This document summarizes field testing of injecting carbon dioxide into coalbed methane wells near Fenn and Big Valley, Alberta. It describes injecting over 91,500 cubic meters of CO2 vapor into well FBV 4A over 12 separate injections. Post-injection production testing found the CO2 sweep efficiency was 46% and the well productivity increased. A second well, FBV 5, was drilled and injected with a mixture of nitrogen and CO2 to further understand enhancing methane recovery and CO2 storage in these coal seams.
Enhanced fluidized bed methanation over a Ni Al2O3 catalyst for production of...Pengcheng Li
This document summarizes a study that investigated the fluidization behavior and CO methanation performance of a Ni/Al2O3 catalyst in a fluidized bed reactor for producing synthetic natural gas. The researchers found that the pure Ni/Al2O3 catalyst failed to properly fluidize on its own due to particle sizes between 10 and 100 μm, but fluidization was improved by adding larger Al2O3 particles. Methanation performance in the fluidized bed reactor increased substantially with the Al2O3 addition. Temperature was found to control the methanation reaction mechanism, with surface reactions dominating at lower temperatures and external diffusion controlling at higher temperatures. Stability tests showed the fluidized bed reactor had higher CO conversion, methane selectivity
Abstracts of publications in ppc whilst affiliated with sask powerEmmanuel Quagraine
1) The document summarizes 5 journal publications by Emmanuel K. Quagraine related to power plant chemistry while affiliated with SaskPower.
2) The publications provide evidence that chlorinated compounds can ingress into power plant condensers in gaseous form through weak seals or porous brass tubesheets, causing chloride contamination issues. Regression models were able to confirm this hypothesis.
3) One publication evaluates using a biologically active carbon filter in series with a granular activated carbon filter for removing organics in boiler makeup water, finding over 80% removal with the two filters working synergistically.
The team designed a water treatment process to remove chromium(VI) and copper(II) ions from contaminated water to meet EPA standards. The process uses a batch reactor with a stirring mechanism to perform oxidation-reduction reactions using ferrous sulfate and iron(0) to reduce the toxic ions to less harmful and precipitated forms. Treated water flows through activated carbon filtration before collection. The system was designed to be low-cost using recycled materials when possible, with an estimated total cost of $57.71.
11.mass transfer coefficient evaluation for lab scale fermenter using sodium ...Alexander Decker
This document discusses using the sodium sulfite oxidation method and response surface methodology to evaluate the volumetric mass transfer coefficient in a lab-scale fermenter. 13 experiments were conducted using a central composite design to determine the effects of impeller speed and airflow rate on the mass transfer coefficient. An empirical expression was developed and found to explain over 92% of the variability in the responses. The results showed that the mass transfer coefficient increases with decreasing impeller speed and increasing airflow rate. The study aimed to optimize conditions for the maximum mass transfer coefficient.
Mass transfer coefficient evaluation for lab scale fermenter using sodium sul...Alexander Decker
This document discusses using the sodium sulfite oxidation method and response surface methodology to evaluate the volumetric mass transfer coefficient in a lab-scale fermenter. 13 experiments were conducted using a central composite design to determine the effects of impeller speed and airflow rate on the mass transfer coefficient. An empirical expression was developed and found to explain over 92% of the variability in the responses. The mass transfer coefficient was found to increase with decreasing impeller speed and increasing airflow rate. The study aimed to optimize the mass transfer coefficient using statistical experimental design.
Presentation given by Auli Niemi of Uppsala University on "PANACEA & TRUST Projects Status update" at the EC FP7 Projects: Leading the way in CCS implementation event, London, 14-15 April 2014
The document summarizes a research paper that experimentally tested and simulated through ECLIPSE software the recovery of heavy oil using injections of carbon dioxide and nitrogen gas. The experimental results using a POROPERM machine and Relative Permeability System machine were inconclusive due to equipment limitations. The ECLIPSE simulations showed that carbon dioxide recovered slightly more oil (37.092 STB) than nitrogen (37.084 STB) over 500 days. The conclusions determined carbon dioxide to be a better injection gas based on its properties, but noted nitrogen is more abundant and cheaper. Recommendations were provided for improvements to future studies.
Enhanced fluidized bed methanation over a Ni Al2O3 catalyst for production of...Pengcheng Li
This document summarizes a study that investigated the fluidization behavior and CO methanation performance of a Ni/Al2O3 catalyst in a fluidized bed reactor for producing synthetic natural gas. The researchers found that the pure Ni/Al2O3 catalyst failed to properly fluidize on its own due to particle sizes between 10 and 100 μm, but fluidization was improved by adding larger Al2O3 particles. Methanation performance in the fluidized bed reactor increased substantially with the Al2O3 addition. Temperature was found to control the methanation reaction mechanism, with surface reactions dominating at lower temperatures and external diffusion controlling at higher temperatures. Stability tests showed the fluidized bed reactor had higher CO conversion, methane selectivity
Abstracts of publications in ppc whilst affiliated with sask powerEmmanuel Quagraine
1) The document summarizes 5 journal publications by Emmanuel K. Quagraine related to power plant chemistry while affiliated with SaskPower.
2) The publications provide evidence that chlorinated compounds can ingress into power plant condensers in gaseous form through weak seals or porous brass tubesheets, causing chloride contamination issues. Regression models were able to confirm this hypothesis.
3) One publication evaluates using a biologically active carbon filter in series with a granular activated carbon filter for removing organics in boiler makeup water, finding over 80% removal with the two filters working synergistically.
The team designed a water treatment process to remove chromium(VI) and copper(II) ions from contaminated water to meet EPA standards. The process uses a batch reactor with a stirring mechanism to perform oxidation-reduction reactions using ferrous sulfate and iron(0) to reduce the toxic ions to less harmful and precipitated forms. Treated water flows through activated carbon filtration before collection. The system was designed to be low-cost using recycled materials when possible, with an estimated total cost of $57.71.
11.mass transfer coefficient evaluation for lab scale fermenter using sodium ...Alexander Decker
This document discusses using the sodium sulfite oxidation method and response surface methodology to evaluate the volumetric mass transfer coefficient in a lab-scale fermenter. 13 experiments were conducted using a central composite design to determine the effects of impeller speed and airflow rate on the mass transfer coefficient. An empirical expression was developed and found to explain over 92% of the variability in the responses. The results showed that the mass transfer coefficient increases with decreasing impeller speed and increasing airflow rate. The study aimed to optimize conditions for the maximum mass transfer coefficient.
Mass transfer coefficient evaluation for lab scale fermenter using sodium sul...Alexander Decker
This document discusses using the sodium sulfite oxidation method and response surface methodology to evaluate the volumetric mass transfer coefficient in a lab-scale fermenter. 13 experiments were conducted using a central composite design to determine the effects of impeller speed and airflow rate on the mass transfer coefficient. An empirical expression was developed and found to explain over 92% of the variability in the responses. The mass transfer coefficient was found to increase with decreasing impeller speed and increasing airflow rate. The study aimed to optimize the mass transfer coefficient using statistical experimental design.
Presentation given by Auli Niemi of Uppsala University on "PANACEA & TRUST Projects Status update" at the EC FP7 Projects: Leading the way in CCS implementation event, London, 14-15 April 2014
The document summarizes a research paper that experimentally tested and simulated through ECLIPSE software the recovery of heavy oil using injections of carbon dioxide and nitrogen gas. The experimental results using a POROPERM machine and Relative Permeability System machine were inconclusive due to equipment limitations. The ECLIPSE simulations showed that carbon dioxide recovered slightly more oil (37.092 STB) than nitrogen (37.084 STB) over 500 days. The conclusions determined carbon dioxide to be a better injection gas based on its properties, but noted nitrogen is more abundant and cheaper. Recommendations were provided for improvements to future studies.
This document summarizes a study on using a triphasic segmented flow millireactor for rapid nanoparticle-catalyzed gas-liquid reactions with facile catalyst recovery. Key points:
- The millireactor creates a pseudo-biphasic gas-liquid segmented flow using an aqueous catalyst phase and an organic substrate/product phase, allowing order-of-magnitude faster reactions than a batch reactor.
- For the hydrogenation of 1-hexene catalyzed by Rh nanoparticles, the millireactor achieves 80% conversion in 1 minute versus 30 minutes for a batch reactor.
- Faster mass transfer in the millireactor is achieved by reducing the diffusion distance for reactants through thinner organic segments at
Electro kinetic fractal dimension for characterizing shajara reservoirsKhalid Al-Khidir
This document discusses using electro kinetic parameters to characterize reservoirs in the Shajara Formation in Saudi Arabia. The author calculates fractal dimensions from relationships between streaming potential, electro osmosis coupling coefficients, and water saturation. Samples were collected from three reservoir units in the formation. Fractal dimensions were determined from plots of streaming potential ratios vs. water saturation and capillary pressure vs. water saturation. Higher fractal dimensions correlated with increased permeability and were found in upper reservoir units compared to lower units. The fractal dimension analysis helps divide the reservoirs into three units and assess their heterogeneity and quality.
1) Groundwater at an industrial site in Portland, Oregon was impacted by TCE and other chlorinated solvents used from 1980-1989. Additional impacts were from historical disposal of manufactured gas plant waste containing naphthalene and other compounds.
2) In situ chemical reduction was used to treat the TCE source area, demonstrating success in removing TCE by 2013. Samples found additional contaminants of interest (COIs) like 1,1,2-trichloroethane in the gas plant waste.
3) The study analyzed data on the COIs to understand their environmental fate and the effectiveness of treatment. Models were used to predict contaminant movement between gas plant waste and groundwater. Degradation
The document presents a study on the hydrodynamic behavior of an external loop airlift reactor for two-phase systems. Experiments were conducted to determine the gas holdup and pressure drop characteristics of various electrolyte and solvent solutions at different concentrations and flow rates. The results show that gas holdup increases with superficial gas velocity and solvent concentration but decreases with electrolyte concentration, while pressure drop increases with gas velocity, liquid flow rate, and solution concentration.
The document outlines the design of a wetland methane flux chamber to measure methane emissions from forest soils and marshes. The objectives are to design a portable chamber compatible with a LiCor 7810 Trace Gas Analyzer that can cover 2m tall wetland vegetation. A literature review informed the design process. A prototype chamber was built out of PVC and tested in the laboratory by collecting soil samples and measuring methane levels over time. The results were analyzed to calculate methane flux and compare different soils and chamber setups.
The document summarizes the evolution of the thin film rotating disk electrode (TF-RDE) technique for characterizing oxygen reduction reaction (ORR) activity of platinum electrocatalysts. Early work developed ink formulations containing platinum catalysts and Nafion ionomer to create relatively thick catalyst layers. Subsequent studies examined how thin Nafion films or "caps" affected oxygen diffusion measurements. More recent improvements involved optimizing ink dispersion and fabrication methods to produce more uniform, thinner catalyst layers. However, the document notes that reported ORR activities still vary significantly depending on experimental conditions. Specifically, the presence of Nafion ionomer creates a complex interface that can affect measured kinetics in poorly defined ways.
The Comprehensive Computation Model of Gas Permeability Based on Fuzzy Comple...IJMERJOURNAL
ABSTRACT: In this paper, in order to reveal the gas migration law of loaded coal under multi-factor coupling, the researches on gas permeability were carried out under different influencing factors, namely effective stress, gas pressure, confining pressure and moisture content, with the self-developed experimental platform of gas permeability. Meanwhile, the function relationship of each influencing factor and permeability was established by use of the mathematical least squares principle. In this paper, the comprehensive expression of gas permeability was established, which is based on fuzzy complementary judgment matrix. And the comprehensive expression was drawn from the experimental conclusions of the loaded coal under multi-factor coupling.
