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Materials Characterization Lab
                                www.mri.psu.edu/mcl




Dielectric Characterization
            Paul Moses
        paulmoses@psu.edu
             167 MRL
          814-863-0857

           June 6, 2005
Materials Characterization Lab
                                                                                                      www.mri.psu.edu/mcl



                     Summer Characterization Open Houses
Technique                                                          Time               Date              Location
Thermal analysis (TGA, DTA, DSC)                                   9:45 AM            June 8            250 MRL Bldg.
Transmission Electron Microscopy (TEM/STEM)                        9:45 AM            June 15           114 MRI Bldg
Scanning electron microscopy (SEM)                                 9:45 AM            June 22           541 Deike Bldg.
Analytical SEM                                                     11:00 AM           June 22           541 Deike Bldg.
X-ray Diffraction (XRD)                                            9:45 AM            June 29           250 MRL Bldg.
Dielectric Characterization (25 min lecture only)                  9:45 AM            July 6            250 MRL bldg.
High temperature sintering lab (20 min lecture only)               10:15 AM           July 6            250 MRL Bldg.
Focused Ion Beam (FIB)                                             9:45 AM            July 13           114 MRI Bldg
TEM sample preparation                                             11:00 AM           July 13           114 MRI Bldg
Orientation imaging microscopy (OIM/EBSD)                          9:45 AM            July 20           250 MRL Bldg.
Chemical analysis (ICP, ICP-MS)                                    9:45 AM            July 27           541 Deike Bldg.
Atomic Force Microscopy (AFM)                                      9:45 AM            August 3          114 MRI Bldg
Small angle x-ray scattering (SAXS)                                9:45 AM            August 10         541 Deike Bldg.
Particle Characterization                                          9:45 AM            August 17         250 MRL
X-ray photoelectron spectroscopy (XPS/ESCA)                        9:45 AM            August 24         114 MRI Bldg
Auger Electron Spectroscopy (AES)                                  11:00 AM           August 24         114 MRI Bldg



 NOTE LOCATIONS: The MRI Bldg is in the Innovation Park near the Penn Stater Hotel; MRL Bldg. is on Hastings Road.
 More information: www.mri.psu.edu/mcl
Materials Characterization Lab
Materials Characterization Lab Locations                                                                                                               www.mri.psu.edu/mcl



Bldg                       Telephone
MRL                        863-7844
MRI                        865-0337                                                                                                          MRI Bldg:
Hosler                     865-1981
                                                                                                                                             XPS/ESCA, SIMS,
E&ES                       863-4225
                                                                                                                                             TEM, HR-TEM, FE-
                                                                                                                                             Auger, AFM, XRD
                                                                                   MRL Bldg:
                                           Hosler Bldg:
                                                                                   SEM, XRD, OIM, DTA,
                                           SEM, ESEM, FE-
                                                                                   DSC, TGA, FTIR,                                                                       Penn Stater
                                           SEM, EPMA, ICP,
                                                                                   Raman, AFM, Powder,                                                                     Hotel
E&ES Bldg:                                 ICP-MS,BET, SAXS
                                                                                   dielectric, prep, shop,
SEM
                                                                                   IC, UV-Vis
                                                                                                                                          Route 322

                                                        Steidle Bldg:
                                                        Nanoindenter
         Atherton Street
         (322 Business)




                                                                                                                                                                                 I-99
                                                                                                               0
                                                                                                                                      Park
                                                                                                               0                                        0
                                                                                             0                                        0            0            0
                                                                                                                                                        0
                                                                                                                                      Ave.
                                                                                             0                                        0            0            0



                                                               Park            0
                                                                               0
                                                                                                                   Beaver
                                                               A0ve.                                               Stadium
                                                                0
                                               0
                                               0
                                                                                                                                                     Centre
               0
               0

                                                                                                                                                   Community




                                                                                                                        Porter Road
                                                                                                 Univ
                                                                   Shortlidg




