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GUJARAT TECHNOLOGICAL UNIVERSITY
Chandkheda, Ahmedabad
Affiliated
K.J.I.T, Savali
A Project Report On
Four Stroke BiodieselEngine
Under subject of
DESIGN ENGINEERING
IIB B. E. Semester – VI
AUTOMOBILE ENGINEERING
Submitted by:
Sr. Name of student Enrollment No.
1 Yash Prakashbhai Ambekar 130640102004
2 Jaykumar Lalit Desai 130640102015
3 Yash Arvindbhai Prajapati 130640102048
4 Rocky Jagdishbhai Yadav 130640102052
Mr. Ronak Suthar
(Faculty Guide)
Mr. Kaustubh Natekar
(HOD)
Academic year
(2016-2017)
Contents
1. Introduction
Name of the team
About team members
About guide and mentor
What is Design Thinking?
2. Empathy Mapping
Users
Stakeholders
Activities
Story
3. Ideation Canvas
People
Activities
Situation/context
Props/Possible Solution
4. Product Development Canvas
Product Experience
Product Function
Components
People
Customer Revalidation
5. AEIOU Sheets
Activities
Environment
Interactions
Objects
Users
6. Learning Need Matrix (LNM) Theory
Purpose/Project Concept
Applicable Standards and Design Specifications
Component Materials’ strength Criteria
Software/Simulation/Skill/Mathematical Requirement
Tools/Methods/Theories/application Process Involved
Literature Review/Secondary Research
7. Design Considerations for detail design part:
7.1 Design for Performance, Safety and Reliability
7.2 Design for Ergonomics and Aesthetics
7.3 Design for Manufacturability & Assembly (DFMA)
7.4 Design for Cost, Environment
8. Design Calculation
9. Measuring Instruments/ techniques - knowledge and use
10. Comparison of existing materials, methods, tools and equipment for your project and
justify your selection of materials, methods, tools and equipment etc.
11. Simulation and Analysis (Software modelling), Mathematical model
12. Conclusion/Future scope
13. Prototype
ACKNOWLEDGMENT
 To innumerable websites in the internet, and to all those who have
uploaded their knowledge, imaginations, ideas, graphic skills etc., on these
websites.
 Also, to all those frompre-historic days to today, who have registered
their knowledge, imaginations, thoughts etc., through different means and
mediums.
 Also Dr. M. Y. Vaijanapurkar M. E. , Ph. D (IITKharakpur) and Mr. Ronak
Suthar for showing the correctpath and guiding us.
 Not forgetting other faculty of the college who gave their contribution till
their extent.
DECLARATION
We hereby declare that the DE-IIB Report Submitted Along With The Canvas Sheets
Entitled “FOUR STROKE BIODIESEL ENGINE” In Partial Fulfillment For 6th Semester
Automobile Engineering Of GTU, Ahmedabad During The Academic Year 2016-17 under the
supervision of Mr. Ronak Suthar and that no part of these DE-IIB reports has been directly copied
from any students reports or taken from any other source, without providing the reference.
YASH PRAKASHBHAI AMBEKAR (130640102004)
JAYKUMAR LALITKUMAR DESAI (130640102015)
YASH ARVINDBHAI PRAJAPATI (130640102048)
ROCKY JAGDISHBHAI YADAV (130640102052)
Internal Guide Head of Department
CERTIFICATE
This Is To Certify That DE-IIB Report Submitted Along With The Canvas Sheets
Entitled “FOUR STROKE BIODIESEL ENGINE” Has Been Carried Out By Yash
Ambekar, Desai Jaykumar, Prajapati Yashand Rocky Yadav Under My
Guidance In Partial Fulfillment For6th Semester Automobile Engineering Of GTU,
Ahmedabad During The Academic Year 2016-17.These Students Have successfully
Completed DE-IIB activity under my guidance.
Internal Guide Head of Department
Yash Ambekar
Yash P. Ambekar is a student of Automobile Engg. Department of K.J.I.T
Savali. He has helped in gathering the information regarding the topic. He has good knowledge
about managing the finance. He has also helped in completing the Canvas Sheets neatly. His
sincerity regarding the project is appreciable. His contribution regarding the DE-IIB is appreciable
and worthwhile.
Jay Desai
Jay L. Desai is a student of Automobile Engg. Department of K.J.I.T Savali.
He has got ability to handle the situation tactfully. He does not gets panic in any of the situation.
He patiently works with the group mates and listen to each and every opinion of the team. He has
got the ability to manage the team.His contribution regarding the DE-IIB is appreciable and
worthwhile.
Yash Prajapati
Yash A. Prajapati is a student of Automobile Engg. Department of K.J.I.T
Savali. He has helped in collecting the basic information about the project. He has helped in
preparing the final Report for the same. He has good quality of creating the friendly environment
among the group mates. He works with the team mates without any expectations. His sincerity
regarding the project is appreciable. His contribution regarding the DE-IIB is appreciable and
worthwhile.
RockyYadav
Rocky J. Yadav is a student of Automobile Engg. Department of K.J.I.T
Savali. He has got ability of finding handy solutions at critical stages, which are very helpful. His
compatibility with the Group mates is good and friendly. He creates humourous environment
while working. His sincerity regarding the project is appreciable. His contribution regarding the
DE-IIB is appreciable and worthwhile.
Mr. Ronak Suthar
Mr. Ronak Suthar (M.E.) is the Asst. Professor in Mechanical Department
at K.J.I.T.,Savali.He is one of the devoted faculty of the department. He is very polite and has
good knowledge about his field. His happy to help nature is really appreciable. Without his
guidance this project was not possible. His Contribution at each level of this project is worthwhile.
Dr. M.Y. Vaijanapurkar (M.E. Ph.D, IIT, Kharagpur ) was the Principal
of K.J.I.T., Savali . He is one of the Best experienced faculty of the college. He is always happy
to help and guide the students regarding exams, projects ,etc. His guidance is very helpful and
worth.
His polite and positive attitude towards students is really appreciable. His Contribution at each
level of this project is worthwhile.
Design Thinking is human-centered
Design thinking has come to be defined as combining empathy for the context of a problem,
creativity in the generation of insights and solutions, and rationality in analyzing and fitting various
solutions to the problem context. According to our team the goal of Design Thinking is "matching
people’s needs with what is technologically feasible and viable as a business strategy". The premise of
teaching Design Thinking is that by knowing about how to successfully approach and solve difficult,
multi-dimensional problems - more specifically, effective methods to ideate, select and execute
solutions - individuals and businesses will be able to improve their own problem solving processes and
skills. There is also significant academic interest in understanding howdesigners think and design
cognition.
Design thinking is a formal method for practical, creative resolution of problems and creation of
solutions, with the intent of an improved future result. In this regard it is a form of solution-based , or
solution-focused thinking; starting with a goal (a better future situation) instead of solving a specific
problem. By considering both present and future conditions and parameters of the problem, alternative
solutions may be explored simultaneously. Cross asserted that this type of thinking most often
happens in the built, or artificial, environment (as in artifacts).
 Focus on people / customers and their needs and not on a specific technology or other
conditions.
 Methods therefore used are observations, interviews, brainstorming, prototyping…
 Innovating at the intersection of business, technology and people leads to radical, new
experience innovation.
 The user is the one to decide if a product or a service should exist or be established
In short Design Thinking is a process through which we can make or modify new technology for
betterment of common people.
EMPATHY MAPPING CANVAS
USERS:
PUBLIC
FARMERS
DESIGNERS
ENGINEERS
DEVELOPERS
MANUFACTURERS
STAKEHOLDERS:
TRANSPORTERS
EXPORTERS
AUTOMOTIVE INDUSTRIES
LOCOMOTIVE INDUSTRIES
ACTIVITIES:
PRODUCTION OF BIO-DIESEL
REFINING OF SEEDS
TRANSESTERIFICATION
BLENDING
NEXT GEN. ENGINE
REFINMENT
CHANGED PIPING
NEW IGNITION SYSTEM
HAPPY
Biodiesel fuel is a renewable energy source unlike petroleum-based diesel. An excessive
production of soybeans in the world makes it an economic way to utilize this surplus for
manufacturing the Biodiesel fuel. One of the main biodiesel fuel advantages is that it is less
polluting than petroleum diesel. The lack of sulfur in 100% biodiesel extends the life of catalytic
converters. Another of the advantages of biodiesel fuel is that it can also be blended with other
energy resources and oil. Biodiesel fuel can also be used in existing oil heating systems and diesel
engines without making any alterations. It can also be distributed through existing diesel fuel
pumps, which is another biodiesel fuel advantage over other alternative fuels. The lubricating
property of the biodiesel may lengthen the lifetime of engines.
SAD
At present, Biodiesel fuel is bout one and a half times more expensive than petroleum diesel fuel.It
requires energy to produce biodiesel fuel from soy crops, plus there is the energy of sowing,
fertilizing and harvesting. Another biodiesel fuel disadvantage is that it can harm rubber hoses in
some engines. As Biodiesel cleans the dirt from the engine, this dirt can then get collected in the
fuel filter, thus clogging it. So, filters have to be changed after the first several hours of biodiesel
use. Biodiesel fuel distribution infrastructure needs improvement, which is another of the biodiesel
fuel disadvantages.
CONCLUSION:
1) Users are clearly mentioned and stakeholders are defined.
2) Activities regarding the project to be conducted step by step.
3) In story boarding it is clearly understood which part may be difficult and which
will be tactfully conquered.
IDEATION CANVAS:
PEOPLE:
PUBLIC
FARMERS
DESIGNERS
ENGINEERS
DEVELOPERS
MANUFACTURERS
ACTIVITIES:
PRODUCTION OF BIO-DIESEL
REFINING OF SEEDS
TRANSESTERIFICATION
BLENDING
NEXT GEN. ENGINE
REFINMENT
CHANGED PIPING
NEW IGNITION SYSTEM
SITUATION/CONTEXT:
PUBLIC TRANSPORT
PRIVATE VEHICLES
LOCOMOTIVES
INDUSTRIES
POWER PLANTS
AGRICULTURE
GENERATORS
PROPS/POSSIBLE SOLUTIONS:
BIO-DIESEL PRODUCTION:
SEED CRUSHERS
PUMPS
BLENDERS
FILTERS
REFINERS
ENGINEDESIGNING:
TOOL BOX
PIPE CUTTERS
MOULDS
DRILL MACHINE
BORING MACHINE
Should be considered for use as an alternative and not a primary fuel. Short and long term
environmental benefits will be worth while. Storage Issues with Stability and
Transportation issues with high cost of delivered fuel compared to fossil fuels. Fuel-supply
reliability. Lack of understanding of environmental impact – Nox emissions. Complexity
of biomass-power infrastructure compared to known well established coal and natural gas
markets.
PRODUCT DEVELOPMENTCANVAS PURPOSE:
AGRICULTURE
TRANSPORTATION
POWER GENERATION
PRODUCT EXPERIENCE:
SUBSIDY AVAILABLE
HIGH INITIAL COST
NOT WIDELY USED
PRODUCT FUNCTION:
RENEWABLE
SUSTAINABLE
LOWER EMISSIONS
COMPONENTS:
TITANIUM VALVES
HEAT EXCHANGER
POLYMER PIPE
FILTERS
FUEL INJECTORS
EXHAUST SYSTEM
PEOPLE:
PUBLIC
FARMERS
DESIGNERS
ENGINEERS
DEVELOPERS
MANUFACTURERS
ENVIRONMENTALISTS
CUSTOMER REVALIDATION
LESS AVAILABLE
ENVIRONMENT FRIENDLY
HIGH INITIAL COST
EQUALLY POWERFUL ENGINE AS COMPARED TO PRESENT ONES.
75 years of diesel vehicles.B5 and B20 engine approvals. Most biodiesel applications =
heavy- and medium-duty vehicles. Biodiesel fueling of light-duty vehicles is less common.
Diesel engines = compression-ignited (CI).Gasoline engines = spark-ignited (SI).More
torque. Most diesel engines can run on biodiesel blends of 5% to 20% with little or no
modification. The use of conventional diesel leaves a deposit in the bottom of fuel lines,
tanks, and delivery systems over time. The use of biodiesel can dissolve this sediment and
result in the need to change filters more frequently when first using biodiesel until the
whole system has been cleaned of the deposits left by the conventional diesel.
To make The Engine as light as possible and to increase the use of biodiesel so that the
fuel that are on verge of extinction finds the better alternative in the near future.
AEIOU SHEETS
AEIOU Framework
AEIOU is a heuristic to help interpret observations gathered by ethnographic practice
in industry. Its two primary functions are to codedata, and to develop building
blocks of models that will ultimately address the objectives and issues of a client.
Taxonomies
AEIOU stands for 5 elements to be coded:Activity, Environment, Interaction,
Object, and User.