Research Inventy : International Journal of Engineering and Science is publis...researchinventy
The document summarizes a study on the simultaneous extraction of copper and iron from chalcopyrite concentrates in hydrochloric acid media using chlorine gas. The study investigated the effect of various parameters including acid concentration, temperature, sodium chloride addition, and time on the dissolution of copper and iron. Key findings include that copper and iron dissolution increased with acid concentration and temperature but decreased with the addition of sodium chloride. Dissolution was also found to increase over time. The best conditions for copper extraction were determined to be 333K temperature, 10% concentrate, and 1 hour leaching time.
This document provides information about assessing the maturity and stability of compost. It introduces the Compost Maturity Index developed by the California Compost Quality Council (CCQC). The index uses a combination of tests to rate compost as very mature, mature, or immature. It requires measuring the carbon to nitrogen ratio and at least one test from list A (measuring biological activity) and one from list B (measuring phytotoxins). The document describes the various test methods that can be used and provides guidelines for interpreting the results.
GEOTECHNICAL INTERPRETATION OF SOIL FOR PROPOSED UTILITY TUNNEL FROM KURIL TO...Johana Sharmin
This presentation was prepared for our published paper in IASTEM publications. And this paper was based on research in geotechnical perspective for feasibility study in proposed utility tunnel from Kuril to Malibagh in Dhaka city.
IRJET- Review on Applications of Metal and Metal Oxide Nanoparticle in Heat a...IRJET Journal
This document reviews applications of metal and metal oxide nanoparticles in heat and mass transfer studies. It summarizes various literature that has investigated using nanoparticles suspended in base fluids. The literature shows that nanoparticles can improve the thermal conductivity and heat transfer rate of base fluids. Nanoparticles like Al2O3, CuO, ZnO, TiO2 suspended in fluids like water and ethylene glycol have demonstrated enhanced heat transfer in applications like heat exchangers and cooling systems. Some literature also found improved mass transfer and absorption rates for processes like CO2 absorption when using nanoparticle suspensions. In general, the reviewed works indicate nanoparticles have potential to improve heat and mass transfer properties and rates compared to conventional fluids without nanoparticles.
15a considerations for performing flowing fluid electrical conductivity (ffec...leann_mays
FFEC surveys provide a rapid method to characterize fluid-transmitting fractures in deep boreholes. The method involves circulating a baseline fluid and monitoring changes to electrical conductivity profiles over time as higher salinity fluid enters fractures. Multiple pumping rates can help determine properties of individual fractures like transmissivity. However, the method assumes ideal conditions like infinite-acting radial flow that may not apply in deep boreholes. Alternative methods involving tracer injection or circulation are also discussed.
The document describes an in situ study using UV-visible spectroscopy to measure the kinetics of propane oxidative dehydrogenation (ODH) on vanadium oxide catalysts. Transients in UV-visible intensity during ODH reactions were analyzed using a surface reaction mechanism. Rate constants for the kinetically relevant C-H bond activation step were determined and compared to values from steady-state ODH rates. The ratio of these values provides a measure of the fraction of active vanadium sites. Reoxidation rate constants, which cannot be obtained from steady-state analysis, were also determined and found to be orders of magnitude larger than C-H bond activation rates.
This document presents a comparative study of the performance of activated sludge processes in a bubble column reactor and compact jet loop reactor. Experiments were conducted using synthetic wastewater in laboratory scale models of each reactor type. The chemical oxygen demand (COD) removal efficiency was measured at different mixed liquor volatile suspended solids (MLVSS) concentrations and hydraulic retention times. The results showed that a COD removal efficiency of over 85% could be achieved in the bubble column reactor, and over 95% in the compact jet loop reactor, when operated at an MLVSS of 3000 mg/L and aeration time of 1 hour. The compact jet loop reactor demonstrated better COD reduction performance than the bubble column reactor under the conditions tested.
On Similarity of Differential Capacity and Capillary Pressure FractalKhalid Al-Khidir
On Similarity of Differential Capacity and Capillary Pressure Fractal Dimensions for Characterizing Shajara Reservoirs of the Permo-Carboniferous Shajara Formation, Saudi Arabia
Internal Coatings on the Rise - World Pipelines September 2016Craig Thomas
1) Internally coating gas transmission pipelines with epoxy provides enhanced gas flow and reduced operational costs. Over 60% of major oil and gas companies now specify these internal coatings.
2) Usage of internal coatings for gas pipelines has increased rapidly in the last decade and is expected to continue rising. Internal coatings allow for 14-21% increased pipeline capacity and provide benefits like reduced corrosion, optimized precommissioning, and lower energy costs.
3) In addition to flow enhancement, internal coatings provide protection from corrosion during storage and precommissioning, allowing for easier cleaning of pipelines and more rapid commissioning. Significant amounts of corrosion can form in uncoated pipes exposed to seawater during construction.
1) Internally coating gas pipelines with epoxy coatings was developed in the 1950s to reduce corrosion and increase pipeline efficiency.
2) Epoxy coatings create a smooth inner surface that allows gas to flow more easily, reducing pressure drops and increasing flow rates. This can allow pipelines to transport more gas without increasing size.
3) Studies have found that epoxy coatings can increase a pipeline's gas transport capacity by 5-20%, reducing operating costs through lower compression needs over the lifetime of the pipeline.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Type 1 diabetes is an autoimmune condition where the body destroys the insulin-producing cells in the pancreas. This prevents the body from properly absorbing and using blood glucose for energy. People with type 1 diabetes must take insulin, usually through injections or a pump, to survive. Carbohydrates raise blood glucose levels the most, so counting and matching carbohydrate intake to insulin dosage is important for blood sugar management. Exercise also helps the body use insulin more effectively.
This document summarizes a study on using a triphasic segmented flow millireactor for rapid nanoparticle-catalyzed gas-liquid reactions with facile catalyst recovery. Key points:
- The millireactor creates a pseudo-biphasic gas-liquid segmented flow using an aqueous catalyst phase and an organic substrate/product phase, allowing order-of-magnitude faster reactions than a batch reactor.
- For the hydrogenation of 1-hexene catalyzed by Rh nanoparticles, the millireactor achieves 80% conversion in 1 minute versus 30 minutes for a batch reactor.
- Faster mass transfer in the millireactor is achieved by reducing the diffusion distance for reactants through thinner organic segments at
Electro kinetic fractal dimension for characterizing shajara reservoirsKhalid Al-Khidir
This document discusses using electro kinetic parameters to characterize reservoirs in the Shajara Formation in Saudi Arabia. The author calculates fractal dimensions from relationships between streaming potential, electro osmosis coupling coefficients, and water saturation. Samples were collected from three reservoir units in the formation. Fractal dimensions were determined from plots of streaming potential ratios vs. water saturation and capillary pressure vs. water saturation. Higher fractal dimensions correlated with increased permeability and were found in upper reservoir units compared to lower units. The fractal dimension analysis helps divide the reservoirs into three units and assess their heterogeneity and quality.
1) Groundwater at an industrial site in Portland, Oregon was impacted by TCE and other chlorinated solvents used from 1980-1989. Additional impacts were from historical disposal of manufactured gas plant waste containing naphthalene and other compounds.
2) In situ chemical reduction was used to treat the TCE source area, demonstrating success in removing TCE by 2013. Samples found additional contaminants of interest (COIs) like 1,1,2-trichloroethane in the gas plant waste.
3) The study analyzed data on the COIs to understand their environmental fate and the effectiveness of treatment. Models were used to predict contaminant movement between gas plant waste and groundwater. Degradation
The document presents a study on the hydrodynamic behavior of an external loop airlift reactor for two-phase systems. Experiments were conducted to determine the gas holdup and pressure drop characteristics of various electrolyte and solvent solutions at different concentrations and flow rates. The results show that gas holdup increases with superficial gas velocity and solvent concentration but decreases with electrolyte concentration, while pressure drop increases with gas velocity, liquid flow rate, and solution concentration.
The document outlines the design of a wetland methane flux chamber to measure methane emissions from forest soils and marshes. The objectives are to design a portable chamber compatible with a LiCor 7810 Trace Gas Analyzer that can cover 2m tall wetland vegetation. A literature review informed the design process. A prototype chamber was built out of PVC and tested in the laboratory by collecting soil samples and measuring methane levels over time. The results were analyzed to calculate methane flux and compare different soils and chamber setups.
The document summarizes the evolution of the thin film rotating disk electrode (TF-RDE) technique for characterizing oxygen reduction reaction (ORR) activity of platinum electrocatalysts. Early work developed ink formulations containing platinum catalysts and Nafion ionomer to create relatively thick catalyst layers. Subsequent studies examined how thin Nafion films or "caps" affected oxygen diffusion measurements. More recent improvements involved optimizing ink dispersion and fabrication methods to produce more uniform, thinner catalyst layers. However, the document notes that reported ORR activities still vary significantly depending on experimental conditions. Specifically, the presence of Nafion ionomer creates a complex interface that can affect measured kinetics in poorly defined ways.
The Comprehensive Computation Model of Gas Permeability Based on Fuzzy Comple...IJMERJOURNAL
ABSTRACT: In this paper, in order to reveal the gas migration law of loaded coal under multi-factor coupling, the researches on gas permeability were carried out under different influencing factors, namely effective stress, gas pressure, confining pressure and moisture content, with the self-developed experimental platform of gas permeability. Meanwhile, the function relationship of each influencing factor and permeability was established by use of the mathematical least squares principle. In this paper, the comprehensive expression of gas permeability was established, which is based on fuzzy complementary judgment matrix. And the comprehensive expression was drawn from the experimental conclusions of the loaded coal under multi-factor coupling.
Research Inventy : International Journal of Engineering and Science is publis...researchinventy
The document summarizes a study on the simultaneous extraction of copper and iron from chalcopyrite concentrates in hydrochloric acid media using chlorine gas. The study investigated the effect of various parameters including acid concentration, temperature, sodium chloride addition, and time on the dissolution of copper and iron. Key findings include that copper and iron dissolution increased with acid concentration and temperature but decreased with the addition of sodium chloride. Dissolution was also found to increase over time. The best conditions for copper extraction were determined to be 333K temperature, 10% concentrate, and 1 hour leaching time.
This document provides information about assessing the maturity and stability of compost. It introduces the Compost Maturity Index developed by the California Compost Quality Council (CCQC). The index uses a combination of tests to rate compost as very mature, mature, or immature. It requires measuring the carbon to nitrogen ratio and at least one test from list A (measuring biological activity) and one from list B (measuring phytotoxins). The document describes the various test methods that can be used and provides guidelines for interpreting the results.
GEOTECHNICAL INTERPRETATION OF SOIL FOR PROPOSED UTILITY TUNNEL FROM KURIL TO...Johana Sharmin
This presentation was prepared for our published paper in IASTEM publications. And this paper was based on research in geotechnical perspective for feasibility study in proposed utility tunnel from Kuril to Malibagh in Dhaka city.
IRJET- Review on Applications of Metal and Metal Oxide Nanoparticle in Heat a...IRJET Journal
This document reviews applications of metal and metal oxide nanoparticles in heat and mass transfer studies. It summarizes various literature that has investigated using nanoparticles suspended in base fluids. The literature shows that nanoparticles can improve the thermal conductivity and heat transfer rate of base fluids. Nanoparticles like Al2O3, CuO, ZnO, TiO2 suspended in fluids like water and ethylene glycol have demonstrated enhanced heat transfer in applications like heat exchangers and cooling systems. Some literature also found improved mass transfer and absorption rates for processes like CO2 absorption when using nanoparticle suspensions. In general, the reviewed works indicate nanoparticles have potential to improve heat and mass transfer properties and rates compared to conventional fluids without nanoparticles.
15a considerations for performing flowing fluid electrical conductivity (ffec...leann_mays
FFEC surveys provide a rapid method to characterize fluid-transmitting fractures in deep boreholes. The method involves circulating a baseline fluid and monitoring changes to electrical conductivity profiles over time as higher salinity fluid enters fractures. Multiple pumping rates can help determine properties of individual fractures like transmissivity. However, the method assumes ideal conditions like infinite-acting radial flow that may not apply in deep boreholes. Alternative methods involving tracer injection or circulation are also discussed.
