) and surface aluminium coating to protect the
testing box from air humidity of the ambient .
35
48. 6.2.2. Measurement above 0°C - Processing
The box was placed in a climate chamber with regulated temperature
and relative humidity. A series of tests were done with temperatures in
the climate chamber set to +20°C, +15°C, +10°C and +5°C (see
FIGURE 20a-b). A dehumidifier kept relative humidity of the chamber
around 40%. These conditions were chosen to establish a moisture flow
through the sample. Before using the box with a material sample, it was
necessary to do a capacity measurement of the testing box to know the
time period needed to reach a steady state under specified outdoor and
indoor conditions. For this test, the box was covered tightly by a damp-
proof membrane at the level of 30 l of the box volume, to prevent any
moisture leakage. The water reservoir in the box contained 400 ml of
water. In this capacity test the time was measured to reach a steady state
of 100% RH at 20°C in the box, which (according to equation 9) means
a vapour concentration of 17,3 g/m3
[9].
The test set-up was designed for quadratic material specimens with
dimensions 300 x 300 mm and 100 mm thick. A stiff heavy board of
stone wool with integrated double-layer characteristics fully
hydrofobised throughout its capacity was used for the measurement
above 0°C. For more detailed description of the tested specimen
(SPECIMEN A) see chapter 4.1. Materials were always dried and
weighed prior to testing. Then they were left in the climate chamber for
24 hours to accomodate to specified climate conditions in the climate
chamber. Then they were weighed for the second time and wrapped by
a non-absorbent tape and a third weighing followed. To avoid any
moisture leakage around the material sample the joint between the
testing box and the block of stone wool was sealed with non-absorbent
flexible elastomeric tube (Armacell LLC, AP Armaflex) and silicon
bonding agent. Each measurement in the set outdoor conditions (and
unchanging indoor temperature in the testing box) lasted for 5 days.
Balances registrated the actual weight every second minute, the same
with humidity and temperature sensors installed in the testing box and
in the climate chamber. Right after ending the appropriate
measurement, the ´deinstalled´ material sample was weighed for the
fourth time to measure possible inbuilt moisture.
The following figures desribe courses of relative humidities and
temperatures during the measurement wih Te above 0°C.
36
49. FIGURE 20a: Temperature and relative humidity inside the box (T1,
RH1) and in the climate chamber (T2,RH2). Detailed courses of
temperatures and relative humidities for specified setup conditions:
I. Te ≈ 20°C, RHe ≈ 40%, Ti ≈ 20°C; in this measurement the
water reservoir in the testing was equipped with two pieces of
wettex textile to bring water closer to the material sample and to
provide as high maximum relative humidity as possible. This
solution will be also used in the future research.
II. Te ≈ 15°C, RHe ≈ 40%, Ti ≈ 20°C; the wettex textile was not
used
37
50. FIGURE 20b: Temperature and relative humidity inside the box (T1,
RH1) and in the climate chamber (T2,RH2). Detailed courses of
temperatures and relative humidities for specified setup conditions:
III. Te ≈ 10°C, RHe ≈ 40%, Ti ≈ 20°C; the wettex textile was not
used
IV. Te ≈ 05°C, RHe ≈ 40%, Ti ≈ 20°C; the wettex textile was not
used
38
51. Evaporation of water from the interior water reservoir was almost constant
with time for all measeruments. This can be seen in the diagrams in
FIGURE 21 a – d where data from the outer balance (which records the
change of weight of the entire system) are presented. In these diagrams the
data are shown together with a best fit straight line) The values during the
time needed to reach steady state are excluded from the diagrams.
FIGURE 21a: Graphs showing the straightline downtrend of weight
of the entire system registered by the balance under the testing box
within the time interval of 100 hours.
I. Te ≈ 20°C, RHe ≈ 40%, Ti ≈ 20°C
The collected data were analysed and charted into figures. Moisture
flow rate G (kg/s) was calculated from a weight change of the entire
system and divided by a chosen time period (100 hours). From this data
the diffusive flux g (kg/m2
s) and moisture resistance factor μ (-) can be
calculated. In the end, the theoretical calculation and results based on
the laboratory measurement were compared and interpreted.
