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Life Cycle Assessment of Fuel
         Ethanol in Brazil




Prof. Dr. Aldo Roberto Ometto

Production Engineering Department
Engineering School of São Carlos
University of São Paulo
AGENDA

•   Sustainability and Environmental Management in
    Agribusiness


•   Life Cycle Impact Assessment (LCIA) of sugar cane
    fuel ethanol in Brazil


•   Sustainable Future Strategies for Fuel Ethanol in
    Brazil
Sustainability Drivers

                            Social




                         Sustainability

         Environmental                    Economic

  Time                                                 Local
Dimension                                            Dimension

                         Society
Environmental Diversity
Agribusiness Diversity
Premise
Environmental Management
Environmental                           Process and
  Features                           Product Life Cycle


Land Use Planning                  Inventory Analysis



           Environmental Analysis



     Monitoring                      Mitigation

                    SOUZA (2000)
Environmental Analysis

                   Territorial                            Analytical
                   Analysis                                 Tools



         Geoinformation                               Life Cycle
                                                     Assessment

         Soils

    Topography
  Hidrography
      Geology
 Infrastructure

Other variables: land use,
socioeconomic aspects


  Potentials and
  constraints
                                              Source: www. ean-int.org/agr_food_meat_livestock
Monitoring


                                                      Internet / Intranet


                                                         Open Source


                                                         (Geo) Traceability
Monitored Products

                                                       Life Cycle Units
  Life Cycle Unit
                                    Sensor   Input



                                    Processing
                     IT-Interface                    Actor Output   Source for LCU: TU Berlin, 2004
AGENDA
•   Brazilian Experience in Fuel Ethanol Production


•   Sustainability and Environmental Management in
    Agribusiness


•   Life Cycle Impact Assessment (LCIA) of sugar cane
    fuel ethanol in Brazil


•   Sustainable Future Strategies for Fuel Ethanol in
    Brazil
Brazilian Fuel Alcohol
     Positive Aspects
 Ethanol: – a renewable fuel (better for global warming);
          – less pollutant than fossil fuel during use phase.
 System: high potential biomass energy production.

     Negative Aspects
 Environmental impacts and energy losses during
the activities of the life cycle:
   – Poor biodiversity; intensive use of
   pesticides, water, erosion, burning and others.
Ethanol Life Cycle Activities
Soil Preparation
Sugar Cane Plantation
Pesticide Application
Irrigation with Recycled Products
Harvesting
Industrial Alcohol Process
Electrical Cogeneration Plant
Transportation
The use of fuel alcohol
Ethanol Life Cycle Activities
 Soil   Preparation Equipment
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
AMA
 Sugar cane milling
 Decanter for the juice
 Fermentators
 Distillation collums
 Vinasse Channels for irrigation
AMA
Electricity Cogenerator




 Boiler           Energy Generator
Matrix: Life Cycle Impact Assessment
A) Systems Establishing (Acquisition of Land and Equipment, Civil
    and Industrial Projects and Civil and Industrial Buildings)
1) Soil Preparation
2) Sugar Cane Plantation
3) Application of agrochemicals
4) Harvesting
5) Industrial Production of Alcohol
6) Steam and electricity cogeneration
7) Irrigation
8) Ethanol Distribution
9) Use of Alcohol as fuel
B) Decommissioning of installations
Environmental System                              Life Cycle Fuel Ethanol Activities
  Environmental    Environmental     Environmental    Raw Material Extraction Industrial     Pos Industrial
   Sub-system       Component           Factor
                                                      A    1    2     3    4     5     6    7    8   9   B

Atmospheric       Atmospheric      Climate            -    -    -+         -                         +    +
                                   Air quality        -         -+    -    -     -     -    -    -   +    +
                                   Soil Quality and   -    -     -    -    -     +          +
Terrestrial       Physical         Erosion
                                   Agricultural            -    -          -
                  Biological       Vegetation         -    -    -          -
                                   Fauna              -         -     -    -
                  Land Use                            -    -    -          -     -
                  Physical-        Rivers             -    -    -     -    -     -     -     -   -
Aquatic           Chemical-        Groundwater        -    -    -     -          -     -     -   -
                  Biological
                                   Biodiversity       -    -    -     -    -     -           -   -
                  Infrastructure   Transport          +               -    -                 -   -
                                   Water use                    -          -     -
                  Demography       Habitant                                -                 -
                                   Migration           -   -+    -    -    -                              -
Cultural -        Economical       Agriculture        -+   +    -+    -    -     -+         +        +   -+
Economic - Social                  Industry            +   +          +    -      +    +    -        +   -+
                                   Business            +                   -      +    +         +   +
                  Life quality     Education           -                   -           +
                                   Health             -               -    -     -     -     -   -
                                   Employment         -    -          -    -     +     +     -            -
                  Landscape - Historical - Cultural    -   -     -         -                         +
                  Political - Institutional           -+        -+   -+    -     -+    +     -   -   +    -
Matrix Results
Most harmful activities:
1. Harvesting – burning:
          Air emissions; health problems; erosion;
          Losses of organic matter,
           microorganisms, vegetation, industrial
           productivity and energy


