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ANTIFOULINGWRAP
a sustainable solution for biofouling prevention
Andrea Ratti, Arianna Bionda
Design Department, Politecnico di Milano
Sustainable Energy for All by Design
Dilemma – Design, development and sustainability
Cape Town, Wed 28th September 2016
PROBLEMSETTING
Scientificbackground
PURPOSE
The current research on SUSTAINABILITY applied to YACHT DESIGN
and NAVAL ARCHITECTURE is focused on three main areas:
• EFFICIENCY OF THE HULL SHAPE
• EFFICIENCY OF THE PROPULSION SYSTEM
• EFFICIENCY OF THE OBJECT-ENVIRONMENTAL INTERFACE
Antifouling Wrap aims to study alternative and sustainable solutions for
BIOFOULING PREVENTION developing a new generation of
environmental friendly marine coatings for public and private water
transport based on WRAP AND NANOTECHNOLOGY STRATEGIES.
Slime film and heavy calcareous fouling caused
• POWERING PENALTIES UP TO 86% at cruising speed
• FUEL CONSUMPTION UP TO 40% at cruising speed
• AIR EMISSIONS due to increased bunker fuel consumption by the world’s
shipping fleet could INCREASE BETWEEN 38% AND 72% by 2020 (without
corrective actions and introduction of new technologies)
THE PROBLEM- INCREASEOF FUEL CONSUMPTION
It’s estimated that antifouling reduced emissions of 384 million of carbon dioxide and 3.6 million tones of sulphur
dioxide per year, with annual fuel savings of $60billion
Biofouling effect
• increasing of fuel consumption causes GREENHOUSE GAS EMISSIONS IN WATER
• Transfers ALIEN SPECIES outside their distributional range
THE PROBLEM–ENVIROMENTALIMPACT
Antifouling coating effect
• SPREAD OF BIOCIDES AND HEAVY METALS IN WATERS (IMO International
Convention on the Control of Harmful Anti-fouling Systems on Ships, entered into force on 17
September 2008)
• Need of managing the WASHING WATERS in the dry dock areas
THE PROBLEM–HEALTH RISKON WORKERS
Antifoulingcoatingduring thehull maintenancestages
• Exposition to FINE DUST, ALLERGENES and VOCS both during
application and removing stages
RESEARCHSTRATEGY
Project rationale
STATEOFTHE ART– BIOFOULINGSETTLEMENTAND
ANTIFOULINGSTRATEGIES
“NONTOXING” ACTIVE COATINGS
inhibiting or limiting biofouling settlement using NATURAL BIOCIDES
AGENTS: ionic liquids, organic matrixes, advanced embedding and
encapsulating technologies
NONFOULING AND SELF-CLEANING SURFACES
controlling the physicochemical, mechanical, and topographic
properties of the hull surface (Silicones coating)
PROJECTRATIONALE–NON FOULINGAND
SELFCLEANINGSURFACE
Cells and zoospores can be inhibited on micro- and nano-structural
topography, which have also been proved to deter colonization of
invertebrate shells and to alter settlement of algae, barnacles, and bacteria.
BIOINSPIRED TOPOGRAPHIES TO DETER FOULING:
the scanning electron micrographs show the skin denticles of spinner shark in face (a - scale
bar 500 μm) and end views (b - scale bar 250 μm) and image of sharklet antifouling
topography moulded in PDmse (c - scale bars are 20 μm). [ref. Schumacher J. F. (2007)
Biofouling 23]
RESEARCHSTRATEGIES– ANTIFOULINGWRAP
• NO TRANSFER OF SUBSTANCES IN WATER
• HEALTHIER WORKING ENVIRONMENTS
• HULL MAINTENANCE COST AND TIME REDUCED UP TO 80%
• RECYCLE OF SELF-ADHESIVE FILMS AT THE END OF THE LIFE
CYCLE
design a new bio-inspired surfaces on a self-adhesive film having
reduced adhesion strength with marine organism
MATERIALS,TOOLS ANDMETHODS
SAMPLES
Film A: repositionable flocked PVC
Film B: repositionable transparent PVC cadmium free
Film C: transparent polyurethane siliconized
Film D: transparent PVC stabilized
Film E: transparent PVC UV rays and abrasions resistant
Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
SAMPLES
Film A: repositionable flocked PVC
Film B: repositionable PVC cadmium free
Film C: transparent polyurethane siliconized
Film D: transparent PVC stabilized
Film E: transparent PVC UV rays and abrasions resistant
Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
METHOD– TESTPROTOCOL
• evaluate the possibility to apply different films selected on DOUBLE-
CURVED SURFACE;
• verify the ADHESIVE POWER of the films IN WATER;
• analyse the antifouling effect, QUANTIFY AND QUALIFY THE
BIOFOULING GROWTH on the surfaces;
• determine the possibility to CLEAN the wraps instead to replace
them.