39
52. FIGURE 21b: Graphs showing the straightline downtrend of weight
of the entire system registered by the balance under the testing box
within the time interval of 100 hours.
II. Te ≈ 15°C, RHe ≈ 40%, Ti ≈ 20°C
FIGURE 21c: Graphs showing the straightline downtrend of weight
of the entire system registered by the balance under the testing box
within the time interval of 100 hours.
III. Te ≈ 10°C, RHe ≈ 40%, Ti ≈ 20°C
40
53. FIGURE 21d: Graphs showing the straightline downtrend of weight
of the entire system registered by the balance under the testing box
within the time interval of 100 hours.
IV. Te ≈ 05°C, RHe ≈ 40%, Ti ≈ 20°C
6.2.3. Measurement below 0°C - Processing
The testing mechanism is the same as for the measurement above 0°C.
In this case the entire testing set-up (see chapter 6.2.1) was placed in the
climate chamber with regulated temperature Te = -20°C. Conditions of
the climate chamber were recorded by a couple of temperature and
humidity sensors. Thanks to two pieces of Wettex (see FIGURE 17) the
inner volume of the box (30 litres) became saturated by water flux
within few minutes. After reaching the saturated state, relative humidity
in the box (RHi) remained stable. Again, the testing cycle lasted for 100
hours.
Conditions remained unchanging during the measurements and were
disturbed just by short freezing intervals of the climate chamber,
providing demanded thermal conditions (Te). Prior to testing, the
specimens were weighed and mounted with three compound sensors
Mitec HMP50U-2 registering temperature and relative humidity at once.
These sensors were installed into the material specimens at the top, in
41
54. the middle and at the bottom, as described in FIGURE 22. This
provided detailed information about courses of temperatures and
humidities throughout the tested specimens.
FIGURE 22: Compound humidity and temperature sensors Mitec
HMP50U-2 and their instalation in the material specimen (Specimen B).
After testing the specimens were cut into 18 sections at two altitudinal
levels (see FIGURE 23) for easier analysis and more accurate
quantification of the measured data. The cut material blocks were
weighed, dried and weighed again and data of accumulated moisture
were used in the calculation for each material sample
FIGURE 23: Discerption of the material sample into 18 sections and
two altitudinal levels.
42
55. Materials analyzed in the measurement below 0°C are stone-wool
specimens (for more detailed description of the tested specimens see
chapter 4.1 and TABLE 4) with different densities and specific sphere
of use:
• SPECIMEN A - primarily used for flat-roof constructions; ρd =
145 kg/m3
(material with the highest content of binders used in
the measurement)
• SPECIMEN B - used for flat roofs; ρd = 112 kg/m3
• SPECIMEN C - used for insulating pitched roofs, ventilated
facades and sandwich walls; ρd = 44 kg/m3
(material with the
lowest content of binders used in the measurement).
Specimens were cut to blocks with following dimensions - 300mm
(length) x 300mm (width) x 100mm (thickness). Samples were dried and
weighed prior to measurements.
Thanks to the methodology of the practical measurement, moisture
flow rate G (kg/s) can be calculated. Consequently, enumeration of the
diffusive flux g (kg/m2
s) and, especially, moisture resistance factor μ (-)
follows.
7. Results of the Test Set-Up and Discussion
Theoretical results, based on formulas mentioned in the chapter 5.1 (see
above), were compared with results based on the experimental
measurement in the laboratory.
7.1. Measurement above 0°C
The results of the tests with Te above 0°C are put together in TABLE
8 and a detailed presentation of the experimental conditions along with
the moisture resistance factor is given in TABLE 8. As can be seen, the
moisture resistance factor, μ, based on the experimental work, is
situated in the interval <1,13 – 1,19>. The value (taken from a product
list from the portfolio of a major producer of thermal insulation
materials the producer) is μ =2,95 (see TABLE 4). It is circa 2,5times
more than the result of measurements.
