SlideShare a Scribd company logo
Entropy (S): a measure of the dispersal of energy,
as a function of temperature, in a system.
To understand entropy, we need to consider probability.
Think about a deck of cards…
Only one way to be ordered
in sequence like a new deck.
Many ways to be out of
sequence.
Improbable after shuffling
Random order much more
probable after shuffling
Spontaneous process: The gas atoms expand to occupy both
flasks when the valve is opened.
How is probability involved in this process?
Why??
Let’s do an exercise involving dice to understand
more about probability.
Note: probability is the likelihood of an event occurring.
If your roll of two dice resulted in a score of 3, 4, 5, 6 or 7,
please click now.
A. 3
B. 4
C. 5
D. 6
E. 7
If your roll of two dice resulted in a score of 7, 8, 9, 10 or 11,
please click now.
A. 7
B. 8
C. 9
D. 10
E. 11
(Yes, the 7’s get to answer both questions.)
Note: depending on polling system being used, you may be able
to gather the data directly. These questions work for multiple
choice type clickers.
If your roll of two dice resulted in a score of 2, 7 or 12, please
click now.
A. 2
B. 7
C. 12
(Yes, the 7’s get to answer again!)
Total probability = 1
Imagine there is only one atom.
• Two possible arrangements when the valve is opened.
• Probability is ½ that the atom will be found in the left bulb.
• Just as with the dice, each of the possible arrangements is called a
microscopic state, or a microstate.
Let’s relate the concept of microstates and
probability to entropy and chemical systems:
Now, add a second atom.
• There are now 4 possible arrangements or 4 microstates.
With three atoms there are 8 microstates.
What is the relationship between the number of microstates, the
number of positions and the number of atoms?
number of microstates = nx
where n = number of positions and x is the number of molecules
Consider the ways that 4 atoms can be arranged…
# of microstates = 24 = 16
All 4 atoms in one bulb
2 possible configurations, or microstates
3 atoms in the left and 1 atom in the right
3 atoms in the right and 1 atom in the left
4 possible configurations, or microstates
4 possible configurations, or microstates
Two atoms in the right and two atoms in the left.
This distribution has the greatest number of microstates
and is the most probable distribution.
6 possible configurations, or microstates
On a macroscopic scale, it is much more probable that the atoms
will be evenly distributed between the two flasks because this is
the distribution with the most microstates.
Ludwig Boltzman related the number of microstates (W) to the
entropy (S) of the system:
S = k ln W
where k = Boltzman constant = 1.38 x 10-23 J/K
• A system with fewer microstates
has lower entropy.
• A system with more microstates
has higher entropy.
The 2nd Law of Thermodynamics can be restated as follows:
An isolated system tends toward an equilibrium macrostate
with maximum entropy, because then the number of
microstates is the largest and this state is statistically most
probable.
Consider two spins.
Assign a value of +½ and a value of –½.
How many microstates are possible?
How many macrostates are possible?
Which macrostate is the most probable?
22 = 4
+½ + +½ = 1
+½ + -½ = 0
-½ + -½ = -1
Probability
¼
¼
½
+½ + -½ = 0
It is more probable to have a pair of electrons with unpaired
spins than with paired spins.
lower entropy greater entropy
Positional probability: depends on the number of positions
in space (positional microstates) that yield a particular state.
lower positional probability higher positional probability
Which distribution of 6 particles into three interconnected boxes
has the highest entropy?
A.
B.
C.
D.
Odyssey simulation of states of matter
Select the correct statement:
A. The solid state has lower positional probability and
greater entropy than the gas state.
B. The solid state has higher positional probability and
greater entropy than the gas state.
C. The solid state has lower positional probability and
lower entropy than the gas state.
entropy solid < entropy liquid < entropy gas
Ludwig Boltzman related the number of microstates (W) to the
entropy (S) of the system:
S = k ln W
where k = Boltzman constant = 1.38 x 10-23 J/K
• A system with fewer microstates
has lower entropy.
• A system with more microstates
has higher entropy.
The use of entropy in predicting the
direction of spontaneous change in states
is in the
Second law of
thermodynamics:
For any spontaneous process, the entropy
of the universe, ΔSuniverse, increases.