The document describes an in situ study using UV-visible spectroscopy to measure the kinetics of propane oxidative dehydrogenation (ODH) on vanadium oxide catalysts. Transients in UV-visible intensity during ODH reactions were analyzed using a surface reaction mechanism. Rate constants for the kinetically relevant C-H bond activation step were determined and compared to values from steady-state ODH rates. The ratio of these values provides a measure of the fraction of active vanadium sites. Reoxidation rate constants, which cannot be obtained from steady-state analysis, were also determined and found to be orders of magnitude larger than C-H bond activation rates.
This document presents a comparative study of the performance of activated sludge processes in a bubble column reactor and compact jet loop reactor. Experiments were conducted using synthetic wastewater in laboratory scale models of each reactor type. The chemical oxygen demand (COD) removal efficiency was measured at different mixed liquor volatile suspended solids (MLVSS) concentrations and hydraulic retention times. The results showed that a COD removal efficiency of over 85% could be achieved in the bubble column reactor, and over 95% in the compact jet loop reactor, when operated at an MLVSS of 3000 mg/L and aeration time of 1 hour. The compact jet loop reactor demonstrated better COD reduction performance than the bubble column reactor under the conditions tested.
On Similarity of Differential Capacity and Capillary Pressure FractalKhalid Al-Khidir
On Similarity of Differential Capacity and Capillary Pressure Fractal Dimensions for Characterizing Shajara Reservoirs of the Permo-Carboniferous Shajara Formation, Saudi Arabia
Internal Coatings on the Rise - World Pipelines September 2016Craig Thomas
1) Internally coating gas transmission pipelines with epoxy provides enhanced gas flow and reduced operational costs. Over 60% of major oil and gas companies now specify these internal coatings.
2) Usage of internal coatings for gas pipelines has increased rapidly in the last decade and is expected to continue rising. Internal coatings allow for 14-21% increased pipeline capacity and provide benefits like reduced corrosion, optimized precommissioning, and lower energy costs.
3) In addition to flow enhancement, internal coatings provide protection from corrosion during storage and precommissioning, allowing for easier cleaning of pipelines and more rapid commissioning. Significant amounts of corrosion can form in uncoated pipes exposed to seawater during construction.
1) Internally coating gas pipelines with epoxy coatings was developed in the 1950s to reduce corrosion and increase pipeline efficiency.
2) Epoxy coatings create a smooth inner surface that allows gas to flow more easily, reducing pressure drops and increasing flow rates. This can allow pipelines to transport more gas without increasing size.
3) Studies have found that epoxy coatings can increase a pipeline's gas transport capacity by 5-20%, reducing operating costs through lower compression needs over the lifetime of the pipeline.
International Journal of Engineering Research and Applications (IJERA) is an open access online peer reviewed international journal that publishes research and review articles in the fields of Computer Science, Neural Networks, Electrical Engineering, Software Engineering, Information Technology, Mechanical Engineering, Chemical Engineering, Plastic Engineering, Food Technology, Textile Engineering, Nano Technology & science, Power Electronics, Electronics & Communication Engineering, Computational mathematics, Image processing, Civil Engineering, Structural Engineering, Environmental Engineering, VLSI Testing & Low Power VLSI Design etc.
Type 1 diabetes is an autoimmune condition where the body destroys the insulin-producing cells in the pancreas. This prevents the body from properly absorbing and using blood glucose for energy. People with type 1 diabetes must take insulin, usually through injections or a pump, to survive. Carbohydrates raise blood glucose levels the most, so counting and matching carbohydrate intake to insulin dosage is important for blood sugar management. Exercise also helps the body use insulin more effectively.
This document lists over 100 properties for sale by Barbara C. Wall & Nancy R. Taylor located in various cities in Brevard County, Florida. The properties range in price from $62,500 to $3,000,000 and include single-family homes, condominiums, and apartments in cities such as Palm Bay, Melbourne, Indian Harbour Beach, Satellite Beach, and Titusville. Contact information is provided for the owners/brokers.
Using Carbon Isotopes to Monitor CO2 at the CONSOL Energy Inc. Coal Sequestr...Stephen Henry
The use of carbon isotopes is one of the most effective ways of monitoring, verifying and accounting (MVA) for injected CO2 as carbon forms part of the CO2 molecule itself. This study focuses on using carbon isotopes to understand CO2 dissolution, monitor CO2 plume migration, and identify the presence/absence of CO2 leakage into overlying formations and shallow subsurface at the CONSOL Energy Inc. sequestration test site located in Marshall County, West Virginia along the Pennsylvania Fork of Fish Creek. The CO2 gas is being injected, for testing both coal bed methane recovery and carbon sequestration, into the Upper Freeport coal bed at ~1200 feet depth. Ongoing CO2 injection began in 2009, and continuous geochemical environmental monitoring of shallow ground water, Fish Creek, and vadose zone gas began in 2008. In summer 2012 water and gas sampling began for carbon isotopic analysis at or near the test site; water is being sampled and tested from three groundwater monitoring wells, a few domestic groundwater supplies, and Fish Creek. Gas is being sampled and tested from the CO2 injection source gas tank, two deep coal bed methane producing wells, one deep monitoring well, and eight shallow vadose zone monitoring wells. The preliminary data indicate that the CO2 gas used in this sequestration operation has a different isotopic value compared to naturally occurring CO2 in the geologic formations. Initial data indicate that carbon isotopes can be used as an effective “natural built-in tracer” for monitoring the CO2 plume and/or its leakage into overlying shallow aquifers and subsurface.
Presentation given by Professor Colin Snape from University of Nottingham on "Performance Enhanced Activated Spherical Carbon Adsorbents for CO2 Capture" in the Capture Technical Session on Solid Adsorption at the UKCCSRC Biannual Meeting - CCS in the Bigger Picture - held in Cambridge on 2-3 April 2014
Permeability Evaluation in Pilaspi (M. Eocene - U. Eocene) FormationIJERA Editor
Studying the permeability in a particular formation will be our address in this paper, through collection of a set of data in relates to the past real core analyses by the oil operators and correlating them to our lab works on the samples of the same formation from Pilaspi formation (M.EOCENE - U.EOCENE) outcrop on Haibat Sultan Mountain near Taq Taq oil Field. Lab works were done in Koya University using most of reservoir lab equipments for getting and determining the most important properties like porosity and permeability on plug samples of that formation. The key study in this paper is oil well TT-02 in Taq Taq oil field. In this paper we will try to nominate and recognize the more active porosity type through measuring air and liquid permeability in our reservoir lab and show the effects of increasing flowing pressure on the permeability using saturated and dry core plug. Water and air were used as flowing fluids and two methods were used to measure the permeability; steady-state method, measures the permeability of a saturated Core plug under constant flow rate conditions and air permeability with (N2) for dry core plug.
A Review On Development Of Flyash Based High Strength Geopolymer Concretecedmmantc5411
Geopolymer concrete is the latest development in the field of concrete technology and it is still
developing. Geopolymers are inorganic, stable, hard and non-inflammable binder. The application of
geopolymer binder are in fire resistance fiber composite, sealant industry, tooling aeronautics SPF aluminium,
foundry equipment’s, radioactive toxic waste, ceramic, bricks and other precast concrete. The current review is
aims to put forward the development in geopolymer concrete for the production high strength geopolymer
concrete having strength more than 90MPa. The development of high strength concrete is aimed to reduce
structural member sizes and for economical construction in case of long span bridges and tall buildings. Also
the use flyash in concrete to reduce green gas house emission into the atmosphere by reducing cement usage
Phase 1 Project: Methane Oxycombustion in a Pressurised Swirl Stabilised A Gas Turbine Burner - presentation by Richard Marsh in the Natural Gas CCS session at the UKCCSRC Cardiff Biannual Meeting, 10-11 September 2014
Carbon Sequestration Final Proposal (LINKEDIN)Alex Rojas
This report proposes a design to capture and store carbon dioxide emissions from Cornell University's power plant. The major components are a water spray cooler to lower the temperature of flue gas from the plant, a series of MEA columns to separate CO2 from the flue gas, and a pipeline to transport CO2 16.5 miles to a storage site near another power plant. The total estimated cost is $80 million to capture 65,000 lbs/hr of CO2, and the project would take 5.5 years to construct with storage lasting 125 years. Risks like pipeline failures and groundwater displacement are also analyzed.
A preliminary (small) study of samples at 11 producing Marcellus gas wells in Pennsylvania to determine the actual amount of radon present. The study shows that theoretical claims by anti-drillers that Marcellus Shale gas contains high, life-threatening levels of radon are simply not true.
Apec workshop 2 presentation 12 lh ci cinco presidentes-pemex-apec workshop 2Global CCS Institute
This document outlines a life cycle assessment of CO2 emissions from a CO2-EOR project in southern Mexico. It describes the goal of understanding environmental impacts from a life cycle perspective and estimating CO2 emissions associated with various steps of the project. The methodology estimates emissions using activity data and emission factors. Results found that CO2 emissions from the offshore platform to refinery via the EOR project were 5.41 tCO2eq per ton of CO2 injected, and the project reduced greenhouse gas emissions and environmental impacts compared to business as usual.
Drexel University Study on Air Quality Near Marcellus Shale Drilling SitesMarcellus Drilling News
A new study of the effects of Marcellus Shale extraction on air quality. The study was published in the peer reviewed journal Environmental Science & Technology and titled "Atmosphere Emission Characterization of Marcellus Shale Natural Gas Development Sites". It finds far less impact on air quality near drilling sites than previously thought, but also a measurable impact on air quality near compressor stations.
1. Gas hydrates are crystalline structures of water and natural gas like methane found in ocean sediments and arctic permafrost that could potentially be exploited as an energy source for India.
2. Technologies for exploration include using seismic reflections to detect the bottom of the gas hydrate stability zone, while exploitation methods include depressurization, thermal stimulation, and carbon dioxide substitution.
3. India has conducted research expeditions in the Eastern Coast and Andaman Sea that discovered significant gas hydrate deposits, but challenges remain around economic viability and understanding the environmental impacts of large-scale production.
This document summarizes a pilot plant study on capturing CO2 from power plant flue gas using a vacuum swing adsorption (VSA) process with zeolite 13X. Key findings include:
1) A basic 4-step VSA cycle was able to achieve 95.9% CO2 purity and 86.4% recovery from a 15% CO2 flue gas stream.
2) A modified 4-step cycle with light product pressurization and two beds achieved improved performance of 94.8% purity and 89.7% recovery.
3) Energy consumption in the pilot plant was 339-583 kWh/tonne of CO2 captured, higher than theoretical calculations due to non
Production of Renewable Fuels by the Photocatalytic Reduction of CO2 using Ma...Pawan Kumar
The photo-reductive performance of natural ilmenite was boosted and the production of renewable fuels from the reduction of CO2 was enhanced by doping the natural mineral with magnesium. The doping was achieved by high energy ball milling in the presence of MgO and Mg(NO3)2. The photo-reduction of CO2 in aqueous solution led to the evolution of H2, CH4, C2H4, and C2H6, and the insertion of Mg in the structure of ilmenite enabled increases of up to 1245% in the fuel production yield, reaching total production of 210.9 µmol h-1 gcat-1. Displacements of the conduction band to more negative potentials were evidenced for the samples doped with magnesium. Indirect effects such as increases in the valence band maximum, and the introduction of intermediate energy levels were also evidenced through the measurement of the crystallite size and the determination of the band structure of the materials. Mott-Schottky analyses of the samples showed the n-type nature of the semiconductor materials and enabled the estimation of the density of charge carriers, which strongly influenced the photocatalytic performance. The strong potential of the application of natural ilmenite in gas phase artificial photosynthesis was proved by the evaluation of CO2 reduction in gas conditions, which allowed the enhancement in the selectivity and significantly increased the production of CH4 as compared to aqueous solution, reaching an important yield of CH4 of 16.1 µmol h-1 gcat-1.