                2. Conventional Soil Conservation; Plantation
                    and Pesticide Application:
                       High toxicity: health problems, water and soil
                        contamination

 3. Manufacturing:
           High water consumption and
            vinasse production
EDIP Method

            Main Assumptions
 The functional unit of this study is 10000
kilometers.
Considering a mean consumption of 8 km/l, the
reference flow is 1000 kg of ethanol.
The results are calculated assuming the average
sugar cane and ethanol productivity from 2001 to
2008, which are 72t sugar cane/ha and 85 l ethanol/ t
sugar cane, according to the primary data.
For the reference flow (1t of ethanol), the sugar
cane plantation area is 0,20 ha, which is the needed
land-use for this one-year crop cultivation.
Fuel Ethanol Product System
Life Cycle Impact Assessment
             EDIP
Environmental Impact Categories
       (Impact Potentials)

      • Global Warming
      • Ozone Formation
      • Acidification
      • Nutrient Enrichment
      • Ecotoxicity
      • Human Toxicity
Global Warming
Photochemical Ozone Formation
Acidification
Nutrient Enrichment
Nutrient Enrichment
Ecotoxicity in Soil
Ecotoxicity in Water (Chronic)
Human Toxicity via Air
Human Toxicity via Soil
Human Toxicity via Water
Life Cycle Impact Assessment
         Thermodynamic Analysis

  Exergy: work potential that can be obtained as the
  system changes from the given state to a state of
  equilibrium with the environment (dead state) while
  exchanging heat solely with the environment

         ex straw = B (LHV + hw Zw) + exw Zw (1)

                      ZH 2        ZO 2         ZH 2 
               
         1.0412 0.2160     0.2499      10.7884
                       ZC          ZC          ZC   2
 palha
                                 ZO 2
                         10.3035
                                  ZC
Life Cycle Impact Assessment


            Exergy Results


• The specific exergy of sugarcane
straw is calculated as 17,761.53 kJ/kg

• Bagasse has a specific exergy of
10,259.335 kJ/kg
Life Cycle Assessment




• Social


• Costs
AGENDA
•   Brazilian Experience in Fuel Ethanol Production


•   Sustainability and Environmental Management in
    Agribusiness


•   Life Cycle Impact Assessment (LCIA) of sugar cane
    fuel ethanol in Brazil


•   Sustainable Future Strategies for Fuel Ethanol in
    Brazil
Sustainable Future Directions

   No Burning
   Electricity production from straw
   Less pesticides
   Less internal transportation
   Less fossil fuel use
   Less water consumption in industry
   Species diversity mantaining natural vegetation
   Ethanol combustion otimization in vehicles
   Economic, Social and Environmental integrated
    system
GERIPA: Ethanol and Food Production
Thank you