 Activities aregoal-directed sets of actions—paths towards things people
want to accomplish. What are the modes people work in, and the specific
activities and processes they go through?
 Environments includethe entire arena where activities take place. What is
the character and function of the spaceoverall, of each individual's spaces,
and of shared spaces?
 Interactions arebetween a person and someone or something else; they are
the building blocks of activities. Whatis the nature of routine and special
interactions between people, between people and objects in their
environment, and across distances?
 Objects are building blocks of the environment, key elements sometimes put
to complex or unintended uses (thus changing their function, meaning and
context). What are the objects and devices people have in their environments
and how do they relate to their activities.
 Users are the people whose behaviors, preferences, and needs are being
observed. Who is there? What are their roles and relationships? What are their
values and prejudices?
Activities
Environment
Interactions
Objects
Users
Learning NeedsMatrix (LNM) Theory
Description
A training/competency matrix is a tool used to document and compare the required
competencies for a position with the current skill level of the employees performing
the roles.
It is used in a gap analysis for determining where you have critical training needs and
as a tool for managing people development.
It can also be used in successionplanning as a means of identifying employees who
have critical skills needed for promotion.
Benefits
 Provides a comprehensive view of all the skills and behaviors needed.
 Aids in managing your training budget becauseit identifies skill gaps across
your organization rather than just one person at a time.
 Assists with planning by helping you identify and target new skill areas that you
might need for the long term.
 Helps managers with development planning by providing a framework of
common skills required.
LNM Sheet
 In this sheet we studied various topics such as Performanceparameters, Basic
construction Of diesel engine and it’s assembly, Parts and material
specifications, Properties Of oil (Soyabean oil, karanja, Mahua ,etc).
 Also we are able to justify and decide what Materials, Parts, softwareetc. will
be needed further.
 LNM Sheet helped us to decide various needs that will be helpful and handy in
further study.
Rapeseedand Canola
Rapeseed adapts well to low fertility soils, but with high sulfur content. With a high oil yield (40–
50%), it may be grown as a winter-cover crop, allows double cultivation and crop rotation.
It is the most important raw material for biodiesel production in the European Community.
However, there were technological limitations for sowing and har- vesting in some Central and South
American countries, mainly due to the lack of adequate information about fertilization, seed
handling, and storage (the seeds are very small and require specialized agricultural machinery).
Moreover, low prices in comparison to wheat (its main competitor for crop rotation) and low
production per unit area have limited its use.
Rapeseed flour has high nutritional value, in comparison to soybean; it is used as a protein
supplement in cattle rations.
Sometimes canola and rapeseed are considered to be synonymous; canola (Canadian oil low acid)
is the result of the genetic modification of rapeseed in the past 40 years, in Canada, to reduce the
content of erucic acid and glucosinolates in rapeseed oil, which causes inconvenience when used in
animal and human consumption.
Canola oil is highly appreciated due to its high quality, and with olive oil, it is considered as one
of the best for cooking as it helps to reduce blood cholesterol levels.
Soybean
It is a legume originating in East Asia. Depending on environmental conditions and genetic varieties,
the plants show wide variations in height. Leading soybean producing countries are the United States,
Brazil, Argentina, China, and India.
Biodiesel production form soybean yields other valuable sub-products in addition to glycerin:
soybean meal and pellets (used as food for livestock) and flour (which have a high content of lecithin,
a protein). Grain yield varies between 2,000 and 4,000 kg/hectare. Since the seeds are very rich in
protein, oil content is around 18%.
Oil Palm
Oil palm is a tropical plant that reaches a height of 20–25 m with a life cycle of about 25 years. Full
production is reached 8 years after planting.
Two kinds of oil are obtained from the fruit: palm oil proper, from the pulp, and palm kernel oil,
from the nut of the fruit (after oil extraction, palm kernel cake is used as livestock food). Several
high oil-yield varieties have been developed. Indonesia and Malaysia are the leading producers.
International demand for palm oil has increased steadily during the past years, the oil being used
for cooking, and as a raw material for margarine production and as an additive for butter and bakery
products.
It is important to remark that pure palm oil is semisolid at room temperature(20–22LC), and in
many applications is mixed with other vegetable oils, sometimes partially hydrogenated.
Sunflower
Sunflower ‘‘seeds’’ are really a fruit, the inedible wall (husk) surrounding the seed that is in the
kernel.
The great importance of sunflower lies in the excellent quality of the edible oil extracted from its
seeds. It is highly regarded from the point of view of nutritional quality, taste and flavor. Moreover,
after oil extraction, the remaining cake is used as a livestock feed. It must be noted that sunflower oil
has a very low content of linoleic acid, and therefore it may be stored for long periods.
Sunflower adapts well to adverse environmental conditions and does not require specialized
agricultural equipment and can be used for crop rotation with soybean and corn. Oil yield of current
hybrids is in the range 48–52%.
Peanut
The quality of peanut is strongly affected by weather conditions during the harvest. Peanuts are
mainly used for human consumption, in the manufacture of peanut
Flax
Flax is a plant of temperate climates, with blue flowers. Linen is made with the threads from the stem
of the plant and the oil from the seeds is called linseed oil, used in paint manufacture. Flax seeds
have nutritional value for human con- sumption since they are a source of polyunsaturated fatty acids
necessary for human health. Moreover, the cake left over, following oil extraction, is used as a
livestock feed.
The plant adapts well to a wide range of temperature and humidity; however, high temperatures
and plentiful rain do not favor high yields of seed and fiber.
Flax seeds contain between 30 and 48% of oil, and protein content is between 20 and 30%. It is
important to remark that linseed oil is rich in polyunsaturated fatty acids, linolenic acid being from
40 to 68% of the total.
Safflower
Safflower adapts well to dry environments. Although the grain yield per hectare is low, the oil content
of the seed is high, from 30 to 40%. Therefore, it has economic potential for arid regions. Currently,
safflower is used in oil and flour production and as bird feed.
There are two varieties, one rich in mono-unsaturated fatty acids (oleic acid) and the other with a
high percentage of polyunsaturated fatty acids (linoleic acid). Both varieties have a low content of
saturated fatty acids.
The oil from safflower is of high quality and low in cholesterol content. Other than being used for
human consumption, it is used in the manufacture of paints and other coating compounds, lacquers
and soaps.
It is important to note that safflower oil is extracted by means of hydraulic presses, without the use
of solvents, and refined by conventional methods, without anti-oxidant additives.
The flour from safflower is rich in fiber and contains about 24% proteins. It is used as a protein
supplement for livestock feed.
Castor Seed
The castor oil plant grows in tropical climates, with temperatures in the range20–30LC; it cannot
endure frost. It is important to note that once the seeds start germinating, the temperature must not
fall below 12LC. The plant needs a warm and humid period in its vegetative phase and a dry season
for ripening and har- vesting. It requires plenty of sunlight and adapts well to several varieties of
soils. The total rainfall during the growth cycle must be in the range 700–1,400 mm; although it is
resistant to drought, the castor oil plant needs at least 5 months of rain during the year.
Castor oil is a triglyceride, ricinolenic acid being the main constituent (about 90%). The oil is non-
edible and toxic owing to the presence of 1–5% of ricin, a toxic protein that can be removed by cold
pressing and filtering. The presence of hydroxyl groups in its molecules makes it unusually polar as
compared to other vegetable oils.
Tung
Tung is a tree that adapts well to tropical and sub-tropical climates. The optimum temperature for
tung is between 18 and 26LC, with low yearly rainfall.
During the harvest season, the dry nuts fall off from the tung tree and are collected from the ground.
Nut production starts 3 years after the planting.
The oil from tung nuts is non-edible and used in the manufacture of paints and varnishes, especially
for marine use.
Cotton
Among non-foodstuffs, cotton is the most widely traded commodity. It is produced in more than 80
countries and distributed worldwide. After the harvest, it may be traded as raw cotton, fiber or seeds.
In cotton mills, fiber and seeds are separated from raw cotton.
Cotton fiber is processed to produce fabric and thread, for use in the textile industry. In addition,
cotton oil and flour are obtained from the seed; the latter is rich in protein and is used in livestock
feed and after further processing, for human consumption.
Jojoba
Although jojoba can survive extreme drought, it requires irrigation to achieve an economically viable
yield.
Jojoba needs a warm climate, but a cold spell is necessary for the flowers to mature. Rainfall must
be very low during the harvest season (summer). The plant reaches its full productivity 10 years after
planting.
The oil from jojoba is mainly used in the cosmetics industry; therefore, its market is quickly
saturated.
Jatropha
Jatropha is a shrub that adapts well to arid environments. Jatropha curcas is the most known variety;
it requires little water or additional care; therefore, it is adequate for warm regions with little fertility.
Productivity may be reduced by irregular rainfall or strong winds during the flowering season. Yield
depends on climate, soil, rainfall and treatment during sowing and harvesting. Jatropha plants
become productive after 3 or 4 years, and their lifespan is about 50 years.
Oil yield depends on the method of extraction; it is 28–32% using presses and up to 52% by solvent
extraction. Since the seeds are toxic, jatropha oil is non- edible. The toxicity is due to the presence
of curcasin (a globulin) and jatrophic acid (as toxic as ricin).
Avocado
Avocado is a tree between 5 and 15 m in height. The weight of the fruit is between 120 and 2.5 kg
and the harvesting period varies from 5 to 15 months. The avocado fruit matures after picking and
not on the tree.
Oil may be obtained from the fruit pulp and pit. It has a high nutritional value, since it contains
essential fatty acids, minerals, protein and vitamins A, B6, C, D, and E. The content of saturated fatty
acids in the pulp of the fruit and in the oil is low; on the contrary, it is very high in mono-
unsaturated fatty acids (about 96% being oleic acid). The oil content of the fruit is in the range 12–
30%.
Microalgae
Microalgae have great potential for biodiesel production, since the oil yield (in liters per hectare)
could be one to two orders of magnitude higher than that of other raw materials. Oil content is usually
from 20 to 50%, although in some species it can be higher than 70% . However, it is important to
note that not all mic- roalgae are adequate for biodiesel production.
High levels of CO2, water, light, nutrients and mineral salts are necessary for the growth of
microalgae. Production processes take place in raceway ponds and photobiological reactors.
Chemical formulas of the main fatty acids in
vegetable oils
Fatty acid Chemical formula
Lauric (12:0) CH3(CH2)10COOH
Palmitic (16:0) CH3(CH2)14COOH
Estearic (18:0) CH3(CH2)16COOH
Oleic (18:1) CH3 (CH2)7
CH = CH
(CH2)7 COOH
Linoleic (18:2) CH3(CH2)4
CH = CH CH2 CH =
CH (CH2)7 COOH
Linolenic (18:3) CH3
CH2 (CH = CH
CH2)3 (CH2)6 COOH
Erucic (22:1) CH3(CH2)7
CH = CH
(CH2)11 COOH
Ricinoleic (18:1) CH3(CH2)5
CHOH CH2 CH =
CH (CH2)7 COOH
Approximate content (in weight) of saturated and non-saturated fatty acids in some vegetable
oils and animal fats
Oil/fat
SFA
(& % w/w)
NSFA
(& % w/w)
Coconut 90 10
Corn 13 87
Cottonseed 26 74
Olive 14 86
Palm 49 51
Peanut 17 83
Rapeseed 6 94
Soybean 14 86
Sunflower 11 89
Safflower 9 91
Castor 2 98
Yellow grease 33 67
Lard 41 59
Beef tallow 48 52
Injection Experiments
The process of injecting diesel, biodiesel, or a blend into the cylinder through
orifices within the body of the injector leads to a naturally leads to a particular
distribution of equivalence ratio. Diesel fuel being expelled from an injector . The type
and quantity of harmful emissions thus depends on the cylinder conditions at the SOI,
the physical properties of the fuel, the injector geometry, and the combustion chamber
geometry. The injector, nozzle, and fuel properties directly affect the fuel droplet
diameter distribution. Typically injection studies have been done at atmospheric
pressure so that surface wave phenomenon, caused by drag, can be observed
occurring on droplets as they travel away from the fuel nozzle. The effect of injection
pressure on velocity and its subsequent affect on droplet size was studied extensively
by Koo and Martin .
Spray emitted from a high-pressure diesel fuel injector.
Injection studies tend to be done in high pressure spray boxes or in CFD. With
advents in high-speed signal processing equipment, researchers are now able to study
combusting dynamic sprays in high pressure environments. Injectors with various
geometries and orifice diameters were tested to observe the effect on spray penetration
lengths. conducted an extensive study effects orifice diameter and injection pressure on
CH after mixture and OH formation after ignition around the jet. A spray penetration
model was introduced by Abani and Reitz. using jet theory for the incorporation of time
varying injection into CFD models.