43
56. G
[kg/s]
*10-7
g
[kg/m2s]
*10-6
Te
[°C]
vs (Te)
[kg/m3]
*10-2
ve
[kg/m3]
*10-3
vi
[kg/m3]
*10-2
δv
[m2/s]
*10-5
Z
[s/m]
*103
μ
[-]
1,74 1,94 20,02 1,73 7,34 1,61 2,22 4,51 1,13
1,93 2,14 15,11 1,29 4,91 1,41 2,34 4,28 1,14
1,76 1,95 9,76 9,26 3,56 1,34 1,99 5,02 1,18
1,62 1,80 5,74 7,14 2,86 1,18 2,01 4,96 1,14
TABLE 7: Table of the calculated magnitudes based on the
experimental measurement for varying character of the ambient and for
stagnant indoor temperature.
Time
period
Exterior
conditions
Change of weight
of the entire system
[g]
Interior
conditions
μ
[-]
Te= 20,02°C a 6630,2 Ti= 20,91 °C
Φe=42,42 % b 6567,5 Φi = 92,88 %100 h
∆ = a-b 62,7
1,13
Te= 15,11°C a 5249,9 Ti= 20,60 °C
Φe=38,03 % b 5180,6 Φi = 81,23 %100 h
∆ = a-b 69,3
1,14
Te= 9,756°C a 5212,6 Ti= 20,51 °C
Φe=38,41 % b 5149,3 Φi = 77,23 %100 h
∆ = a-b 63,3
1,18
Te= 5,736°C a 5277,4 Ti= 20,31 °C
Φe=40,05 % b 5219 Φi = 68,23 %100 h
∆ = a-b 58,4
1,14
TABLE 8: Table of conditions (exterior and interior) for the
experimental measurement together with a change of weight of the
entire system within a time period of 100 hours. Numeration of μ is also
attached.
44
57. 7.2. Measurement below 0°C
The amount of moisture evaporated from the inner vessel in the box
was measured with the inner balance. The weight change of the entire
system, which means the moisture transport through the material
specimens, was measured with the outer balance. These values for the
test period (100 hours) are given in TABLE 9 below. In this table also
the amount of frost and condensate in the samples after tests are given
and the amount of condensate inside the box, both registered as weight
increase. The rest of the evaporated moisture was trapped in the sealed
padding around the box. This is also given in TABLE 9, although it was
not possible to weigh this moisture because of difficulties in handling
the samples.
Specimen
Evaporated
from inner
vessel
[g]
Weight
change for
entire
system
[g]
Condensate
in the box
[g]
Frost and
condensate
in the
sample
[g]
Moisture
trapped in
sealed
padding
around
the box
[g]
A 166 28 30 86 22
B 164 35 23 72 34
C 166 30 35 55 46
TABLE 9: Moisture balance in the testing set-up after the test
Data about moisture content in each piece of the divided specimen (see
FIGURE 23) together with information about inbuilt moisture was
used for calculation of moisture content mass by mass (u[%]), as well as,
moisture content mass by volume (w[kg/m3
]) [10]. Formation of frost
for the appropriate material specimen can be seen on photographs.
Results are charted into graphs showing 3D comparison of moisture
content (given both as “mass-% and as volume-kg/m3
) in sections of
the divided material.
• SPECIMEN A
The water in the upper part of the specimen A was in form of frost
which accumulates with time. The frost is quite equally spread over the
depth of the material. The frost is stationary and will not move until it is
melted or evaporated. Growth of frost formation in the specimen A can
45
58. be also seen on the following photograph of the cross section of the
sample A.
FIGURE 24: Frost formation (upper level) and the region of
condensation (lower level) in the specimen A. The bottom surface of
the lower level seems to be saturated by condensate, which could drain
out of the material.
In the lower part there is liquid water. At the bottom surface the
material A seems to be saturated by condensate which probably has
drained through the material. Next step would be water dropping back
into the box.
