The Potential Credit Exposure measure aims to determine the largest unsecured exposure that could arise if a counterparty defaults due to market shocks. It examines scenarios where assets and liabilities are stressed and the mark-to-market value changes, which could cause the net position to become a liability. If the stress impact creates a shortfall larger than the excess margin, the bank may face an unsecured loss upon default. The measure will be positive if the collateral value covers positions under stress scenarios, but negative if there is a shortfall that could cause potential loss.