                                                                                                                                                    Hospital
                   0
                   0
                           Burrowes Road




                                                                                                  ersi
                                                                                                    ty D
                                                                      e Road




                                                    Pollock Road
                                                                                                        rive




                                                                                                                                                                         North
                                                                                        Hastin
                                              Deike Bldg:                               Road gs


                                                   College Ave.
Materials Characterization Lab
                                                      www.mri.psu.edu/mcl




Google finds 2.4 million quot;dielectricquot; pages, PSU has 1660
Materials Characterization Lab
                                                                  www.mri.psu.edu/mcl




   What's Dielectric Characterization?
    E.G.: conductivity (V=RI), permittivity (D= E), impedance (V*=Z*ยทI*),
piezoelectricity (P=dฯƒ), pyroelectricity (i=pยทdT/dt), ferroelectricity (nonlinear
           relationship between electric field, polarization, strain, ...)

           For sure it involves charge and many orders of magnitude.
Materials Characterization Lab
                                                www.mri.psu.edu/mcl




Irreversible (DC)                   Reversible (AC)
      V = RI
                                         LCR Meter
        PE
                                          D33 Meter
Quasi-Static Strain
                                      Charge/Analyzer
  Pulse Discharge
                                            RF IV
        IV




 Others including transformer ratio bridges, microwave
              techniques, ๏ฌ‚uid immersion
Materials Characterization Lab
                                               www.mri.psu.edu/mcl




           Irreversible (DC)
                         Pulse
        PE                                       CV
                       Discharge
4
 0                                  9
                 9
-3
  -3 0 3     6                          -3 0       3       69
                     -3 0   3   6


    V            V                                V
                                I
                                                              I
Materials Characterization Lab
                                            www.mri.psu.edu/mcl




            Reversible (AC)
                Charge Converter
    LCR                                     RF IV
                Network Analyzer
   Meter
                4
                 0
                -3
-3 0 3     69        -3 0    3   69   -3 0        3        69

                                        V
                      Ref
   V
                                        V
                      Test
   I
Materials Characterization Lab
                                                          www.mri.psu.edu/mcl


               PE               LCR         Charge         RF-IV
                      CV
              Pulse            LCR++       Charge++       RF-IV++
              4
Log Voltage




              0



              -3
                -3         0           3              6                            9
                                 Log Frequency
Materials Characterization Lab
                                                  www.mri.psu.edu/mcl




              How To Get Started

contact: Jeff Long or Paul Moses

you will need:
โ€• a question or a plan
โ€• a sample with electrodes, contacts, or connections
โ€• a budget/fund number (cost center/project number)
โ€• possibly expendables: silver foil, dielectric fluid
โ€• possibly special fixture