The highest moisture content in the lower part was in the section where
the sensor for temperature and humidity was located (s15 – see
FIGURE 23). This is probably caused by the drilled space around the
sensor and its feeding cable, where thermal qualities are weakened.
46
59. s7
s8
s9 s9
s6
s3
0
1
2
3
4
5
6
7
8
9
% by weight
Material sample No.
Material sample
No.
Moisture content mass by mass in material
samples
SPECIMEN A - upper level
s16
s17
s18 s18
s15
s12
0
2
4
6
8
10
12
% by weight
Material sample No.
Material sample
No.
Moisture content mass by mass in material
samples
SPECIMEN A - lower level
FIGURE 25: Specimen A - moisture content mass by mass in each part
of the divided tested block in both upper and lower level.
47
60. s7
s8
s9 s9
s6
s3
0
2
4
6
8
10
12
14
weight by
volume
[kg/m3]
Material sample No.
Material sample
No.
Moisture content mass by volume in material
samples
SPECIMEN A - upper level
s16
s17
s18 s18
s15
s12
0
2
4
6
8
10
12
14
16
18
weight by
volume
[kg/m3]
Material sample No.
Material sample
No.
Moisture content mass by volume in material
samples
SPECIMEN A - lower level
FIGURE 26: Specimen A - moisture content mass by volume in each
part of the divided tested block in both upper and lower level.
48
61. • SPECIMEN B
The same data are given for material B in figures 27, 28 and 29. The
amount of frost is somewhat lower than for material A. The lower part
of the sample did not seem saturated by condensate to the same extent
as material A. Also here the highest moisture content was in the part
with the sensor (s15 – see FIGURE 23).
FIGURE 27: Frost formation (upper level) and the region of
condensation (lower level) in the specimen B. The bottom surface of
the lower level does not seem saturated by condensate as much as for
the specimen A.
49
62. s7
s8
s9 s9
s6
s3
0
2
4
6
8
10
12
% by weight
Material sample No.
Material sample
No.
Moisture content mass by mass in material
samples
SPECIMEN B - upper level
s16
s17
s18 s18
s15
s12
0
2
4
6
8
10
12
% by weight
Material sample No.
Material sample
No.
Moisture content mass by mass in material
samples
SPECIMEN B - lower level
FIGURE 28: Specimen B - moisture content mass by mass in each part
of the divided tested block in both upper and lower level.
50
63. s7
s8
s9 s9
s6
s3
0
2
4
6
8
10
12
14
weight by
volume
[kg/m3]
Material sample No.
Material sample
No.
Moisture content mass by volume in material
samples
SPECIMEN B - upper level
s16
s17
s18 s18
s15
s12
0
2
4
6
8
10
12
14
weight by
volume
[kg/m3]
Material sample No.
Material sample
No.
Moisture content mass by volume in material
samples
SPECIMEN B - lower level
FIGURE 29: Specimen B - moisture content mass by volume in each
part of the divided tested block in both upper and lower level.
51
64. • SPECIMEN C
Data for material C are given in figures 30, 31 and 32.
There is frost formation in the specimen C, although it may seem not as
clearly visible as in material samples A and B. Also in this case moisture
uptake was high in the opening for the moisture and temperature sensor.
FIGURE 30: Frost formation (upper level) and the region of
condensation (lower level) in the specimen C. The frost formation is
not as visible as in the previous insulants with higher densities, anyway,
it occurs.
52
65. s7
s8
s9 s9
s6
s3
0
5
10
15
20
25
30
35
40
45
% by weight
Material sample No.
Material sample No.
Moisture content mass by mass in material
samples
SPECIMEN C - upper level
s16
s17
s18 s18
s15
s12
0
5
10
15
20
25
30
35
% by weight
Material sample No.
Material sample
No.
Moisture content mass by mass in material
samples
SPECIMEN C - lower level
FIGURE 31: Specimen C - moisture content mass by mass in each part
of the divided tested block in both upper and lower level.
53
66. s7
s8
s9 s9
s6
s3
0
2
4
6
8
10
12
14
16
18
20
weight by
volume
[kg/m3]
Material sample No.
