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Chemical
Measurements
Unit 1: Stoichiometry
Chapter 10 – The Mole
Monday, 2/2
Learning Target:
Distinguish between atomic mass, formula
mass and molar mass.
Learning Outcome:
Complete “Formula Mass and Molar Mass”
Worksheet.
Measurements in Chemistry
• We use measurements all of the time!
• Atomic Mass is a measurement that we have
already used in class.
o units for atomic mass = atomic mass unit (amu)
o Used to express masses of atoms on a relative
scale. We compare everything to carbon-12.
Particle location Mass (g) Mass
(amu)
Proton
Inside
nucleus
1.673X10 -24
1.0073=1
Neutron
Inside
nucleus
1.675X10 -24 1.0087=1
Electron
Outside
nucleus 7.109X10 -28
0.0006=0
Atomic Mass & Formula Mass
• Atomic Mass
o The weighted average of the masses of the
existing isotopes of an element
o Ex. Carbon C 12.01 amu
• Formula Mass
o The sum of the atomic masses of all atoms in a
compound
o Ex. Carbon Dioxide CO2 44.01 amu
Calculating Formula Mass
• What is the formula mass for SO2?
o S: 1 atom x 32.1 amu
o O: 2 atoms x 16.0 amu
Formula Mass = 32.1 amu + 32.0 amu= 64.1 amu
Calculating Formula Mass
• What is the formula mass for H2O2?
o H: 2 atoms x 1.01 amu
o O: 2 atoms x 16.0 amu
Formula Mass = 2.02 amu + 32.0 amu = 34.02 amu
Calculating Formula Mass
• Methylene chloride (CH2Cl2) is used as a solvent in paint
strippers. What is the formula mass of methylene
chloride?
o C: 1 atom x 12.01 amu
o H: 2 atoms x 1.01 amu
o Cl: 2 atoms x 35.45 amu
Formula Mass = 12.01(1) + 1.01(2) + 35.45(2) = 85.0 amu
Moving from AMU to grams
• The use of atomic mass units (amu) are impractical
in the chemistry lab where the preferred unit of
measurement is grams.
• Scientists needed to establish a relationship between
# of atoms and masses of atoms.
The Mole
• Definition
o The number of atoms of that element equal to the
number of atoms in exactly 12.0 grams of carbon-
12.
o Abbreviated mol (without the ‘e’)
• The number of atoms in one mole of atoms is
always the same! Avogadro’s Number (N)
o 6.02 x 1023 atoms
o 602,000,000,000,000,000,000,000
Same Number, Different Mass
Element # atoms/mol mass of 1 mole
Carbon 6.02x1023 atoms
12.01 g C
Copper 6.02x1023 atoms
63.55 g Cu
Tin 6.02x1023 atoms
118.71 g Sn
Why do the amounts of each look different?
Calculating Molar Mass
• Methylene chloride (CH2Cl2)
o C: 1 atom x 12.01 amu
o H: 2 atoms x 1.01 amu
o Cl: 2 atoms x 35.45 amu
• Formula Mass = 12.0(1) + 1.0(2) + 35.5(2) = 85.0 amu
• Molar Mass = 84.95 g/mol
Molecules and Moles
• The number of molecules in 1mole of a
molecular compound is 6.02 x 1023 (same as
with atoms in a mole)
• 1 mol of water (H2O) contains 1 mol of water
molecules but 2 mol of hydrogen atoms and
1 mol oxygen.
• How many moles of Ca2+ and F- are in 1
mole of calcium fluoride?
o 1 mole of Ca2+ ions and 2 moles of F- ions
Molar Mass
• Definition
o The mass in grams of 1 mole of a substance
• We calculate molar mass the same way as
formula mass.
o Atomic/Formula Molar Mass
o Ex. Calcium 40.08 amu = 40.08 g/mol
Same Number, Different Mass
Practice
• What is the formula and molar mass for propane,
C3H8?
– C: 3 atoms x 12.01 amu = 36.03 amu
– H: 8 atoms x 1.01 amu = 8.08 amu
Formula Mass = 36.03 amu + 8.08 amu = 44.11 amu
Molar Mass = 44.11 g/mol
Same Number, Different Mass
Practice
• What is the formula and molar mass for glucose,
C6H12O6?
