This document summarizes research on fiber reinforced composite super alloys for high temperature applications. Various refractory metal fibers have been studied for reinforcement, including tungsten, hafnium, niobium and molybdenum fibers. Nickel, cobalt and iron-based superalloys have been used as matrices. Composites are fabricated using liquid and solid phase methods like slip casting and powder metallurgy. Tungsten fiber reinforced superalloy composites exhibit improved creep resistance, stress rupture strength, fatigue strength and thermal conductivity compared to conventional superalloys. However, thermal fatigue and oxidation resistance remain challenges. Exploratory research demonstrates these composites have good potential for advanced high temperature applications.
Composites are made by combination of two or more natural or artificial materials to maximize their useful properties and minimize their weaknesses.
Example: The oldest and best-known composites,
Natural: Wood combination of cellulose fibre provides strength and lignin is the "glue" that bonds and stabilizes. Bamboo is a very efficient wood composite structure.
o is a very efficient wood composite structure
Artificial: The glass-fibre reinforced plastic (GRP), combines glass fiber (which are strong but brittle) with plastic (which is flexible) to make a composite material that is tough but not brittle.
70 to 90% of load carried by fibers
Provide structural properties to the composite
Stiffness
Strength
Thermal stability
Provide electrical conductivity or insulation
Example: Glass, Carbon, Organic Boron, Ceramic, Metallic
Function of Fiber/Dispersion phase
Composites are made by combination of two or more natural or artificial materials to maximize their useful properties and minimize their weaknesses.
Example: The oldest and best-known composites,
Natural: Wood combination of cellulose fibre provides strength and lignin is the "glue" that bonds and stabilizes. Bamboo is a very efficient wood composite structure.
o is a very efficient wood composite structure
Artificial: The glass-fibre reinforced plastic (GRP), combines glass fiber (which are strong but brittle) with plastic (which is flexible) to make a composite material that is tough but not brittle.
70 to 90% of load carried by fibers
Provide structural properties to the composite
Stiffness
Strength
Thermal stability
Provide electrical conductivity or insulation
Example: Glass, Carbon, Organic Boron, Ceramic, Metallic
Function of Fiber/Dispersion phase
Presentation on Composite Materials
Rana zia ur rehman
Graduate Researcher at KAIST (Korea Advanced of Science & Technology)
My Email ID: ranazia517@gmail.com
PPT Includes physical Metallurgy for Titanium and its alloys, Weld ability of them and two welding processes : GTAW and EBW. PPT also describes the Problems with the Welding of Titanium and alloys.
Explained Molten metal transfers in GMAW process ( MIG / MAG)
and equipments used in GMAW process and set up images are arranged in this welding process
Basic knowledge of Gas Tungsten Arc Welding (GTAW) for freshers in the field. This is one of the welding process that produces one of the highest quality of weld for high integrity structures...
Presentation on Composite Materials
Rana zia ur rehman
Graduate Researcher at KAIST (Korea Advanced of Science & Technology)
My Email ID: ranazia517@gmail.com
PPT Includes physical Metallurgy for Titanium and its alloys, Weld ability of them and two welding processes : GTAW and EBW. PPT also describes the Problems with the Welding of Titanium and alloys.
Explained Molten metal transfers in GMAW process ( MIG / MAG)
and equipments used in GMAW process and set up images are arranged in this welding process
Basic knowledge of Gas Tungsten Arc Welding (GTAW) for freshers in the field. This is one of the welding process that produces one of the highest quality of weld for high integrity structures...
Polymeric and Hybrid Composite Materials for Aircraft Engine applications / ...Padmanabhan Krishnan
Contents: Introduction to Engines used in Aircrafts,
Materials and Manufacturing,
Basic Mechanics,
Meso and Macro mechanics and Interfaces in Composites,
Tests and failure theories,
Possibilities in Product Design and Development,
Possibilities in Aircraft Engine Applications
Overview of the fundamental roles in Hydropower generation and the components involved in wider Electrical Engineering.