More Related Content

Similar to entropy_0.pptx

Sci 214 Massive Success / snaptutorial.com
Sci 214 Massive Success / snaptutorial.comSci 214 Massive Success / snaptutorial.com
Sci 214 Massive Success / snaptutorial.com
Reynolds065
 
Measurement  of  the  angle  θ          .docx
Measurement  of  the  angle  θ          .docxMeasurement  of  the  angle  θ          .docx
Measurement  of  the  angle  θ          .docx
wkyra78
 
Power pt on shapes and molecules1
Power pt on shapes and molecules1Power pt on shapes and molecules1
Power pt on shapes and molecules1Andrew Matovu
 
ChemE_2200_lecture_T1.ppt weryuiutewryyuuu
ChemE_2200_lecture_T1.ppt weryuiutewryyuuuChemE_2200_lecture_T1.ppt weryuiutewryyuuu
ChemE_2200_lecture_T1.ppt weryuiutewryyuuu
sadafshahbaz7777
 
Hill_5p4_MaxwellBoltzmannDistribution.pdf
Hill_5p4_MaxwellBoltzmannDistribution.pdfHill_5p4_MaxwellBoltzmannDistribution.pdf
Hill_5p4_MaxwellBoltzmannDistribution.pdf
caitlin54
 
Scientific Method
Scientific MethodScientific Method
Scientific Method
anhdbh
 
Applications of Magnon Excitations in Spintronic and Optomagnetic Devices
Applications of Magnon Excitations in Spintronic and Optomagnetic DevicesApplications of Magnon Excitations in Spintronic and Optomagnetic Devices
Applications of Magnon Excitations in Spintronic and Optomagnetic DevicesEmeka Ikpeazu
 
Chapter7ppt.pdf
Chapter7ppt.pdfChapter7ppt.pdf
Chapter7ppt.pdf
SohailBhatti21
 
Quantum chaos in clean many-body systems - Tomaž Prosen
Quantum chaos in clean many-body systems - Tomaž ProsenQuantum chaos in clean many-body systems - Tomaž Prosen
Quantum chaos in clean many-body systems - Tomaž Prosen
Lake Como School of Advanced Studies
 
Bachelor's Thesis
Bachelor's ThesisBachelor's Thesis
Bachelor's Thesis
Bastiaan Frerix
 
Thermodynamics AND GIBBS PARADOX
Thermodynamics AND GIBBS PARADOXThermodynamics AND GIBBS PARADOX
Thermodynamics AND GIBBS PARADOX
selvakumar948
 
Entropy andthesecondlaw
Entropy andthesecondlawEntropy andthesecondlaw
Entropy andthesecondlawMidoOoz
 
Chapter 4 and 5
Chapter 4 and 5Chapter 4 and 5
Chapter 4 and 5smithdk
 
Qunatum computing
Qunatum computing Qunatum computing
Qunatum computing
Shivangi Gupta
 
Fi ck law
Fi ck lawFi ck law
Fi ck law
AJAL A J
 
Vasil Penchev. Continuity and Continuum in Nonstandard Universum
Vasil Penchev. Continuity and Continuum in Nonstandard UniversumVasil Penchev. Continuity and Continuum in Nonstandard Universum
Vasil Penchev. Continuity and Continuum in Nonstandard UniversumVasil Penchev
 
The Basic of Molecular Dynamics Simulation
The Basic of Molecular Dynamics SimulationThe Basic of Molecular Dynamics Simulation
The Basic of Molecular Dynamics Simulation
Syed Lokman
 
Final Report
Final ReportFinal Report
Final ReportCan Liu
 

Similar to entropy_0.pptx (20)

Sci 214 Massive Success / snaptutorial.com
Sci 214 Massive Success / snaptutorial.comSci 214 Massive Success / snaptutorial.com
Sci 214 Massive Success / snaptutorial.com
 
Measurement  of  the  angle  θ          .docx
Measurement  of  the  angle  θ          .docxMeasurement  of  the  angle  θ          .docx
Measurement  of  the  angle  θ          .docx
 
Power pt on shapes and molecules1
Power pt on shapes and molecules1Power pt on shapes and molecules1
Power pt on shapes and molecules1
 
ChemE_2200_lecture_T1.ppt weryuiutewryyuuu
ChemE_2200_lecture_T1.ppt weryuiutewryyuuuChemE_2200_lecture_T1.ppt weryuiutewryyuuu
ChemE_2200_lecture_T1.ppt weryuiutewryyuuu
 
Hill_5p4_MaxwellBoltzmannDistribution.pdf
Hill_5p4_MaxwellBoltzmannDistribution.pdfHill_5p4_MaxwellBoltzmannDistribution.pdf
Hill_5p4_MaxwellBoltzmannDistribution.pdf
 
