Characteristics of Perovskite Solar Cells

A comparison among different types of perovskite solar cells. https://www.orkg.org/orkg/comparison/R139642

Education

Characteristics of Perovskite Solar
Cells
Mariana Amorim Fraga

Characteristics of Perovskite Solar Cells
https://www.orkg.org/orkg/comparison/R139642

Visualization 1: Performance of Perovskite Solar Cells
https://www.orkg.org/orkg/comparison/R139642

References
Kojima, Akihiro, Kenjiro Teshima, Yasuo Shirai, and Tsutomu Miyasaka. “Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells.” Journal of the American Chemical
Society 131, no. 17 (April 14, 2009): 6050–6051. doi:10.1021/ja809598r.
Minemoto, Takashi, and Masashi Murata. “Device Modeling of Perovskite Solar Cells Based on Structural Similarity with Thin Film Inorganic Semiconductor Solar Cells.” Journal of Applied
Physics 116, no. 5 (August 7, 2014): 054505. doi:10.1063/1.4891982.
Kumar, Mulmudi Hemant, Sabba Dharani, Wei Lin Leong, Pablo P. Boix, Rajiv Ramanujam Prabhakar, Tom Baikie, Chen Shi, et al. “Lead-Free Halide Perovskite Solar Cells with High
Photocurrents Realized Through Vacancy Modulation.” Advanced Materials 26, no. 41 (September 11, 2014): 7122–7127. doi:10.1002/adma.201401991.
Hao, Feng, Constantinos C. Stoumpos, Duyen Hanh Cao, Robert P. H. Chang, and Mercouri G. Kanatzidis. “Lead-Free Solid-State Organic–inorganic Halide Perovskite Solar Cells.” Nature
Photonics 8, no. 6 (May 4, 2014): 489–494. doi:10.1038/nphoton.2014.82.
Lee, Seojun, and Dong-Won Kang. “Highly Efficient and Stable Sn-Rich Perovskite Solar Cells by Introducing Bromine.” ACS Applied Materials & Interfaces 9, no. 27 (June 30, 2017): 22432–
22439. doi:10.1021/acsami.7b04011.
Zhou, Yu, Xuewen Yin, Qiang Luo, Xingyue Zhao, Duanliang Zhou, Jianhua Han, Feng Hao, et al. “Efficiently Improving the Stability of Inverted Perovskite Solar Cells by Employing
Polyethylenimine-Modified Carbon Nanotubes as Electrodes.” ACS Applied Materials & Interfaces 10, no. 37 (August 20, 2018): 31384–31393. doi:10.1021/acsami.8b10253.
Bansode, Umesh, Rounak Naphade, Onkar Game, Shruti Agarkar, and Satishchandra Ogale. “Hybrid Perovskite Films by a New Variant of Pulsed Excimer Laser Deposition: A Room-Temperature
Dry Process.” The Journal of Physical Chemistry C 119, no. 17 (April 21, 2015): 9177–9185. doi:10.1021/acs.jpcc.5b02561.
Jung, Eui Hyuk, Nam Joong Jeon, Eun Young Park, Chan Su Moon, Tae Joo Shin, Tae-Youl Yang, Jun Hong Noh, and Jangwon Seo. “Efficient, Stable and Scalable Perovskite Solar Cells Using
Poly(3-Hexylthiophene).” Nature 567, no. 7749 (March 2019): 511–515. doi:10.1038/s41586-019-1036-3.
Yang, Zhibin, Adharsh Rajagopal, Chu-Chen Chueh, Sae Byeok Jo, Bo Liu, Ting Zhao, and Alex K.-Y. Jen. “Stable Low-Bandgap Pb-Sn Binary Perovskites for Tandem Solar Cells.” Advanced
Materials 28, no. 40 (August 22, 2016): 8990–8997. doi:10.1002/adma.201602696.
Liao, Weiqiang, Dewei Zhao, Yue Yu, Niraj Shrestha, Kiran Ghimire, Corey R. Grice, Changlei Wang, et al. “Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining
Formamidinium Tin Iodide with Methylammonium Lead Iodide.” Journal of the American Chemical Society 138, no. 38 (September 19, 2016): 12360–12363. doi:10.1021/jacs.6b08337.
Shao, Shuyan, Jian Liu, Giuseppe Portale, Hong-Hua Fang, Graeme R. Blake, Gert H. ten Brink, L. Jan Anton Koster, and Maria Antonietta Loi. “Highly Reproducible Sn-Based Hybrid Perovskite
Solar Cells with 9% Efficiency.” Advanced Energy Materials 8, no. 4 (September 22, 2017): 1702019. doi:10.1002/aenm.201702019.
Wang, Jacob Tse-Wei, Zhiping Wang, Sandeep Pathak, Wei Zhang, Dane W. deQuilettes, Florencia Wisnivesky-Rocca-Rivarola, Jian Huang, et al. “Efficient Perovskite Solar Cells by Metal Ion
Doping.” Energy & Environmental Science 9, no. 9 (2016): 2892–2901. doi:10.1039/c6ee01969b.