Thermal regeneration of activated carbon saturated with nitrate ions from an ...IJAEMSJORNAL
The present study was initiated to help the simple and less expensive regeneration of activated carbons after saturation in rural area. In order to determine a regeneration time and the number of regeneration cycles, an adsorption test was necessary. Thus, 3h and 4 cycles of carbon regeneration are obtained after evaluation of the performance, percentage and adsorption capacity after each cycle. Regeneration percentages of 71.29, 54.05, 40.40, 28.06 % and 72.6, 69.84, 64.33, 34.98 %for respective concentrations of 30± 1.2 mg/L and 55 ± 1.6 mg/L are observed. Also, the performances of activated carbon 8.5, 10, 12, 20 g/L and capacities 24.04, 19.93, 14.9 and 10.35mg/g 35.7, 34.12, 31.43 and 17.09 mg/g respectively for dry season and rainy season were necessary to fix the number of cycles. The artisanal furnace with its ease of installation and its maximum temperature of 500±2°C is suitable for the regeneration of saturated activated carbon.
CO2-Driven Enhanced Gas Recovery and Storage in Depleted Shale Reservoir- A N...Steve Wittrig
1) The document discusses using numerical simulation to analyze CO2-enhanced gas recovery and storage in depleted shale gas reservoirs. It aims to maximize methane production while delaying CO2 breakthrough and maximizing CO2 storage.
2) Different injection scenarios are defined based on modifications to well patterns, reservoir characteristics, fracture properties, sorption parameters, and operational constraints. The scenarios vary the spacing between injection and production wells.
3) The best injection practice will be proposed based on analyzing different scenarios to enhance methane recovery and minimize CO2 production from the reservoir while storing more CO2.
This study evaluated the performance of porous adsorbents for CO2 capture under humid conditions through breakthrough
measurements over multiple cycles. Most adsorbents showed poor recyclability except for HKUST-1 and MCM-41, which were
able to capture CO2 under humid conditions over successive cycles. However, MCM-41's poor adsorption kinetics resulted in
lower CO2 capture under dynamic conditions compared to equilibrium. The study highlights the importance of evaluating
adsorbents' CO2 capture ability over multiple cycles under humid feed gas conditions and their kinetics for practical carbon
capture applications.
This document summarizes a study that investigated the effect of granulation on the activity and stability of a Co-Al2O3 aerogel catalyst for methane-carbon dioxide reforming in a fluidized-bed reactor. The aerogel catalyst was granulated using ethanol as a binding agent to improve its fluidization properties. Testing found that granulation significantly improved the catalytic performance of the aerogel catalyst, giving it better stability and higher methane conversion compared to the non-granulated catalyst. The improved performance was attributed to the better fluidization quality achieved through granulation.
Increasing interest by governments worldwide on reducing CO2 released into the atmosphere form a nexus of of opportunity with enhanced oil recovery which could benefit mature oil fields in nearly every country. Overall approximately two-thirds of original oil in place (OOIP) in mature conventional oil fields remains after primary or primary/secondary recovery efforts have taken place. CO2 enhanced oil recovery (CO2 EOR) has an excellent record of revitalizing these mature plays and can dramatically increase ultimate recovery. Since the first CO2 EOR project was initiated in 1972, more than 154 additional projects have been put into operation around the world and about two-thirds are located in the Permian basin and Gulf coast regions of the United States. While these regions have favorable geologic and reservoir conditions for CO2 EOR, they are also located near large natural sources of CO2.
In recent years an increasing number of projects have been developed in areas without natural supplies, and have instead utilized captured CO2 from a variety of anthropogenic sources including gas processing plants, ethanol plants, cement plants, and fertilizer plants. Today approximately 36% of active CO2 EOR projects utilize gas that would otherwise be vented to the atmosphere. Interest world-wide has increased, including projects in Canada, Brazil, Norway, Turkey, Trinidad, and more recently, and perhaps most significantly, in Saudi Arabia and Qatar. About 80% of all energy used in the world comes from fossil fuels, and many industrial and manufacturing processes generate CO2 that can be captured and used for EOR. In this 30 minute presentation a brief history of CO2 EOR is provided, implications for utilizing captured carbon are discussed, and a demonstration project is introduced with an overview of characterization, modeling, simulation, and monitoring actvities taking place during injection of more than a million metric tons (~19 Bcf) of anthropogenic CO2 into a mature waterflood.
Longer versions of the presentation can be requested and can cover details of geologic and seimic characterization, simulation studies, time-lapse monitoring, tracer studies, or other CO2 monitoring technologies.
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1. Copyright 2004, Society of Petroleum Engineers Inc.
This paper was prepared for presentation at the SPE Annual Technical Conference and Exhi-
bition held in Houston, Texas, U.S.A., 26–29 September 2004.
This paper was selected for presentation by an SPE Program Committee following review of
information contained in a proposal submitted by the author(s). Contents of the paper, as
presented, have not been reviewed by the Society of Petroleum Engineers and are subject to
correction by the author(s). The material, as presented, does not necessarily reflect any posi-
tion of the Society of Petroleum Engineers, its officers, or members. Papers presented at SPE
meetings are subject to publication review by Editorial Committees of the Society of Petroleum
Engineers. Electronic reproduction, distribution, or storage of any part of this paper for com-
mercial purposes without the written consent of the Society of Petroleum Engineers is prohib-
ited. Permission to reproduce in print is restricted to a proposal of not more than 300 words;
illustrations may not be copied. The proposal must contain conspicuous acknowledgment of
where and by whom the paper was presented. Write Librarian, SPE, P.O. Box 833836,
Richardson, TX 75083-3836, U.S.A., fax 01-972-952-9435.
Abstract
The Alberta Research Council (ARC) is performing a project
entitled “Sustainable Development of Coalbed Methane; A
Life-Cycle Approach to Production of Fossil Energy” that is
funded by an international consortium of companies. The main
objectives of the project are to reduce greenhouse gas emis-
sions by subsurface injection of CO2 into deep coalbeds and to
enhance coalbed methane recovery and production rates. We
have performed extensive field tests that includes efforts on
two wells located near the towns of Fenn and Big Valley in
Alberta that penetrated Medicine River (Mannville) coal
seams. This paper presents test procedures, quantitative data
measured during this effort, and the interpretation thereof. The
evaluation was completed over three years ago and was based
upon procedures described previously.1
These data have al-
lowed complete characterization of the coal seam properties
with new insights gained into the behavior of coal seams, the
volume of natural gas that can be produced, and the volumes
of CO2 that can be sequestered in this area.
The fieldwork began by reentering the Gulf Canada (now
ConocoPhillips) well FBV 4A-23-36-20 (FBV 4A) well. We
conducted a series of single well micro-pilot tests. We began
by production and shut-in testing to obtain estimates of the
reservoir pressure and permeability before CO2 injection. A
CO2 injection test was followed by a shut-in test to insure that
CO2 injection was possible. We then injected over 91,500 m3
of CO2 vapor in 12 separate injection cycles. Although CO2
reduced the absolute permeability, injectivity actually in-
creased. The CO2 was allowed to soak into the coal and we
returned the well to production. Post-injection testing allowed
us to determine the CO2 sweep efficiency as well as the
ECBM and CO2 storage potential. Fourteen months later, we
injected 83,500 m3
of flue gas using underbalanced drilling
equipment that was followed by a post injection-production
test.
A second well (FBV 5) was drilled 487 m north of the first
well. FBV 5 was cored and logged for reservoir property data.
The well was then cased and completed in one Medicine River
coal seam. A combination of production tests and water-
injection falloff tests were conducted to determine original
reservoir pressure, permeability, and gas composition. N2 in-
jectivity tests were performed before injecting 75,483 m3
of a
53%-47% mix of N2 and CO2. The gas mixture was allowed to
soak into the coal and the well was returned to production.
All of the post-injection production tests of both wells in-
cluded detailed measurement of pressure and temperature
conditions as well as gas composition variations vs. time.
These data allowed us to determine the changes in permeabil-
ity caused by the injected gas, to estimate possible hydrocar-
bon sweep efficiency, and possible CO2 storage volumes.
FBV 4A Micro-Pilot Testing
Gulf Canada donated the FBV 4A well to the project. After
review of available data, we concluded that the well pene-
trated Medicine River coal seams typical of those penetrated
by many wells in the Alberta Plains region. The absolute per-
meability also appeared to be typical.
FBV 4A History The FBV 4A well was originally an oil
production well but after the original completion was aban-
doned, the well was recompleted into two Medicine River
(Mannville) coal intervals. The upper coal interval was perfo-
rated from 1,259 to 1,263 m and the lower coal interval from
1,277 to 1,283 m. A bridge plug set above the lower coal in-
terval isolated the upper interval, which is the subject of this
paper.
The upper Mannville coal interval was hydraulically frac-
ture stimulated with a 10 metric ton liquid CO2 treatment in
August 1992. A 40-m3
liquid CO2 pre-pad was pumped to
initiate the fracture treatment. 160 m3
of liquid CO2 was mixed
with sand proppant in concentrations increasing from 50 to
200 kg/m3
and injected into the coal at a rate of 8 m3
/min at 20
MPa. The fracture gradient was 14.1 kPa/m. The well was
produced for 48 hours with a final recorded gas rate of 2,600
m3
/D. Gas samples taken just before production ceased still
contained significant CO2 concentrations indicating incom-
plete CO2 recovery.
A second stimulation treatment was performed in January
1993. 14 m3
of CO2 was injected followed by 1,600 m3
of N2.
Both fluids were pumped at 1 m3
/min at a surface pressure of
13 MPa(g).
SPE 90256
Alberta Multiwell Micro-Pilot Testing for CBM Properties, Enhanced Methane Recovery
and CO2 Storage Potential
Matthew J. Mavor, SPE, Tesseract Corp., William D. Gunter, SPE, John R. Robinson, SPE, Alberta Research Council
2. 2 SPE 90256
Initial Production Testing We did not have access to the
production history of the well until we returned it to produc-
tion for a short test in March 1998. The well was capable of
producing 2,800 m3
/D against a bottom-hole pressure of ap-
proximately 1,400 kPa(g). Water was not produced to surface
due to lack of artificial lift.
A static survey and a production / shut-in test with down-
hole gauges were conducted in June and July 1998. The gas
rate during 64 hours of production was constantly declining
from 15,900 to 2,970 m3
/D as artificial lift was not used for
the test. Water rates estimated from the rise in water level
were roughly constant at 0.92 m3
/D. Produced gas composi-
tion averaged 91.2% C1, 1.8% C2, 0.3% C3, 1.6% CO2, and
5.1% N2.
Table 1 summarizes the estimates of reservoir properties at
that time. Effective permeability to each phase and saturations
were estimated from the gas and water rates. San Juan Basin2
relative permeability data were used since measured data from
Mannville coal were unavailable. The data were evaluated
with a constant wellbore storage and skin, infinite acting, ho-
mogeneous reservoir model3
using the Kamal and Six coal gas
potential relationship.4
Initial CO2 Injection We had no previous experience with
CO2 injection into Medicine River coal seams and we planned
a single injection test to insure that injection was possible.
Bottom-hole transducers were installed and liquid CO2 was
injected at between 100 and 132 liters per min. 21 metric tons
(20 m3
) of liquid CO2 were displaced into the well. The CO2
vaporized in the well and an estimated 18 metric tons (17 m3
)
were injected into the coal. CO2 vapor volume is 542.8 m3
at
standard conditions per m3
of liquid, therefore 9,230 m3
of
CO2 vapor were injected into the coal. The final surface injec-
tion pressure was 1,500 kPa(g) with a bottom-hole pressure of
10,200 kPa(a). A four-day fall-off test followed injection. Be-
cause of the low injection rate, the minimum bottom-hole
temperature during injection was 42.8 o
C., not greatly reduced
from the static temperature of 47.1 o
C., and did not affect the
transducer.