Prof. Dr. Aldo Roberto Ometto

 E-mail: aometto@sc.usp.br

   Tel. +55 (16) 3373-8608

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Aldo Ometto

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  • 4. Life Cycle Assessment of Fuel Ethanol in Brazil Prof. Dr. Aldo Roberto Ometto Production Engineering Department Engineering School of São Carlos University of São Paulo
  • 5. AGENDA • Sustainability and Environmental Management in Agribusiness • Life Cycle Impact Assessment (LCIA) of sugar cane fuel ethanol in Brazil • Sustainable Future Strategies for Fuel Ethanol in Brazil
  • 6. Sustainability Drivers Social Sustainability Environmental Economic Time Local Dimension Dimension Society
  • 10. Environmental Management Environmental Process and Features Product Life Cycle Land Use Planning Inventory Analysis Environmental Analysis Monitoring Mitigation SOUZA (2000)
  • 11. Environmental Analysis Territorial Analytical Analysis Tools Geoinformation Life Cycle Assessment Soils Topography Hidrography Geology Infrastructure Other variables: land use, socioeconomic aspects Potentials and constraints Source: www. ean-int.org/agr_food_meat_livestock
  • 12. Monitoring Internet / Intranet Open Source (Geo) Traceability Monitored Products Life Cycle Units Life Cycle Unit Sensor Input Processing IT-Interface Actor Output Source for LCU: TU Berlin, 2004
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  • 14. AGENDA • Brazilian Experience in Fuel Ethanol Production • Sustainability and Environmental Management in Agribusiness • Life Cycle Impact Assessment (LCIA) of sugar cane fuel ethanol in Brazil • Sustainable Future Strategies for Fuel Ethanol in Brazil
  • 15. Brazilian Fuel Alcohol Positive Aspects  Ethanol: – a renewable fuel (better for global warming); – less pollutant than fossil fuel during use phase.  System: high potential biomass energy production. Negative Aspects  Environmental impacts and energy losses during the activities of the life cycle: – Poor biodiversity; intensive use of pesticides, water, erosion, burning and others.
  • 16. Ethanol Life Cycle Activities Soil Preparation Sugar Cane Plantation Pesticide Application Irrigation with Recycled Products Harvesting Industrial Alcohol Process Electrical Cogeneration Plant Transportation The use of fuel alcohol
  • 17. Ethanol Life Cycle Activities
  • 18.  Soil Preparation Equipment
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  • 20. AMA
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  • 27. AMA
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  • 30. AMA
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  • 35. AMA
  • 36. AMA
  • 37. AMA
  • 38. AMA
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  • 40.  Sugar cane milling
  • 41.  Decanter for the juice
  • 44.  Vinasse Channels for irrigation
  • 45. AMA
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  • 48. Electricity Cogenerator  Boiler  Energy Generator
  • 49. Matrix: Life Cycle Impact Assessment A) Systems Establishing (Acquisition of Land and Equipment, Civil and Industrial Projects and Civil and Industrial Buildings) 1) Soil Preparation 2) Sugar Cane Plantation 3) Application of agrochemicals 4) Harvesting 5) Industrial Production of Alcohol 6) Steam and electricity cogeneration 7) Irrigation 8) Ethanol Distribution 9) Use of Alcohol as fuel B) Decommissioning of installations
  • 50. Environmental System Life Cycle Fuel Ethanol Activities Environmental Environmental Environmental Raw Material Extraction Industrial Pos Industrial Sub-system Component Factor A 1 2 3 4 5 6 7 8 9 B Atmospheric Atmospheric Climate - - -+ - + + Air quality - -+ - - - - - - + + Soil Quality and - - - - - + + Terrestrial Physical Erosion Agricultural - - - Biological Vegetation - - - - Fauna - - - - Land Use - - - - - Physical- Rivers - - - - - - - - - Aquatic Chemical- Groundwater - - - - - - - - Biological Biodiversity - - - - - - - - Infrastructure Transport + - - - - Water use - - - Demography Habitant - - Migration - -+ - - - - Cultural - Economical Agriculture -+ + -+ - - -+ + + -+ Economic - Social Industry + + + - + + - + -+ Business + - + + + + Life quality Education - - + Health - - - - - - - Employment - - - - + + - - Landscape - Historical - Cultural - - - - + Political - Institutional -+ -+ -+ - -+ + - - + -
  • 51. Matrix Results Most harmful activities: 1. Harvesting – burning:  Air emissions; health problems; erosion;  Losses of organic matter, microorganisms, vegetation, industrial productivity and energy 2. Conventional Soil Conservation; Plantation and Pesticide Application:  High toxicity: health problems, water and soil contamination 3. Manufacturing:  High water consumption and vinasse production
  • 52. EDIP Method Main Assumptions  The functional unit of this study is 10000 kilometers. Considering a mean consumption of 8 km/l, the reference flow is 1000 kg of ethanol. The results are calculated assuming the average sugar cane and ethanol productivity from 2001 to 2008, which are 72t sugar cane/ha and 85 l ethanol/ t sugar cane, according to the primary data. For the reference flow (1t of ethanol), the sugar cane plantation area is 0,20 ha, which is the needed land-use for this one-year crop cultivation.
  • 54. Life Cycle Impact Assessment EDIP Environmental Impact Categories (Impact Potentials) • Global Warming • Ozone Formation • Acidification • Nutrient Enrichment • Ecotoxicity • Human Toxicity
  • 61. Ecotoxicity in Water (Chronic)
  • 65. Life Cycle Impact Assessment Thermodynamic Analysis Exergy: work potential that can be obtained as the system changes from the given state to a state of equilibrium with the environment (dead state) while exchanging heat solely with the environment ex straw = B (LHV + hw Zw) + exw Zw (1) ZH 2 ZO 2  ZH 2   1.0412 0.2160 0.2499 10.7884 ZC ZC  ZC   2  palha ZO 2 10.3035 ZC
  • 66. Life Cycle Impact Assessment Exergy Results • The specific exergy of sugarcane straw is calculated as 17,761.53 kJ/kg • Bagasse has a specific exergy of 10,259.335 kJ/kg
  • 67. Life Cycle Assessment • Social • Costs
  • 68. AGENDA • Brazilian Experience in Fuel Ethanol Production • Sustainability and Environmental Management in Agribusiness • Life Cycle Impact Assessment (LCIA) of sugar cane fuel ethanol in Brazil • Sustainable Future Strategies for Fuel Ethanol in Brazil
  • 69. Sustainable Future Directions  No Burning  Electricity production from straw  Less pesticides  Less internal transportation  Less fossil fuel use  Less water consumption in industry  Species diversity mantaining natural vegetation  Ethanol combustion otimization in vehicles  Economic, Social and Environmental integrated system
  • 70. GERIPA: Ethanol and Food Production
  • 71. Thank you Prof. Dr. Aldo Roberto Ometto E-mail: aometto@sc.usp.br Tel. +55 (16) 3373-8608