This paper presents the design and construction of hydroelectric dams from the hydrologist’s survey of the valley before construction, all aspects and involved disciplines, fluid dynamics, structural engineering, generation and mains frequency regulation to the very transmission of power through the network in the United Kingdom.
Author: Robbie Edward Sayers
Collaborators and co editors: Charlie Sims and Connor Healey.
(C) 2024 Robbie E. Sayers
Welcome to WIPAC Monthly the magazine brought to you by the LinkedIn Group Water Industry Process Automation & Control.
In this month's edition, along with this month's industry news to celebrate the 13 years since the group was created we have articles including
A case study of the used of Advanced Process Control at the Wastewater Treatment works at Lleida in Spain
A look back on an article on smart wastewater networks in order to see how the industry has measured up in the interim around the adoption of Digital Transformation in the Water Industry.
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)MdTanvirMahtab2
This presentation is about the working procedure of Shahjalal Fertilizer Company Limited (SFCL). A Govt. owned Company of Bangladesh Chemical Industries Corporation under Ministry of Industries.
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptxR&R Consult
CFD analysis is incredibly effective at solving mysteries and improving the performance of complex systems!
Here's a great example: At a large natural gas-fired power plant, where they use waste heat to generate steam and energy, they were puzzled that their boiler wasn't producing as much steam as expected.
R&R and Tetra Engineering Group Inc. were asked to solve the issue with reduced steam production.
An inspection had shown that a significant amount of hot flue gas was bypassing the boiler tubes, where the heat was supposed to be transferred.
R&R Consult conducted a CFD analysis, which revealed that 6.3% of the flue gas was bypassing the boiler tubes without transferring heat. The analysis also showed that the flue gas was instead being directed along the sides of the boiler and between the modules that were supposed to capture the heat. This was the cause of the reduced performance.
Based on our results, Tetra Engineering installed covering plates to reduce the bypass flow. This improved the boiler's performance and increased electricity production.
It is always satisfying when we can help solve complex challenges like this. Do your systems also need a check-up or optimization? Give us a call!
Work done in cooperation with James Malloy and David Moelling from Tetra Engineering.
More examples of our work https://www.r-r-consult.dk/en/cases-en/
Hybrid optimization of pumped hydro system and solar- Engr. Abdul-Azeez.pdffxintegritypublishin
Advancements in technology unveil a myriad of electrical and electronic breakthroughs geared towards efficiently harnessing limited resources to meet human energy demands. The optimization of hybrid solar PV panels and pumped hydro energy supply systems plays a pivotal role in utilizing natural resources effectively. This initiative not only benefits humanity but also fosters environmental sustainability. The study investigated the design optimization of these hybrid systems, focusing on understanding solar radiation patterns, identifying geographical influences on solar radiation, formulating a mathematical model for system optimization, and determining the optimal configuration of PV panels and pumped hydro storage. Through a comparative analysis approach and eight weeks of data collection, the study addressed key research questions related to solar radiation patterns and optimal system design. The findings highlighted regions with heightened solar radiation levels, showcasing substantial potential for power generation and emphasizing the system's efficiency. Optimizing system design significantly boosted power generation, promoted renewable energy utilization, and enhanced energy storage capacity. The study underscored the benefits of optimizing hybrid solar PV panels and pumped hydro energy supply systems for sustainable energy usage. Optimizing the design of solar PV panels and pumped hydro energy supply systems as examined across diverse climatic conditions in a developing country, not only enhances power generation but also improves the integration of renewable energy sources and boosts energy storage capacities, particularly beneficial for less economically prosperous regions. Additionally, the study provides valuable insights for advancing energy research in economically viable areas. Recommendations included conducting site-specific assessments, utilizing advanced modeling tools, implementing regular maintenance protocols, and enhancing communication among system components.
