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INTRODUCTION TO CORROSION
 Corrosion can be defined as the deterioration of metal due to
its interaction with the environment. Corrosion is a natural
phenomenon, which should not surprise one, but rather
should be expected to occur.
 Metals are high energy materials, which exist because heat
energy was added to natural iron ores during the smelting
process.
 Nature, by environmental contact, constantly attacks these
high energy materials and breaks them down to the natural
elements from which they were derived.
2/14/2019
3
Conditions Required for Corrosion
 Corrosion is an electrochemical process
occurring at the interface between metal and
environment. Three conditions must be
present for this to occur.
 1. Two areas on a structure or two structures
must differ in electrical potential.
 2. Those areas, called anodes and cathodes,
must be electrically interconnected.
 3. Those areas must be exposed to a common
electrolyte (soil or water).
2/14/2019
4
Corrosion Rate
 As a result of this process, electric current flows
through the interconnection between cathode and
anode.
 The cathodic area is protected from corrosion
damage at the expense of the metal, which is
consumed at the anode.
 The amount of metal lost is directly proportional to
the current flow. Mild steel is lost at approximately
20 pounds for each ampere flowing for a year.
2/14/2019
5
Factors Affecting Corrosion Rate
 Potential Difference Between Anode and
Cathode (Galvanic Series)
 Circuit resistance – Resistivity of the
Electrolyte
 Chemical Activity
 Stray Currents
2/14/2019
6
Potential Difference
Interconnecting two dissimilar metals
in an electrolyte will create a corrosion
cell. The strength of this cell increases
as the distance within the galvanic
series increases.
2/14/2019
7
TYPES OF CORROSION
 Uniform or near uniform - Corrosion attacks all
areas of the metal at the same or similar rate.
 Localized - Some areas of the metal corrode at
different rates due to heterogeneities in the
metal or environment. This type of attack can
approach pitting.
 Pitting - Very highly localized attack resulting
in small pits that may penetrate to
perforation.
2/14/2019
8
Commonly Affected Structures
 Buried Piping
 Steel Piles
 Storage Tanks - Above Ground / Underground
 Reinforcing Steel in Concrete
Ships/Boats
2/14/2019

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Corrosion

  • 2. 2 INTRODUCTION TO CORROSION  Corrosion can be defined as the deterioration of metal due to its interaction with the environment. Corrosion is a natural phenomenon, which should not surprise one, but rather should be expected to occur.  Metals are high energy materials, which exist because heat energy was added to natural iron ores during the smelting process.  Nature, by environmental contact, constantly attacks these high energy materials and breaks them down to the natural elements from which they were derived. 2/14/2019
  • 3. 3 Conditions Required for Corrosion  Corrosion is an electrochemical process occurring at the interface between metal and environment. Three conditions must be present for this to occur.  1. Two areas on a structure or two structures must differ in electrical potential.  2. Those areas, called anodes and cathodes, must be electrically interconnected.  3. Those areas must be exposed to a common electrolyte (soil or water). 2/14/2019
  • 4. 4 Corrosion Rate  As a result of this process, electric current flows through the interconnection between cathode and anode.  The cathodic area is protected from corrosion damage at the expense of the metal, which is consumed at the anode.  The amount of metal lost is directly proportional to the current flow. Mild steel is lost at approximately 20 pounds for each ampere flowing for a year. 2/14/2019
  • 5. 5 Factors Affecting Corrosion Rate  Potential Difference Between Anode and Cathode (Galvanic Series)  Circuit resistance – Resistivity of the Electrolyte  Chemical Activity  Stray Currents 2/14/2019
  • 6. 6 Potential Difference Interconnecting two dissimilar metals in an electrolyte will create a corrosion cell. The strength of this cell increases as the distance within the galvanic series increases. 2/14/2019
  • 7. 7 TYPES OF CORROSION  Uniform or near uniform - Corrosion attacks all areas of the metal at the same or similar rate.  Localized - Some areas of the metal corrode at different rates due to heterogeneities in the metal or environment. This type of attack can approach pitting.  Pitting - Very highly localized attack resulting in small pits that may penetrate to perforation. 2/14/2019
  • 8. 8 Commonly Affected Structures  Buried Piping  Steel Piles  Storage Tanks - Above Ground / Underground  Reinforcing Steel in Concrete Ships/Boats 2/14/2019