Material sample No.
Moisture content mass by volume in material
samples
SPECIMEN C - upper level
s16
s17
s18 s18
s15
s12
0
2
4
6
8
10
12
14
weight by
volume
[kg/m3]
Material sample No.
Material sample No.
Moisture content mass by volume in material
samples
SPECIMEN C - lower level
FIGURE 32: Specimen C - moisture content mass by volume in each
part of the divided tested block in both upper and lower level.
54
67. In TABLE 10 below, data are processed for calculation of moisture
resistance factor according to equation 5 (see chapter 5.1). Any
distinctive increase in resistance factor with frost formation was not
noted as the rate of moisture transport through the specimens was quite
the same during the testing period.
Te
[°C]
Rhe
[-]
Ti
[°C]
Rhi
[-]
ve
[kg/m3
]
Specimen
A
-20 0,63 20 0,72 0,000558
Specimen
B
-20 0,66 20 0,72 0,000585
Specimen
C
-20 0,63 20 0,72 0,000558
vi
[kg/m3
]
G
[kg/s]
g
[kg/m2
s]
δv
[m2
/s]
μ
[-]
Specimen
A
0,012446
7,78E
-08
8,64E
-07
7,27E
-06
2,67
Specimen
B
0,012446
9,72E
-08
1,08E
-06
9,11E
-06
2,13
Specimen
C
0,012446
8,33E
-08
9,26E
-07
7,79E
-06
2,49
TABLE 10: Experimentally measured moisture resistance factor μ of
stone-wool specimens with varying density for outdoor temperature
Te=-20°C and the time interval 100 hours.
7.3. Discussion
The aim of this laboratory research was to describe the design and use
of a laboratory set-up that provides a very well controlled moisture load
to detect material properties of thermal insulation materials. The
designed testing set-up carried out its competence for the measurement,
which was done and which will follow.
The measured values of moisture resistance factor for laboratory tests
above 0°C (Te) for SPECIMEN A were about μ=1,2. This matches
with the values given in the standard EN 12524, where the tabulated
55
68. value of moisture resistance factor equals to 1 for mineral wool with
density between 10-200 kg/m3
[11]. The value declared by manufacturer
is μ = 2,95[-]; we are not able to explain the discrepancy between these
results, because we don´t know about how the producer´s data are
measured.
For the laboratory tests below 0°C (Te), frost formation in samples of
stone wool open to air was noted in cases when the temperature field
over the specimens was between + 20 and – 20ºC and the air on the
warm side was saturated with moisture. In the part of the specimen
facing the warm humid air condense formation occurred.
The studied specimens had varying densities (SPECIMEN A -
ρd=145kg/m3
, SPECIMEN B - ρd=112kg/m3
, SPECIMEN C -
ρd=44kg/m3
). Samples with higher densities (A, B) were visibly divided
into one zone of frost formation and another zone of condensation in
the cut. Also in the lightest sample (C) frost formation and
condensation occurred but no sharp borderline was observed.
The border between frozen part and condensate is close to where
temperature in the stone-wool specimen passes 0°C according to the
simulation.
Moisture content mass by mass has an upward trend with decreasing
density of the material sample. Also moisture content mass by volume
points out that storage of water is highest in the tested material with the
lowest density. In the part where condensation occurred the material
had moisture content considerably higher than what could be
anticipated from data such as moisture isotherms (see FIGURE 33).
FIGURE 33: Sorption curves for mineral wool and stone wool with
density 42 kg/m3
[12].
56
69. Measured moisture resistance factors μ for the measurement below 0°C
are 2 times or 2,5 times higher than the tabulated value [11], which is
μ=1 for mineral wool with density between 10-200 kg/m3
.
Consequently, EN 13162 says:” In the absence of measurements, the
moisture resistance factor, μ, of mineral wool products, either unfaced
or faced with a fabric with an open structure, may be assumed to be
equal to 1.“ [1] Why the moisture resistance factor was that high under
these circumstances is not clear and might need a further study.