– C: 6 atoms x 12.01 amu = 72.06 amu
– H: 12 atoms x 1.01 amu = 12.12 amu
– O: 6 atoms x 16.00 amu = 96.00 amu
Formula Mass = 72.06 amu + 12.12amu + 96 amu =
180.18 amu
Molar Mass = 180.18 g/mol

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Chemical Measurement (1).ppt

  • 2. Monday, 2/2 Learning Target: Distinguish between atomic mass, formula mass and molar mass. Learning Outcome: Complete “Formula Mass and Molar Mass” Worksheet.
  • 3. Measurements in Chemistry • We use measurements all of the time! • Atomic Mass is a measurement that we have already used in class. o units for atomic mass = atomic mass unit (amu) o Used to express masses of atoms on a relative scale. We compare everything to carbon-12.
  • 4. Particle location Mass (g) Mass (amu) Proton Inside nucleus 1.673X10 -24 1.0073=1 Neutron Inside nucleus 1.675X10 -24 1.0087=1 Electron Outside nucleus 7.109X10 -28 0.0006=0
  • 5. Atomic Mass & Formula Mass • Atomic Mass o The weighted average of the masses of the existing isotopes of an element o Ex. Carbon C 12.01 amu • Formula Mass o The sum of the atomic masses of all atoms in a compound o Ex. Carbon Dioxide CO2 44.01 amu
  • 6. Calculating Formula Mass • What is the formula mass for SO2? o S: 1 atom x 32.1 amu o O: 2 atoms x 16.0 amu Formula Mass = 32.1 amu + 32.0 amu= 64.1 amu
  • 7. Calculating Formula Mass • What is the formula mass for H2O2? o H: 2 atoms x 1.01 amu o O: 2 atoms x 16.0 amu Formula Mass = 2.02 amu + 32.0 amu = 34.02 amu
  • 8. Calculating Formula Mass • Methylene chloride (CH2Cl2) is used as a solvent in paint strippers. What is the formula mass of methylene chloride? o C: 1 atom x 12.01 amu o H: 2 atoms x 1.01 amu o Cl: 2 atoms x 35.45 amu Formula Mass = 12.01(1) + 1.01(2) + 35.45(2) = 85.0 amu
  • 9. Moving from AMU to grams • The use of atomic mass units (amu) are impractical in the chemistry lab where the preferred unit of measurement is grams. • Scientists needed to establish a relationship between # of atoms and masses of atoms.
  • 10. The Mole • Definition o The number of atoms of that element equal to the number of atoms in exactly 12.0 grams of carbon- 12. o Abbreviated mol (without the ‘e’) • The number of atoms in one mole of atoms is always the same! Avogadro’s Number (N) o 6.02 x 1023 atoms o 602,000,000,000,000,000,000,000
  • 11. Same Number, Different Mass Element # atoms/mol mass of 1 mole Carbon 6.02x1023 atoms 12.01 g C Copper 6.02x1023 atoms 63.55 g Cu Tin 6.02x1023 atoms 118.71 g Sn Why do the amounts of each look different?
  • 12. Calculating Molar Mass • Methylene chloride (CH2Cl2) o C: 1 atom x 12.01 amu o H: 2 atoms x 1.01 amu o Cl: 2 atoms x 35.45 amu • Formula Mass = 12.0(1) + 1.0(2) + 35.5(2) = 85.0 amu • Molar Mass = 84.95 g/mol
  • 13. Molecules and Moles • The number of molecules in 1mole of a molecular compound is 6.02 x 1023 (same as with atoms in a mole) • 1 mol of water (H2O) contains 1 mol of water molecules but 2 mol of hydrogen atoms and 1 mol oxygen. • How many moles of Ca2+ and F- are in 1 mole of calcium fluoride? o 1 mole of Ca2+ ions and 2 moles of F- ions
  • 14. Molar Mass • Definition o The mass in grams of 1 mole of a substance • We calculate molar mass the same way as formula mass. o Atomic/Formula Molar Mass o Ex. Calcium 40.08 amu = 40.08 g/mol
  • 15. Same Number, Different Mass Practice • What is the formula and molar mass for propane, C3H8? – C: 3 atoms x 12.01 amu = 36.03 amu – H: 8 atoms x 1.01 amu = 8.08 amu Formula Mass = 36.03 amu + 8.08 amu = 44.11 amu Molar Mass = 44.11 g/mol
  • 16. Same Number, Different Mass Practice • What is the formula and molar mass for glucose, C6H12O6? – C: 6 atoms x 12.01 amu = 72.06 amu – H: 12 atoms x 1.01 amu = 12.12 amu – O: 6 atoms x 16.00 amu = 96.00 amu Formula Mass = 72.06 amu + 12.12amu + 96 amu = 180.18 amu Molar Mass = 180.18 g/mol