2. INTRODUCTION
The need for improved materials at elevated
temperatures has stimulated research in many
areas including efforts to develop fiber reinforced
super alloy matrix composites
Improved performance of heat engines is largely
dependent upon maximum cycle temperatures.
3. • A number of fibers have been studied for
such use including submicron diameter
ceramic whiskers, continuous length ceramic
filaments, boron filaments, carbon filaments,
and refractory metal alloy wires.
• Attainment of high temperature strength with
superalloy matrix composites has been
successful using refractory metal alloy wires.
INTRODUCTION
4. • The theoretical specific strength potential of
refractory alloy fiber reinforced superalloys is
less than that of ceramic fiber reinforced
superalloys.
• However, the more ductile metal fiber systems
are more tolerant of fiber-matrix reactions and
thermal expansion mismatches.
• Also, the superalloy matrices can protect high
strength refractory metal fibers from
environmental attack.
INTRODUCTION
5. WHAT IS A COMPOSITE?
• A composite is considered to be any multiphase
material that exhibits a significant proportion of
the properties of both constituent phases such
that a better combination of properties is
realized.
• Technologically, the most important
composites are those in which the dispersed
phase is in the form of a fiber.
• Matrix, which is continuous and surrounds the
other phase(fibers), often called the dispersed
phase.
6. FIBER DEVELOPMENT
• Refractory metal wires have received a great deal
of attention as fiber reinforcement materials for
high temperature composites inspite of their poor
oxidation resistance and high density.
• The strongest wire fabricated, W-Re-Hf-C, had a
tensile strength of 2165 MN/m at 1093 ◦C (2000
◦ F ) which is more than 6 times as strong as
the strongest Nickel or Cobalt based superalloy.
7. MATRIX DEVELOPMENT
• The primary function of the matrix is to bind the
fibers into a useful body and to protect the fibers
from oxidation and hot corrosion.
• The matrix must be relatively ductile compared to
the fibers to facilitate load transfer from the
matrix to the fiber.
• For high temperature use, nickel-base, cobalt-base
and iron-base superalloys are preferred as the
matrices for refractory metal fiber composites
10. LIQUID PHASE METHOD
• Liquid phase methods consists of casting the
molten matrix using Investment casting
techniques so that the matrix infiltrates the
bundle of fibers in the form of parallel stacks
or mats.
• The molten metal must wet the fibers, form a
chemical bond and yet be controlled so as not
to degrade the fibers by dissolution, reaction,
or recrystallization.
11. SOLID PHASE METHODS
• Solid phase processing requires diffusion, which Is time-
temperature dependent.
• Solid phase processing temperatures are much lower
than liquid phase processing temperatures; diffusion
rates are much lower and reaction with the fiber can be
less severe.
• The prerequisite for solid state processing is that the
matrix be in either wire, sheet, foil, or powder form.
• Use of matrix materials in the form of sheet or foil
involves placing the reinforcing fibers between layers of
the matrix sheet or foil which are then pressed together.
12. • SLIP CASTING
Slip casting of metal alloy powders around
bundles of fibers followed by sintering and hot
pressing was developed for the solid state
fabrication of refractory fiber-superalloy
composites
This method is capable of achieving good matrix
consolidation and bonding between fiber and
matrix without excursions into the liquid metal
region which would greatly increase fiber matrix
reactions.
13. • ARC SPRAYING
Arc spraying represents the most versatile form of
composite fabricatlon.
Molten matrix alloy droplets are sprayed in a
controlled atmosphere chamber onto a cylindrical
drum wrapped with fibers.
The drum is rotated and translated within the
chamber In front of the spray to produced a
controlled porosity monotape.
Monotapes can then be cut into any shape desired
with any orientation of fiber deslred and
subsequently stacked up and hot pressed into any
desired layup.
14.