Engine Experiments
Engine experiments mostly test injection strategies on engines of particular
displacements or piston geometries. investigated how the depth of omega piston
geometry affects emissions and efficiency of diesel engines. Much like the injection
experiments, either physical experimentation or numerical investigations are conducted.
There have been quite a number of studies where researchers have measured the
emissions of biodiesel combustion at various operating conditions and loads.
demonstrate percentage decreases in oxides of carbon and nitrogen (NOX) as well as
particulate matter and unburned hydrocarbons using soybean B20 fuel. both used a
Caterpillar SCORE similar to investigate the increase in oxides of nitrogen using SME
fuel and attributed its cause to factors other than the start of combustion crank angle
window. Increased NOx emissions can be attributed to a difference in flame lift-off
length (LOL) and the higher elapsed time of combustion
Experiments have been conducted using methyl esters made from several oils.
produced several batches of cotton seed oil methyl ester (CSOME) and the trend of
reduced emissions and increased NOx. used blends of diesel, biodiesel, and bio-ethanol
and identified a decrease in engine thermal efficiency.
Properties of Biodiesel
Liquid Properties and Sprays
The liquid properties of biodiesel can negatively influence the quality of its
movement throughout the fuel system of the engine as shown by Tefsa
. Biodiesel of various types is known to dissolve fuel lines and clog filtration devices
due to its chemical composition and other physical differences.
immersed several types of elastomers into palm methyl ester (PME) and recorded
reduction in material strength. Electrochemical reactivity is not a typical focus of
numerical flow studies however, some material properties are measured which are of
concern. The fluid properties are needed in CFD studies to adjust the spray and
breakup models. studied the effect of liquid fuel properties of five fuels
on liquid penetration distance length in diesel engines and found that it is proportional to
viscosity. Most literature, involving biodiesel, cites common proprieties at room
temperature. For the best precision, it is necessary to have property curves as functions
of temperature. utilized a capacitance densitometer to measure the density of soy,
canola, and fish oil methyl ester up to 573K. measured and curve fit the specific heat
and enthalpy of SME and several other biofuels.
Vapor Properties and Combustion
The characteristics of biodiesel fuels must be known at temperatures in the vapor
phase in order to model droplet atomization, evaporation, and combustion within the
cylinder. There is not a sizable volume of literature with the vapor properties of plant oils
or methyl esters verified using specialized experiments.
By dividing sprays into separate areas, separate discrete and empirical models can then
be interjected to simplify complex aspect of sprays. A quiescent chamber CFD model
was used to calibrate the overall injection and breakup models against the liquid and
vapor penetration distances provided in the experimental data of Singh [11]. The stand-
alone high pressure chamber allowed the parameters of the spray model to be studied
and augmented independently of the overall engine model. Figure
15 is a labeled depiction of a mini-sac injector.
Mini-sac diesel injector tip
A phenomenological plain orifice atomization model was utilized to empirically
incorporate internal nozzle conditions and their physical effects on the spray angle,
droplet geometry, and droplet velocity. High pressure flows through cylindrical nozzles
is very complex. In the plain orifice model, the nozzle flow velocity,coefficient of
discharge, the spray angle, and the cavitation number, for separate nozzle operation
regimes, are calculated using the injection pressure, cylinder pressure near the nozzle
orifice, Reynolds number, nozzle geometry, area coefficient,
and the fuel properties such as liquid density, and vapor pressure . Fuel kinematic
viscosity,mass flow rate,and a proportionality constant,are also
used to calculate injection parameters.
As the needle closes the fuel supply to the mini-sac, the flow transitions back
through the modes of flow in reverse. It is the transitional flow phenomenon in concert
with fluid properties which leads to the complexity of high pressure orifice sprays. There
is a lot of interplay between the cylinder pressure and the spray velocity implied by
Bernoulli's equation. It is the increase in cylinder pressure that overcomes liquid fuel
viscosity and leads to cavitation and atomization. Droplet breakup, collision, and
secondary breakup are simulated using the Kelvin-Helmholtz (KH) aerodynamic drag
model, O'Rourke's collision probability algorithm, and the Raleigh-Taylor (RT) instability
breakup model. A Lagrangian discrete phase model (DPM) is used to simulate turbulent
droplet dispersion. The KH-RT model assumes that fuel droplets are emitted from a
column of liquid blobs because of shear forces imparted by the continuous phase.
Those droplets may collide and form larger droplets or travel on being guided by the
continuous phase. The smallest discrete droplets, which will no longer collide or
breakup, are in the domain after the secondary breakup process, the continuous gas
phase interacts with them. The mass and velocity of the droplets is reduced via thermal
and momentum energy transfer. The droplets vaporize and deposit their fuel mass into
the cells along their path of travel through the combustion chamber and become part of
the continuous gas phase. The aggregate continuous gas phase properties go into the
finite-rate or eddy dissipation chemistry model and energy equation calculations.
The quiescent spray chamber model consists of one nozzle centered at the top
with its spray axis in the downward vertical direction. The initial pressure within the
chamber is held at the motored TDC pressure. The entire spray formation is simulated
across all degrees of crankshaft angle movement for the DOI at 1200 revolutions per
minute. The elapsed time of the spray is approximately 1389 microseconds, at high
temperature engine operating conditions, with a 691 microsecond short ignition
delay. The shape of the equivalence ratio field, liquid penetration length, and vapor
penetration field with petroleum diesel were compared to the experimental data from.
The use of a phenomenological spray model, that predicts initial spray distribution
based on the injector specifications and fuel fluid properties, allows direct substitution
of liquid fuels with slightly different physical properties with adjustments to the breakup
model. The breakup model coefficient adjustments were arrived at using trial and error.
The mesh used for the quiescent spray chamber is depicted.
: Quiescent spray chamber mesh
The specifications of the injector are listed
Sandia/Cummin Injector Specification
Sandia/CumminsN14 Injector Specifications
Type Common Rail, pilot valve
Rail pressure 120MPa or 160MPa
Cup type Mini sac
Number of orifices 8 - 1/45°
Orifice diameter (mm) 0.196
Orifice
Length/Diameter
5
Included spray angle 152°
Discharge coefficient 0.67
Area coefficient 0.93
Velocity coefficient 0.72
Combustion Chamber Mesh Grid
The key geometry that must be reproduced is the piston and the proximity of its
crown geometry to the head surface, within the combustion chamber during crankshaft
angle change. The overall number of computations is directly related to mesh density,
the number of steps during compression, the number of steps during combustion, and
the complexity of the solver configuration. The mesh grid geometry of the combustion
chamber volume, are pre-generated outside of ANSYS Fluent™ with ANSYS ICEM©.
The mesh grids used for this thesis work are shown in Figure . The mesh grids are
sector meshes that represent one eighth of the cylinder. Only one injection orifice is
considered. The crevice measured from the top most surface of the piston down to the
first ring was omitted.
Figure Cylinder combustion mesh grids
Dynamic Meshing
The volume and shape of the combustion chamber are augmented along the
cylinder axis. It is assumed that the crankshaft's angular velocity is constant which
allows the time step size to be constant during the various phases of combustion. The
Fluent solver requires that the user provides the number of desired steps. All of the
engine sector mesh grids, used in this thesis, that are read into Fluent, start at TDC and
must be manipulated to expand them to the appropriate volume associated with the IVC
crankshaft angular position. From that time point forward, the number of time steps
required to reach the period just before the exhaust valve opens is defined by the
following equation:
Diagram depicting all terms in piston position calculation
The cells are grown from and collapsed into the head boundary during the
solution. The result is a separate mesh for each individual timestep. Figure 19 is a
depiction of the mesh growth.
Mesh grid cell augmentation during the solution process
CFD Solver Configuration
Initial and Boundary Conditions
The typical steps for IC simulation, when the intake, valve, manifold port
geometry, and velocity profiles are known, is to setup and solve a cold flow case with no
combustion. In a cold flow case, the introduction of charge air through the intake port
and valve is considered. The cold flow solution can be applied as the initial conditions of
the compression and combustion simulation so that the initial field values at IVC can be
made as realistic as possible. If the head port and valve geometry are not known, the
initial conditions of swirl and tumble after IVC can be approximated. Because the
detailed cylinder head geometry of the N14 engine is unknown, at this time, all of the
simulation in this work omits valve motion by simulating the time period from IVC to
EVO. Also, cylinder air swirl and tumble are assumed to occur about cylinder axis. A
user defined function, written in C, was used to define the initial velocity field at
IVC. Trial and error methods were used to set the swirl ratio number at IVC such that
the TDC swirl ratio was about 0.52 as stated by Singh. Figure is a depiction of the swirl
phenomenon.
Figure Intake swirl flow diagram
The initial air component mass fractions, gauge pressure, and temperature were
set according to the specifications given. The injection
settings were configured for each case by calculating the effective mass flow rate for
one nozzle.
Pollutant Formation Modeling
Two pollutants of main concern are NOx and soot. They are both formed at
opposite ends of the combustion operating range. NOx is typically formed when the
combustion equivalence ratio is less than unity and flame temperatures are high. Soot is
formed mostly as the result of pyrolysis within fuel rich regions at medium and lower
temperatures. Because diesel engines operate at maximum volumetric frequency and
rely on turbulent diffusion for reactant mixing, these two major pollutants are formed
simultaneously. Figure is a depiction of the soot and NOx formation zones as functions
of equivalence ratio, combustion temperature, and air oxygen volume percentage.
Figure Soot and NOx production zones typical of diesel engines (Sandia 1993)
It was assumed that the major component of NOx emissions was nitric oxide
(NO). Several models are used to predict NO formation. NO that is promptly formed in
the regions of high equivalence ratio and low temperature can predicted using the
Fenimore model. The Fenimore model was not used because the residence time of all
species is 0.020seconds, which is particularly long. Without activating a return model,
overproduction of NO would be a trend. Thermal NO is modeled using the Zeldovich
mechanism correlations for the oxidation of nitrogen within the intake air.
The Tenser model was utilized for soot emission prediction which involves
carbon forming on nucleating particles. Soot formation properties were set according to
default values The stoichiometric of soot and fuel combustion were set respectively for
each fuel based on carbon number.
Several Fluent custom field functions are used to calculate ending pollutant
quantities at EVO and other points in the cylinder and are shown as a contiguous file in
appendix A.
Solution Process
Along with the momentum equations, the pressure based Fluent solver is
configured to solve the energy, viscous model, species transport, and reaction
equations. Pressure and velocity is coupled using the pressure implicit with splitting of
operators (PISO) scheme. The overall solution process that results from the
configuration of ANSYS Fluent is depicted in figure.
Figure ANSYS Fluent™ transient solution process after configuration
Post-processing and Analysis
The was solver configured to output several parameters which allow generation
of heat release curves. The apparent heat release rate (AHRR), , was numerically
estimated using the calculated average cylinder pressure as a function of crank angle.
The heat release equation in (Heywood 1988) was numerically represented as is the
typical practice to produce an AHRR curve from an experimental pressure trace. The
Eichelberg empirical relation for convective heat transfer, out of the continuous phase,
into the cylinder wall, was added.
The average cylinder wall temperature, , the bulk continuous phase
temperature, , the cylinder wall area, , and the combustion chamber volume, ,
are obtained at the end of each converged time step. The values of pollutant quantities
are only considered at EVO as it is assumed that combustion has concluded prior to
that event.
Cylinder Pressure
The mean cylinder pressure is a measure of volume averaged cylinder pressure
from IVC to EVO during the simulation. For case one, three diesel and one biodiesel
simulations were conducted. The ignition delay is over predicted for case one. The RNG
k-e turbulence model was utilized for the first diesel case in conjunction with a laminar
finite-rate combustion model and had the longest ignition delay. The first of the diesel
simulations also over predicted the peak average combustion pressure. The effect on
MeanCylinderPressure(MPa)
combustion because of fuel property, injection rate, and spray formation differences
between fuels can be visualized with the pressure curve. Pressure curves for all cases
are shown in figures.
Sandia Cummins N14 Mean Pressure - Case1 [HT-SID]
9
8
7
6
5
Singh2006 Pressure1
c1-D1-Pressure (MPa)
4 c1-D2-Pressure (MPa)
c1-D3-Pressure (MPa)
c1-MD2-Pressure (MPa)
3
2
705 715 725 735 745 755
Crank Angle (CAD)
Figure Case 1, High Temperature, short ignition delay pressure curves
Singh2006 Pressure2
c2-D1-Pressure (MPa)
c2-D2-Pressure (MPa)
c2-MD-Pressure (MPa)
MeanCylinderPressure(MPa)
Sandia/Cummins N14 - Mean Pressure [HT-LID]
8
7
6
5
4
3
2
705 715 725 735 745 755
Crank Angle (CAD)
Figure Case 2, High-temperature, long ignition delay pressure curves
For case two, the ignition delay was predicted well using the RNG k-e turbulence
model for the first diesel simulation. The second diesel and methyl decanoate
simulations have shorter ignition delays. Short ignition delay and high peak pressure
indicate maladjustment of the autoignition model.