As all of the injected fluid was in the vapor phase, the fal-
loff period analysis was based on the real gas potential5
ap-
proach. CO2 vapor properties were computed with equation of
state software. Although the data were erratic due to wellbore
effects, it was possible to evaluate the data. Injection of CO2
apparently created or opened existing fractures. The effective
permeability to gas estimate (0.632 md) was similar to but
slightly greater than the pre-CO2 estimate of 0.529 md. A skin
factor of -4 (equivalent to a fracture half length of 9 m)
matched the data.
Post-CO2 Production Testing After the falloff test, FBV
4A was returned to production to determine the effect of the
CO2 upon productivity and reservoir properties. The well sta-
bilized to a tubing head pressure of 160 kPa(g) and a gas rate
of 3,200 to 3,300 m3
/D. 14,635 m3
of gas were produced over
a four-day flow test. This volume was 1.58 times greater than
the injected volume of CO2. The cumulative CO2 produced
was 4,205 m3
, 46% of the injection volume.
The first produced gas composition was 100% CO2 as all
gas originated from the well. After 2.2 hours, the gas composi-
tion was 55.4% C1, 0.8% C2, 40.8 CO2, and 3.0% N2. At the
end of the production, the composition was 77.6% C1, 1.2%
C2, 16.6% CO2, and 4.7% N2.
Analysis of following shut-in period data resulted in essen-
tially the same estimate of absolute permeability (3.47 md) as
the estimate obtained from shut-in test data prior to CO2 injec-
tion (3.65 md). The skin factor estimate was 2 indicating that
the stimulation caused by CO2 injection was reversed to the
original pre-injection level.
Extended CO2 Injection Once CO2 injectivity was deter-
mined to be sufficient, larger scale CO2 injection commenced.
180 metric tons of liquid CO2 were injected during 12 separate
injection periods over 31 days. 15 metric tons were injected
during each of the 12 injection periods equivalent to 7,750 m3
of vapor. Injection time ranged from 4 to 7 hours at approxi-
mate injection rates of 30 l/min. After 12 injection periods, the
total vapor volume displaced into the wellbore was 93,050 m3
of which 91,500 m3
were injected into the coal seam. Bottom-
hole injection pressures declined from 14,000 to 10,600
kPa(a).
The falloff periods were not designed to obtain reservoir
property estimates as no attempt was made to minimize well-
bore effects. However, we evaluated each of the falloff periods
by history matching the observed pressure changes and deriva-
tive behavior with a wellbore storage and skin model.3
Table 2 summarizes the analysis results from each of the
falloff periods. In general, with some exceptions probably due
to analysis problems caused by wellbore effects, the effective
permeability to gas decreased with continued injection while
the skin factor became progressively more negative. The ef-
fective permeability to gas decreased from the pre-injection
estimates of 0.53 md to 0.24 after injection of 91,500 m3
of
CO2: a decrease by a factor of 2.2. The skin factor decreased
from -3.6 after the first injection period to -5.3 after the 12th
injection period. These skin factors corresponded to an in-
crease in the apparent fracture half-length from 6 to 31 m.
As will be discussed later, we believe that the permeability
reduction during the falloff periods was due to swelling of the
coal caused by sorption of CO2. However, the permeability
probably increased during injection. The increase in the effec-
tive induced fracture length may have been due to creation of
new fractures or due to opening pre-existing fractures induced
by the original stimulation as reported previously.6
Following the final injection, we allowed the CO2 to soak
in the coal for 39 days. The long soak time reduced transient
effects caused by CO2 sorption and methane expulsion.
Post-CO2 Production Testing Near the end of the soak
period, the well was killed with water while circulating CO2
from the well. We wished to eliminate the volume of CO2 in
the wellbore so that the gas composition data measured after
the well was returned to production were representative of the
gas contained in the coal natural fracture system. The well was
then equipped with a rod pump for artificial lift.
Production rates were dramatically reduced by injection of
CO2. The gas production rate before CO2 injection was
roughly 3,100 m3
/D. Gas production rates after CO2 injection
were in the range of 680 to 975 m3
/D, a decrease of 69 to
78%. Water rates dropped from roughly 0.9 to 0.3 m3
/D, a
reduction of 67%. The similar decrease in gas and water pro-
duction rates indicated that the CO2 affected both phases
equally due to a decrease in absolute permeability. Had the
decrease been due to changes in relative permeability caused
3. SPE 90256 3
by near-well saturation changes, the gas-water rate ratio would
have differed.
At the end of the production period, cumulative CO2 pro-
duction was 19,564 m3
or 21% of the 91,500 m3
injected into
the coal seam. The initial produced gas composition at the
start of production was 30.5% C1, 0.3% C2, 68.2% CO2, and
0.9% N2. As will be discussed later, this composition was used
to determine the volume of methane displaced by CO2 and the
potential CO2 storage volumes. The fraction of CO2 in the
produced stream decreased steadily during production. At the
conclusion of production, the produced gas composition was
62.3% C1, 1.3% C2, 34.0% CO2, and 2.5% N2.
A final shut-in test was performed and evaluated. The ef-
fective permeability to gas was reduced from the value of 0.53
md obtained from pre-CO2 injection tests to 0.17 md. The ra-
tio of the post- to pre-stimulation effective permeability to gas
was 0.32. The ratio between the gas rate after CO2 injection to
the rate before CO2 injection was identical, 0.32. The corre-
sponding water rate ratio was 0.34. The ratio between the pre-
and post-CO2 absolute permeability was 0.27. The final abso-
lute permeability estimate was 0.985 md. The consistency of
the ratios supports that the production decrease was due to
absolute permeability reduction.
The reduction in the effective permeability to gas appeared
to be uniform. The post-CO2 skin factor 1.78 was the same as
the value of 1.8 obtained from the pre-CO2 test. This indicates
that the near-well absolute permeability reduction was similar
to the reduction away from the well.
The estimates of the near-well gas and water saturations
after CO2 injection were very similar to those obtained before
injection. This agreement indicated that injection of CO2 did
not displace water away from the wellbore.
Flue Gas Injection Fourteen months after the final pro-
duction period, we injected flue gas into the FBV 4A well.
The purposes of the test were to determine injectivity and to
conduct a single well micro-pilot test using both CO2 and N2.
The well was returned to production before flue gas injec-
tion to obtain gas composition data after the extended soak.
The gas rate stabilized at approximately 2,400 m3
/day at a
casing pressure of 400 kPa(g). Approximately 3,400 m3
of gas
were produced during the test. The gas rate was substantially
greater than the final gas rate of 975 m3
/D at a surface pres-
sure of roughly 400 kPa(g) recorded after CO2 injection due to
the near-well pressure increase during the extended shut-in.
The produced gas composition at the start of production was
65.1% C1, 1.4% C2, 29.8% CO2, and 23.2% N2, similar to that
at the end of the preceding production period.
We used Northland Energy Corporation’s flue gas under-
balanced drilling system for flue gas injection. The system
used propane-fired compressors to generate flue gas. The flue
gas was captured, passed through a catalytic converter to re-
move oxygen, and compressed in four stages with inter-
cooling and scrubbing between each stage. A final trap recov-
ered oil from the compressed gas. The flue gas was then in-
jected downhole.
After initial start up problems, flue gas injection continued
for six days at a injection rates between 11 and 24 m3
/min. at a
pressure of 12,400 kPa(g). The total amount of flue gas in-
jected was 85,000 m3
. The volume injected into the reservoir
was 83,450 m3
. Argon was injected as a tracer every 12 hours.
248 m3
of argon was injected over the six-day injection period.
Eight flue gas samples were taken throughout the injection.
Injected composition averaged 84.2% N2, 12.4% CO2, 2.1%
Ar, and 1.2% CO.
Following flue gas injection, the 4A well was shut-in to
reduce the transient effects of injection. Bottom-hole pressure
gauges were left in the well to measure falloff data. The data
were analyzed to obtain estimates reservoir properties after
flue gas injection. The pressure data indicated composite res-
ervoir model7
behavior with a near-well region of greater per-
meability to gas (3.43 md) with a far well region of lesser
permeability to gas (1.2 md). Assuming that gas injection did
not displace water, the near and far region absolute permeabil-
ity values were 23.7 and 8.3 md, respectively. The near-well
region skin factor was 0.7. Flue gas injection substantially
increased the absolute permeability from the 1 md post-CO2
injection. We believe that this increase was due to stripping
CO2 and methane from the coal matrix causing matrix shrink-
age.
Natural fracture permeability varied dramatically through-
out the various tests. Figure 1 illustrates the estimated values.
FBV 5 Evaluation and Micro-Pilot Testing
Gulf Canada at the consortium’s recommendation and expense
drilled a second well, the Fenn Big Valley 5-23-36-20 (FBV
5) into the Medicine River (Manville) coal seams. This well
was located 493 m north of the FBV 4A well. Both wells were
completed in the same upper coal interval.
After spudding, a 200-mm hole was drilled to 1,257 m. A
9.1-m core barrel was used to core shale and coal between
depths of 1,257 and 1,264.5 m with near 100% recovery. The
well was deepened to TD at 1,303 m and logged. Following
logging, 139.7-mm casing was run and cemented in place. A
casing conveyed pressure / temperature transducer connected
to surface with wireline was cemented in the casing-open hole
annulus to monitor pressure and temperature inside the casing
at 1,240 m.
A core analysis and log interpretation effort fully described
the Upper Medicine River coal gas reservoir properties with
well documented analysis methods.8,9
The properties are
summarized in Table 3. Table 4 summarizes the dry, ash-free
Langmuir isotherm parameters. Figure 2 compares the Lang-
muir curves and the measured data points. The dry, ash-free
values must be converted to in-situ moisture and ash-content
before they can be used. Note that it can be very inaccurate to
extrapolate isotherm relationships beyond the measurement
range.
The untested lower Medicine River coal seam had a thick-
ness of 6.28 m and an average density of 1.350 g/cm3
. Total
Medicine River coal thickness at this location was 10.40 m
with an average density of 1.358 g/cm3
. Total original gas-in-
place volume for both seams was 106.3(106
) m3
/km2
assuming
that the gas content vs. inorganic content relationship was the
same for both coal seams.
The upper coal seam was completed by perforating fol-
lowed by hydraulic fracture stimulation. The water-based
stimulation consisted of a 65 m3
pad and 66 m3
of water con-
taining 20/40 mesh sand at concentrations ramped from 60 to
240 kg/m3
. The average pump rate was 8.4 m3
/min. The frac-
ture gradient was 14.36 kg/m. Proppant was tagged with irid-
4. 4 SPE 90256
ium while water was tagged with scandium. Post-stimulation
gamma ray logs indicated that the stimulation was contained
within the perforated coal seam with some upward growth into
the overlying shale.
The well was cleaned out and tubing, wellhead, rod pump,
and rods were installed. Production began by pumping. Gas
was produced almost immediately indicating that the coal was
gas saturated (gas content equal to storage capacity). Gas and
water productivity stabilized at 117 and 1.3 m3
/D, respectively
at a bottom-hole pressure of 251 kPa(a). A shut-in test was
dominated by storage and two water injection falloff tests
were run to determine reservoir pressure and permeability
estimates summarized in Table 3. The low productivity was
due to the low absolute permeability of 1.2 md, not due to
ineffective stimulation, as the skin factor estimate was -3.5 as
expected for this type of stimulation.
N2 Injection Testing After water injection-falloff testing,
a N2 injection-falloff test was conducted. An O2 tracer con-
firmed that the injected gases entered the coal seam. O2
chemically reacts with coal and cannot be produced during
subsequent production testing if the O2 entered the coal.10
N2 stimulation equipment was rigged up on the wellhead.
A total of 8,300 m3
of N2 vapor was pumped down the well-
bore at an injection rate of 23 m3
/min. 6,931 m3
entered the
coal seam. Injection was stopped periodically to inject eight
O2 slugs into the surface lines. Bottom-hole injection pressure
at the end of injection was 15,600 kPa(a). The well was shut-
in on surface for nine days to perform a falloff test.