LABORATORY tests, IN SITU tests and visual and photographic
inspection, with the support of CHROMATIC ANALYSIS SOFTWARE,
are performed in order to:
METHOD– TESTPROTOCOL
Data collecting on month 1, 2, 3, 6 (3 summer + 3 winter).
Results images were processed through photo-editing tools and
computer analysis for the definition of the biofouling saturation
percentage.
ORIGINAL IMAGE AND PROCESS OF PHOTO-EDITING WITH BLACK CHANNEL
PROPORTION ON 200,000 PIXELS:
Original image adjustment of brightness and
contrast (-10%) (+ 100%); tonal
values correction ​​to reflected light
exclusion
exposure adjustment to highlight
the biofouling on the film colour
background (+ 9%, 0%, 5%)
colour dropout with a
selective filter of green and
yellow channels; white and
black channels reverse on A
and B films
RESULTS
Conclusion and Futuredevelopments
RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH
Antifouling Paint: hydrophilic self-polishing with carbon additive
RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH
Film B: repositionable PVC cadmium free
RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH
Film A: repositionable flocked PVC
RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH
Film A: repositionable flocked PVC
Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
FUTUREDEVELOPMENTS
It’s experimentally demonstrate that THE FLOCKED SURFACE HAS
FOULING RELEASE AND SELF-CLEANING PROPRIETIES. Hull
maintenance TIME REDUCED UP TO 80% in comparison with traditional
painting techniques.
These first results lead us to explore the following areas of investigation:
• FILM SURFACE DESIGN
• FRICTIONAL RESISTANCE OF RUGGED SURFACE
Naval basin test on flat sheets samples and on hull model samples
• INTEGRETIONAL OF ANTIBACTERIACAL COMPOUNDS
ANTIFOULINGWRAP
Thanks for your attention

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Antifouling wrap: a sustainable solutions for biofouling prevention

  • 1. ANTIFOULINGWRAP a sustainable solution for biofouling prevention Andrea Ratti, Arianna Bionda Design Department, Politecnico di Milano Sustainable Energy for All by Design Dilemma – Design, development and sustainability Cape Town, Wed 28th September 2016
  • 3. PURPOSE The current research on SUSTAINABILITY applied to YACHT DESIGN and NAVAL ARCHITECTURE is focused on three main areas: • EFFICIENCY OF THE HULL SHAPE • EFFICIENCY OF THE PROPULSION SYSTEM • EFFICIENCY OF THE OBJECT-ENVIRONMENTAL INTERFACE Antifouling Wrap aims to study alternative and sustainable solutions for BIOFOULING PREVENTION developing a new generation of environmental friendly marine coatings for public and private water transport based on WRAP AND NANOTECHNOLOGY STRATEGIES.