MeanCylinderPressure(MPa) Sandia Cummins N14 - Mean Pressure [LT-EI]
10
9 Singh2006 Pressure3
c3-D1-Pressure (MPa)
c3-MD1-Pressure (MPa)
8
7
6
5
4
690 700 710 720 730 740 750 760
Crank Angle (CAD)
Figure Case 3, Low-temperature, early injection pressure curves
Case three ignition delays and peak combustion pressure seem to show the
effects of differing physical properties of fuels. The combustion rate of the fuels seems
to be higher than the experimental data in all cases leading up to case three.
Singh2006 Pressure4
c4-D1-Pressure (MPa)
MeanCylinderPressure(MPa)
The pressure level in cases four and five match the experimental pressure
curves very well. The ignition delay is smaller than that of the experimental data but,
combustion rate seems to match in case five.
Sandia/Cummins N14 - Mean Pressure [LT-LI]
8
7
6
5
4
3
2
705 715 725 735 745 755
Crank Angle (CAD)
Figure Case 4, Low-temperature, late injection pressure curves
Singh2006 Pressure5
c5-D1-Pressure (MPa)
MeanCylinderPressure(MPa)
Sandia/Cummins N14 - Mean Pressure [LT-DI]
8
7
6
5
4
3
2
705 715 725 735 745 755
Crank Angle (CAD)
Figure Case 5, Low-temperature, double injection pressure curves
All results could be improved by determining a method to match the experimental
injection mass flow rate curves, more tuning of the droplet collision breakup model, and
having accurate information about the kinematic viscosity of biodiesel. The spray model
is very dependent on accurate fuel properties to determine which modes the injector
nozzle is operating in. The autoignition energy of the fuels also need to be known more
accurately so that the detonation and high a burn rate of the fuel does not occur. Sharp
spikes in simulated pressure mean that the injector nozzle may spend more time in the
flipped mode than the cavitating mode during the DOI. The accurate simulation liquid
spray impingement and subsequent modes of evaporation require very fine wall mesh
grids because of interaction with turbulence modeling.
Temperature(K)
Combustion Temperature
The temperature result of the simulations is compared with experimental data.
The adiabatic temperatures in the experimental data are calculated using STANJAN
code with optical data during the soot formation and soot combustion as input. Since
the experimental data is actually a theoretical calculation of maximum adiabatic flame
temperature, simulation results are only provided so that general temperature trends
correlations can be identified. Additional Temperature plots are in
appendix B
2540
Sandia Cummins N-14 Combustion Temperature [HT-SID]
2440
2340
2240
2140
2040
1940
1840
Singh2006 Temperature1
c1-D1-Temperature (K)
c1-D2-Temperature (K)
c1-D3-Temperature (K)
c1-MD2-Temperature (K)
1740
720 722 724 726 728 730 732
Crank Angle (CAD)
Figure Case 1, High Temperature, short ignition delay temperature curves
ApparentHeatReleaseRate(J/°)
Apparent Heat Release Rate
The AHRR curves are modeled using a single zone zero-dimensional
thermodynamic model. Because of error in the temperature and pressure curves in
section , the calculated maximum AHRR overshoot the experimental data
significantly however, trends such as a negative AHRR at the SOI before autoignition
are reproduced. Tuning of the autoignition model alone could have positive effects for
the increase of accuracy. The AHRR curves for cases two, three, four, and five are in
appendix B.
650
SCORE Cummins N14 - Apparent Heat Release Rate
Results [HT-SID]
550
450
350
250
150
Singh-c1-AHHR(J/deg)
c1-D1-AHHR(J/deg)
c1-D2-AHHR(J/deg)
c1-D3-AHHR(J/deg)
c1-MD2-AHHR(J/deg)
50
-50
713 723 733 743 753
Crank Angle (CAD)
Figure Case 1, High Temperature, short ignition delay heat release curves
%changeinemissions
Combustion Emissions
Given most of the published data at the time, the EPA characterized the
overall average trend in reduction of regulated emissions when using soy methyl ester
biodiesel in heavy-duty highway engines. is the EPA's published emission impacts of
SME on heavy duty highway engines.
20 % Change in USEPA Regulated Emission with SME
Biodiesel
10
0
-10
-20
-30
-40
0 20 40 60 80 100
NOx
PM
CO
HC
-50
-60
-70
Volumetric % SME biodiesel in fuel
Figure Percent change in regulated emissions with SME biodiesel
Table is a comparison of NOx emissions at EVO between biodiesel and diesel fuel.
The high temperature case with long ignition delay is the only case that is somewhat in
agreement with the emissions trends.
Table Percent increase in NOx between simulated fuels
Simulated NOx at EVO (845deg) [g/(hp*hr)] or [ppm]
HT-SID HT-LID LT-EI LT-LI (ppm) LT-DI (ppm)
Diesel#2 29.6 16.8 1 63 87.7
MD 5.4 20.9 0.47 -- --
-452% 19.8% -126% -- --
UnburntFuelatEVO[g/(hp*hr)]
Unconsumed Fuel
Unconsumed fuel is a regulated pollutant in most jurisdictions. In the U.S., the
EPA specifies that an on-road heavy truck or combination tractor powered by a heavy-
duty compression ignition engine, such as the Cummins N14, can only emit up to
1.3g hp hr of unburned fuel from the exhaust. If an engine produces 100 brake
horse power at speed, it could only output up to 130 grams of unconsumed fuel over the
course of an hour of operation. Table depict the estimated average levels of fuel
pollutants.
Fuel emissions at end of simulation
Unburnt Hydrocarbons at EVO (845deg) [g/(hp*hr)]
HT-SID HT-LID LT-EI LT-LI LT-DI
Diesel#2 4.33E-05 5.75E-03 1.06E-04 1.56E-04 5.21E-04
MD 6.18E-05 6.87E-05 2.56E-02 -- --
Unconsumed Fuel at EVO (845deg)
3.00E-02
2.50E-02
2.00E-02
1.50E-02
1.00E-02
Diesel#2
MD
5.00E-03
0.00E+00
HT-SID HT-LID LT-EI LT-LI LT-DI
Figure Unconsumed fuel in domain at EVO
SootParticulateVolume[mm3]
Particulates
Soot luminosity and processing techniques were used by Singh to determine
soot volume from optical experiments. The simulation results for all cases match the
trend of the experimental results well. Table depict the volume of soot particulates in
the fuel jet.
0.6
Particulates [mm3]
0.5
0.4
0.3
0.2
Singh 2006
Diesel#2
MD
0.1
0
HT-SID HT-LID LT-EI LT-LI LT-DI
Figure Particulates in domain at EVO
Table Particulate emissions at specified crankshaft angles
Particulates [mm
3
]
HT-SID HT-LID LT-EI LT-LI LT-DI
CAD 725 728 715 741 755
Singh 2006 0.55667 0.08357 0.04296 0.0677 0.0677
Diesel#2 0.01213 0.01046 2.45E-05 1.78E-09 1.17E-09
MD 8.41E-04 1.18E-05 7.90E-09 -- --
Fuelspray characteristis
Injection spray is the process that fuel is injected from nozzle, and it is
associated with following fuel atomisation, interaction with surrounding gas,
mixture formation and com‐ bustion. Regarding to a new fuel applied into the
diesel engine, the spray process is differ‐ ent due to the different properties
from diesel, and the control strategy should be changed accordingly in order
to achieve the optimum performance. Viscosity, surface tension and density
are the three main parameters, which influence fuel spray characteristics.
Higher viscosity and surface tension will prohibit the atomisation and
instability of fuel droplets. Due to the different biodiesels properties from
diesel, studies on the spray characteristics are necessary.
Near-fieldspray
characteristics
In the near-field of nozzle, the spray is dominated by the injection dynamics
while the spray is affected by the ambient conditions in the far field.
According to Hiroyasu’s model, before the t breakup, which represents the
time for fuel jet breakup, the penetration length is proportion‐ al to the time
after start of injection, namely ASOI. However, the non-linear phenomenon
has been observed by a number of researchers. The acceleration process has
been found to be different among fuels. Figure 4 compares the morphology of
the spray process of the three tested fuels, ULSD, RME and GTL and Figure 5
shows the spray tip penetration length evolution after start of injection (ASOI)
using an ultrahigh-speed CCD camera of up to 1 million shots per second. The
initial non-linear penetration can be observed, indicating the acceleration
period at the initial spray stage. GTL fuel has longer penetrating length than
RME and die‐ sel even though it was overtaken by RME 70 µs ASOI. Several
publications have reported that GTL with lower density has a shorter
penetration delay. However, these were based on the global fuel spray
characteristics using a relatively low speed camera [21, 13]. The temporal
resolution is not high enough to capture the near-field spray process.
Sequence of spray images in a single time-resolved ULSD spray (Pinj=120 MPa,
Pamb =3.0 MPa and tdur=1.5 ms
Macroscopic spray
characteristics
Normally, biodiesel shows a longer penetration and narrower spray angle than
fossil fuel due to the higher viscosity, surface tension and density. The
penetration length of biodiesel increases with the blend ratio, higher biodiesel
content requires longer breakup time . The difference between the two type
fuels can be varied at different conditions. experimentally studied biodiesel
spray characteristics at different ambient pressures. The authors showed that
little difference can be observed at the ambient pressure of 1.2 MPa while the
penetration length significantly increased in contrast to diesel spray at the
ambient pressure of 5.0 MPa. In addition, biodiesel may have a lower
penetration velocity due to the negative effect of fuel density on spray velocity
.
Sauter Mean diameter
(SMD)
SMD is one of the parameters to evaluate fuel atomisation quality and
represents the ratio of total droplet volume to surface area. Smaller SMD
indicates more small fuel droplets and the larger contact area with
surrounding gas. Due to the high viscosity and surface tension, SMD of
biodiesel is higher than fossil diesel. conducted the comparative anal‐ ysis on
15 biodiesels and a larger SMD, between 5%-40%, can be observed and
concluded an empirical equation to estimate SMD:
SMD =0.002103µ + 0.000330σ
where µis fuel dynamic viscosity (Pa.s) and σis fuel surface
tension (N/m).
compared diesel with neat RME and GTL at different injection pressure along
the spray axis in terms of SMD. It can be seen that the injection pressure has
a significant impact on droplet size. The SMD decreases dramatically when
the injection pressure increases from 80MPa to 120MPa.
Exhaust particulate number concentration (total)
Particle morphology (captured under engine mode of 1800 rpm, 30
Nm): (a) Diesel magnification of
10000; (b) Diesel magnification of 65000; (c) RME 10 magnification
of 10000; (d) RME magnification of 65000; (e) GTL10 magnification
of 10000; (f) GTL10 magnification of 65000
Engine emission optimisation
Two popular methods have been used to reduce the engine out emission for biodiesel-fuel‐
led engines: injection strategy and EGR. For the former, the combustion process can be con‐
trolled by injection timing and injection pressure. For the time being, the common rail
injection system has been widely used and multiple injections up to of 5 times can be real‐
ised. Through this way, the fuel injection rate is controllable. The NOx can be reduced
through pre-injection with small amount fuel; this prevents a long period of ignition delay
and therefore leads to a lower peak pressure; for the latter, EGR is always an effective way
to reduce NOx emission. Due to the induction of exhaust gas, the global in-cylinder tempera‐
ture is reduced, avoiding the thermal conditions favoured by NOx formation. Ladommatos
et al. [18] also revealed that the reduction in combustion temperature is a consequence of
the reduced peak rate of the premixed phase combustion due to the lower oxygen
availability.
Conclusions
Biodiesel is the most promising fuel in the near future as an alternative to fossil diesel. De‐
spite of its advantages, it still has some disadvantages such as source for massive feedstock,
relatively poor low-temperature properties, increase in NOx emissions, etc. These issues
should be sorted out before biodiesel is applied into diesel engines in a large scale. There‐
fore, in-depth studies on the application of biodiesel into diesel engines are necessary. The
research on alternative feedstocks is also an important area and the second-generation bio‐
diesel is more promising made from algae and the genetic modification is a potential way to
solve this problem of source of massive feedstock. The low-temperature fuel properties can
be improved by additives or the production routine. In addition, diesel engines should also
be optimised in order to achieve the optimal performance and emissions.
REFERENCE
 www.ideo.com
 www.howstuffworks.com
 www.wikipedia.com
 www.biodiesel.org
 Zhang, X., Wang, H., et al. (2008). Characteristics of Output
Performances and Emissions of Diesel Engine Employed Common Rail
Fueled with Biodiesel Blends from Wasted Cooking Oil. SAETechnical
Paper 2008-01-1833.