15. • POWDER METALLURGY
The powder metallurgy approach is one of the
most versatile methods for producing refractory
fiber-superalloy composites and has yielded some
excellent results.
However, the large surface area of the fine
powders is easily contaminated and introduces
impurities that must be removed. High capital cost
equipment is necessary to apply pressure and
temperature in an inert atmosphere. Most powder-
fabration techniques limit fiber content to 40 to 50
vol fraction.
Powder processing has been used to achieve
control of matrix-fiber reactions and has resulted in
excellent composite properties.
16. COMPOSITE PROPERTIES
• The principal reason for most of the work on
refractory fiber superalloy composites has been to
produce a material capable of operation as highly
stressed components such as turbine blades.
• In advanced aircraft and industrial gas turbine
engines at temperatures of 1100 to 1200 ◦c.
18. CREEP RESISTANCE
• Reinforcement reduces second stage
minimum creep rate due to the presence of
fibers.
• The fibers are mainly responsible for
controlling the creep behavior rather than the
matrix.
• The creep deformation does not generally
occur at matrix except at the interface.
19. STRESS RUPTURE STRENGTH
• At temperatures of 1100 ◦C (2010 ◦F) and above,
a superalloy matrix contributes very little to the
rupture strength of the composite compared to the
contribution of the refractory fibers.
• Fiber stress-rupture strength, volume fraction of
fiber, and the degree of fiber-matrix reaction all
control the stress-rupture strength of the
composite.
21. FATIGUE STRENGTH
• Fatigue strength is mainly the function of the
strength and volume fraction of fibers.
22. THERMAL FATIGUE
• Rapid changes in the temperature of the
environment can cause transient temperature
gradients in components.
• Such temperature gradients give rise to thermal
stresses and strains.
• Because of the large difference in expansion
coefficients between the fiber and matrix and the
resulting strains, thermal fatigue is believed to be
the most serious limitation on composite
usefulness.
23. IMPACT STRENGTH
• Impact strength decreased with increasing fiber
content at the lower temperature, but increased with
increasing
• The matrix's contribution to impact strength for the
composite is most significant at low temperatures,
while the fiber controls higher temperature impact
strength, above 260 ◦C.
• Heat treatment or hot rolling improved the room
temperature impact strength of the composite.
24. OXIDATION AND CORROSION
• The basic design of the composite material assumes
that the superalloy matrix will provide oxidation
resistance, including protection of the tungsten fibers.
• Oxidation proceeding perpendicular to the fibers
(through the blade or vane thickness) would destroy the
exposed fibers , but intervening matrix would prevent
oxidation of subsequent layers.
• Oxidation parallel to the fibers (along the blade or vane
span) potentially is more severe, since all the exposed
fibers in the transverse section potentially could be
oxidized along the entire length.
26. THERMAL CONDUCTIVITY
• The conductivity of tungsten fiber/superalloy
composites is markedly superior to that of
superalloys.
• Thermal conductivity of the composite is greatest
in the direction of the fiber axes since there is a
continuous path for conduction along the tungsten
fibers.
• Conduction perpendicular to the fiber axes is
lower because the heat cannot find a continuous
path through tungsten.
28. CONLUDING REMARKS
Exploratory development and material property
screening have indicated that tungsten fiber
reinforced superalloy composites have
considerable potential for application as advanced
high temperature material.
Studies of a wide range of physical and mechanial
properties in laboratory tests have demonstrated
the advantage of tungsten fiber reinforced
superalloy composites over conventional
superalloys.
29. REFERENCES
• NASA Technical Memorandum 89865
• Fiber Reinforced Superalloys
Donald W. Petrasek and Robert A. Signorelli
Lewis Research Center
Cleveland, Ohio
And
Thomas Caulfield and John K. Tien
Columbia University
New York
For high temperature use, nickel-base, cobalt-base and iron-base supera
l l o y s are preferred as the matrices for r e f r a c t o r y metal f i b e r composites