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Dielectric

  • 1. Materials Characterization Lab www.mri.psu.edu/mcl Dielectric Characterization Paul Moses paulmoses@psu.edu 167 MRL 814-863-0857 June 6, 2005
  • 2. Materials Characterization Lab www.mri.psu.edu/mcl Summer Characterization Open Houses Technique Time Date Location Thermal analysis (TGA, DTA, DSC) 9:45 AM June 8 250 MRL Bldg. Transmission Electron Microscopy (TEM/STEM) 9:45 AM June 15 114 MRI Bldg Scanning electron microscopy (SEM) 9:45 AM June 22 541 Deike Bldg. Analytical SEM 11:00 AM June 22 541 Deike Bldg. X-ray Diffraction (XRD) 9:45 AM June 29 250 MRL Bldg. Dielectric Characterization (25 min lecture only) 9:45 AM July 6 250 MRL bldg. High temperature sintering lab (20 min lecture only) 10:15 AM July 6 250 MRL Bldg. Focused Ion Beam (FIB) 9:45 AM July 13 114 MRI Bldg TEM sample preparation 11:00 AM July 13 114 MRI Bldg Orientation imaging microscopy (OIM/EBSD) 9:45 AM July 20 250 MRL Bldg. Chemical analysis (ICP, ICP-MS) 9:45 AM July 27 541 Deike Bldg. Atomic Force Microscopy (AFM) 9:45 AM August 3 114 MRI Bldg Small angle x-ray scattering (SAXS) 9:45 AM August 10 541 Deike Bldg. Particle Characterization 9:45 AM August 17 250 MRL X-ray photoelectron spectroscopy (XPS/ESCA) 9:45 AM August 24 114 MRI Bldg Auger Electron Spectroscopy (AES) 11:00 AM August 24 114 MRI Bldg NOTE LOCATIONS: The MRI Bldg is in the Innovation Park near the Penn Stater Hotel; MRL Bldg. is on Hastings Road. More information: www.mri.psu.edu/mcl
  • 3. Materials Characterization Lab Materials Characterization Lab Locations www.mri.psu.edu/mcl Bldg Telephone MRL 863-7844 MRI 865-0337 MRI Bldg: Hosler 865-1981 XPS/ESCA, SIMS, E&ES 863-4225 TEM, HR-TEM, FE- Auger, AFM, XRD MRL Bldg: Hosler Bldg: SEM, XRD, OIM, DTA, SEM, ESEM, FE- DSC, TGA, FTIR, Penn Stater SEM, EPMA, ICP, Raman, AFM, Powder, Hotel E&ES Bldg: ICP-MS,BET, SAXS dielectric, prep, shop, SEM IC, UV-Vis Route 322 Steidle Bldg: Nanoindenter Atherton Street (322 Business) I-99 0 Park 0 0 0 0 0 0 0 Ave. 0 0 0 0 Park 0 0 Beaver A0ve. Stadium 0 0 0 Centre 0 0 Community Porter Road Univ Shortlidg Hospital 0 0 Burrowes Road ersi ty D e Road Pollock Road rive North Hastin Deike Bldg: Road gs College Ave.
  • 4. Materials Characterization Lab www.mri.psu.edu/mcl Google finds 2.4 million quot;dielectricquot; pages, PSU has 1660
  • 5. Materials Characterization Lab www.mri.psu.edu/mcl What's Dielectric Characterization? E.G.: conductivity (V=RI), permittivity (D= E), impedance (V*=Z*ยทI*), piezoelectricity (P=dฯƒ), pyroelectricity (i=pยทdT/dt), ferroelectricity (nonlinear relationship between electric field, polarization, strain, ...) For sure it involves charge and many orders of magnitude.
  • 6. Materials Characterization Lab www.mri.psu.edu/mcl Irreversible (DC) Reversible (AC) V = RI LCR Meter PE D33 Meter Quasi-Static Strain Charge/Analyzer Pulse Discharge RF IV IV Others including transformer ratio bridges, microwave techniques, ๏ฌ‚uid immersion
  • 7. Materials Characterization Lab www.mri.psu.edu/mcl Irreversible (DC) Pulse PE CV Discharge 4 0 9 9 -3 -3 0 3 6 -3 0 3 69 -3 0 3 6 V V V I I
  • 8. Materials Characterization Lab www.mri.psu.edu/mcl Reversible (AC) Charge Converter LCR RF IV Network Analyzer Meter 4 0 -3 -3 0 3 69 -3 0 3 69 -3 0 3 69 V Ref V V Test I
  • 9. Materials Characterization Lab www.mri.psu.edu/mcl PE LCR Charge RF-IV CV Pulse LCR++ Charge++ RF-IV++ 4 Log Voltage 0 -3 -3 0 3 6 9 Log Frequency
  • 10. Materials Characterization Lab www.mri.psu.edu/mcl How To Get Started contact: Jeff Long or Paul Moses you will need: โ€• a question or a plan โ€• a sample with electrodes, contacts, or connections โ€• a budget/fund number (cost center/project number) โ€• possibly expendables: silver foil, dielectric fluid โ€• possibly special fixture