 Shashikant,V.G. and Hifjur Raheman, 2005.
Biodiesel production FromMahua oil having high free fatty
acids,JournalOf Biomass and Bioenergy,
28:601-605.
 Ramadhas, A.S., S.Jayaraj and C. Muraleedharan,2004
Use of Vegetable oils as I.C. engine fuel-a review,Renewableenergy,
29(5):721-742.
 Machine Design by R.S. Khurmi and J.K. Gupta
 Design of Machine Elements by V.P. Singh
 Automotive Mechanics by Crouseand Anglin.
 InternalCombustion engines By V.Ganesan.
 ICEngines by Mathur & Sharma.
 Automobile Engineering By Dr. Kirpal Singh.
 Alternative Fuels By Dr. KirpalSingh.
 Also different books, papers and other websites.

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Design Engineering

  • 1. GUJARAT TECHNOLOGICAL UNIVERSITY Chandkheda, Ahmedabad Affiliated K.J.I.T, Savali A Project Report On Four Stroke BiodieselEngine Under subject of DESIGN ENGINEERING IIB B. E. Semester – VI AUTOMOBILE ENGINEERING Submitted by: Sr. Name of student Enrollment No. 1 Yash Prakashbhai Ambekar 130640102004 2 Jaykumar Lalit Desai 130640102015 3 Yash Arvindbhai Prajapati 130640102048 4 Rocky Jagdishbhai Yadav 130640102052 Mr. Ronak Suthar (Faculty Guide) Mr. Kaustubh Natekar (HOD) Academic year (2016-2017)
  • 2. Contents 1. Introduction Name of the team About team members About guide and mentor What is Design Thinking? 2. Empathy Mapping Users Stakeholders Activities Story 3. Ideation Canvas People Activities Situation/context Props/Possible Solution 4. Product Development Canvas Product Experience Product Function Components People Customer Revalidation 5. AEIOU Sheets Activities Environment Interactions Objects Users 6. Learning Need Matrix (LNM) Theory Purpose/Project Concept Applicable Standards and Design Specifications Component Materials’ strength Criteria Software/Simulation/Skill/Mathematical Requirement Tools/Methods/Theories/application Process Involved
  • 3. Literature Review/Secondary Research 7. Design Considerations for detail design part: 7.1 Design for Performance, Safety and Reliability 7.2 Design for Ergonomics and Aesthetics 7.3 Design for Manufacturability & Assembly (DFMA) 7.4 Design for Cost, Environment 8. Design Calculation 9. Measuring Instruments/ techniques - knowledge and use 10. Comparison of existing materials, methods, tools and equipment for your project and justify your selection of materials, methods, tools and equipment etc. 11. Simulation and Analysis (Software modelling), Mathematical model 12. Conclusion/Future scope 13. Prototype
  • 4. ACKNOWLEDGMENT  To innumerable websites in the internet, and to all those who have uploaded their knowledge, imaginations, ideas, graphic skills etc., on these websites.  Also, to all those frompre-historic days to today, who have registered their knowledge, imaginations, thoughts etc., through different means and mediums.  Also Dr. M. Y. Vaijanapurkar M. E. , Ph. D (IITKharakpur) and Mr. Ronak Suthar for showing the correctpath and guiding us.  Not forgetting other faculty of the college who gave their contribution till their extent.
  • 5. DECLARATION We hereby declare that the DE-IIB Report Submitted Along With The Canvas Sheets Entitled “FOUR STROKE BIODIESEL ENGINE” In Partial Fulfillment For 6th Semester Automobile Engineering Of GTU, Ahmedabad During The Academic Year 2016-17 under the supervision of Mr. Ronak Suthar and that no part of these DE-IIB reports has been directly copied from any students reports or taken from any other source, without providing the reference. YASH PRAKASHBHAI AMBEKAR (130640102004) JAYKUMAR LALITKUMAR DESAI (130640102015) YASH ARVINDBHAI PRAJAPATI (130640102048) ROCKY JAGDISHBHAI YADAV (130640102052) Internal Guide Head of Department
  • 6. CERTIFICATE This Is To Certify That DE-IIB Report Submitted Along With The Canvas Sheets Entitled “FOUR STROKE BIODIESEL ENGINE” Has Been Carried Out By Yash Ambekar, Desai Jaykumar, Prajapati Yashand Rocky Yadav Under My Guidance In Partial Fulfillment For6th Semester Automobile Engineering Of GTU, Ahmedabad During The Academic Year 2016-17.These Students Have successfully Completed DE-IIB activity under my guidance. Internal Guide Head of Department
  • 7. Yash Ambekar Yash P. Ambekar is a student of Automobile Engg. Department of K.J.I.T Savali. He has helped in gathering the information regarding the topic. He has good knowledge about managing the finance. He has also helped in completing the Canvas Sheets neatly. His sincerity regarding the project is appreciable. His contribution regarding the DE-IIB is appreciable and worthwhile. Jay Desai Jay L. Desai is a student of Automobile Engg. Department of K.J.I.T Savali. He has got ability to handle the situation tactfully. He does not gets panic in any of the situation. He patiently works with the group mates and listen to each and every opinion of the team. He has got the ability to manage the team.His contribution regarding the DE-IIB is appreciable and worthwhile.
  • 8. Yash Prajapati Yash A. Prajapati is a student of Automobile Engg. Department of K.J.I.T Savali. He has helped in collecting the basic information about the project. He has helped in preparing the final Report for the same. He has good quality of creating the friendly environment among the group mates. He works with the team mates without any expectations. His sincerity regarding the project is appreciable. His contribution regarding the DE-IIB is appreciable and worthwhile. RockyYadav Rocky J. Yadav is a student of Automobile Engg. Department of K.J.I.T Savali. He has got ability of finding handy solutions at critical stages, which are very helpful. His compatibility with the Group mates is good and friendly. He creates humourous environment while working. His sincerity regarding the project is appreciable. His contribution regarding the DE-IIB is appreciable and worthwhile.
  • 9. Mr. Ronak Suthar Mr. Ronak Suthar (M.E.) is the Asst. Professor in Mechanical Department at K.J.I.T.,Savali.He is one of the devoted faculty of the department. He is very polite and has good knowledge about his field. His happy to help nature is really appreciable. Without his guidance this project was not possible. His Contribution at each level of this project is worthwhile. Dr. M.Y. Vaijanapurkar (M.E. Ph.D, IIT, Kharagpur ) was the Principal of K.J.I.T., Savali . He is one of the Best experienced faculty of the college. He is always happy to help and guide the students regarding exams, projects ,etc. His guidance is very helpful and worth. His polite and positive attitude towards students is really appreciable. His Contribution at each level of this project is worthwhile.
  • 10. Design Thinking is human-centered Design thinking has come to be defined as combining empathy for the context of a problem, creativity in the generation of insights and solutions, and rationality in analyzing and fitting various solutions to the problem context. According to our team the goal of Design Thinking is "matching people’s needs with what is technologically feasible and viable as a business strategy". The premise of teaching Design Thinking is that by knowing about how to successfully approach and solve difficult, multi-dimensional problems - more specifically, effective methods to ideate, select and execute solutions - individuals and businesses will be able to improve their own problem solving processes and skills. There is also significant academic interest in understanding howdesigners think and design cognition. Design thinking is a formal method for practical, creative resolution of problems and creation of solutions, with the intent of an improved future result. In this regard it is a form of solution-based , or solution-focused thinking; starting with a goal (a better future situation) instead of solving a specific problem. By considering both present and future conditions and parameters of the problem, alternative solutions may be explored simultaneously. Cross asserted that this type of thinking most often happens in the built, or artificial, environment (as in artifacts).  Focus on people / customers and their needs and not on a specific technology or other conditions.  Methods therefore used are observations, interviews, brainstorming, prototyping…  Innovating at the intersection of business, technology and people leads to radical, new experience innovation.  The user is the one to decide if a product or a service should exist or be established
  • 11. In short Design Thinking is a process through which we can make or modify new technology for betterment of common people. EMPATHY MAPPING CANVAS USERS: PUBLIC FARMERS DESIGNERS ENGINEERS DEVELOPERS
  • 12. MANUFACTURERS STAKEHOLDERS: TRANSPORTERS EXPORTERS AUTOMOTIVE INDUSTRIES LOCOMOTIVE INDUSTRIES ACTIVITIES: PRODUCTION OF BIO-DIESEL REFINING OF SEEDS TRANSESTERIFICATION BLENDING NEXT GEN. ENGINE REFINMENT CHANGED PIPING NEW IGNITION SYSTEM
  • 13.
  • 14. HAPPY Biodiesel fuel is a renewable energy source unlike petroleum-based diesel. An excessive production of soybeans in the world makes it an economic way to utilize this surplus for manufacturing the Biodiesel fuel. One of the main biodiesel fuel advantages is that it is less polluting than petroleum diesel. The lack of sulfur in 100% biodiesel extends the life of catalytic converters. Another of the advantages of biodiesel fuel is that it can also be blended with other energy resources and oil. Biodiesel fuel can also be used in existing oil heating systems and diesel engines without making any alterations. It can also be distributed through existing diesel fuel pumps, which is another biodiesel fuel advantage over other alternative fuels. The lubricating property of the biodiesel may lengthen the lifetime of engines. SAD At present, Biodiesel fuel is bout one and a half times more expensive than petroleum diesel fuel.It requires energy to produce biodiesel fuel from soy crops, plus there is the energy of sowing, fertilizing and harvesting. Another biodiesel fuel disadvantage is that it can harm rubber hoses in some engines. As Biodiesel cleans the dirt from the engine, this dirt can then get collected in the fuel filter, thus clogging it. So, filters have to be changed after the first several hours of biodiesel use. Biodiesel fuel distribution infrastructure needs improvement, which is another of the biodiesel fuel disadvantages.
  • 15. CONCLUSION: 1) Users are clearly mentioned and stakeholders are defined. 2) Activities regarding the project to be conducted step by step. 3) In story boarding it is clearly understood which part may be difficult and which will be tactfully conquered. IDEATION CANVAS: PEOPLE:
  • 16. PUBLIC FARMERS DESIGNERS ENGINEERS DEVELOPERS MANUFACTURERS ACTIVITIES: PRODUCTION OF BIO-DIESEL REFINING OF SEEDS TRANSESTERIFICATION BLENDING NEXT GEN. ENGINE REFINMENT CHANGED PIPING NEW IGNITION SYSTEM SITUATION/CONTEXT: PUBLIC TRANSPORT PRIVATE VEHICLES LOCOMOTIVES INDUSTRIES POWER PLANTS
  • 17. AGRICULTURE GENERATORS PROPS/POSSIBLE SOLUTIONS: BIO-DIESEL PRODUCTION: SEED CRUSHERS PUMPS BLENDERS FILTERS REFINERS ENGINEDESIGNING: TOOL BOX
  • 18. PIPE CUTTERS MOULDS DRILL MACHINE BORING MACHINE Should be considered for use as an alternative and not a primary fuel. Short and long term environmental benefits will be worth while. Storage Issues with Stability and Transportation issues with high cost of delivered fuel compared to fossil fuels. Fuel-supply reliability. Lack of understanding of environmental impact – Nox emissions. Complexity of biomass-power infrastructure compared to known well established coal and natural gas markets.
  • 20. PRODUCT EXPERIENCE: SUBSIDY AVAILABLE HIGH INITIAL COST NOT WIDELY USED
  • 21. PRODUCT FUNCTION: RENEWABLE SUSTAINABLE LOWER EMISSIONS COMPONENTS: TITANIUM VALVES HEAT EXCHANGER POLYMER PIPE FILTERS FUEL INJECTORS EXHAUST SYSTEM
  • 23. CUSTOMER REVALIDATION LESS AVAILABLE ENVIRONMENT FRIENDLY HIGH INITIAL COST EQUALLY POWERFUL ENGINE AS COMPARED TO PRESENT ONES.
  • 24. 75 years of diesel vehicles.B5 and B20 engine approvals. Most biodiesel applications = heavy- and medium-duty vehicles. Biodiesel fueling of light-duty vehicles is less common. Diesel engines = compression-ignited (CI).Gasoline engines = spark-ignited (SI).More torque. Most diesel engines can run on biodiesel blends of 5% to 20% with little or no modification. The use of conventional diesel leaves a deposit in the bottom of fuel lines, tanks, and delivery systems over time. The use of biodiesel can dissolve this sediment and result in the need to change filters more frequently when first using biodiesel until the whole system has been cleaned of the deposits left by the conventional diesel. To make The Engine as light as possible and to increase the use of biodiesel so that the fuel that are on verge of extinction finds the better alternative in the near future.
