Blockchain technology allows data to be stored and exchanged on a peer-to-peer network in a secure and decentralized manner without intermediaries. It works by validating transactions and adding them as blocks to an immutable blockchain that is shared across all nodes in the network. Blockchains use cryptography to ensure data integrity and prevent alteration of past records. Real-world applications of blockchain include powering cryptocurrencies like Bitcoin, implementing smart contracts, building decentralized applications, and developing government services like in Dubai.