Perovskite-based PV have triggered widespread interest in the scientific community because these materials offer the attractive combinations of low cost and theoretically high efficiency. However, several challenges must be overcome for these relatively new PV materials. Among the many important challenges, one is the choice of materials to be used in thin film PV devices.. Based on fundamental principles of solar photovoltaics, this problem focuses on two aspects of the perovskite system: 1) Based on a planar p-i-n device structure, a potential list of p- and n-type charge collecting layers as well as the conductive contacts that could be used with a promising perovskite absorber material was identified, and a proper justification for the selection of each material in the device was given. 2) Three theoretical p-i-n type solar cells were made with the chosen materials and appropriate conductive contacts.

Organometal halide perovskite solar cells: Degradation and stability

Taame Abraha Berhe

Organometal halide perovskite solar cells have evolved in an exponential manner in the two key areas of efficiency and stability. The power conversion efficiency (PCE) reached 20.1% late last year. The key disquiet was stability, which has been limiting practical application, but now the state of the art is promising, being measured in thousands of hours. These improvements have been achieved through the application of different materials, interfaces and device architecture optimizations, especially after the investigation of hole conductor free mesoporous devices incorporating carbon electrodes, which promise stable, low cost and easy device fabrication methods. However, this work is still far from complete.

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Solar Cells: when will they become economically feasible

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The cost of solar cells are rapidly falling through increases in efficiency and reductions in cost per area. But the installation costs have become the largest part of solar cells costs and their costs are not falling. How can these costs be reduced. These slides discuss the potentially installation costs for perovskite and organic cells, along with a general discussion of costs and efficiency. this general discussion covers roll to roll printing and a wide number of solar cells (e.g., quantum dots, cadmium telluride, cadmium indium gallium selenide).

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Graphene is a 2-D atomic layer of carbon atoms with unique electronic properties like outstanding carrier mobility, high carrier saturation velocity, excellent thermal conductivity, high mechanical strength, transparency, thinness, and flexibility which make graphene an excellent choice of material for advanced applications in future solar cell design. We modeled a solar cell using graphene as the front electrode to study its performance and compare the performance with that of other possible contenders- indium tin oxide (ITO), widely used material at present and carbon nanotube (CNT), another promising material in this regard. Numerical solutions of the electrostatic and transport equations were obtained using the finite-element method. It was found that solar cell with graphene electrode can outperform the others. We also studied its performance as a function of various parameters. The developed model and obtained results are important for the design of solar cell with graphene as electrode.

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Use of conventional sources of energy to generate electricity is increasing rapidly due to growing energy demands. This is a major cause of pollution as well and also is an environmental concern for future. Considering this, there is lot of R&D going on in the field of alternate energy sources with recent advancements in technology. One of the most recent advancement is the perovskite solar technology in the photovoltaics industry. The power conversion efficiency of perovskite solar cells has been improved from 9.7 to 20.1% within 4 years which is the fastest advancement ever in the photovoltaic industry. Such a high photovoltaic performance can be attributed to optically high absorption characteristics of the hybrid lead perovskite materials. In this review, different perovskite materials are breifly discussed along with the fundamental details of the hybrid lead halide perovskite materials. The fabrication techniques, stability, device structure and the chemistry of the perovskite structure are also briefly described aiming for a better understanding of these materials and thus highly efficient perovskite solar cell devices. The main focus of this resarch is to understand possible methods to reduce toxicity due to lead and to improve Perovskite stability.

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Photocatalysis has now become an emerging scientific discipline due to its interdisciplinary nature. The wide range of research groups is now working on different aspects of photocatalysis worldwide. It is one of the technology the world looking forward to address environmental as well as energy related issues. Hence we can call it as a technology for the future or a dream technology! We need to overcome too many hurdles to implement this technology in real life. Like any other discipline there is a lot of misunderstanding/ misconceptions in photocatalysis. Most frequently cited article in the field of photocatalysis is by Fujishima and Honda published in 1972 in nature and it has been cited by the photocatalytic community as an origin of photocatalysis. This aspect is not true at all. This article cannot be the origin of photocatalysis. This article only promoted photocatalytic studies. The author itself, actually, started a research career in the “boom” of photocatalytic studies initiated by this article. This small presentation aims to deliver some misconceptions like above in photocatalysis. The entire presentation is based on different personal commentaries written by Jean Mary Hermann and Bunsho Ohtani. Some recent articles relevant to the topic are collected by the speaker itself and put it in one platform.

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