  • 25. AEIOU SHEETS AEIOU Framework AEIOU is a heuristic to help interpret observations gathered by ethnographic practice in industry. Its two primary functions are to codedata, and to develop building blocks of models that will ultimately address the objectives and issues of a client. Taxonomies AEIOU stands for 5 elements to be coded:Activity, Environment, Interaction, Object, and User.  Activities aregoal-directed sets of actions—paths towards things people want to accomplish. What are the modes people work in, and the specific activities and processes they go through?  Environments includethe entire arena where activities take place. What is the character and function of the spaceoverall, of each individual's spaces, and of shared spaces?
  • 26.  Interactions arebetween a person and someone or something else; they are the building blocks of activities. Whatis the nature of routine and special interactions between people, between people and objects in their environment, and across distances?  Objects are building blocks of the environment, key elements sometimes put to complex or unintended uses (thus changing their function, meaning and context). What are the objects and devices people have in their environments and how do they relate to their activities.  Users are the people whose behaviors, preferences, and needs are being observed. Who is there? What are their roles and relationships? What are their values and prejudices? Activities Environment
  • 28. Users
  • 29. Learning NeedsMatrix (LNM) Theory Description A training/competency matrix is a tool used to document and compare the required competencies for a position with the current skill level of the employees performing the roles. It is used in a gap analysis for determining where you have critical training needs and as a tool for managing people development. It can also be used in successionplanning as a means of identifying employees who have critical skills needed for promotion. Benefits  Provides a comprehensive view of all the skills and behaviors needed.  Aids in managing your training budget becauseit identifies skill gaps across your organization rather than just one person at a time.  Assists with planning by helping you identify and target new skill areas that you might need for the long term.  Helps managers with development planning by providing a framework of common skills required.
  • 30. LNM Sheet  In this sheet we studied various topics such as Performanceparameters, Basic construction Of diesel engine and it’s assembly, Parts and material specifications, Properties Of oil (Soyabean oil, karanja, Mahua ,etc).  Also we are able to justify and decide what Materials, Parts, softwareetc. will be needed further.  LNM Sheet helped us to decide various needs that will be helpful and handy in further study.
  • 31. Rapeseedand Canola Rapeseed adapts well to low fertility soils, but with high sulfur content. With a high oil yield (40– 50%), it may be grown as a winter-cover crop, allows double cultivation and crop rotation. It is the most important raw material for biodiesel production in the European Community. However, there were technological limitations for sowing and har- vesting in some Central and South American countries, mainly due to the lack of adequate information about fertilization, seed handling, and storage (the seeds are very small and require specialized agricultural machinery). Moreover, low prices in comparison to wheat (its main competitor for crop rotation) and low production per unit area have limited its use. Rapeseed flour has high nutritional value, in comparison to soybean; it is used as a protein supplement in cattle rations. Sometimes canola and rapeseed are considered to be synonymous; canola (Canadian oil low acid) is the result of the genetic modification of rapeseed in the past 40 years, in Canada, to reduce the content of erucic acid and glucosinolates in rapeseed oil, which causes inconvenience when used in animal and human consumption. Canola oil is highly appreciated due to its high quality, and with olive oil, it is considered as one of the best for cooking as it helps to reduce blood cholesterol levels. Soybean It is a legume originating in East Asia. Depending on environmental conditions and genetic varieties, the plants show wide variations in height. Leading soybean producing countries are the United States, Brazil, Argentina, China, and India. Biodiesel production form soybean yields other valuable sub-products in addition to glycerin: soybean meal and pellets (used as food for livestock) and flour (which have a high content of lecithin, a protein). Grain yield varies between 2,000 and 4,000 kg/hectare. Since the seeds are very rich in protein, oil content is around 18%. Oil Palm Oil palm is a tropical plant that reaches a height of 20–25 m with a life cycle of about 25 years. Full production is reached 8 years after planting. Two kinds of oil are obtained from the fruit: palm oil proper, from the pulp, and palm kernel oil, from the nut of the fruit (after oil extraction, palm kernel cake is used as livestock food). Several high oil-yield varieties have been developed. Indonesia and Malaysia are the leading producers. International demand for palm oil has increased steadily during the past years, the oil being used for cooking, and as a raw material for margarine production and as an additive for butter and bakery products. It is important to remark that pure palm oil is semisolid at room temperature(20–22LC), and in many applications is mixed with other vegetable oils, sometimes partially hydrogenated. Sunflower
  • 32. Sunflower ‘‘seeds’’ are really a fruit, the inedible wall (husk) surrounding the seed that is in the kernel. The great importance of sunflower lies in the excellent quality of the edible oil extracted from its seeds. It is highly regarded from the point of view of nutritional quality, taste and flavor. Moreover, after oil extraction, the remaining cake is used as a livestock feed. It must be noted that sunflower oil has a very low content of linoleic acid, and therefore it may be stored for long periods. Sunflower adapts well to adverse environmental conditions and does not require specialized agricultural equipment and can be used for crop rotation with soybean and corn. Oil yield of current hybrids is in the range 48–52%. Peanut The quality of peanut is strongly affected by weather conditions during the harvest. Peanuts are mainly used for human consumption, in the manufacture of peanut Flax Flax is a plant of temperate climates, with blue flowers. Linen is made with the threads from the stem of the plant and the oil from the seeds is called linseed oil, used in paint manufacture. Flax seeds have nutritional value for human con- sumption since they are a source of polyunsaturated fatty acids necessary for human health. Moreover, the cake left over, following oil extraction, is used as a livestock feed. The plant adapts well to a wide range of temperature and humidity; however, high temperatures and plentiful rain do not favor high yields of seed and fiber. Flax seeds contain between 30 and 48% of oil, and protein content is between 20 and 30%. It is important to remark that linseed oil is rich in polyunsaturated fatty acids, linolenic acid being from 40 to 68% of the total. Safflower Safflower adapts well to dry environments. Although the grain yield per hectare is low, the oil content of the seed is high, from 30 to 40%. Therefore, it has economic potential for arid regions. Currently, safflower is used in oil and flour production and as bird feed. There are two varieties, one rich in mono-unsaturated fatty acids (oleic acid) and the other with a high percentage of polyunsaturated fatty acids (linoleic acid). Both varieties have a low content of saturated fatty acids. The oil from safflower is of high quality and low in cholesterol content. Other than being used for human consumption, it is used in the manufacture of paints and other coating compounds, lacquers and soaps. It is important to note that safflower oil is extracted by means of hydraulic presses, without the use of solvents, and refined by conventional methods, without anti-oxidant additives. The flour from safflower is rich in fiber and contains about 24% proteins. It is used as a protein supplement for livestock feed. Castor Seed The castor oil plant grows in tropical climates, with temperatures in the range20–30LC; it cannot endure frost. It is important to note that once the seeds start germinating, the temperature must not fall below 12LC. The plant needs a warm and humid period in its vegetative phase and a dry season for ripening and har- vesting. It requires plenty of sunlight and adapts well to several varieties of
  • 33. soils. The total rainfall during the growth cycle must be in the range 700–1,400 mm; although it is resistant to drought, the castor oil plant needs at least 5 months of rain during the year. Castor oil is a triglyceride, ricinolenic acid being the main constituent (about 90%). The oil is non- edible and toxic owing to the presence of 1–5% of ricin, a toxic protein that can be removed by cold pressing and filtering. The presence of hydroxyl groups in its molecules makes it unusually polar as compared to other vegetable oils. Tung Tung is a tree that adapts well to tropical and sub-tropical climates. The optimum temperature for tung is between 18 and 26LC, with low yearly rainfall. During the harvest season, the dry nuts fall off from the tung tree and are collected from the ground. Nut production starts 3 years after the planting. The oil from tung nuts is non-edible and used in the manufacture of paints and varnishes, especially for marine use. Cotton Among non-foodstuffs, cotton is the most widely traded commodity. It is produced in more than 80 countries and distributed worldwide. After the harvest, it may be traded as raw cotton, fiber or seeds. In cotton mills, fiber and seeds are separated from raw cotton. Cotton fiber is processed to produce fabric and thread, for use in the textile industry. In addition, cotton oil and flour are obtained from the seed; the latter is rich in protein and is used in livestock feed and after further processing, for human consumption. Jojoba Although jojoba can survive extreme drought, it requires irrigation to achieve an economically viable yield. Jojoba needs a warm climate, but a cold spell is necessary for the flowers to mature. Rainfall must be very low during the harvest season (summer). The plant reaches its full productivity 10 years after planting. The oil from jojoba is mainly used in the cosmetics industry; therefore, its market is quickly saturated. Jatropha
  • 34. Jatropha is a shrub that adapts well to arid environments. Jatropha curcas is the most known variety; it requires little water or additional care; therefore, it is adequate for warm regions with little fertility. Productivity may be reduced by irregular rainfall or strong winds during the flowering season. Yield depends on climate, soil, rainfall and treatment during sowing and harvesting. Jatropha plants become productive after 3 or 4 years, and their lifespan is about 50 years. Oil yield depends on the method of extraction; it is 28–32% using presses and up to 52% by solvent extraction. Since the seeds are toxic, jatropha oil is non- edible. The toxicity is due to the presence of curcasin (a globulin) and jatrophic acid (as toxic as ricin). Avocado Avocado is a tree between 5 and 15 m in height. The weight of the fruit is between 120 and 2.5 kg and the harvesting period varies from 5 to 15 months. The avocado fruit matures after picking and not on the tree. Oil may be obtained from the fruit pulp and pit. It has a high nutritional value, since it contains essential fatty acids, minerals, protein and vitamins A, B6, C, D, and E. The content of saturated fatty acids in the pulp of the fruit and in the oil is low; on the contrary, it is very high in mono- unsaturated fatty acids (about 96% being oleic acid). The oil content of the fruit is in the range 12– 30%. Microalgae Microalgae have great potential for biodiesel production, since the oil yield (in liters per hectare) could be one to two orders of magnitude higher than that of other raw materials. Oil content is usually from 20 to 50%, although in some species it can be higher than 70% . However, it is important to note that not all mic- roalgae are adequate for biodiesel production. High levels of CO2, water, light, nutrients and mineral salts are necessary for the growth of microalgae. Production processes take place in raceway ponds and photobiological reactors. Chemical formulas of the main fatty acids in vegetable oils Fatty acid Chemical formula Lauric (12:0) CH3(CH2)10COOH Palmitic (16:0) CH3(CH2)14COOH
  • 35. Estearic (18:0) CH3(CH2)16COOH Oleic (18:1) CH3 (CH2)7 CH = CH (CH2)7 COOH Linoleic (18:2) CH3(CH2)4 CH = CH CH2 CH = CH (CH2)7 COOH Linolenic (18:3) CH3 CH2 (CH = CH CH2)3 (CH2)6 COOH Erucic (22:1) CH3(CH2)7 CH = CH (CH2)11 COOH Ricinoleic (18:1) CH3(CH2)5 CHOH CH2 CH = CH (CH2)7 COOH Approximate content (in weight) of saturated and non-saturated fatty acids in some vegetable oils and animal fats Oil/fat SFA (& % w/w) NSFA (& % w/w) Coconut 90 10 Corn 13 87 Cottonseed 26 74 Olive 14 86 Palm 49 51 Peanut 17 83 Rapeseed 6 94
  • 36. Soybean 14 86 Sunflower 11 89 Safflower 9 91 Castor 2 98 Yellow grease 33 67 Lard 41 59 Beef tallow 48 52
  • 37. Injection Experiments The process of injecting diesel, biodiesel, or a blend into the cylinder through orifices within the body of the injector leads to a naturally leads to a particular distribution of equivalence ratio. Diesel fuel being expelled from an injector . The type and quantity of harmful emissions thus depends on the cylinder conditions at the SOI, the physical properties of the fuel, the injector geometry, and the combustion chamber geometry. The injector, nozzle, and fuel properties directly affect the fuel droplet diameter distribution. Typically injection studies have been done at atmospheric pressure so that surface wave phenomenon, caused by drag, can be observed occurring on droplets as they travel away from the fuel nozzle. The effect of injection pressure on velocity and its subsequent affect on droplet size was studied extensively by Koo and Martin . Spray emitted from a high-pressure diesel fuel injector.
  • 38. Injection studies tend to be done in high pressure spray boxes or in CFD. With advents in high-speed signal processing equipment, researchers are now able to study combusting dynamic sprays in high pressure environments. Injectors with various geometries and orifice diameters were tested to observe the effect on spray penetration lengths. conducted an extensive study effects orifice diameter and injection pressure on CH after mixture and OH formation after ignition around the jet. A spray penetration model was introduced by Abani and Reitz. using jet theory for the incorporation of time varying injection into CFD models. Engine Experiments Engine experiments mostly test injection strategies on engines of particular displacements or piston geometries. investigated how the depth of omega piston geometry affects emissions and efficiency of diesel engines. Much like the injection experiments, either physical experimentation or numerical investigations are conducted. There have been quite a number of studies where researchers have measured the emissions of biodiesel combustion at various operating conditions and loads. demonstrate percentage decreases in oxides of carbon and nitrogen (NOX) as well as particulate matter and unburned hydrocarbons using soybean B20 fuel. both used a Caterpillar SCORE similar to investigate the increase in oxides of nitrogen using SME fuel and attributed its cause to factors other than the start of combustion crank angle window. Increased NOx emissions can be attributed to a difference in flame lift-off length (LOL) and the higher elapsed time of combustion
  • 39. Experiments have been conducted using methyl esters made from several oils. produced several batches of cotton seed oil methyl ester (CSOME) and the trend of reduced emissions and increased NOx. used blends of diesel, biodiesel, and bio-ethanol and identified a decrease in engine thermal efficiency.