  • 4. Slime film and heavy calcareous fouling caused • POWERING PENALTIES UP TO 86% at cruising speed • FUEL CONSUMPTION UP TO 40% at cruising speed • AIR EMISSIONS due to increased bunker fuel consumption by the world’s shipping fleet could INCREASE BETWEEN 38% AND 72% by 2020 (without corrective actions and introduction of new technologies) THE PROBLEM- INCREASEOF FUEL CONSUMPTION It’s estimated that antifouling reduced emissions of 384 million of carbon dioxide and 3.6 million tones of sulphur dioxide per year, with annual fuel savings of $60billion
  • 5. Biofouling effect • increasing of fuel consumption causes GREENHOUSE GAS EMISSIONS IN WATER • Transfers ALIEN SPECIES outside their distributional range THE PROBLEM–ENVIROMENTALIMPACT Antifouling coating effect • SPREAD OF BIOCIDES AND HEAVY METALS IN WATERS (IMO International Convention on the Control of Harmful Anti-fouling Systems on Ships, entered into force on 17 September 2008) • Need of managing the WASHING WATERS in the dry dock areas
  • 6. THE PROBLEM–HEALTH RISKON WORKERS Antifoulingcoatingduring thehull maintenancestages • Exposition to FINE DUST, ALLERGENES and VOCS both during application and removing stages
  • 8. STATEOFTHE ART– BIOFOULINGSETTLEMENTAND ANTIFOULINGSTRATEGIES “NONTOXING” ACTIVE COATINGS inhibiting or limiting biofouling settlement using NATURAL BIOCIDES AGENTS: ionic liquids, organic matrixes, advanced embedding and encapsulating technologies NONFOULING AND SELF-CLEANING SURFACES controlling the physicochemical, mechanical, and topographic properties of the hull surface (Silicones coating)
  • 9. PROJECTRATIONALE–NON FOULINGAND SELFCLEANINGSURFACE Cells and zoospores can be inhibited on micro- and nano-structural topography, which have also been proved to deter colonization of invertebrate shells and to alter settlement of algae, barnacles, and bacteria. BIOINSPIRED TOPOGRAPHIES TO DETER FOULING: the scanning electron micrographs show the skin denticles of spinner shark in face (a - scale bar 500 μm) and end views (b - scale bar 250 μm) and image of sharklet antifouling topography moulded in PDmse (c - scale bars are 20 μm). [ref. Schumacher J. F. (2007) Biofouling 23]
  • 10. RESEARCHSTRATEGIES– ANTIFOULINGWRAP • NO TRANSFER OF SUBSTANCES IN WATER • HEALTHIER WORKING ENVIRONMENTS • HULL MAINTENANCE COST AND TIME REDUCED UP TO 80% • RECYCLE OF SELF-ADHESIVE FILMS AT THE END OF THE LIFE CYCLE design a new bio-inspired surfaces on a self-adhesive film having reduced adhesion strength with marine organism
  • 12. SAMPLES Film A: repositionable flocked PVC Film B: repositionable transparent PVC cadmium free Film C: transparent polyurethane siliconized Film D: transparent PVC stabilized Film E: transparent PVC UV rays and abrasions resistant Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
  • 13. SAMPLES Film A: repositionable flocked PVC Film B: repositionable PVC cadmium free Film C: transparent polyurethane siliconized Film D: transparent PVC stabilized Film E: transparent PVC UV rays and abrasions resistant Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
  • 14. METHOD– TESTPROTOCOL • evaluate the possibility to apply different films selected on DOUBLE- CURVED SURFACE; • verify the ADHESIVE POWER of the films IN WATER; • analyse the antifouling effect, QUANTIFY AND QUALIFY THE BIOFOULING GROWTH on the surfaces; • determine the possibility to CLEAN the wraps instead to replace them. LABORATORY tests, IN SITU tests and visual and photographic inspection, with the support of CHROMATIC ANALYSIS SOFTWARE, are performed in order to:
  • 15. METHOD– TESTPROTOCOL Data collecting on month 1, 2, 3, 6 (3 summer + 3 winter). Results images were processed through photo-editing tools and computer analysis for the definition of the biofouling saturation percentage. ORIGINAL IMAGE AND PROCESS OF PHOTO-EDITING WITH BLACK CHANNEL PROPORTION ON 200,000 PIXELS: Original image adjustment of brightness and contrast (-10%) (+ 100%); tonal values correction ​​to reflected light exclusion exposure adjustment to highlight the biofouling on the film colour background (+ 9%, 0%, 5%) colour dropout with a selective filter of green and yellow channels; white and black channels reverse on A and B films
  • 17. RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH Antifouling Paint: hydrophilic self-polishing with carbon additive
  • 20. RESULTS–QUANTIFYANDQUALIFYTHE BIOFOULINGGROWTH Film A: repositionable flocked PVC Antifouling Paint (AP): hydrophilic self-polishing with carbon additive
  • 21. FUTUREDEVELOPMENTS It’s experimentally demonstrate that THE FLOCKED SURFACE HAS FOULING RELEASE AND SELF-CLEANING PROPRIETIES. Hull maintenance TIME REDUCED UP TO 80% in comparison with traditional painting techniques. These first results lead us to explore the following areas of investigation: • FILM SURFACE DESIGN • FRICTIONAL RESISTANCE OF RUGGED SURFACE Naval basin test on flat sheets samples and on hull model samples • INTEGRETIONAL OF ANTIBACTERIACAL COMPOUNDS