Analysis of the injection data indicated that during injec-
tion, the absolute permeability reached 13.8 md. The injection
ballooned the natural fracture system and substantially in-
creased the permeability. Analysis of the subsequent falloff
test was complicated by pressure dependent permeability be-
havior. A composite model with a greater near-well perme-
ability than the far region was used to match the data. The near
and far region effective permeability estimates were 3.9 and
0.14 md, respectively with a near-region skin factor of -0.15.
The far region absolute permeability estimate was 8.7 md,
which was believed to be influenced by the injection period.
Post N2 Injection Production After the falloff test, FBV 5
was returned to production by pumping the well for 9 days.
Gas and water rates after the first day were 562 and 9.3 m3
/D,
respectively, that declined to 116 and 1.6 m3
/D, respectively.
N2 injection had little but a positive effect upon productivity.
The produced gas composition after 1 day was 30% C1 and
70% N2. After nine days, C1 concentration climbed to 75.2%
while N2 concentration declined to 24.9%. Bottom-hole pres-
sures were in the range of 1,373 to 1,450 kPa(a).
Simulated Flue Gas Injection We conducted a simulated
flue gas injection micro-pilot test to obtain data to understand
reservoir behavior during processed flue gas injection. The test
was designed for a mixture consisting of 50% N2 and 50%
CO2 40,911 m3
of N2 and 35,938 m3
of CO2 vapor were in-
jected during the 67-hour injection period. Of the total gas
volume of 76,849 m3
, 1,369 m3
remained in the wellbore at the
end of injection. The average injection rate was 10.18 m3
/min
for the N2 and 8.94 m3
/min for the CO2. After injection of ap-
proximately 59,000 m3
, the CO2 injection rate decreased due
to suction pump problems. 170 m3
of argon was also injected
in slugs at 30-minute intervals. The bottom-hole injection
pressure increased gradually to 15,660 kPa(a) at a temperature
of 43 o
C. The injectivity of this test will be discussed later.
A falloff test was conduced when injection ceased. Analy-
sis of these data was complicated by pressure dependent per-
meability behavior and was performed with a composite res-
ervoir model. The near and far region effective permeability to
gas estimates were 5.9 and 0.14 md, respectively. The far re-
gion effective gas permeability estimate was a maximum
value due to lack of far region derivative stabilization but in
line with that estimated after N2 injection.
Final Production Testing A final 26-day production test
was conducted to obtain produced gas composition and gas
and water production rate data after the simulated flue gas
injection. Gas and water rates were stable at the end of pro-
duction at 173 and 0.74 m3
/D, respectively at a bottom-hole
pressure of 405 kPa(a). Gas productivity was greater than be-
fore the micro-pilot tests while the water productivity was
less. The initial produced gas composition included 10.8% C1,
0.3% C2, 557 ppm C3, 499 ppm Ar, 33.0% N2, and 57.8%
CO2. At the end of production, the composition was 53.8% C1,
1.1% C2, 1,774 ppm C3, 564 ppm Ar, 25.0% N2, and 19.9%
CO2. Because of the low productivity, only 2.4% of the in-
jected N2 and 2.6% of the injected CO2 was produced during
this period.
A shut-in test followed the production period. Unfortu-
nately, wellbore storage effects precluded permeability esti-
mates.
Gas Injectivity
Although the upper Medicine River coal seam produced gas
and water at rates commensurate with a 1.2 to 3.6 md natural
fracture system, we had few problems injecting water or gases.
We obtained substantial data concerning gas injectivity during
this project. Gas injectivity is simply defined as the gas injec-
tion rate divided by the down-hole pressure differential re-
quired to inject the gas
When injecting gas, two competing processes affect both
the absolute permeability and the relative permeability to gas
as discussed in detail elsewhere.11
Concisely, pressure strain
(strain=change in volume divided by the original volume) bal-
loons natural fractures and increases porosity and absolute
permeability during injection while sorption strain tends to
swell the coal matrix which reduces natural fracture porosity
and absolute permeability. Injection of gas increases fracture
porosity, which in turn, reduces water saturation, increasing
relative permeability to gas. Sorption strain, caused by adsorp-
tion of stronger adsorbing gases than methane, offsets the gain
in permeability during injection to a degree dependent upon
the relative magnitude of pressure and sorption strain effects.
In some cases, injection increases the aperture of natural frac-
tures or reopens induced fractures to such a degree that the
near-well region appears stimulated and skin factors become
negative.
The ability to inject strongly adsorbing gases while matrix
swelling is significant is due to ballooning existing or extend-
ing pre-existing fractures away from the wellbore during in-
jection. The increase in injectivity due to ballooning and water
saturation reduction overcomes any reduction in injectivity
caused by swelling.
5. SPE 90256 5
CO2 Injectivity Figure 3 illustrates the pressure differen-
tial and the injectivity during each of the 12 CO2 injection
periods vs. the cumulative CO2 injection volume for the FBV
4A well. The pressure differential required for each injection
period decreased by roughly 55% over the twelve injection
periods from 6,100 kPa to 2,700 kPa. Injectivity increased
from 5.5 m3
/D-kPa for the first injection period to 13.6 m3
/D-
kPa for the final injection period, an increase of 147%. The
injectivity for the 11th
injection period was the greatest as was
the injection rate. Injectivity may be sensitive to injection rate.
Injectivity Comparison Even more surprising than the in-
creased injectivity in the presence of sorption strain was the
greater injectivity of CO2 than other gases in both wells. Fig-
ure 4 illustrates a comparison of injectivity vs. total injected
fluid volume for each of the tests. In general, N2 and flue gas
injectivity was similar regardless of the injection well. While
the FBV 4A flue gas injectivity began at lower levels due to
swelling caused by CO2 sorption, it eventually was greater
than the FBV 5 N2 - CO2 flue gas injectivity, partially due to
the greater absolute permeability at the FBV 4A location. The
FBV 5 N2 injectivity was similar to the N2 - CO2 injectivity.
The greater CO2 injectivity was likely caused by a combi-
nation of greater permeability and/or effective fracture length
during injection due to ballooning. While a decrease in perme-
ability was observed for the falloff periods after injection
ceased, permeability while injecting was greater than during
the falloff periods. Unfortunately, we were unable to obtain
accurate permeability estimates during injection. Weakening
of the coal matrix by CO2 may have caused greater ballooning
of the natural fracture system (resulting in greater permeability
during injection) than possible with the other gases.
When comparing two different gases, the injectivity ratio
is dependent on the fluid properties if all other factors are
equal including the injection time, effective permeability to
gas, and skin factor. Eq. 1 defines the injectivity ratio.
21 2 2 2
2 1 1 1 1
g
g
Bi z
i B z
µ µ
µ µ
= = (1)
Table 5 compares the fluid properties at downhole injection
conditions of 14,500 kPa(a) and 47 o
C. 12
Based upon this
comparison, one would expect CO2 to have the greatest injec-
tivity and N2 the least. While the observed trends were in
agreement with Table 5, the magnitude of the injectivity ratio
was not.
One possible explanation for the injectivity differences
was the injection rates at bottom-hole conditions. In the FBV
4A well, flue gas bottom-hole injection rates (at bottom-hole
temperature and pressure) increased from roughly 20 to 60
m3
/D. Bottom-hole CO2 injection rates were substantially
greater and ranged from 95 to 217 m3
/D. At early times, CO2
injection rates were over three times the flue gas injection rate.
The ratio later was less, roughly a factor of 2.4 for the last CO2
injection rate period. Since the CO2 rate was greater, a greater
portion of the natural fracture system was filled in a given
time by CO2 than by other gases causing the area of the bal-
looned, higher permeability, region to be larger, increasing
injectivity. In addition, the greater viscosity of CO2 along with
swelling may have reduced the leak off volume from bal-
looned fractures allowing retention of greater energy for ex-
tending the ballooned region. The combination of higher rate
and viscosity may increase the frictional drag along fracture
surfaces causing more fracture surface movement and greater
permeability retention due to asperity creation.
One other major difference was that CO2 was injected in
alternating injection-falloff periods. We believe that the alter-
nating sequence improved injectivity and we received a patent
for this process.13
The improved injectivity may have been the
result of coal failure resulting from weakening by CO2. The
shut-in periods resulted in more weakening that may have
been possible without shut-in periods.
Gas Composition Data Analysis
An important part of this project was to use the gas composi-
tion data to assist in understanding the enhanced recovery and
storage mechanisms. The analysis discussed in this section
was based upon material balance of the injection and produc-
tion volumes and application of extended Langmuir isotherm
theory14
to determine gas storage capacity vs. composition.
Gas Composition & Storage Capacity Variations Gas
composition in the near-well region of both wells differed
substantially at various times due to injection of CO2, N2, Ar,
and flue gas. Figure 5 illustrates the near well gas composition
for FBV 5 at various times for three of the principal gas com-
ponents. Before the first injection, the gas was 94% C1, 3%
N2, and minor components. Injection of N2 increased the near-
well N2 conc. to 70% and reduced the C1 conc. to 30%. Pro-
duction of the well increased the near-well C1 conc. to 75%
while the N2 conc. was reduced to 25%. Injection of a 53% N2
- 47% CO2 mixture increased the near-well CO2 conc. to 59%,
increased the N2 conc. slightly to 33%, and reduced the C1
conc. to 8%. After the final production period, the C1 conc.
increased to 53% while the CO2 conc. dropped to 20%, and
the N2 conc. dropped to the pre-flue gas injection level. Figure
6 illustrates similar data for FBV 4A.
Extended Langmuir isotherm theory and the isotherm data
included in Table 4 allowed computation of the storage capac-
ity of each component and the total storage capacity. Figures 7
and 8 illustrate the estimated storage capacity for each compo-
nent and the total storage capacity for both wells. The storage
capacity values of the individual components do not always
sum to the total storativity in Figures 7 and 8 due to the pres-
ence of small amounts of ethane and propane included in the
calculations.
At the FBV 5 location, injection of N2 decreased the total
storage capacity from 7.6 to 4.9 scc/g due to the lower sorptive
capability of N2. Production of some of the N2 increased the
near-well storage capacity to 6.7 scc/g. Injection of simulated
flue gas increased the total storage capacity to 16.8 scc/g due
to the greater affinity for CO2. The final production period did
not remove all of the CO2 and as a result, the total storage ca-
pacity remained greater than the initial storage capacity.
At the FBV 4A location, injection of CO2 increased the to-
tal storage capacity from 7.57 to 17.06 scc/g due to greater
CO2 sorption. Production of 21% of the CO2 injection volume
reduced the storage capacity to 13.70 scc/g. During the four-
teen-month shut-in period, migration of CO2 away from the
near-well region reduced the storage capacity to 12.92 scc/g.
Injection of flue gas and the final production period reduced
6. 6 SPE 90256
the total storage capacity to 11.02 and 10.50 scc/g,
respectively.
Hydrocarbon Sweep Efficiency & Displacement We
used two primary terms to evaluate hydrocarbon displacement
by injected gas. The first term, hydrocarbon displacement effi-
ciency, was the fraction of hydrocarbons removed from an
area contacted by an injected fluid. The second term, hydro-
carbon displacement ratio was the ratio of the displaced hy-
drocarbon volume to the injected fluid volume.
The hydrocarbon displacement efficiency, Edh, was com-
puted from the ratio of the end to the beginning hydrocarbon
storage capacity with Eq. 2. The area containing the injected
fluid volume, Ad, was computed with Eq. 3 based upon the
storage capacity of the injected fluid. The volume of hydro-
carbons displaced from the displacement area, Dh, was com-
puted with Eq. 4 based upon the change in the hydrocarbon
storage capacity. Finally, the hydrocarbon displacement ratio,
Rd, was computed with Eq. 5.