  • 40. Properties of Biodiesel Liquid Properties and Sprays The liquid properties of biodiesel can negatively influence the quality of its movement throughout the fuel system of the engine as shown by Tefsa . Biodiesel of various types is known to dissolve fuel lines and clog filtration devices due to its chemical composition and other physical differences. immersed several types of elastomers into palm methyl ester (PME) and recorded reduction in material strength. Electrochemical reactivity is not a typical focus of numerical flow studies however, some material properties are measured which are of concern. The fluid properties are needed in CFD studies to adjust the spray and breakup models. studied the effect of liquid fuel properties of five fuels on liquid penetration distance length in diesel engines and found that it is proportional to viscosity. Most literature, involving biodiesel, cites common proprieties at room temperature. For the best precision, it is necessary to have property curves as functions of temperature. utilized a capacitance densitometer to measure the density of soy, canola, and fish oil methyl ester up to 573K. measured and curve fit the specific heat and enthalpy of SME and several other biofuels.
  • 41. Vapor Properties and Combustion The characteristics of biodiesel fuels must be known at temperatures in the vapor phase in order to model droplet atomization, evaporation, and combustion within the cylinder. There is not a sizable volume of literature with the vapor properties of plant oils or methyl esters verified using specialized experiments.
  • 42. By dividing sprays into separate areas, separate discrete and empirical models can then be interjected to simplify complex aspect of sprays. A quiescent chamber CFD model was used to calibrate the overall injection and breakup models against the liquid and vapor penetration distances provided in the experimental data of Singh [11]. The stand- alone high pressure chamber allowed the parameters of the spray model to be studied and augmented independently of the overall engine model. Figure 15 is a labeled depiction of a mini-sac injector. Mini-sac diesel injector tip A phenomenological plain orifice atomization model was utilized to empirically incorporate internal nozzle conditions and their physical effects on the spray angle, droplet geometry, and droplet velocity. High pressure flows through cylindrical nozzles is very complex. In the plain orifice model, the nozzle flow velocity,coefficient of
  • 43. discharge, the spray angle, and the cavitation number, for separate nozzle operation regimes, are calculated using the injection pressure, cylinder pressure near the nozzle orifice, Reynolds number, nozzle geometry, area coefficient, and the fuel properties such as liquid density, and vapor pressure . Fuel kinematic viscosity,mass flow rate,and a proportionality constant,are also used to calculate injection parameters. As the needle closes the fuel supply to the mini-sac, the flow transitions back through the modes of flow in reverse. It is the transitional flow phenomenon in concert with fluid properties which leads to the complexity of high pressure orifice sprays. There is a lot of interplay between the cylinder pressure and the spray velocity implied by Bernoulli's equation. It is the increase in cylinder pressure that overcomes liquid fuel viscosity and leads to cavitation and atomization. Droplet breakup, collision, and secondary breakup are simulated using the Kelvin-Helmholtz (KH) aerodynamic drag model, O'Rourke's collision probability algorithm, and the Raleigh-Taylor (RT) instability breakup model. A Lagrangian discrete phase model (DPM) is used to simulate turbulent droplet dispersion. The KH-RT model assumes that fuel droplets are emitted from a column of liquid blobs because of shear forces imparted by the continuous phase.
  • 44. Those droplets may collide and form larger droplets or travel on being guided by the continuous phase. The smallest discrete droplets, which will no longer collide or breakup, are in the domain after the secondary breakup process, the continuous gas phase interacts with them. The mass and velocity of the droplets is reduced via thermal and momentum energy transfer. The droplets vaporize and deposit their fuel mass into the cells along their path of travel through the combustion chamber and become part of the continuous gas phase. The aggregate continuous gas phase properties go into the finite-rate or eddy dissipation chemistry model and energy equation calculations. The quiescent spray chamber model consists of one nozzle centered at the top with its spray axis in the downward vertical direction. The initial pressure within the chamber is held at the motored TDC pressure. The entire spray formation is simulated across all degrees of crankshaft angle movement for the DOI at 1200 revolutions per minute. The elapsed time of the spray is approximately 1389 microseconds, at high temperature engine operating conditions, with a 691 microsecond short ignition delay. The shape of the equivalence ratio field, liquid penetration length, and vapor penetration field with petroleum diesel were compared to the experimental data from. The use of a phenomenological spray model, that predicts initial spray distribution based on the injector specifications and fuel fluid properties, allows direct substitution of liquid fuels with slightly different physical properties with adjustments to the breakup model. The breakup model coefficient adjustments were arrived at using trial and error. The mesh used for the quiescent spray chamber is depicted.
  • 45. : Quiescent spray chamber mesh The specifications of the injector are listed Sandia/Cummin Injector Specification Sandia/CumminsN14 Injector Specifications Type Common Rail, pilot valve Rail pressure 120MPa or 160MPa Cup type Mini sac Number of orifices 8 - 1/45° Orifice diameter (mm) 0.196 Orifice Length/Diameter 5 Included spray angle 152° Discharge coefficient 0.67 Area coefficient 0.93 Velocity coefficient 0.72
  • 46. Combustion Chamber Mesh Grid The key geometry that must be reproduced is the piston and the proximity of its crown geometry to the head surface, within the combustion chamber during crankshaft angle change. The overall number of computations is directly related to mesh density, the number of steps during compression, the number of steps during combustion, and the complexity of the solver configuration. The mesh grid geometry of the combustion chamber volume, are pre-generated outside of ANSYS Fluent™ with ANSYS ICEM©. The mesh grids used for this thesis work are shown in Figure . The mesh grids are sector meshes that represent one eighth of the cylinder. Only one injection orifice is considered. The crevice measured from the top most surface of the piston down to the first ring was omitted. Figure Cylinder combustion mesh grids Dynamic Meshing The volume and shape of the combustion chamber are augmented along the cylinder axis. It is assumed that the crankshaft's angular velocity is constant which allows the time step size to be constant during the various phases of combustion. The Fluent solver requires that the user provides the number of desired steps. All of the
  • 47. engine sector mesh grids, used in this thesis, that are read into Fluent, start at TDC and must be manipulated to expand them to the appropriate volume associated with the IVC crankshaft angular position. From that time point forward, the number of time steps required to reach the period just before the exhaust valve opens is defined by the following equation: Diagram depicting all terms in piston position calculation
  • 48. The cells are grown from and collapsed into the head boundary during the solution. The result is a separate mesh for each individual timestep. Figure 19 is a depiction of the mesh growth. Mesh grid cell augmentation during the solution process CFD Solver Configuration Initial and Boundary Conditions The typical steps for IC simulation, when the intake, valve, manifold port geometry, and velocity profiles are known, is to setup and solve a cold flow case with no combustion. In a cold flow case, the introduction of charge air through the intake port and valve is considered. The cold flow solution can be applied as the initial conditions of the compression and combustion simulation so that the initial field values at IVC can be made as realistic as possible. If the head port and valve geometry are not known, the initial conditions of swirl and tumble after IVC can be approximated. Because the
  • 49. detailed cylinder head geometry of the N14 engine is unknown, at this time, all of the simulation in this work omits valve motion by simulating the time period from IVC to EVO. Also, cylinder air swirl and tumble are assumed to occur about cylinder axis. A user defined function, written in C, was used to define the initial velocity field at IVC. Trial and error methods were used to set the swirl ratio number at IVC such that the TDC swirl ratio was about 0.52 as stated by Singh. Figure is a depiction of the swirl phenomenon. Figure Intake swirl flow diagram The initial air component mass fractions, gauge pressure, and temperature were set according to the specifications given. The injection
  • 50. settings were configured for each case by calculating the effective mass flow rate for one nozzle. Pollutant Formation Modeling Two pollutants of main concern are NOx and soot. They are both formed at opposite ends of the combustion operating range. NOx is typically formed when the combustion equivalence ratio is less than unity and flame temperatures are high. Soot is formed mostly as the result of pyrolysis within fuel rich regions at medium and lower temperatures. Because diesel engines operate at maximum volumetric frequency and rely on turbulent diffusion for reactant mixing, these two major pollutants are formed simultaneously. Figure is a depiction of the soot and NOx formation zones as functions of equivalence ratio, combustion temperature, and air oxygen volume percentage. Figure Soot and NOx production zones typical of diesel engines (Sandia 1993)
  • 51. It was assumed that the major component of NOx emissions was nitric oxide (NO). Several models are used to predict NO formation. NO that is promptly formed in the regions of high equivalence ratio and low temperature can predicted using the Fenimore model. The Fenimore model was not used because the residence time of all species is 0.020seconds, which is particularly long. Without activating a return model, overproduction of NO would be a trend. Thermal NO is modeled using the Zeldovich mechanism correlations for the oxidation of nitrogen within the intake air. The Tenser model was utilized for soot emission prediction which involves carbon forming on nucleating particles. Soot formation properties were set according to default values The stoichiometric of soot and fuel combustion were set respectively for each fuel based on carbon number. Several Fluent custom field functions are used to calculate ending pollutant quantities at EVO and other points in the cylinder and are shown as a contiguous file in appendix A.
  • 52. Solution Process Along with the momentum equations, the pressure based Fluent solver is configured to solve the energy, viscous model, species transport, and reaction equations. Pressure and velocity is coupled using the pressure implicit with splitting of
  • 53. operators (PISO) scheme. The overall solution process that results from the configuration of ANSYS Fluent is depicted in figure. Figure ANSYS Fluent™ transient solution process after configuration Post-processing and Analysis The was solver configured to output several parameters which allow generation of heat release curves. The apparent heat release rate (AHRR), , was numerically estimated using the calculated average cylinder pressure as a function of crank angle. The heat release equation in (Heywood 1988) was numerically represented as is the
  • 54. typical practice to produce an AHRR curve from an experimental pressure trace. The Eichelberg empirical relation for convective heat transfer, out of the continuous phase, into the cylinder wall, was added. The average cylinder wall temperature, , the bulk continuous phase temperature, , the cylinder wall area, , and the combustion chamber volume, , are obtained at the end of each converged time step. The values of pollutant quantities are only considered at EVO as it is assumed that combustion has concluded prior to that event.
  • 55. Cylinder Pressure The mean cylinder pressure is a measure of volume averaged cylinder pressure from IVC to EVO during the simulation. For case one, three diesel and one biodiesel simulations were conducted. The ignition delay is over predicted for case one. The RNG k-e turbulence model was utilized for the first diesel case in conjunction with a laminar finite-rate combustion model and had the longest ignition delay. The first of the diesel simulations also over predicted the peak average combustion pressure. The effect on
  • 56. MeanCylinderPressure(MPa) combustion because of fuel property, injection rate, and spray formation differences between fuels can be visualized with the pressure curve. Pressure curves for all cases are shown in figures. Sandia Cummins N14 Mean Pressure - Case1 [HT-SID] 9 8 7 6 5 Singh2006 Pressure1 c1-D1-Pressure (MPa) 4 c1-D2-Pressure (MPa) c1-D3-Pressure (MPa) c1-MD2-Pressure (MPa) 3 2 705 715 725 735 745 755 Crank Angle (CAD) Figure Case 1, High Temperature, short ignition delay pressure curves
  • 57. Singh2006 Pressure2 c2-D1-Pressure (MPa) c2-D2-Pressure (MPa) c2-MD-Pressure (MPa) MeanCylinderPressure(MPa) Sandia/Cummins N14 - Mean Pressure [HT-LID] 8 7 6 5 4 3 2 705 715 725 735 745 755 Crank Angle (CAD) Figure Case 2, High-temperature, long ignition delay pressure curves For case two, the ignition delay was predicted well using the RNG k-e turbulence model for the first diesel simulation. The second diesel and methyl decanoate simulations have shorter ignition delays. Short ignition delay and high peak pressure indicate maladjustment of the autoignition model.
  • 58. MeanCylinderPressure(MPa) Sandia Cummins N14 - Mean Pressure [LT-EI] 10 9 Singh2006 Pressure3 c3-D1-Pressure (MPa) c3-MD1-Pressure (MPa) 8 7 6 5 4 690 700 710 720 730 740 750 760 Crank Angle (CAD) Figure Case 3, Low-temperature, early injection pressure curves Case three ignition delays and peak combustion pressure seem to show the effects of differing physical properties of fuels. The combustion rate of the fuels seems to be higher than the experimental data in all cases leading up to case three.