Orbitals hl
Orbitals hlOrbitals hl
Orbitals hl
 
Scientific Method
Scientific MethodScientific Method
Scientific Method
 
Applications of Magnon Excitations in Spintronic and Optomagnetic Devices
Applications of Magnon Excitations in Spintronic and Optomagnetic DevicesApplications of Magnon Excitations in Spintronic and Optomagnetic Devices
Applications of Magnon Excitations in Spintronic and Optomagnetic Devices
 
Chapter7ppt.pdf
Chapter7ppt.pdfChapter7ppt.pdf
Chapter7ppt.pdf
 
Quantum chaos in clean many-body systems - Tomaž Prosen
Quantum chaos in clean many-body systems - Tomaž ProsenQuantum chaos in clean many-body systems - Tomaž Prosen
Quantum chaos in clean many-body systems - Tomaž Prosen
 
Bachelor's Thesis
Bachelor's ThesisBachelor's Thesis
Bachelor's Thesis
 
Thermodynamics AND GIBBS PARADOX
Thermodynamics AND GIBBS PARADOXThermodynamics AND GIBBS PARADOX
Thermodynamics AND GIBBS PARADOX
 
PHY 492 Final Paper
PHY 492 Final PaperPHY 492 Final Paper
PHY 492 Final Paper
 
Entropy andthesecondlaw
Entropy andthesecondlawEntropy andthesecondlaw
Entropy andthesecondlaw
 
Chapter 4 and 5
Chapter 4 and 5Chapter 4 and 5
Chapter 4 and 5
 
Qunatum computing
Qunatum computing Qunatum computing
Qunatum computing
 
Fi ck law
Fi ck lawFi ck law
Fi ck law
 
Vasil Penchev. Continuity and Continuum in Nonstandard Universum
Vasil Penchev. Continuity and Continuum in Nonstandard UniversumVasil Penchev. Continuity and Continuum in Nonstandard Universum
Vasil Penchev. Continuity and Continuum in Nonstandard Universum
 
The Basic of Molecular Dynamics Simulation
The Basic of Molecular Dynamics SimulationThe Basic of Molecular Dynamics Simulation
The Basic of Molecular Dynamics Simulation
 
Final Report
Final ReportFinal Report
Final Report
 

Recently uploaded

English lab ppt no titlespecENG PPTt.pdf
English lab ppt no titlespecENG PPTt.pdfEnglish lab ppt no titlespecENG PPTt.pdf
English lab ppt no titlespecENG PPTt.pdf
BrazilAccount1
 
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdfAKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
SamSarthak3
 
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdf
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdfGoverning Equations for Fundamental Aerodynamics_Anderson2010.pdf
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdf
WENKENLI1
 
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&BDesign and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
Sreedhar Chowdam
 
Architectural Portfolio Sean Lockwood
Architectural Portfolio Sean LockwoodArchitectural Portfolio Sean Lockwood
Architectural Portfolio Sean Lockwood
seandesed
 
Gen AI Study Jams _ For the GDSC Leads in India.pdf
Gen AI Study Jams _ For the GDSC Leads in India.pdfGen AI Study Jams _ For the GDSC Leads in India.pdf
Gen AI Study Jams _ For the GDSC Leads in India.pdf
gdsczhcet
 
CME397 Surface Engineering- Professional Elective
CME397 Surface Engineering- Professional ElectiveCME397 Surface Engineering- Professional Elective
CME397 Surface Engineering- Professional Elective
karthi keyan
 
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
MdTanvirMahtab2
 
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
obonagu
 
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
bakpo1
 
ML for identifying fraud using open blockchain data.pptx
ML for identifying fraud using open blockchain data.pptxML for identifying fraud using open blockchain data.pptx
ML for identifying fraud using open blockchain data.pptx
Vijay Dialani, PhD
 
Railway Signalling Principles Edition 3.pdf
Railway Signalling Principles Edition 3.pdfRailway Signalling Principles Edition 3.pdf
Railway Signalling Principles Edition 3.pdf
TeeVichai
 
Water Industry Process Automation and Control Monthly - May 2024.pdf
Water Industry Process Automation and Control Monthly - May 2024.pdfWater Industry Process Automation and Control Monthly - May 2024.pdf
Water Industry Process Automation and Control Monthly - May 2024.pdf
Water Industry Process Automation & Control
 