2
1
1 sh
dh
sh
G
E
G
= − (2)
i
d
c si
V
A
h Gρ
= (3)
( )1 2h d c sh shD A h G Gρ= − (4)
h
d
i
D
R
V
= (5)
Estimates of hydrocarbon displacement efficiency were
computed from the storage capacity information illustrated in
Figures 7 and 8. As an example, at the FBV 5 location, before
injection of N2, the hydrocarbon storage capacity was 7.43
scc/g. After injection of a relatively small volume of N2, the
hydrocarbon storage capacity was reduced to 3.48 scc/g.
Therefore, the hydrocarbon displacement efficiency was 53%
in the region contacted by N2. The N2 storage capacity after
injection was 1.386 scc/g. Since the injected volume was
6,931 m3
, the displacement area was 878.5 m2
for a thickness
of 3.97 m and an average density of 1.434 g/cm3
. The hydro-
carbon displacement volume in this area was 19,763 m3
. The
ratio of the hydrocarbon displacement volume to the injected
fluid volume was 2.85. All gas volumes are at standard condi-
tions since gas storage capacity is at standard conditions.
Computations such as these were performed after injection
periods and after the production periods that followed injec-
tion. Material balance was required to account for all injected
and produced volumes.
Injected Gas Distributions To evaluate the fluid distribu-
tions, we considered the near-well free gas concentration to be
uniform within the region contacted by the injected gas. We
will discuss the consequences of this simple assumption later.
We assumed that the entire thickness adsorbed the gas to con-
vert volume to area estimates. For illustration, we assumed
that the gases were distributed elliptically around the wellbore
however; the area is the same regardless of the assumed shape.
Figure 9 illustrates the areas required to storage the in-
jected fluid volumes at four different times around the FBV 5
well. We discussed the computations above after N2 was first
injected. The second time was after production of 13.9% of
the injected N2 volume. N2 concentration in the produced gas
dropped from 70 to 25%. The produced N2 volume alone
could not explain this reduction. The area required to store the
remaining N2 volume (5,966 m3
) was 2,909 m2
. N2 appeared
to move farther away from the well during production al-
though the pressure gradient was toward the well. Physically,
sorbed gas could have been moving away from the well via
diffusion through the coal matrix while vapor phase produc-
tion was toward the well in the coal natural fracture system.
Mixed gas injection ended up with three concentric regions
around FBV 5. The near-well region contained all of the CO2,
some N2, Ar, and remaining hydrocarbons. Beyond the near-
well region, there was a ring of gases that contained the in-
jected gases not sorbed in the near-well region and the hydro-
carbons displaced from the near-well well region. Finally,
there was an outer region that contained the displaced hydro-
carbons that originated from both the near-well and outer-ring
regions and the original hydrocarbon gases.
Mixed gas injection of 75,480 m3
of 53% N2 (40,184 m3
)
and 47% CO2 (35,299 m3
) displaced 93% of the hydrocarbons
from the region contacted by CO2. The area required to store
the CO2 volume was 387 m2
. The hydrocarbon volume dis-
placed from this region by the CO2 was 12,924 m3
. The hy-
drocarbon displacement ratio for the near-well region was
0.366. This value was substantially lower than for N2 since
CO2, being more strongly sorbed, contacts much less of the
reservoir although the displacement efficiency was substan-
tially greater than for N2.
The outer ring region contained 75.6% N2, 24.3% hydro-
carbons, and Ar in the free-gas phase. The area of this ring
was 4,510 m2
excluding the near-well region. The volume of
hydrocarbons displaced from the outer-ring was 124,900 m3
.
This corresponded to a hydrocarbon displacement ratio of 3.1,
similar to that for pure N2 injection. Hydrocarbon displace-
ment by the simulated flue gas injection was 140,200 m3
. The
hydrocarbon displacement ratio was 1.86, intermediate to the
results for pure CO2 and N2.
The final computation was for the gas composition after
production of the injected N2-CO2 mixture. As for production
after pure N2 injection, the area of the reservoir appeared to
increase. The calculated area required to store the remaining
CO2 volume increased by 124% to 866 m2
. The area required
to store the remaining N2 volume increased by 436% to 26,229
m2
. This difference will be discussed later.
The same analysis was performed for the FBV 4A well.
The upper ellipse in Figure 10 illustrates the area that could
contain the CO2 volumes at three different times, after CO2
injection, after the subsequent production test, and after the
fourteen-month shut-in period. The lower two ellipses illus-
trate the distribution after the flue gas injection test and after
the final production period.
After the first CO2 injection, the hydrocarbon displacement
efficiency was 80.6% within the region contacted by CO2,
which was less than after N2 and CO2 injection in FBV 5. The
area containing CO2 was 1,029 m2
. The volume of hydrocar-
bons displaced was 35,119 m3
corresponding to a hydrocarbon
displacement ratio of 0.384.
7. SPE 90256 7
Following production, the area of containing CO2 appeared
to expand 19% to 1,226 m2
. After 14 months, the area ex-
panded another 14% to 1,402 m2
. The degree of expansion
was less than for the combination of CO2 and N2 due to the
stronger sorption properties of CO2.
During the flue gas test, the injected volume included
70,289 m3
of N2, 10,367 m3
of CO2 and 243 m3
of Ar. 79,475
m3
of CO2 remained in the reservoir after both tests. The CO2
volume was contained in an area of 1,968.1 m2
. The hydrocar-
bon displacement efficiency in this region was 0.552 as pro-
duction after the 1st
CO2 injection and N2 injection stripped
both hydrocarbons and CO2 from the near well region. The
displaced hydrocarbon volume from this region was 10,139
m3
. The hydrocarbon displacement injection volume ratio was
1.02.
The outer ring region contained 87.1% N2, 12.6% hydro-
carbons, and 0.4% Ar in the free gas phase resulting in a N2
storage capacity of 2.01 scc/g. The hydrocarbon displacement
efficiency was 0.772. The area of the outer ring region was
22,180 m2
. The hydrocarbon volume displaced from the outer
ring was 200,800 m3
corresponding to a hydrocarbon dis-
placement ratio of 2.86. The total hydrocarbon displacement
ratio to the total injected fluid volume was 2.61. This ratio was
higher than for the FBV 5 since the previous CO2 injection
and N2 forced the CO2 injected with the flue gas to contact a
greater area of the reservoir.
After the final post-flue gas production period, 71,294 m3
of CO2 remained in the reservoir within an area of 2,950 m2
.
The area of the outer ring appeared to expand to 30,130 m2
.
Distribution Errors We used the analysis of the gas com-
position data to assist with understanding the variation in pro-
duced gas composition data. There were two primary assump-
tions. These were that the gases in the vapor and sorbed
phases were in equilibrium and that the gas compositions were
constant within a displacement area. There are problems with
these assumptions that will cause errors in the estimates of the
extent of displacement areas.
After injection of various gases, we shut in the wells and
allowed the gases to “soak” in the reservoir. We used this pro-
cedure to allow the gas compositions to reach equilibrium.
The soak duration varied from 7 to 39 days. Sorption time
(which is related to the inverse of diffusivity) is the time re-
quired to release 63% of gas stored by sorption. The methane
sorption time of the Medicine River coal was 4.9 hours and we
believed that seven or more days were sufficient to reach equi-
librium. Application of extended Langmuir isotherm theory
requires equilibrium conditions and as a result, we believed
that our interpretations of the produced gas composition data
immediately after a soak period were reasonable. If there was
a sorbed gas composition gradient present, our assumption of
uniform concentration distribution underestimated the sorbed
region area after a soak period.
Interpretation of the gas composition data at the end of a
production period was much more subject to error as the res-
ervoir was not in an equilibrium state. Gas compositions
changed rapidly during production. The drop in pressure near
the well released methane and CO2 from the near well region.
Due to the low natural fracture porosity, production affected
the region beyond the displacement area bringing hydrocar-
bons back into the displacement region. There was a substan-
tial variation in the gas composition in the natural fracture
system through the reservoir. It was likely that diffusion of
different gas components in different directions (i.e., into and
out of) the coal matrix was occurring simultaneously. These
concentration variations may be the reason that the displace-
ment area appeared to be increasing after production. We were
less concerned about these errors as we were more interested
in using the equilibrium gas composition data to predict hy-
drocarbon sweep efficiency during a long-term displacement
processes.
Enhanced CH4 Production - CO2 Storage Potential
One of the primary goals of this project was to predict the
volumes of methane that may be produced and the volumes of
CO2 that may be stored under a full-scale ECBM-storage pro-
ject. We were able to make these computations based upon the
data reported in this paper.
Since CO2 is strongly sorbed, there is a relatively distinct
displacement front within the coal seams at the CO2 - original
gas boundary similar to that observed during water flooding
with favorable mobility ratios. Under favorable conditions,
i.e., uniform permeability, we expect to sweep 70% of a five-
spot pattern at breakthrough based upon water flooding stud-
ies.15
Within the CO2 swept zone, 80.6% of the hydrocarbon
gases were displaced by CO2. Therefore, we expect to recover
up to 56.4% of the hydrocarbons in place at CO2 breakthrough
if the reservoir pressure is maintained relatively constant.
Greater recovery would be achieved with a reduction in reser-
voir pressure.
We estimated maximum primary production potential us-
ing a coal gas reservoir simulator for a hypothetical well pene-
trating a reservoir with an absolute permeability of 4 md,
which was slightly greater than that estimated for the upper
Medicine River coal seam at the FBV 4A location. Under pri-
mary recovery at the FBV 4A site with a 0.32-km2
(80-acre)
development scenario, a properly stimulated well was capable
of recovering 43% of the gas-in-place volume over a 6.2 year
period if the bottom-hole pressure was maintained at 276
kPa(a) until gas production declined to 1,420 m3
/D.
Injection of CO2 at a rate twice the production rate raised
the recovery to 56.4% and reduced the recovery time to 3.6
years. Therefore, the incremental gain in recovery was 13.2%
of the gas-in-place volume with an economic assist due to the
faster recovery.
Total original gas-in-place volume for both seams was
106.3 (106
) m3
/km2
. Under primary recovery, 45.7 (106
)
m3
/km2
was recovered. The incremental gain in recovery dur-
ing CO2 injection was 14.0 (106
) m3
/km2
.
The gain in recovery due to enhanced recovery could be
much greater for a lower permeability reservoir since primary
recovery volumes would be low. Economic recovery of gas
under primary depletion is not possible for a one-md reservoir
such as penetrated by FBV 5. Without regard for cost, the
simulated gas recovery factor from a one-md reservoir was
21.7% in 6.4 years. If recovery can be improved to the same
level as primary depletion from a four-md reservoir by en-
hanced recovery, economic operation of production wells may
be possible.
The maximum CO2 storage possible at the time of CO2
breakthrough was 70% of the pattern area times the CO2 sorp-
8. 8 SPE 90256
tive capacity. In the swept zone, the CO2 sorptive capacity was
15.61 scc/g. Therefore, the maximum storage capacity was
10.93 scc/g. Including both Medicine River coal seams, the
maximum storage capacity was 154.3 (106
) m3
/km2
. This vol-
ume was equivalent to 286,600 kg tons/km2
. This estimate
assumed that reservoir pressure was maintained at 7,900
kPa(a). Greater CO2 storage would have resulted if production
ceased at breakthrough and CO2 injection continued, increas-
ing reservoir pressure above the initial level.
Summary
We conducted an extensive testing program on two wells
completed in Medicine River Coal seams in the Alberta Plains
Region. By sequential injection, soak, and production tests,
along with accurate bottom-hole pressure and produced gas
composition monitoring, we were able to increase our under-
standing of the enhanced coalbed methane - CO2 storage proc-
ess. The detailed data resulted in conclusions that were oppo-
site to general beliefs before the project started.
It was generally thought that CO2 injection would be hin-
dered by coal swelling caused by CO2 sorption. We found the
opposite to be the case as CO2 injectivity was greater than for
weakly adsorbing N2 through the use of alternating injection
shut-in sequences and perhaps as the result of coal weakening.