  • 59. Singh2006 Pressure4 c4-D1-Pressure (MPa) MeanCylinderPressure(MPa) The pressure level in cases four and five match the experimental pressure curves very well. The ignition delay is smaller than that of the experimental data but, combustion rate seems to match in case five. Sandia/Cummins N14 - Mean Pressure [LT-LI] 8 7 6 5 4 3 2 705 715 725 735 745 755 Crank Angle (CAD) Figure Case 4, Low-temperature, late injection pressure curves
  • 60. Singh2006 Pressure5 c5-D1-Pressure (MPa) MeanCylinderPressure(MPa) Sandia/Cummins N14 - Mean Pressure [LT-DI] 8 7 6 5 4 3 2 705 715 725 735 745 755 Crank Angle (CAD) Figure Case 5, Low-temperature, double injection pressure curves All results could be improved by determining a method to match the experimental injection mass flow rate curves, more tuning of the droplet collision breakup model, and having accurate information about the kinematic viscosity of biodiesel. The spray model is very dependent on accurate fuel properties to determine which modes the injector nozzle is operating in. The autoignition energy of the fuels also need to be known more accurately so that the detonation and high a burn rate of the fuel does not occur. Sharp spikes in simulated pressure mean that the injector nozzle may spend more time in the flipped mode than the cavitating mode during the DOI. The accurate simulation liquid spray impingement and subsequent modes of evaporation require very fine wall mesh grids because of interaction with turbulence modeling.
  • 61. Temperature(K) Combustion Temperature The temperature result of the simulations is compared with experimental data. The adiabatic temperatures in the experimental data are calculated using STANJAN code with optical data during the soot formation and soot combustion as input. Since the experimental data is actually a theoretical calculation of maximum adiabatic flame temperature, simulation results are only provided so that general temperature trends correlations can be identified. Additional Temperature plots are in appendix B 2540 Sandia Cummins N-14 Combustion Temperature [HT-SID] 2440 2340 2240 2140 2040 1940 1840 Singh2006 Temperature1 c1-D1-Temperature (K) c1-D2-Temperature (K) c1-D3-Temperature (K) c1-MD2-Temperature (K) 1740 720 722 724 726 728 730 732 Crank Angle (CAD) Figure Case 1, High Temperature, short ignition delay temperature curves
  • 62. ApparentHeatReleaseRate(J/°) Apparent Heat Release Rate The AHRR curves are modeled using a single zone zero-dimensional thermodynamic model. Because of error in the temperature and pressure curves in section , the calculated maximum AHRR overshoot the experimental data significantly however, trends such as a negative AHRR at the SOI before autoignition are reproduced. Tuning of the autoignition model alone could have positive effects for the increase of accuracy. The AHRR curves for cases two, three, four, and five are in appendix B. 650 SCORE Cummins N14 - Apparent Heat Release Rate Results [HT-SID] 550 450 350 250 150 Singh-c1-AHHR(J/deg) c1-D1-AHHR(J/deg) c1-D2-AHHR(J/deg) c1-D3-AHHR(J/deg) c1-MD2-AHHR(J/deg) 50 -50 713 723 733 743 753 Crank Angle (CAD) Figure Case 1, High Temperature, short ignition delay heat release curves
  • 63. %changeinemissions Combustion Emissions Given most of the published data at the time, the EPA characterized the overall average trend in reduction of regulated emissions when using soy methyl ester biodiesel in heavy-duty highway engines. is the EPA's published emission impacts of SME on heavy duty highway engines. 20 % Change in USEPA Regulated Emission with SME Biodiesel 10 0 -10 -20 -30 -40 0 20 40 60 80 100 NOx PM CO HC -50 -60 -70 Volumetric % SME biodiesel in fuel Figure Percent change in regulated emissions with SME biodiesel Table is a comparison of NOx emissions at EVO between biodiesel and diesel fuel. The high temperature case with long ignition delay is the only case that is somewhat in agreement with the emissions trends. Table Percent increase in NOx between simulated fuels Simulated NOx at EVO (845deg) [g/(hp*hr)] or [ppm] HT-SID HT-LID LT-EI LT-LI (ppm) LT-DI (ppm) Diesel#2 29.6 16.8 1 63 87.7 MD 5.4 20.9 0.47 -- -- -452% 19.8% -126% -- --
  • 64. UnburntFuelatEVO[g/(hp*hr)] Unconsumed Fuel Unconsumed fuel is a regulated pollutant in most jurisdictions. In the U.S., the EPA specifies that an on-road heavy truck or combination tractor powered by a heavy- duty compression ignition engine, such as the Cummins N14, can only emit up to 1.3g hp hr of unburned fuel from the exhaust. If an engine produces 100 brake horse power at speed, it could only output up to 130 grams of unconsumed fuel over the course of an hour of operation. Table depict the estimated average levels of fuel pollutants. Fuel emissions at end of simulation Unburnt Hydrocarbons at EVO (845deg) [g/(hp*hr)] HT-SID HT-LID LT-EI LT-LI LT-DI Diesel#2 4.33E-05 5.75E-03 1.06E-04 1.56E-04 5.21E-04 MD 6.18E-05 6.87E-05 2.56E-02 -- -- Unconsumed Fuel at EVO (845deg) 3.00E-02 2.50E-02 2.00E-02 1.50E-02 1.00E-02 Diesel#2 MD 5.00E-03 0.00E+00 HT-SID HT-LID LT-EI LT-LI LT-DI Figure Unconsumed fuel in domain at EVO
  • 65. SootParticulateVolume[mm3] Particulates Soot luminosity and processing techniques were used by Singh to determine soot volume from optical experiments. The simulation results for all cases match the trend of the experimental results well. Table depict the volume of soot particulates in the fuel jet. 0.6 Particulates [mm3] 0.5 0.4 0.3 0.2 Singh 2006 Diesel#2 MD 0.1 0 HT-SID HT-LID LT-EI LT-LI LT-DI Figure Particulates in domain at EVO Table Particulate emissions at specified crankshaft angles Particulates [mm 3 ] HT-SID HT-LID LT-EI LT-LI LT-DI CAD 725 728 715 741 755 Singh 2006 0.55667 0.08357 0.04296 0.0677 0.0677 Diesel#2 0.01213 0.01046 2.45E-05 1.78E-09 1.17E-09 MD 8.41E-04 1.18E-05 7.90E-09 -- --
  • 66. Fuelspray characteristis Injection spray is the process that fuel is injected from nozzle, and it is associated with following fuel atomisation, interaction with surrounding gas, mixture formation and com‐ bustion. Regarding to a new fuel applied into the diesel engine, the spray process is differ‐ ent due to the different properties from diesel, and the control strategy should be changed accordingly in order to achieve the optimum performance. Viscosity, surface tension and density are the three main parameters, which influence fuel spray characteristics. Higher viscosity and surface tension will prohibit the atomisation and instability of fuel droplets. Due to the different biodiesels properties from diesel, studies on the spray characteristics are necessary. Near-fieldspray characteristics In the near-field of nozzle, the spray is dominated by the injection dynamics while the spray is affected by the ambient conditions in the far field. According to Hiroyasu’s model, before the t breakup, which represents the time for fuel jet breakup, the penetration length is proportion‐ al to the time after start of injection, namely ASOI. However, the non-linear phenomenon has been observed by a number of researchers. The acceleration process has been found to be different among fuels. Figure 4 compares the morphology of the spray process of the three tested fuels, ULSD, RME and GTL and Figure 5 shows the spray tip penetration length evolution after start of injection (ASOI) using an ultrahigh-speed CCD camera of up to 1 million shots per second. The initial non-linear penetration can be observed, indicating the acceleration period at the initial spray stage. GTL fuel has longer penetrating length than RME and die‐ sel even though it was overtaken by RME 70 µs ASOI. Several publications have reported that GTL with lower density has a shorter penetration delay. However, these were based on the global fuel spray characteristics using a relatively low speed camera [21, 13]. The temporal resolution is not high enough to capture the near-field spray process. Sequence of spray images in a single time-resolved ULSD spray (Pinj=120 MPa, Pamb =3.0 MPa and tdur=1.5 ms
  • 67. Macroscopic spray characteristics Normally, biodiesel shows a longer penetration and narrower spray angle than fossil fuel due to the higher viscosity, surface tension and density. The penetration length of biodiesel increases with the blend ratio, higher biodiesel content requires longer breakup time . The difference between the two type fuels can be varied at different conditions. experimentally studied biodiesel spray characteristics at different ambient pressures. The authors showed that little difference can be observed at the ambient pressure of 1.2 MPa while the penetration length significantly increased in contrast to diesel spray at the ambient pressure of 5.0 MPa. In addition, biodiesel may have a lower penetration velocity due to the negative effect of fuel density on spray velocity . Sauter Mean diameter (SMD) SMD is one of the parameters to evaluate fuel atomisation quality and represents the ratio of total droplet volume to surface area. Smaller SMD indicates more small fuel droplets and the larger contact area with surrounding gas. Due to the high viscosity and surface tension, SMD of biodiesel is higher than fossil diesel. conducted the comparative anal‐ ysis on 15 biodiesels and a larger SMD, between 5%-40%, can be observed and concluded an empirical equation to estimate SMD: SMD =0.002103µ + 0.000330σ where µis fuel dynamic viscosity (Pa.s) and σis fuel surface tension (N/m). compared diesel with neat RME and GTL at different injection pressure along the spray axis in terms of SMD. It can be seen that the injection pressure has a significant impact on droplet size. The SMD decreases dramatically when the injection pressure increases from 80MPa to 120MPa.
  • 68. Exhaust particulate number concentration (total) Particle morphology (captured under engine mode of 1800 rpm, 30 Nm): (a) Diesel magnification of 10000; (b) Diesel magnification of 65000; (c) RME 10 magnification of 10000; (d) RME magnification of 65000; (e) GTL10 magnification of 10000; (f) GTL10 magnification of 65000
  • 69. Engine emission optimisation Two popular methods have been used to reduce the engine out emission for biodiesel-fuel‐ led engines: injection strategy and EGR. For the former, the combustion process can be con‐ trolled by injection timing and injection pressure. For the time being, the common rail injection system has been widely used and multiple injections up to of 5 times can be real‐ ised. Through this way, the fuel injection rate is controllable. The NOx can be reduced through pre-injection with small amount fuel; this prevents a long period of ignition delay and therefore leads to a lower peak pressure; for the latter, EGR is always an effective way to reduce NOx emission. Due to the induction of exhaust gas, the global in-cylinder tempera‐ ture is reduced, avoiding the thermal conditions favoured by NOx formation. Ladommatos et al. [18] also revealed that the reduction in combustion temperature is a consequence of the reduced peak rate of the premixed phase combustion due to the lower oxygen availability. Conclusions Biodiesel is the most promising fuel in the near future as an alternative to fossil diesel. De‐ spite of its advantages, it still has some disadvantages such as source for massive feedstock, relatively poor low-temperature properties, increase in NOx emissions, etc. These issues should be sorted out before biodiesel is applied into diesel engines in a large scale. There‐ fore, in-depth studies on the application of biodiesel into diesel engines are necessary. The research on alternative feedstocks is also an important area and the second-generation bio‐ diesel is more promising made from algae and the genetic modification is a potential way to solve this problem of source of massive feedstock. The low-temperature fuel properties can be improved by additives or the production routine. In addition, diesel engines should also be optimised in order to achieve the optimal performance and emissions. REFERENCE
  • 70.  www.ideo.com  www.howstuffworks.com  www.wikipedia.com  www.biodiesel.org  Zhang, X., Wang, H., et al. (2008). Characteristics of Output Performances and Emissions of Diesel Engine Employed Common Rail Fueled with Biodiesel Blends from Wasted Cooking Oil. SAETechnical Paper 2008-01-1833.  Shashikant,V.G. and Hifjur Raheman, 2005. Biodiesel production FromMahua oil having high free fatty acids,JournalOf Biomass and Bioenergy, 28:601-605.  Ramadhas, A.S., S.Jayaraj and C. Muraleedharan,2004 Use of Vegetable oils as I.C. engine fuel-a review,Renewableenergy, 29(5):721-742.  Machine Design by R.S. Khurmi and J.K. Gupta  Design of Machine Elements by V.P. Singh  Automotive Mechanics by Crouseand Anglin.  InternalCombustion engines By V.Ganesan.  ICEngines by Mathur & Sharma.  Automobile Engineering By Dr. Kirpal Singh.  Alternative Fuels By Dr. KirpalSingh.  Also different books, papers and other websites.