AP LAB PPT.pdf ap lab ppt no title specific
AP LAB PPT.pdf ap lab ppt no title specificAP LAB PPT.pdf ap lab ppt no title specific
AP LAB PPT.pdf ap lab ppt no title specific
BrazilAccount1
 
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
Amil Baba Dawood bangali
 
HYDROPOWER - Hydroelectric power generation
HYDROPOWER - Hydroelectric power generationHYDROPOWER - Hydroelectric power generation
HYDROPOWER - Hydroelectric power generation
Robbie Edward Sayers
 
ethical hacking in wireless-hacking1.ppt
ethical hacking in wireless-hacking1.pptethical hacking in wireless-hacking1.ppt
ethical hacking in wireless-hacking1.ppt
Jayaprasanna4
 
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptxCFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
R&R Consult
 
DESIGN A COTTON SEED SEPARATION MACHINE.docx
DESIGN A COTTON SEED SEPARATION MACHINE.docxDESIGN A COTTON SEED SEPARATION MACHINE.docx
DESIGN A COTTON SEED SEPARATION MACHINE.docx
FluxPrime1
 
space technology lecture notes on satellite
space technology lecture notes on satellitespace technology lecture notes on satellite
space technology lecture notes on satellite
ongomchris
 

Recently uploaded (20)

English lab ppt no titlespecENG PPTt.pdf
English lab ppt no titlespecENG PPTt.pdfEnglish lab ppt no titlespecENG PPTt.pdf
English lab ppt no titlespecENG PPTt.pdf
 
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdfAKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
AKS UNIVERSITY Satna Final Year Project By OM Hardaha.pdf
 
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdf
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdfGoverning Equations for Fundamental Aerodynamics_Anderson2010.pdf
Governing Equations for Fundamental Aerodynamics_Anderson2010.pdf
 
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&BDesign and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
Design and Analysis of Algorithms-DP,Backtracking,Graphs,B&B
 
Architectural Portfolio Sean Lockwood
Architectural Portfolio Sean LockwoodArchitectural Portfolio Sean Lockwood
Architectural Portfolio Sean Lockwood
 
Gen AI Study Jams _ For the GDSC Leads in India.pdf
Gen AI Study Jams _ For the GDSC Leads in India.pdfGen AI Study Jams _ For the GDSC Leads in India.pdf
Gen AI Study Jams _ For the GDSC Leads in India.pdf
 
CME397 Surface Engineering- Professional Elective
CME397 Surface Engineering- Professional ElectiveCME397 Surface Engineering- Professional Elective
CME397 Surface Engineering- Professional Elective
 
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
Industrial Training at Shahjalal Fertilizer Company Limited (SFCL)
 
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
在线办理(ANU毕业证书)澳洲国立大学毕业证录取通知书一模一样
 
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
一比一原版(SFU毕业证)西蒙菲莎大学毕业证成绩单如何办理
 
ML for identifying fraud using open blockchain data.pptx
ML for identifying fraud using open blockchain data.pptxML for identifying fraud using open blockchain data.pptx
ML for identifying fraud using open blockchain data.pptx
 
Railway Signalling Principles Edition 3.pdf
Railway Signalling Principles Edition 3.pdfRailway Signalling Principles Edition 3.pdf
Railway Signalling Principles Edition 3.pdf
 
Water Industry Process Automation and Control Monthly - May 2024.pdf
Water Industry Process Automation and Control Monthly - May 2024.pdfWater Industry Process Automation and Control Monthly - May 2024.pdf
Water Industry Process Automation and Control Monthly - May 2024.pdf
 
AP LAB PPT.pdf ap lab ppt no title specific
AP LAB PPT.pdf ap lab ppt no title specificAP LAB PPT.pdf ap lab ppt no title specific
AP LAB PPT.pdf ap lab ppt no title specific
 
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
NO1 Uk best vashikaran specialist in delhi vashikaran baba near me online vas...
 
HYDROPOWER - Hydroelectric power generation
HYDROPOWER - Hydroelectric power generationHYDROPOWER - Hydroelectric power generation
HYDROPOWER - Hydroelectric power generation
 
ethical hacking in wireless-hacking1.ppt
ethical hacking in wireless-hacking1.pptethical hacking in wireless-hacking1.ppt
ethical hacking in wireless-hacking1.ppt
 
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptxCFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
CFD Simulation of By-pass Flow in a HRSG module by R&R Consult.pptx
 