It was generally thought that any injection into a coal seam
with one md permeability would be difficult. We found that
injection increased the absolute permeability and effective
permeability to gas to a level easily allowing injection.
The combination of these two observations suggests that
low permeability coal seams that may not be commercial un-
der primary production could still be CO2 storage sites with
the added benefit of improving the possibility for commercial
gas productivity.
It was generally thought that CO2 would displace all of the
hydrocarbons away from injection wells. This was not the case
as 20% of the hydrocarbons remained in the CO2 contact area.
We have also found the data to be very useful to investiga-
tors that are developing reservoir simulation software to model
primary and enhanced recovery from coal seams. These data
can serve as history matching files to test the accuracy of the
modeling methods.
Acknowledgements
The data from Alberta Canada were collected as part of an
Alberta Research Council (ARC) project entitled Sustainable
Development of Coalbed Methane, A Life-Cycle Approach to
Production of Fossil Energy. A consortium of international
companies funded this project, which included development of
the field procedures and analyses presented in this paper. We
gratefully acknowledge the consortium’s support and permis-
sion to release this paper. Numerous other individuals were
involved in the drilling, coring, logging, core analysis, produc-
tion, and testing operations. We appreciate their contributions
to the acquisition of this high quality data set.
Nomenclature
Ad displacement (contacted) area, m2
Bg1, Bg2 formation volume factor of gas one or two at
downhole conditions, reservoir volume/surface
volume
Dh hydrocarbon displacement efficiency,
dimensionless
Edh hydrocarbon displacement efficiency,
dimensionless
Gsh2 final hydrocarbon storage capacity, scc/g
Gsh1 initial hydrocarbon storage capacity, scc/g
Gsi injected fluid storage capacity, scc/g
h reservoir thickness, m
i1, i2 injectivity of gas one or two, m3
/D-kPa
Rd hydrocarbon displacement ratio, dimensionless
Vi injection volume, m3
z1, z2 real gas deviation factor of gas one or two at
downhole conditions, dimensionless
µ1, µ2 viscosity of gas one or two at downhole
conditions, Pa-s
cρ average reservoir (coal) density, g/cm3
References
1. Mavor, M.J., Gunter, W.D., Robinson, J.R., Law, D., H-S,
and Gale, J.: “Testing for CO2 Sequestration and En-
hanced Methane Production from Coal,” paper SPE
75683, SPE Gas Tech. Sym., Calgary, Alberta, Canada
(April 3 - May 2, 2002).
2. Gash, B.W.: Voltz, R.F., Potter, G., and Corgan, J.M.:
“The Effects of Cleat Orientation and Confining Pressure
on Cleat Porosity, Permeability, and Relative Permeabil-
ity,” Paper 9321, Proceedings of the 1993 International
Coalbed Methane Symposium, Vol. 1, University of Ala-
bama/Tuscaloosa (May 17-21, 1993) pp. 247-255.
3. Agarwal, R.G., Al-Hussainy, R. and Ramey, H.J., Jr.: “An
Investigation of Wellbore Storage and Skin Effect in Un-
steady Liquid Flow: I. Analytical Treatment,” Society of
Petroleum Engineers Journal (Sept. 1970) pp. 279-290.
4. Kamal, M.M. and Six, J.L.: “Pressure Transient Testing
of Methane Producing Coalbeds,” paper SPE 19789, 64th
Annual Tech. Conference and Exhibition of the Society of
Pet. Eng., San Antonio, Texas (October 8-11, 1989).
5. Al-Hussainy, and H.J. Ramey, Jr.: “Application of Real
Gas Flow Theory to Well Testing and Deliverability
Forecasting,” Journal of Petroleum Technology, (May
1966) pp. 637-642.
6. Fokker, P.A. and van der Meer, L.G.H.: “The Injectivity
of Coalbed CO2 Injection Wells,” Gale, J. and Kaya, Y.
(eds): Proceedings of the 6th
International Conference on
Greenhouse Gas Control Technologies, Vol. I, Elsevier
Science, Ltd. Oxford, UK (2003) pp. 551-556.
7. Satman, A.: “Pressure Transient Analysis of a Composite
Naturally Fractured Reservoir,” paper SPE 18587, Society
of Petroleum Engineers (1991).
8. Mavor, M.J.: “Coalbed Methane Reservoir Properties” in
A Guide to Coalbed Methane Reservoir Engineering, Gas
Research Institute Report GRI-94/0397, Chicago, Illinois
(March 1996).
9. Mavor, M.J. and Nelson, C.R.: Coalbed Reservoir Gas-
In-Place Analysis, Gas Research Institute Report No.
GRI-97/0263, Chicago, Illinois (October 1997).
9. SPE 90256 9
10. Puri, R., Voltz, R., and Duhrkopf, D.: “A Micro-Pilot
Approach to Coalbed Methane Reservoir Assessment,”
Paper 9556, Intergas ’95 Proceedings, University of Ala-
bama / Tuscaloosa, Tuscaloosa, Alabama (May 15-19,
1995) pp. 265-274.
11. Mavor, M.J. and Gunter, W.D.: “Secondary Porosity and
Permeability of Coal vs. Gas Composition and Pressure,”
SPE 90255, SPE Annual Tech. Conf., Houston, TX (Sept.
26-29, 2004).
12. Huber, M.L.: NIST Thermophysical Properties of Hydro-
carbon Mixtures Database – SUPERTRAPP, Version 3.0,
Users’ Guide, National Institute of Standards and Tech-
nology, Gaithersburg, MD (September 1999).
13. Gunter, W.D., Mavor, M.J., and Law, D.H-S: Process for
Recovering Methane and/or Sequestering Fluids, United
States Patent 6,412,559 (July 2, 2002).
14. Yang, R.T.: Gas Separation by Adsorption Processes,
Imperial College Press, London, (1997) pp. 49-51.
15. Lake, L.W.: Enhanced Oil Recovery, Prentice Hall, New
Jersey (1989) p. 191.
Table 1. FBV 4A Properties Before CO2 Injection Table 2. FBV 4A CO2 Falloff Period Properties
Property Units Value Shut-In
Period
Shut-in
Duration
Effective
Perm. to
Gas
Skin
Factor
Apparent
Frac.
Length
Original pressure (12/17/92) kPa 7,901 hours md -- m
Average pressure (7/2/98) kPa 7,653-7,770 Pre-Injection- 0.53 1.8 -
Pressure gradient to surface kPa/m 6.11 1 41.37 0.40 -3.6 6.0
Pressure depth below ground m 1,252.54 2 42.19 0.50 -4.2 11.0
Absolute permeability md 3.65 3 42.89 0.50 -4.2 11.0
Near-well gas saturation % 40 4 42.97 0.40 -4.2 11.0
Near-well water saturation % 60 5 44.31 0.55 -4.3 12.1
Effective permeability to gas md 0.529 6 40.26 0.51 -4.3 12.1
Effective permeability to water md 0.157 7 42.31 0.52 -4.3 12.1
Relative permeability to gas - 0.145 8 42.42 0.40 -4.7 18.1
Relative permeability to water - 0.157 9 41.08 0.41 -4.7 18.1
Skin factor - 1.8 10 42.75 0.30 -5.1 27.0
Wellbore storage coefficient m
3
/kPa 8.6(10
-5
) 11 44.34 0.30 -5.4 36.4
Radius of investigation m 63 12 145.55 0.24 -5.3 31.4
10. 10 SPE 90256
Table 3. FBV 5 Upper Medicine River Coal Properties
Property Units Value Units Value
Geometry
Upper Medicine River Coal Top Depth meters 1,257.5 feet 4,125.7
Upper Medicine River Coal Bottom Depth meters 1,262.0 feet 4,140.4
Upper Medicine River Coal Thickness meters 3.97 feet 13.0
Reservoir Temperature, Pressure, Permeability, and Saturations
Average Temperature
o
C. 47.2
o
F. 117
Average Pressure kPa(a) 7,901 psia 1,146
Effective Permeability to Water µm
2
7.43(10
-4
) md 0.753
Effective Permeability to Gas µm
2
1.9(10
-5
) md 0.019
Absolute Permeability µm
2
1.16(10
-4
) md 1.18
Water Saturation % 90.9 % 90.9
Gas Saturation % 9.1 % 9.1
Coal Properties
Average In-Situ Moisture Content wt. % 6.72 wt. % 6.72
Average In-Situ Ash Content (moist) wt. % 15.6 wt. % 15.6
Average In-Situ Density (moist with ash) g/cm
3
1.434 g/cm
3
1.434
Average Sulfur Content (moist) wt. % 2.99 wt. % 2.99
Organic Fraction Density (dry) g/cm
3
1.328 g/cm
3
1.328
Inorganic Fraction Density (dry) g/cm
3
3.081 g/cm
3
3.081
ASTM Coal Rank Classification - hvBb - hvBb
Calorific Value (moist, mineral-matter-free) MJ/kg 30.5 BTU/lbm 13,100
Vitrinite Reflectance % 0.51 % 0.51
Vitrinite Content (mineral-matter-free) vol. % 62.8 vol. % 62.8
Inertinite Content (mineral-matter-free) vol. % 35.8 vol. % 35.8
Liptinite Content (mineral-matter-free) vol. % 1.4 vol. % 1.4
Gas Content, Composition, and Sorption Time
In-Situ Sorbed Gas Content (moist with ash) scc/g 7.57 scf/ton 243
In-Situ Gas Storage Capacity (moist with ash) scc/g 7.57 scf/ton 243
In-Situ Gas-in-Place/Area Mm
3
/km
2
43.1 Bscf/mi
2
3.94
Free Gas Methane Concentration mole % 94.42 mole % 94.42
Free Gas Ethane Concentration mole % 1.53 mole % 1.53
Free Gas Propane+ Concentration mole % 0.29 mole % 0.29
Free Gas Nitrogen Concentration mole % 3.46 mole % 3.46
Free Gas Carbon Dioxide Concentration mole % 0.26 mole % 0.26
Coal Sorption Time hours 4.93 hours 4.93
11. SPE 90256 11
Table 4. Upper Medicine River Sorption Properties
Property Units Value Units Value
DAF Methane Langmuir Storage Capacity scc/g 15.14 scf/ton 485.0
Methane Langmuir Pressure kPa(a) 4,688.5 psia 680.0
DAF Ethane Langmuir Storage Capacity scc/g 14.15 scf/ton 453.2
Ethane Langmuir Pressure kPa(a) 1,496.9 psia 217.1
DAF Argon Langmuir Storage Capacity scc/g 18.53 scf/ton 593.6
Argon Langmuir Pressure kPa(a) 9,673.4 psia 1,401
DAF CO2 Langmuir Storage Capacity scc/g 31.02 scf/ton 993.8
CO2 Langmuir Pressure kPa(a) 1,903.0 psia 276.0
DAF Nitrogen Storage Capacity scc/g 15.01 scf/ton 480.9
Nitrogen Langmuir Pressure kPa(a) 27,241 psia 3,951
DAF H2S Storage Capacity scc/g 37.82 scf/ton 1,211
H2S Langmuir Pressure kPa(a) 190.0 psia 27.55
DAF H2 Storage Capacity scc/g 1.03 scf/ton 33.0
H2 Langmuir Pressure kPa(a) 410 psia 59.46
DAF: dry, ash-free - scc: cm
3
at standard conditions of 101.3 kPa(a) and 15.56
o
C
Table 5. Gas Properties at Injection Conditions
Fluid Viscosity Formation Volume
Factor
z Factor CO2/Fluid Injectiv-
ity Ratio
cp res. vol./surf. vol. - -
CO2 0.06114 0.02770 0.3370 1.00
N2 0.02273 0.08135 1.0481 1.16
13%CO2-87%N2 0.02315 0.07864 1.0086 1.13
50%CO2-50% N2 0.02447 0.06740 0.8509 1.01
CH4 0.01644 0.06930 0.8764 0.70
Figure 1. FBV 4A Permeability Estimates Figure 2. Upper Medicine River Coal Isotherm Data