8. Conclusions and Future Research
8.1. Concluding remarks
First of all, studies of moisture transport and absorbent properties of
mineral-wool insulants are not so frequent as studies concerning
thermal properties.
Insulants based on stone wool are widely used within the building
sector. They are popular for unique range of properties combining high
thermal resistance with long-term stability. Nevertheless, stone-wool
insulants are often at risk from moisture and condensation due to
unpredictable changes on a building site or due to other factors.
Everytime we use fibrous insulation, we should keep in mind that
precise proofing from water leakage can have major credit on lifetime of
this kind of insulating products. Therefore, we must pay attention to
detailed planning, proper installation and correct usage.
The experimental part of our project brought us valuable experience.
Observing situation and problems in real cases helped us to formulate
the essentials and requirements for designing a suitable laboratory set-
up with controlled moisture load to measure basic moisture properties
of chosen stone-wool specimens. Periodic controlling and monitoring
the climate conditions, as well as, weights was important to obtain
reliable data for the following calculations.
Finally, stone wool is just a building material, meaning that this material
does not always behave as we assume, but that is typical for laboratory
work and all researchers have to struggle with.
57
70. 8.2. Future Research
There is plenty of research work left to be done in this field. To get
wider perspective about formation of frost in stone wool insulants,
similar studies should be done in cases, when the temperature on the
cold side is not as low as in the presented measurement (Te=-20°C), but
still below 0ºC.
FIGURE 34: Computer simulation of condensation regions in stone-
wool layer for the following conditions
A. Te= -5°C, Ti=20°C; B. Te= -10°C, Ti=20°C; C. Te= -15°C,
Ti=20°C
where 1. is insulation of the testing box d=40 mm, 2. is stone-wool
sample d=100 mm and 3. is calculated condensation region.
NOTE: The computer simulation was created in the software Area
2005, developed at CVUT in Prague. This software allows 2D
simulations of steady-state thermal and pressure field together with
balance of water vapour in 2-D construction details according to CSN
EN ISO 10211-1 and CSN EN ISO 10077-2.
Further studies are needed to explain why the moisture resistance factor
is comparatively high under the circumstances of frost formation.
Another issue deals with under which circumstances a moisture
accumulation like this may occur in practice and what harm it could do
to a building construction.
Experiments could be also enlarged to insulants based on glass wool.
58
71. 9. References
[1] EN 13162 (2001), Thermal insulation products for buildings – Factory made
mineral wool (MW) products – Specification. Brussels: European Committee
for Standardization, pp 8-23
[2] Svoboda L., Tobolka Z. (1996), Stavební izolace 1,2 – Materiály. Praha:
Vydavatelství ČVUT, pp 45-47
[3] Eurima - European Insulation Manufacturers Association,
http://www.eurima.org/mineral_wool/composition.html (August 2007)
[4] Svoboda L. (2004), Stavební hmoty. Bratislava: Jaga, pp 125-128
[5] Rockwool a.s., Czech Republic
http://www.rockwool.cz (August 2007)
[6] Hagentoft, C.E. (2001), Introduction to Building Physics. Lund:
Studentlitteratur, pp 87-149
[7] Jóhannesson, G. (2004), Lectures on Building Physics. Stockholm, pp
117-147
[8] Semerák, P., Michalko, O. (2001), Přehled metod měření vlhkosti
stavebních materiálů. Praha: Česká stavební společnost, pp. 293-296
[9] Padfield T.,(1999) The role of absorbent building materials in moderating
changes of relative humidity. DTU Lyngby, pp 18-87
[10] ISO/FDIS 9346 (2007), Hygrothermal performance of buildings and
building materials – Physical quantities for mass tranfer - Vocabulary. ISO
Geneva pp 1-10
[11] EN 12524 (2000), Building materials and products – Hygrothermal
properties – Tabulated design values. Brussels: European Committee for
Standardization, pp 1-9
[12] Nevander L.E., Elmarsson B. (1994), Fukt handbok-praktik och teori.
AB Svensk Byggtjänst och föfattarna, pp 481
59
72. 10. Bibliography
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