DESIGN A COTTON SEED SEPARATION MACHINE.docx
DESIGN A COTTON SEED SEPARATION MACHINE.docxDESIGN A COTTON SEED SEPARATION MACHINE.docx
DESIGN A COTTON SEED SEPARATION MACHINE.docx
 
space technology lecture notes on satellite
space technology lecture notes on satellitespace technology lecture notes on satellite
space technology lecture notes on satellite
 

entropy_0.pptx

  • 1. Entropy (S): a measure of the dispersal of energy, as a function of temperature, in a system. To understand entropy, we need to consider probability. Think about a deck of cards…
  • 2. Only one way to be ordered in sequence like a new deck. Many ways to be out of sequence. Improbable after shuffling Random order much more probable after shuffling
  • 3. Spontaneous process: The gas atoms expand to occupy both flasks when the valve is opened. How is probability involved in this process? Why?? Let’s do an exercise involving dice to understand more about probability. Note: probability is the likelihood of an event occurring.
  • 4. If your roll of two dice resulted in a score of 3, 4, 5, 6 or 7, please click now. A. 3 B. 4 C. 5 D. 6 E. 7
  • 5. If your roll of two dice resulted in a score of 7, 8, 9, 10 or 11, please click now. A. 7 B. 8 C. 9 D. 10 E. 11 (Yes, the 7’s get to answer both questions.) Note: depending on polling system being used, you may be able to gather the data directly. These questions work for multiple choice type clickers.
  • 6. If your roll of two dice resulted in a score of 2, 7 or 12, please click now. A. 2 B. 7 C. 12 (Yes, the 7’s get to answer again!)
  • 8. Imagine there is only one atom. • Two possible arrangements when the valve is opened. • Probability is ½ that the atom will be found in the left bulb. • Just as with the dice, each of the possible arrangements is called a microscopic state, or a microstate. Let’s relate the concept of microstates and probability to entropy and chemical systems:
  • 9. Now, add a second atom. • There are now 4 possible arrangements or 4 microstates.
  • 10. With three atoms there are 8 microstates. What is the relationship between the number of microstates, the number of positions and the number of atoms? number of microstates = nx where n = number of positions and x is the number of molecules
  • 11. Consider the ways that 4 atoms can be arranged… # of microstates = 24 = 16 All 4 atoms in one bulb 2 possible configurations, or microstates
  • 12. 3 atoms in the left and 1 atom in the right 3 atoms in the right and 1 atom in the left 4 possible configurations, or microstates 4 possible configurations, or microstates
  • 13. Two atoms in the right and two atoms in the left. This distribution has the greatest number of microstates and is the most probable distribution. 6 possible configurations, or microstates
  • 14. On a macroscopic scale, it is much more probable that the atoms will be evenly distributed between the two flasks because this is the distribution with the most microstates.
  • 15. Ludwig Boltzman related the number of microstates (W) to the entropy (S) of the system: S = k ln W where k = Boltzman constant = 1.38 x 10-23 J/K • A system with fewer microstates has lower entropy. • A system with more microstates has higher entropy.
  • 16. The 2nd Law of Thermodynamics can be restated as follows: An isolated system tends toward an equilibrium macrostate with maximum entropy, because then the number of microstates is the largest and this state is statistically most probable.
  • 17. Consider two spins. Assign a value of +½ and a value of –½. How many microstates are possible? How many macrostates are possible? Which macrostate is the most probable? 22 = 4 +½ + +½ = 1 +½ + -½ = 0 -½ + -½ = -1 Probability ¼ ¼ ½ +½ + -½ = 0 It is more probable to have a pair of electrons with unpaired spins than with paired spins.
  • 18. lower entropy greater entropy Positional probability: depends on the number of positions in space (positional microstates) that yield a particular state. lower positional probability higher positional probability
  • 19. Which distribution of 6 particles into three interconnected boxes has the highest entropy? A. B. C. D.
  • 20. Odyssey simulation of states of matter
  • 21. Select the correct statement: A. The solid state has lower positional probability and greater entropy than the gas state. B. The solid state has higher positional probability and greater entropy than the gas state. C. The solid state has lower positional probability and lower entropy than the gas state. entropy solid < entropy liquid < entropy gas
  • 22. Ludwig Boltzman related the number of microstates (W) to the entropy (S) of the system: S = k ln W where k = Boltzman constant = 1.38 x 10-23 J/K • A system with fewer microstates has lower entropy. • A system with more microstates has higher entropy.
  • 23. The use of entropy in predicting the direction of spontaneous change in states is in the Second law of thermodynamics: For any spontaneous process, the entropy of the universe, ΔSuniverse, increases.