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1895 To overcome expansion problems G.V. Black developed a formula for
modern amalgam alloy 67% silver, 27% tin, 5% copper, 1% zinc
Spheroidal
Part two
the setting reaction begins with dissolution of silver and tin into liquid
mercury; most of the product phases precipitate in the liquid mercury.
As can be seen from the reaction, not all of the alloy particles dissolve in
the mercury. On the contrary, a considerable amount remains, so that the
final structure is one of a core of γ held together by a matrix of
predominantly γ1, which is interspersed with γ2.
a core of γ held together by a matrix of predominantly γ1, which is interspersed with
γ2.
traditional dental amalgams suffer from a
lack of strength and excessive creep and
corrosion.
ADVANCES IN AMALGAM
ADVANCES IN AMALGAM
• GALLIUM ALOYS
• BONDED AMALGAM
• FLOURIDATED AMALGAM
• CONSOLIDATED SILVER ALLOY
• LOW MERCURY ALLOY
• INDIUM CONTAINING
GALLIUM ALLOYS
• Gallium is used to replace mercury & make mercury
free alloy.
• Gallium has lowest melting point
• Unique property  increased wetting – evenly on the
tooth surface.
Advantages
Good compressive strength
Less creep
Good wettability
Rapid solidification
Disadvantages
• sticky
• Corrodes easily
• Extremely technique sensitive
• Expensive
• Excessive expansion even after
setting
FLOURIDATED AMALGAM
• Flourine – cariostatic
• Objective : to solve recurrent caries.
CONSOLIDATED SILVER ALLOY
• Ag-Sn particles of amalgam are coated with silver.
• Mercury free
• Patented by ADA-NIST (AMERICAN DENTAL
ASSOCIATION- NATIONAL INSTITUTE OF STANDARDS
AND TECH)
Disadvantages
difficult to condense
Internal voids present
Poor adaptation to walls
LOW MERCURY AMALGAM
• Mercury reduced by 15-20%
INDIUM CONTAINING
• AIM : To reduce mercury vapours from amalgam
• Powell added pure indium to high copper amlagm
BONDED AMALGAM
• 1897  BALDWIN TECHNIQUE : ZnPO4 / GIC applied
as base and condense amalgam before it sets.
• 1978 ZAIDIACKER TECHNIQUE :
• ZnPolycarboxylate + Silver alloy particles
indications
• short tooth clinically
• Foundation for full crowns
• For extra retention
• In extensive caries in posteriors
• In conservative preparations

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Amalgam

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  • 7. 1895 To overcome expansion problems G.V. Black developed a formula for modern amalgam alloy 67% silver, 27% tin, 5% copper, 1% zinc
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  • 36. the setting reaction begins with dissolution of silver and tin into liquid mercury; most of the product phases precipitate in the liquid mercury. As can be seen from the reaction, not all of the alloy particles dissolve in the mercury. On the contrary, a considerable amount remains, so that the final structure is one of a core of γ held together by a matrix of predominantly γ1, which is interspersed with γ2.
  • 37. a core of γ held together by a matrix of predominantly γ1, which is interspersed with γ2.
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  • 50. traditional dental amalgams suffer from a lack of strength and excessive creep and corrosion.
  • 52. ADVANCES IN AMALGAM • GALLIUM ALOYS • BONDED AMALGAM • FLOURIDATED AMALGAM • CONSOLIDATED SILVER ALLOY • LOW MERCURY ALLOY • INDIUM CONTAINING
  • 53. GALLIUM ALLOYS • Gallium is used to replace mercury & make mercury free alloy. • Gallium has lowest melting point • Unique property  increased wetting – evenly on the tooth surface. Advantages Good compressive strength Less creep Good wettability Rapid solidification Disadvantages • sticky • Corrodes easily • Extremely technique sensitive • Expensive • Excessive expansion even after setting
  • 54. FLOURIDATED AMALGAM • Flourine – cariostatic • Objective : to solve recurrent caries.
  • 55. CONSOLIDATED SILVER ALLOY • Ag-Sn particles of amalgam are coated with silver. • Mercury free • Patented by ADA-NIST (AMERICAN DENTAL ASSOCIATION- NATIONAL INSTITUTE OF STANDARDS AND TECH) Disadvantages difficult to condense Internal voids present Poor adaptation to walls
  • 56. LOW MERCURY AMALGAM • Mercury reduced by 15-20%
  • 57. INDIUM CONTAINING • AIM : To reduce mercury vapours from amalgam • Powell added pure indium to high copper amlagm
  • 58. BONDED AMALGAM • 1897  BALDWIN TECHNIQUE : ZnPO4 / GIC applied as base and condense amalgam before it sets. • 1978 ZAIDIACKER TECHNIQUE : • ZnPolycarboxylate + Silver alloy particles indications • short tooth clinically • Foundation for full crowns • For extra retention • In extensive caries in posteriors • In conservative preparations